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المتحسس الكهروكيميائي المعتمد على الاقطاب المطورة Electro Chemical Sensor Based on Modified Electrodes

اسم المؤلف: مثنى سعيد علي كريم
اسم المشرف: سهام توفيق امين عبد الرحمن خضيرعبد الحسين الطائي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء العضوية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: الدراسة تتضمن ثلاثة خطوات : - الخطوة الاولى : _ تحضير قواعد شيف (H1 - H15) التي تحتوي على موقع بارامع رسم المجموعات تحتوي على التحضيرات على التوالي في وسط متعادل خلال التفاعل بين مركبات الامينات الاروماتية ومعوضات البنزلديهايد في الايثانول المطلق. الخطوة | First step Schiff bases [H1 - 15] containing Para donating and with drawing groups have been prepared respectively in a neutral medium, through the reaction between aromatic amines compounds and substituted enz aldehyde in absolute ethanol. Second steppreparation of some of heterocyclic compounds include 3 - chloro - 2 - oxo - zetidine - 2 - one (H16 - 30) through its rection with chloro acetyl chloride in presence of tri ethyl amine in 1,4 - Dioxan and2 - (substituted aryl)thiozoldin - 4 - one (H31 - 40) is prepared from the reaction of thioglycolic acid with Schiff bases in presence of zinc chloride in dry Benzene and2 - (sub.aryl) - 5,7 - di - one oxazipene (H41 - 50) are synthesized by cyclization of Schiff bases using malic anhydride in methanol.Third stepthis part of the research included the preparation of compounds similar to chalcones which are the phenyl propene amide derivatives by the condensation of acetanilide and substituted acetanilide with substituted benzadehydes The phenyl propene amide derivatives were reacted with hydrazaid(iso nazaid) is preparation of Pyrazoline compounds (H56 - 60) are synthesized from the reaction of chalcons (H50 - 55).The structures of the synthesized compounds were supported by means of (FTIR), (UV - Vis), (1H - NMR) and the results are agreement with the proposed structures assigned to the synthesized compounds. Study of the biological activity for prepared compounds The study also includes the biological activity for some of the prepared compounds against four kinds of germs which known by its resistance against antibiotics, these are the compounds (H18,H31,H35,H41,H42,H53,H5) are tested on four types of germs which cause illness and resist the antibiotic agents and these germs( Bacillus submits, E - coli, salmonella, Enter course)and study the biological activity for some of the activity using different concentration and different type of fungous The results showed prominent activity against these bacteria, the detailed antibacterial screening are reported in Table (15) and the Inhibition of the fungus screening are reported in Table (16).

التقدير الطيفي للترايفلوبيرازين والكلوربرومازين في المستحضرات الصيدلانية باستخدام تفاعلات الاكسدة Spectrophotometric Determination of Trifluoperazine Hydrochloride And Chlorpromazine Hydrochloride in Pharmaceutical Formulation By Oxidation Reactions

اسم المؤلف: عمر عدنان هاشم شريف ال ابليش
اسم المشرف: علي ابراهيم خليل الجبوري محسن حمزة بكر
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: This study contained ageneral introduction about the Ion - Selective electrodes and ageneral introduction about Schiff's Base and the determination of Diphenhydramine Hydrochloride (DPH) and Phenylephrine Hydrochloride (PEH) and Metoclopramide Hydrochloride (METO) and Metformin Hydrochloride (METF ) drugs using new methods applying potentiometric (the first part) and using Schiff's Base as ionophor In ISES membranes ( the second part).The first part includes construction of membrane selective electrodes for DPH and PEH drugs based on complexation of drugs with Ammonium Reinckate (AR) and Phospho Molybdic acid (PMA) as an active substance using Di - n - Butyl phthalate (DBPH) as a plasticizers , poly vinyl chloride was used as a matrix for all electrodes.The Characters of each electrode were as follow : 1. For the Diphenhydramine - Ammonium Reinckate (DP - AR) electrode using (DBPH) as a plasticizers, the optimum condition were (4.5 - 6.5), (20 - 30?C), 10 - 2 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29.40) mv/decade, correlation coefficient r= 0.9971, detection limit (8.88x10 - 7 M) and life time of the electrode was 34 days.2. For the Diphenhydramine - Phospho Molybdic acid (DP - PMA) electrode using (DBPH) as a plasticizers, the optimum condition were (4.5 - 6.5), (20 - 30 ?C), 10 - 4 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29. 90) mv/decade, correlation coefficient r= 0.9960, detection limit (6.8x10 - 8 M )and life time of the electrode was 40 days.3. For the Phenylephrine - Ammonium Reinckate (PE - AR) electrode using (DBPH) as a plasticizers, the optimum condition were (5 - 6), (25 - 30 ?C), 10 - 3 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29.8) mv/decade, correlation coefficient r= 0.9990, detection limit (2.22x10 - 7 M) and life time of the electrode was 24 days.4. For the Phenylephrine - Phospho Molybdic acid (PE - PMA) electrode using (DBPH) as a plasticizers, the optimum condition were (5 - 6), (25 - 30 ?C), 10 - 3 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29.5mv\decade), correlation coefficient r= 0.9990, detection limit (4.87x10 - 7 M ) and life time of the electrode was 26 days.The second part includes the use of Schiff's Base as ionophor in ISES MembranesThe second part includes construction of membrane selective electrodes for METO and METF drugs based on complexation of drugs Schiff METO and Schiff METF as Ionophor with Phospho Molybdic acid (PMA) as an active substance using Nitro benzene (NB) and Di - n - Butyl phthalate (DBPH) as a plasticizers , poly vinyl chloride was used as a matrix for all electrodes.The Characters of each electrode were as follow : 1.For the Metoclopramide - Phospho Molybdic acid (Schiff’s METO - PMA) electrode using (NB) as a plasticizers, the optimum condition were (4 - 6), (20 - 35 ?C), 10 - 4 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (19.90) mv/decade, correlation coefficient r= 0.9970, detection limit (4.5x10 - 7 M) and life time of the electrode was 122 days.2.For the Metoclopramide - Phospho Molybdic acid (Schiff’s METO - PMA) electrode using (DBPH) as a plasticizers, the optimum condition were (4 - 6), (20 - 35 ?C), 10 - 4 M for pH , temperature and concentration of filling solution respectively. The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29. 70) mv/decade, correlation coefficient r= 0.9950, detection limit (3.83x10 - 7 M )and life time of the electrode was 108 days.3.For the Metformin - Phospho Molybdic acid (Schiff’s METF - PMA) electrode using (NB) as a plasticizers, the optimum condition were (5 - 6), (25 - 35 ?C), 10 - 4 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29. 30) mv/decade, correlation coefficient r= 0.9970, detection limit (3.87x10 - 7M )and life time of the electrode was 102 days.4.For the Metformin - Phospho Molybdic acid (Schiff’s METF - PMA) electrode using (DBPH) as a plasticizers, the optimum condition were (5 - 6), (25 - 35 ?C), 10 - 4 M for pH , temperature and concentration of filling solution respectively.The linear concentration range was from (10 - 5 - 10 - 1) M with a slope of (29. 10) mv/decade, correlation coefficient r= 0.9980, detection limit (2.37x10 - 7 M )and life time of the electrode was 90 days

دراسة مستوى انزيم الرينيين والفا - ل - فيوكوز وبعض المتغيرات الكيموحيوية للمرضى المصابين بالعجز الكلوي المزمن Level of Renin Enzyme, ? - L - Fucose And Some Biochemical Markers for Chronic Renal Failure Patients

اسم المؤلف: سروت بهرام عارف محمود الكاكةئي
اسم المشرف: صباح حسين خورشيد
الموضوع العام: علوم الكيمياء
السنة: 2013
الموضوع الدقيق: الكيمياء الحياتية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: خلفيه البحث : سوفان المفاصل هو مرض مزمن يؤدي الى حدوث تغيرات ضارة في الغضاريف والعظام والاربطة والعضلات , علما ان وصف المرض بشكل دقيق غير محدد لحد الان. والسؤال المطروح عن العلاقة بين العلامات الناتجة عن هذا المرض وتلك الناتجة عن مرض السكري, هل الام السك | خلفيه البحث : سوفان المفاصل هو مرض مزمن يؤدي الى حدوث تغيرات ضارة في الغضاريف والعظام والاربطة والعضلات , علما ان وصف المرض بشكل دقيق غير محدد لحد الان. والسؤال المطروح عن العلاقة بين العلامات الناتجة عن هذا المرض وتلك الناتجة عن مرض السكري, هل الام السكري تخفي الام المفاصل ؟ حيث ان كلا المرضين(السكري والمفاصل) هما من الامراض المزمنة وتتصف بمستويات غير واضحة من التغيرات البايولوجية للمريض.الهدف من البحث : صممت هذه الدراسة لايجاد العلاقة بين داء السكري وسوفان المفاصل من خلال دراسة بعض المتغيرات الحياتية المشتركة بين المرضين مثل الفسفاتين واللبتين وهرمون النمو المشابه للانسولين... , وايضا دراسة تاثير داء السكري على تطور سوفان المفاصل. العينات, المواد وطرائق العمل : تضمنت هذه الدراسة (88)عينة مرضية من النساء فقط تراوحت اعمارهم (40 - 60) سنه ,في بداية التشخيص لمرض سوفان المفاصل من المصابين وغير المصابين بداء السكري الذين يعانون من السمنه)وقد تم جمع العينات من مستشفى الكاظمية التعليمي والمركز الوطني لبحوث وعلاج السكري / مستشفى اليرموك,من شهر ايار - تشرين الاول(2013 ) وقد تم تقسيم عينات المرضى الى ثلاث مجاميع وهي( مجموعة سوفان المفاصل وعددهم 24)و(مجموعة داء السكري وعددهم 20عينه)و(المجموعة الحاملة كلا المرضين عددهم 24عينه) فضلا عن مجموعة السيطرة وعددهم (20عينه) وقد تم تقدير مستويات الدوال في امصال العينات من خلال اجراء الفحوصات المختبرية التالية : هرمون الفس?اتين, هرمون االلبتين, هرمون النمو الشبيه بالانسولين - 1,مستوى الانسولين الصائم , هرمون المناسل المحفز الجربي FSH والمحفز للجسم الاصفر LH , مؤشر معصد البلازما بوساطه العلاقة اللوغاريتمية المتمثلة بالكسر المولي للدهون الثلاثية والدهون عالية الكثافة وفحص مقاومه الانسولين,وفحص السكر الصائم, الدهون في الدم وخضاب الدم المعسل والتي تم قياسها لجميع المرضى وافراد مجموعة السيطرة.النتائج : كانت النتائج المستحصلة من هذه الدراسة كما يلي : ? اظهر المستوى االمصلي للفسفاتين واللبتين وكذلك قيم مؤشر معصد البلازما زياده معنويه في مجاميع المرضى الثلاث وهي (داء السكري , سوفان المفاصل والذين يعانون كلا المرضين) بمجموعه السيطرة بمستوى احتماليه p< 0.05)),في حين لوحظ انخفاض معنوي لدى المرضى الذين يعانون من كلا المرضين (السكري والسوفان) في حالة اخذ الدواء مقارنة بالمرضى بدون دواء تحت احتماليه p< 0.05)).? اظهر المستوى المصلي لهرمون النمو الشبيه بالانسولين انخفاض معنوي في مجاميع المرضى الثلاث وهي (داء السكري , سوفان المفاصل والذين يعانون كلا المرضين) بمجموعه السيطرة تحت احتماليه p< 0.05)), في حين لوحظت زيادة معنوية لدى المرضى الذين يعانون من كلا المرضين (السكري والسوفان) في حالة اخذ الدواء مقارنة بالمرضى بدون دواء تحت احتماليه p< 0.05)), ووجد ايضا ان عامل العمر له تاثير " كبير جدا على قيم مؤشر معصد البلازما ومستوى الفسفاتين ,اللبتين وهرمون النمو الشبيه بالانسولين.? اظهر انخفاض معنوي في مستوى نسبة LH/ FSH في مجاميع المرضى الثلاث وهي (داء السكري , سوفان المفاصل والذين يعانون كلا المرضين) بمجموعه السيطرة تحت احتماليه p< 0.05)), في حين وجدت زياده معنوية في مستوى نسبة LH/FSH في مجموعة المرضى اللذين يعانون من كلا المرضين مقارنة بمجموعة مرضى السكري ومجموعة سوفان المفاصل ولوحدها. ? مستوى الفسفاتين يرتبط ايجابيا مع قيم مؤشر معصد البلازما في مجموعة مرضى داء السكري والمجموعة اللذين يعانون كلا المرضين تحت احتماليه p< 0.01)),في حين لايوجد ارتباط بين مستوى الفسفاتين وقيم مؤشر معصد البلازما في مجموعة مرضى سوفان المفاصل ومجموعة السيطرة. ? اظهر مستوى هرمون النمو الشبيه بالانسولين ارتباطا سلبيا مع قيم مؤشر معصد البلازما عند مجاميع المرضى الثلاثة ( داء السكري , سوفان المفاصل وكلا المرضين) تحت احتماليه p< 0.01)), لكن لايوجد ارتباط مع مجموعة السيطرة. ? اظهر مستوى اللبتين ارتباطا ايجابيا مع قيم مؤشر معصد البلازما عند مجاميع المرضى الثلاث ( داء السكري , سوفان المفاصل وكلا المرضين) تحت احتماليه p< 0.01)), لكن لايوجد ارتباط مع مجموعة السيطرة.? وايضا وجد ارتباط سلبي بين مستوى الفسفاتين ومستوى اللبتين عند المجموعة الحاملة كلا المرضين داء السكري وسوفان المفاصل تحت احتماليه p< 0.01)),في حين كان هناك ارتباطا ايجابيا بين مستوى الفسفاتين ومستوى اللبتين عند مجموعة السكري ومجموعة سوفان المفاصل ولوحدها تحت احتماليه p< 0.01)), وقد وجد ايضا ارتباطا سلبيا بين مستوى الفسفاتين ومستوى هرمون النموالشبيه بالانسولين عند مجاميع المرضى الثلاث تحت احتماليه p< 0.01)) , ولايوجد ارتباط مع مجموعة السيطرة. ? اظهر ارتباطا ايجابيا بين مستوى نسبة LH/FSH وكل من مستوى الفسفاتين , اللبتين وهرمون النمو الشبيه بالانسولين عند مجاميع المرضى الثلاث تحت احتماليه p< 0.01)), لكن لايوجد ارتباط في مجموعة السيطرة. الاستنتاج : نستنتج ان سوفان المفاصل له تاثير مباشر على بعض المؤشرات الحياتية مثل مستويات هرموني اللبتين والفسفاتين واختلال الدهون وقيم مؤشر معصد البلازما. ومن اهم النتائج ان الفسفاتين مؤشر جيد لدراسة تطور المرض ومن الممكن استخدامه كوسيلة للعلاج وكذلك نستنتج ان السيطرة على مستويات السكر عند مرضى سوفان المفاصل مهم جدا خلال العلاج وبالاخص لو تطلب الامر اجراء عملية جراحية.

تحضير، تشخيص وتقييم بايولوجي لبعض الادوية المصاحبة المشتقة من بعض مضادات الالتهابات غير الستيرويدية Synthesis , Characterization And Biological Evaluation of Some Prodrugs Derived From Non - Steroidal Anti - Inflammatory Drugs (NSAIDs)

اسم المؤلف: مصطفى راجي عايد حمد
اسم المشرف: خالد مطني محمد الجنابي اياد سعدي حميد الدليمي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء الحياتية
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: اجري هذا البحث لايجاد العلاقة بين العجز الكلوي المزمن ومستويات بعض المتغيرات الكيموحيوية عن طريق قياس مستوى انزيم الرينيين والفيوكوز الكلي (TF), الفيوكوز المرتبط بالبروتين (PBF) , البروتين المرتبطة بالسكريات السداسية (PBHex) وعدد من المتغيرات الكيموحيوية | This study has been done to determine the relationship between chronic renal failure and the level of some biochemical parameters (Rennin enzyme, Total Fucose(TF), Protein bound Fucose(PBF), protein bound Hexose (PBHex), and some other biochemical parameters including glucose , Urea, createnine, Uric acid, High density lipoproteins Cholestrol(HDL - c.), low density lipoproteins Cholestrol (LDL - c.) and electrolytes (Na+, K+ and Ca+2). Case study included (80) patients with chronic renal failure,Who admitted to the Kirkuk General Hospital Department of Dialysis , there ages were (31 - 60 years) of both sexes , patients has been divided into subgroups according to age {(31 - 35),(36 - 40),(41 - 45),(46 - 50),(51 - 550),(56 - 60)}year and severity compared with (45) normal persons as control with same ages, the results was as follows : Results showed a significant increase (P?0.01) in the level of rennin enzyme (5.013±0.052 ng/mL.h) of patients before dialysis compared with control group (2.58±0.32 ng/mL.h) for different age groups, and there was a significant increase slightly for different age groups.There was a significant increase (P?0.01) in the level of TF and PBF (12.14±0.89 mg/dL),(7.450±0.18 mg/dL) respectively compared with control group (28.76±0.03 mg/dL), (2.26±0.27 mg/dL) respectively for different age groups, and there was no significant correlation between age groups or sex.There was significant decrease (P?0.01) in the level of protein bound hexose PBHex, (123.35±0.9 mg/dL) compared with control group (89.76±0.9 mg/dl) for different age groups, and there was no significant correlation between age groups or sex.There was a significant increase (P?0.01) in the level of glucose (5.072±0.13 mmol/L) compared with control group (7.03±0.46 mmol/L) for different age groups, and there was a significant increase for females (7.40±0.7 mmol/L) compared with males (6.84±0.4 mmol/L).There was a significant increase (P?0.01) in the level of urea, uric acid and createnine, (5.66±0.24 mmol/L) , (336.5±1.4 mmol/L) , (90.8±1.3 mmol/L) respectively when compared with control group (34.27±0.9mmol/L) ,(516±1.8 mmol/L), (866±1.9 mmol/L) respectively for different age groups, and there was significant increase for males compared with females.There was a significant increase (P?0.01) in K+ level (5.896±0.05mmol/L) compared with control group (4.253±0.12mmol/L) and there was no significant correlation for males compared with females.There was a significant decrease (P?0.01) in Na+, Ca+2 level, (2.317±0.044 mmol/L), (144.35±1.6mmol/L) respectively compared with control group (1.89±0.046 mmol/L) , (121.00±1.1mmol/L) respectively and there was no significant correlation for different age groups or males and females, while there was a a significant correlation for male (1.979±1.1mmol/L) compared with female (1.768±0.073mmol/L).Result showed a significant decrease in HDL_c in the serum of patients before dialysis (1.263±0.027 mmol/L) compared with control (0.701±0.014 mmol/L) and there was a significant increase in HDL - c for female group compared with male group.There was significant increase in LDL_c in the serum of patients before dialysis (2.946±0.019mmol/L) compared with control (5.1±0.68mmol/L) and there was a significant increase in LDL - c for female (6.30±1.3 mmol/L) compared with male group(5.076±0.023mmol/L).

تحضير وتشخيص بعض مشتقات السكارين العضوية ومعقدات السكارين ومشتقاته الفوسفينية مع بعض الفلزات Synthesis And Characterization Some of Organic Saccharin Derivatives And Metal Complexes of Saccharin And Its Phosphine Derrivative

اسم المؤلف: عفراء صابر شهاب الزوبعي
اسم المشرف: احمد عبد الحسن احمد الكاظمي صبحي عطية محمود الجبوري
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء العضوية
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمن البحث تحضير عدد من الادوية المصاحبة المشتقة من مضادات التهاب غير ستيرويدية تم الحصول عليها من معمل ادوية سامراء هي الايبوبروفين، الاندوميثاسين، النابروكسين، الاسبرين، الكابتوبريل والايزونوزايد. عملية تحوير ال | In this study, a number of prodrugs have been synthesized starting from Non - steroidal anti inflammatory drugs such as Ibuprofen, Indomethacin, Naproxen, Aspirin, Captopril and Isoniazid. The modification process started from the conversion of carboxyl group which is existing in these drugs (except in Isoniazid) into esters, chlorides and acid hydrazide.The drugs have been linked to each other and to itself via amide linkage through the reaction of their acid chlorides and acid hydrazides to afford 1,2 - diacyl hydrazine derivatives(M17 - M27). Some acid hydrazides have been treated with isophthaloyl chloride to Benzene - 1,3 - dicarbo hydrazide - 1,3 - Bis substituent(M28 - M30). The same hydrazides have been treated with Benzen - 1,3,5 - tri carbonyl tri chloride to afford Benzen - 1,3,5 - tricarbhydrazide - 1,3 - Tris substituent (M31 - M33). Compounds M28 and M29 have been treated with POCl3 to afford Bis - substituent - 5 - phenyl - 1,3,4 - Oxadizole(M34 - M35). Another modification onto drugs has been done through the linking of these drugs with quinazoline nucleus through amide linkage to afford N - (4 - oxo - 2 - phenylquinazolin - 3(4H) - yl)amide - substit derivatives (M38 - M42). Another modification has been carried out through the reaction of hydrazides with Aromatic aldehydes to afford the mono hydrazide - hydrazones derivatives or Schiff's bases (M43 - M65) and di hydrazide - hydrazones derivatives in which two moles from hydrazide have been treated with one mole of dialdehyde(M66 - M73). In addition, new hydrazones have been synthesized through the reaction of hydrazides with Isatin nucleus which is well known as biological active center to afford the compounds (M74 - M77) with good biological activity. Benzodiazepines have been obtained through the reaction of Isoniazid hydrazones with glycene phthalimide and p - aminobenzoic acid(M82 - M92). Indomethacin hydrazones have been treated with acetic anhydride to afford 1 - [2 - (substituent) - 5 - (5 - methoxy - 2 - methyl - 1H - indol - 3 - ylmethyl) - [1,3,4]oxadiazol - 3 - yl] - ethanone derivatives (93 - M97). The Derivatives of 5 - substit - 2 - Mercapto - 1,3,4 - Oxadiazole(M98 - M103) have been obtained through the reaction of the drug hydrazides with CS2 in the presence of KOH. The oxadizoles have been treated with hydrazine hydrate to afford 4 - amino - 5 - sub - 4H - 1,2,4 - triazole - 3 - thiol derivatives for the Non - steroidal anti - inflammatory drugs(M104 - M107). In addition, 5 - sub - 1,3,4 - Oxadiazole - 2 - amine derivatives have been obtained through the reaction of drug hydrazides with BrCN(M108 - M111). The compound 5 - {1 - [4 - (2 - methylpropyl)phenyl]ethyl} - N3 - phenyl - 4H - 1,2,4 - triazole - 3,4 - diamine (M113) has been synthesized through the reaction of the compound 2 - {2 - [4 - (2 - methylpropyl)phenyl]propanoyl} - N - phenylhydrazinecarbothioamide (M112) with hydrazine hydrate. The ester compound 2 - hydroxyphenyl 2 - [4 - (2 - methylpropyl)phenyl]propanoate (M114) have been obtained through the reaction of Ibuprofen chloride with salicylic acid. The two compounds, 2 - (4 - Isobutyl - phenyl) - propionic acid [1 - (4 - methyl - piperazin - 1 - ylmethyl) - 2 - oxo - 1,2 - dihydro - indol - 3 - ylidene] - hydrazide (M115) and 2 - (4 - Isobutyl - phenyl) - propionic acid [5 - fluoro - 1 - (4 - methyl - piperazin - 1 - ylmethyl) - 2 - oxo - 1,2 - dihydro - indol - 3 - ylidene] - hydrazide (M116) have been obtained through the reaction of M74, M77 with excess of formaldehyde and equimolar of N - methyl piperazine.The synthesized compounds have been identified using Infra - red spectroscopy FTIR, Nuclear Magnetic resonance (1H,13C), Mass spectroscopy and X - Ray. In addition , the changes in physical properties such as melting points, boiling points and color have been considered. Finally, the biological activity of some synthesized compounds has been evaluated and some of them have shown good biological activity especially those containing Isatin nucleus (M74 - M77) and (M115 - M116).

تحضيروتشخيص بعض المشتقات الجديدة لثنائي هيدروبريميدينون باستخدام تفاعل بكينيلي ودراسة فعاليتها البايلوجية Synthesis And Characterization And Biological Activity Study of Some New Dihydropyrimidinones Derivatives Via Application Biginelli Reaction

اسم المؤلف: احمد ماهر فهيم
اسم المشرف: نبيل عبد عبد الرضا
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: The present work involved synthesis of new indole derivatives containing other heterocyclic ring. These derivatives could be divided into the following parts : 1. The first part involved synthesis and characterization of novel 1,3 - diazidine[XIII]a - d and [XIV]a - d by the following steps : Scheme(1).a. Synthesis of 3 - [(5 - hydrazinyl - 4 - phenyl - 1,2,4 - triazol - 3 - yl)methyl] - 1H - indole [VI], this compound is synthesized by neucleophilic substitution reaction of 1,2,4 - triazole - 5 - thiol compound [V]a with excess of hydrazine hydrate in absolute ethanol as a solvent.b. Synthesis of 2 - {5 - [(1H - indol - 3 - yl) - propyl] - 4 - phenyl - 1,2,4 - triazol - 3 - yl} - thio - acetohydrazide[VIII]b, by the reaction of ester compounds[VII]b with excess of 80% hydrazine hydrate in ethanol under reflux.c. Synthesis of new Schiff bases[IX]a - d and [X]a - d by condensation reaction of primary amino compounds[VI] or [VIII]b with different aromatic aldehyde in absolute ethanol as a solvent.d. Synthesis of new N - acyl derivatives[XI]a - d and [XII]a - d by reaction of acetyl chloride with the synthesized Schiff bases[IX]a - d, [X] a - d in dry benzene.e. Synthesis of 1, 3 - diazetine derivatives[XIII]a - d and [XIV]a - d by addition reaction of compound[XI]a - d or [XII]a - d with sodium azide in dimethylformamid as a solvent at (55 - 60)0C temperature.2 - While the second part involved synthesis and characterization of novel thiazolidine - 4 - one compounds[XXI]a - d and [XXII]a - d by the following steps : Scheme(2).a. Synthesis of 2 - [5 - (2 - methyl - 1H - indol - 3 - yl) - 4H - 1,2,4 - triazol - yl] - thio - ethyl hydrazide[XVIII] by the reaction of ester compound[XVII] with excess of 80% hydrazine hydrate in ethanol under reflux.b. Synthesis of 2 - {5 - [(1H - indol - 3 - yl) - methylene] - 4 - phenyl - 1,2,4 - triazol - 3 - yl} - IXthio - ethylhydrazide[XVIII], by the reaction of ester compounds[XVII] with excess of hydrazine hydrate in ethanol under reflux. Also synthesize new Schiff bases [XIX]a - d and [XX]a - d by condensation reaction of acid hydrazide compounds [VIII]a or [XVIII] with different aromatic aldehyde in absolute ethanol as a solvent.c. Synthesis of new thiazolidine - 4 - one derivatives, [XXI]a - d and [XXII]a - d by refluxing equimolar amounts from Schiff bases[XIX]a - d and [XX]a - d with excess of thioglycolic acid in dry benzene.3. The third part involved synthesis and characterization of new series of thiazolidine - 4 - one [XXVII]a - c and [XXVIII]a - c by many steps reaction as follows : Scheme(3).a. Synthesis of new Schiff [XXIII]a,b, [XXIV]a,b by condensation reaction of acid hydrazide [III]a,b with two types of aromatic aldehyde in absolute ethanol.b. Synthesis of another type from thiazolidine - 4 - one derivatives [XXV]a, b and [XXVI]a, b from the reaction of Schiff bases [XXIII]a,b, [XXIV] a,b with excess of thioglycolic acid in dry benzene. The alkoxy derivatives of compounds [XXVII] and [XXVIII]; 2 - (4 - N - alkoxyphenyl) - 3 - (2 - methyl - 1H - indol - 3 - yl)amido - 1,3 - thiazolidine - 4 - one[XXVII]a - c and 2 - (4 - N - alkoxyphenyl) - 3 - (1H - indol - 3 - yl) acetamido - 1,3 - thiazolidine - 4 - one [XXVIII]a - c were synthesized by the reaction of terminal OH group of compound[XXV]a or [XXVI]a with different n - alkyl bromide in alkaline media.4 - The fourth part involved synthesis and characterization of amide derivatives of 1,3,4 - thiadiazole[XXXI]a - d, [XXXII]a - d and [XXXIII]a - d by the following steps : Scheme(4)a. Preparation of 2 - amino - 5 - (2 - methyl - 1H - indol - 3 - yl) - 1,3,4 - thiadiazole[XXIX] by cyclization reaction of 2 - (2 - methyl - 1H - indole - 3 - carbonyl) hydrazine carbo - thio amide [XV] in conc. H2SO4 under reflux followed by neutralized with liquid ammonia. While 2 - amino - 5 - [(1H - indol - 3 - yl)methyl] - 1,3,4 - thiadiazole[XXX]aand 2 - amino - 5 - [(1H - indol - 3 - yl)propyl] - 1,3,4 - thiadiazole[XXX]b synthesized by cyclization reaction under reflux of indole - 3 - acetic acid or indole - 3 - butric acid with thiosemicarbazide in the presence of phosphorous oxychloride.b. Synthesis of new amide derived from 2 - amino - 1,3,4 - thiadiazole [XXXI]a - d, [XXXII]a - d and [XXXIII]a - d from the reaction equimolar of suitable 2 - amino - 1,3,4 - thiadiazoles[XXIX] and [XXX]a,b with different acid chlorides in DMF and pyridine as accepter.5. The fifth part involved synthesis and characterization of new hydrazones [XXXVII]a - d and [XXXVIII]a - d. These compounds were synthesized according to the follows steps : Scheme(5)a. Synthesis and characterization of 1 - (2 - methyl - 1H - indole - 3 - yl) carbonyl - 3 - methyl - pyrazol - 5(4H) - one[XXXIV] and 1 - [(1H - indol - 3 - yl) ethanoyl or butanoyl] - 3 - methyl - pyrazol - 5(4H) - one [XXXV]a, b by heating under reflux a solution of equimolar from acid hydrazides[III]a - c with ethylacetoacetate in absolute ethanol.b. Synthesis and characterization of 1 - [4 - acetyl - (1H - indol - 3 - yl)ethanoyl or butanoyl] - 3 - methyl - pyrazol - 5 - one [XXXVI]a, b through reaction of pyrazolone derivatives[XXXV]a,b with acetyl chloride in 1,4 - dioxane in presence of calcium hydroxide.c. Synthesis and characterization of novel hydrazones [XXXVII]a - d and [XXXVIII]a - d by the reaction of 4 - acetyl - pyrazolone compounds[XXXVI]a, b with phenyl hydrazine or substituted phenyl hydrazine in ethanol.The synthesized compounds have been characterized by their melting points, elemental analysis (C.H.N) and by their spectral data, FTIR, 1HNMR and Mass spectroscopy (of some of theme).Study of the biological activity of some of the synthesized compounds against Gram - positive bacteria (Staphylococcus aureus) and Gram - negative bacteria (Escherichia coli). The results showed that most of the tested

دراسة الخواص الميكانيكية لخلائط المطاط الطبيعي باستخدام انواع مختلفة من البوليمرات والمالئات Study of Mechanical Properties For Natural Rubber Blends Using Different Types of Polymers And Fillers

اسم المؤلف: قصي خزعل موجر
اسم المشرف: محمد علي مطر
الموضوع العام: علوم الكيمياء
السنة: 2005
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: تم تحضير مركبات نانو مغناطيسية جديدة باستخدام الكوليستيرول والسلفادايزين مع اوكسيد الحديد المغناطيسي. حضرت هذه المركبات باستعمال طريقة الترسيب المشترك لاوكسيدي الحديد الثنائي والثلاثي ومن ثم ربطه بالحامض بطريقة فوق الاشباع. تم تشخيص المركبات المحضرة بالطر | Two new magnetic nanoparticles (MNPs) were prepared using magnetic iron oxides with cholesterol and sulfadiazine. These compounds were prepared by iron oxide (II and III) co - precipitation, and then the prepared MNP were incubated with cholesterol and sulfadiazine. The synthesized compounds were identified using multiple techniques, including transmission electron microscopy, scanning electron microscopy, diffractive light scattering, and thermogravimetric analysis. Results demonstrated the formation of new magnetic nanoparticles, namely, MNP@Cholesterol and MNP@Sulfadiazine. The interaction between the prepared MNPs and xanthine oxidase (XO) was evaluated as a potential method for the inhibition of the enzymatic activity. The inhibition of XO is an important issue to reduce the formation of uric acid, which is responsible for gout and kidney stone formation. Another potential application is the extraction of the XO enzyme from biological fluids, such as blood, or the immobilization of XO on the surfaces of MNPs as a new application of these insoluble particles.The interaction studies involved the incubation of XO solution with the suspension of prepared MNPs using XO solutions with different concentration and fixed MNP mass. The adsorption studies of XO on MNPs showed that the prepared MNPS can extract suitable amounts of XO from a solution. Slight differences in the XO quantities adsorbed on different MNPs were found. Adsorption isotherms followed the Sips equation, indicating slight heterogeneity in the adsorption active forces on MNPs. Circular dichroism study of the XO adsorption on the prepared MNPs showed significant changes in the secondary structures, namely, reduction of the ? - helix structure. Furthermore, fluorospectrophotometric studies showed changes in the tertiary structure of the XO caused by the interaction with the active sites of the prepared MNPs. The study of the inhibition of XO activity by the prepared MNPs showed mixed inhibition as a result of the changes in the original XO enzyme after interaction with the surfaces. Magnetic Fe3O4 showed the highest inhibition activity, followed by MNP@Sulfadiazine and MNP@Choleterol - XO.

التحضير والتشخيص الطيفي ودراسة الفعالية البايولوجية لليكاندي البنزاميدازوليل ازو غير متجانسي الحلقة الجديدين وبعض من معقداتهما الفلزية Synthesis, Spectral Characterization And Biological Activity Study For New Heterocyclic Benzimidazolyl Azo Ligands And Their Metal Complexes

اسم المؤلف: بان عدنان حاتم
اسم المشرف: خالد جواد العادلي
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: نتيجة للتقدم العلمي الحاصل في مجال صناعة البوليمرات ظهرت الحاجة الى مواد بوليميرية بمواصفات معينة لا يمكن الحصول عليها من نوع واحد من البوليمرات , لذا كانت هناك محاولات لمزج نوعين او اكثر من البوليمرات للحصول على مزيج بوليميري بمواصفات صناعية مرغوب فيها و| As a result of scientific progress made in the field of polymer industry emerged the need for materials polymers with certain features has emerged can not be obtained from one type of polymers, so there have been attempts to blend two or more polymers for combination Self - leveling industrial specifications undesirable and the formation of a physical blends has the common characteristics of basic materials, and this depends on the type of polymers and blending mode. This study included the preparation Ajanta blends of natural rubber with thermoplastics, as follows : 1. Prepare Ajnat of natural rubber by (100phr) has been reinforced and the usual filers used black carbon types (HAFN330, ISAFN220, SAFN110) and adopted ratios (60,50,40,30,20,10 phr), and the results show that the increase in the content of black carbon leads to an increase in the mechanical properties (tensile strength, elastic modulus, hardness) and a decrease in (elongation at break and compressibility), and that the best ratio add was when (50phr) of all kinds of black carbon the study found that the best values of the properties of the species used from black carbon at (50phr) of type (SAFN110).2. Prepare Ajnat of natural rubber by (100phr) has been reinforced and enhanced using filer Nano (black carbon Nano, titanium dioxide Nano) rates (6,5,4,3,2,1 phr) and found that the increase during the study nano filers content leads to an increase in the mechanical properties (tensile strength, elastic modulus, hardness) and a decrease in the elongation at break and compressibility add that the best ratio was (5phr) of all kinds nano filers used. .3. Prepare Ajnat blends of natural rubber with thermoplastics (PP, PE, PS, PVC) adopted the blending ratios (55 / 45,70 / 30,85 / 15 phr), and the study found that an increase in plastics content leads to an increase in the hardness and low in compressibility, has been shown that the best mechanical properties (tensile strength, elastic modulus, elongation, and hardness, and compressibility) was when the proportion of blending (85phr) of natural rubber with (phr 15) of (PP, PS, PVC) and the proportion of blending (70phr) of natural rubber with (30phr) of (PE).4. The results of chemical analysis tests showed that blends prepared characterized by good resistance to chemical solutions (acids and bases) and a decrease in the degree of intumescent greater thermoplastics content ratio of(15phr) to (45phr) Ajnat in combination.5. The results show that the natural rubber blends with polyethylene showed chemical properties and good resistance to chemical solutions best compared with the plastics used in the preparation Ajnat.6. Determine compatibility blends by using technology (DSC) for blends prepared.

تحضير وتشخيص ليكاندات ازو جديدة غير متجانسة الحلقة مشتقة من 5,4 - ثنائي فنيل اميدازول ومعقداتها مع بعض الايونات الفلزية Synthesis And Characterization of New Heterocyclic Ligands Based On 4,5 - Diphenyl Imidazole And Their Complexes With Some of Metal Ions

اسم المؤلف: اسراء نور كاظم وتوت
اسم المشرف: حسين عبد محمد صالح
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: تضمن العمل تحضير ليكاندين جديدين من ليكاندات الازو العضويه غير المتجانسه المشتقة من البنزامبدازول الاول هو اليكاند 2'] - 2 - (بنزايميدازوليل) ازو [ - 6,4 - ثنائي كلورو فينول Benzimidazolyl) Azo] - 4,6 - dichloro phenol (BIADClP)) 2 - [2' - والليكاند الثا | This study deals with the preparation of two new ligands from the heterogeneous organic azo ligands drived from Benzimidazol.The first) 2 - [6 - Benzimidazolyl) Azo] - 2,4 - dichloro phenol (BIADClP). The second is 2 - [6 - (benzimidazolylazo)] - 2,4 - dibromo phenol(BIADBrP).The heterogeneous chain in both ligands includes two nitrogen atoms. These two ligands have been identification by the proton nuclear magnetic resonance spectra (1H - NNMR) ,the mass spectrum, infrared, visibale ultraviolet as well as the analysis of the micro - elements (C.H.N).And two new series of the solid canine complexes for these ligands. The first series includes six solid complexes of the ligand (BIADClP) with the metallic ions Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II). The second series includes the preparation of six solid complexes of the ligand (BIADBrP) with the metallic ions mentioned above. The effect of the solvent and the complexes stsbility have been studied on the prepared ligands with the passage of time starting from the moment of the metallic ion solution reaction with the ligand solution and up to 170 minutes. Also, the stability constants for these complexes have been calculated spectrally by visbale - ultraviolet spectra.All results show that these complexes have high stability. The infrared spectra of the prepared complexes have been studied and when compared with the free ligand spedtra give obvious changes as these spectra show new bands not already found in the spectra of both ligands and this is due to the occurance of the correlation between the metallic ions under study with the donar atoms [the nitrogen atom azo group near the heterogeneous chain (N3) and nitrogen atom benzimidazole molecule (N3) , the oxygen atom of hydroxyl group in the heterogenous chain ] in the ligand molecule whereas the other band suffered from obvious changes in shape, intensity and location and this is a proof on the occurance of consistency process between the metallic ions under study and the tow ligands. Atomic absorption spectrometer is used for assigning percentages of the metallic ions in the prepared complexes as well as the analysis of micro - elements (C.H.N). These results indicate the great consistency between the percentages theoretically calculated and practically gained. The magnetic sensitivity indicated that Ni(II) - complex and Cu(II) - complex for both ligands have baramagnatic characteristics whereas the Co(III) - complex, Zn(II) - complex, Cd(II) - complex, Hg(II) complex have adia magnetic characteristics. Also , the study deals with the molar conductivity of the canine complexes dissolved in DMF nad ethanol in a concentration (1×10 - 3) molar and in lap temperature. The results show that the complexes of Ni(II) , Cu(II), Zn(II), Cd(II), Hg(II) do not have ionic characteristics and they are solution of non - electrolytes nature whereas the complexes of Co(III) and for both prepared ligands (BIADClP) and (BIADBrP) have ionic characteristics of the electrolytes nature of type (1 : 1) whereas other remaining complexes do not have any ionic characteristics. Throughout the results that have been reached at, certain structural forms for the canine complexes have been suggested.It has been indicated that the azo Benzimidazol ligands under study behave as tridentate ligands where the consistency happens through the N atom benzimidazole chain (N3) and N azo group far from the heterogeneous chain (N3) oxygen hydroxyl group of the homogeneous chain which leads to forming canine hexagonal complexes having octahydral as steric form.The hybridization of these complexes is d2sp3 concerning Co(III) - complexes of the ligands (BIADClP) and (BIADBrP) whereas the other complexes have the hybridization sp3d2 with the tow prepared ligands under syudy. Moreover, the study deals with the biological activity of these ligands and metallic complexes in the growth of four types of bacterial spores (germs) by using the solvent DMSO and deployment technology as anti - bacterial such as Staphylococcus aureuse and Staph.lentus representative for Gram positive bacteria and enterobacte and Escherichia coli representative for Gram negative bacteria. It is found that ligands and there complexes have different effect as antidepressants in the inhibition and the growth of bacteria under study wheras the ligand (BIADClP) gave the ability in inhibition of the growth of bacteria more than the ligand (BIADBrO) this is due to the change of substituted group on the homogeneous chain and their different in both ligands which led to the emergence of such difference in the inhibition and growth of bacteria.

تخليق وتشخيص ودراسة الخصائص التفلورية والمضادة لفايروس نقص المناعة المكتسبة لبعض مشتقات البركنينولون الجديدة Synthesis, Characterization, Fluorescence Properties, Anti - Hiv Activity And Molecular Modeling Study of Some New Pregenolone Derivatives

اسم المؤلف: رواء علاوي كاظم القريشي
اسم المشرف: نجم عبود لعيبي المسعودي نبيل عبد عبد الرضا
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: نظرا لما تتمتع به مركبات الازو من تطبيقات مهمة في كل من المجالين الاكاديمي والتطبيقي فقد تمحورت دراستنا على تحضير ستة ليكاندات ازو جديدة مشتقة من المركب 5,4 - ثنائي فنيل اميدازول ودراسة السلوك التناسقي لكل منها مع ستة ايونات فلزية هي Co(II) , Ni(II) , C | Azo compounds have important applications in both of academic and applied fields, Accordingly, our study based on the synthesis of azo compounds derived from 4,5 - diphenyl imidazole and characterization of these azo compounds with their metal complexese containing Co(II) , Ni(II) , Cu(II) , Zn(II), Cd(II) and Hg(II) ions. Mass Spectra of ligands and their complexes were supported their molecular formula, while H1NMR spectra of ligands agreed well with the suggested structures , The C.H.N. and Atomic absorption analysis showed a good agreement with the calculated values , The purity of ligands and their complexes were examined by TLC and the values of Rf were values measured.Electronic spectra of complexes showed a bathochromic shift comparing to ligands spectra as a result of the coordination between the metal ions and ligands. The concentrations that obeyed Beer - Lambert Law of the complexes were determined from calibration curves , Mole Ratio Method indicate a ratio (1 : 2) (Metal : ligand) for the complexes of (DPEPI) and (DPDED) while other complexes with other ligands show a ratio (1 : 1) (Metal : ligand).Satiability Constants of the complexes were calculated and found that the Stability constants of complexes of the first ligand (DPEPI) were ( 2.955×10 12) >(2.294× 1011 ) <(1.121×10 12 ) < (1.108 ×1011 ) varied in the arrangement as Co(II)< Ni(II) < Cu(II)> Zn(II) which agree with Irving - Williams Series. This arrangement was applied on the complexes of the other ligands. The Conductivity measurements of complexes showed non ionic character. Apparently the magnetic susceptibility values agree with their values of the octahedral high spin complexes for Co(II)) while the complexes of Zn(II), Cd(II), and Hg(II) were diamagnetic. IR Spectra of complexes showed obvious changes of the frequencies of ? (N=N) of azo group and ?(C=N) of heterocyclic imidazole ring as result of coordination with metal ions, While the frequencies of ?(C=N) of azomethine group did not show any significant change for complexes comparing to the ligands spectra ,New bands were appeared in the region (400 - 500) cm - 1 in the spectra of complexes that due to frequencies of ?(M - N) because of coordination process. From the previous results the purposed structures of the complexes can be summarized as shown in the following : Proposal structure of (DPEPI) Complexes Proposal structure of (DIDHP), (DIDMP),

التقديرات الطيفية للمركبات الاحادية والمتعددة للادوية Spectrophotometric Determination For Single And Multi Components of Drugs

اسم المؤلف: مروه صباح يونس
اسم المشرف: خالدة حميد محمد السعيدي
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: يتضمن هذا البحث تحضير مشتقات جديدة لنوعين من قواعد شف هما نوع وكذلك [XI]a - d والبايارازولون [X]a - d ومشتقات البايارازول، [XIII]a - d و[XII]a - d ونوع جميعها تحتوي على وحدةالايزوكزولين او البيرمدين باستعمال الجالكون [VII]a - d الكوينولين - مادة اساسية. | The work involves synthesis of new two types from Schiff bases ([IV]a - f , [V]a - f and [XII]a - d, [XIII]a - d), pyrazoles[X]a - d, pyrazolones[XI]a - d and quinolones [VII]a - d derivatives containing isoxazoline or pyrimidine unit starting with chalcones. 4 - Bromoacetophenone was reacted with 4 - hydroxybenzaldehyde, 4 - hydroxyacetophenone was reacted with 4 - bromobenzaldehyde and 3 - Aminoacetophenone was reacted with 4 - bromobenzaldehyde or 4 - N,N - dimethyl aminobenzaldehyde in basic medium to give four chalcone compounds by Claisen - Schemidt reaction. The chalcons [I]a - d was reacted with hydroxylamine hydrochloride to form isoxazolines [II]a - d, while, the chalcones type [I]c,d was reacted with thiourea to give pyrimidine - 2 - thiones [III]a,b in basic medium. The pyrimidine - 2 - thiones [III]a,b and isoxazolines [II]c,d reacted with 4 - or 3 - substituted benzaldehyde and coumarin to form Schiff bases[IV]a - f [V]a - f and quinoline derivatives[VII]a - d, respectively. On the other hand, compounds[II]a,b or [V]b,f were reacted with ethylchloroacetate in basic medium to get new ester compounds[VIII]a - d.The condensation of new ester[VIII]a - dwith hydrazine hydrate led to produce new acid hydrazide [IX]a - d. The later compound refluxed with 4 - substituted benzaldehyde in ethanol to give Schiff bases( [XII]a - d and [XIII]a - d) ,while the reaction of these acid hydrazides [IX]a - d with acetyl acetone and ethyl aceto acetate led to form pyrazoles[X]a - d and pyrazolones[XI]a - d,respectively. The synthesized compounds were characterized by melting points, C.H.N. analysis, FTIR, Mass and 1HNMR spectroscopy(of some of them). Some of the synthesized compounds have been screened for their antibacterial activities using two types of bacteria; E. Coli and Staph. Aureus. All the examined compounds did not show any biological activity towards E. Coli but some of them show activity towards Staph. Aureus.This work can be summarized by the following schemes :

تحضير ودراسة مشتقات 2 - امينو - 5 - ثايول - 4,3,1 - ثايادايازول الجديدة Study And Synthesis of New 2 - Amino - 5 - Thiol - 1,3,4 - Thiadiazole Derivatives

اسم المؤلف: هبه مشتاق احمد علي البدري
اسم المشرف: محمد مهدي صالح الدليمي
الموضوع العام: علوم الكيمياء
السنة: 2007
الموضوع الدقيق: الكيمياء التحليلية
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: The project conducted in this research work was carried out from October 2013 to May 2014 which leads to this thesis. It full's into five chapters. All these chapters cover up the survey, the practical part of preparing,manufacturing and testing many designs that have been adopted during this research work, and the results were subjected into various mathematic and data treatment.Chapter One : discuses the light (first part) absorption process and describes FIA in general (second part), it is classification and fundamentally involved ideas , the uses and applications of FIA. Chapter one also reviews the use of Ceric sulfate (third part) as a reagent definition, properties, uses and the applications. This chapter ends with the aim of the project.Chapter Two : In this chapter a complete description of the chemicals, their preparations and, using them throughout this project. This chapter also describes the use of flow system with all it is components (i.e. peristaltic pump, connection tubes, junction(Y - junction), six ports injection valve, reaction coil, and measuring readout system).Chapter Three : consists of three parts. The first part describes the design of Ayah 3SBGRx3 - 3D solar cell CFIA microphotometer. The idea of the use with the application of new flow injection microphotometer was build up to measure the responses. Flow injection microphotometer was made based on the use of a solar silicon cells as a detectors, and LEDs as an irradiation sources.The second part deals with calculation of dilution factor. This study was carried out to evaluate the change in concentration at each location of the designed manifold system via the chasse of an air bubble.The third part deals with the analysis carried out in this research work.Three different phenolic compounds (Pyrocatechol, Resorcinol, and Pyrogallol) were subjected by Ceric sulfate as oxidizing agent. A comprehensive detailed study was carried out using Ayah 3SBGRx3 - 3D solar cell CFIA microphotometer, the linear range, limit of detection (L.O.D) and percentage relative standard deviation for repeatability were 5 - 40 mMol.L - 1 , 36.63 ng/sample and < 1.5% successively for Pyrocatechol, and 5 - 40 mMol.L - 1, 17.17 ng/sample, and < 0.7% respectively for Resorcinol. While 5 - 40 mMol.L - 1, 41.61 ng/sample, and < 2 % for Pyrogallol. The method was applied successfully for determination of the mentioned phenolic compounds in pure samples. A comparison was made between the newly developed method and the classical method (UV - Vis spectrophotometry) at wave length 492, 481, and 438 nm for Pyrocatechol, Resorcinol and pyrogallol espectively of analysis using the standard additions method via the use of aired t - test. The obtained results was treated mathematically, it was noticed hat there was no significant difference between two different methods for analysis of three different organic compounds; in addition to no significant difference in the contribution of the Pyrocatechol, Resorcinol and pyrogallol to the oxidation reaction path, at 95% confidence level.Chapter Four : deals with the analysis of two different drugs (first part : Amiloride, and second part Ciprofloxacin) carried out in this research work using Ceric sulfate as a oxidizing agent. A comprehensive detailed study was carried out by Ayah 3SBGRx3 - 3D solar cell CFIA microphotometer, the linear range, limit of detection (L.O.D) and percentage relative standard deviation for repeatability were 0.0005 - 10 mMol.L - 1, 9.471 ng/sample, and < 1.3% successively for Amiloride. 0.05 - 12 mMol.L - 1, 0.300 ?g/sample, and < 0.6%, for Ciprofloxacin. The method was applied successfully for determination of mentioned drugs in pharmaceuticals formulation. A comparison (forAmiloride ) was made between the newly developed method and the classical method (UV - Vis spectrophotometry at wave length 540nm) of analysis using the standard additions method via the use of paired t - test. It showed that there was no significant difference between the quoted value of each individual company with calculated t - value at 95% confidence interval from developed method, in addition to comparison between two methods and calculate tvalue, it was noticed that there was no significant differences between two methods at 99% but a significant difference at 95% confidence level. A comparison (for Ciprofloxacin) was made between the newly developed method and the classical method (UV - Vis spectrophotometry) at wave length 551nm of analysis using the standard additions method via the use of paired t - test. It showed that there was no significant difference between the quoted values of each individual company with calculated t - value at 95% confidence interval from developed method, in addition to comparison between two methods and calculate t - value, it was noticed that there was no significant difference between two methods at 95%.Chapter Five : This chapter concludes few interesting points based on the obtained results throughout this research work, such as Conclusions and future prospect, Published work, and references.

تحضير وتشخيص ودراسة الفعالية البايولوجية المحتمله لبعض مشتقات 5,4 - ثنائي فنيل ايميدازول Synthesis, Characterization And Study of The Potential Biological Activity of Some - 4,5 - Di Phenyl Imidazole Derivatives

اسم المؤلف: منار غياث عبد المطلب الموسوي
اسم المشرف: حسن ثامر غانم
الموضوع العام: علوم الكيمياء
السنة: 2013
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: برزت اهمية مركبات الثاياديازول لما لها من فعالية بايولوجية وتطبيقات دوائية، ونظرا لاهمية الازو صناعيا وبايولوجيا لذا تم تحضير مشتقات ازو للثايادايازولات باستخدام المشتق 2 - amino - 5 - thiol - 1,3,4 - thiadiazole كاساس في هذا البحث وكما ياتي : 1 - تحضير ا | Recently, the signifificance of thiadiazole compounds appeared form their biological activity and medical applications therefore.Azo thiadiazole derivatives were prepared by using 2 - amino - 5 - thiol - 1,3,4 - thiadiazole as starting material in this research.1. Preparation of (A1) 2 - amino - 5 - thiol - 1,3,4 - thiadiazole through ring cyclization thiosemicarbazide in the presence of anhydrous sodium carbonate and CS2.[A1]2. Preparation of diazonium salt (A2) by reaction of compounds (A1) with sodium nitrate and hydrochioric acid at low temperature(0 - 50C) with stirring. [A2]3. Preparation of new azo compounds[A3 - A15] by the reaction diazonium salt [A2] with different aromatic compounds. [A3 - A15]4. Schiff bases [A16 - A23] have been prepared from the reaations of azo compounds [A3 - A5] with different aromatic aldehydes.[A16, A17, A18, A19, A20, A21, A22, A23]5. Preparation of new thio ester derivatives[A24, A25, A27] by reaction of azo compounds [A6, A7, A8] with acetyl chloride in the presence of pyridine. [A24, A25, A27] 6. Preparation of new thio ester derivatives [A26, A28] by reaction of azo compounds [A8, A9] with 2 - chloro benzoyl chloride in the presence of pyridine. [A26, A28]7. Preparation of new thio ether derivatives [A29, A30] by alkylation of azo compounds [A11] with bromo butane and bromo pentane in the presence of NaOH. [A29, A30]8.Melting boints of all prepared compounds have been measured and some of physical properties were studied lnddition, the structure eluciclation of a bove compound was carried out by using some spectroscopic methods (F.T.I.R and UV).

تحضير وتشخيص بعض المشتقات البوليمرية الجديدة للبولي فاينايل الكحول Synthesis And Identification of Some New Polymeric Derivatives of Poly(Vinyl Alcohol)

اسم المؤلف: باسل محمد احمد حيود الجميلي
اسم المشرف: احمد عبد الحسن احمد الكاظمي
الموضوع العام: علوم الكيمياء
السنة: 2008
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمنت هذة الدراسة تحضير مركبات مختلفة لل 5,4 - ثنائي فنيل ايميدازول من خلال خطوات كثيرة : شملت الخطوه الاولى من البحث تحضير مركب الازو ايميدازول (H) وذلك عن طريق تفاعل الازدواج لل 5,4 - ثنائي فنيل ايميدازول مع املاح الديازونيوم 4 - امينو اسيتوفينون.اما ا | This study deals with the synthesis of new different compounds of 4,5 - di phenyl imidazole via many steps : The first part of this study includes synthesis of azo compounds of 4,5 - di phenyl imidazole by coupling reaction of 4,5 - di phenyl imidazole with Diazonium salts then of 4 - aminoacetophenone. The second part includes synthesis of new azo - chalcone derivatives (H1 - H4)by react on(H) coumpound with different derivatives of benzaldehyde.The third part includes the synthesis of oxazine compounds (H5 - H7) by reaction of (H1,H2,H3)respectively compounds with urea.The fourth part includes synthesis of Schiff base(H8 - H13) by the reaction of the compound(H) with different derivatives of aniline.The fifth part of includes synthesis of oxazepine derivatives(H14 - H21) from reaction of Schiff bases (H8 - H13)with phthalic anhydride and (H9,H10)with maleic anhydride,and synthesis of titrazoles derivatives (H22)from reaction of Schiff base(H12) with Sodium azid (NaN3).The final part of this research includes the biological activity study of some prepared compounds and showes that there is inhibitory activity against fungul.The chemical reaction are checked by using (T.L.C) Technique, all the prepared compounds were characterized by using FT - IR and (¹H - NMR) and (C.H.N) for some of these compounds , and these identification studies approved the correctness of structures for the prepared derivatives.The following schemes explains the stages of reactions for the prepared compounds

دراسة مستويات الفا - لـ فيوكوز وبعض الدوال الكيموحيوية في مصول دم النساء اللواتي عانين من الاجهاض المفرد للثلث الثاني من الحمل Study of The Level ? - L - Fucose And Some Biochemical Parameters in Seram of Single Abortion At The Second Trimester of Pregnancy

اسم المؤلف: فؤاد احمد عمر
اسم المشرف: صباح حسين خورشيد
الموضوع العام: علوم الكيمياء
السنة: 2013
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
الجامعة: جامعة تكريت
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمن البحث اجـراء بعض التحويرات الكيميائيـة الجديدة للبولي(فاينايل الكحول) وتضمنت التفاعلات تحوير مجموعة الهيدروكسيل الى مجموعة الزانثيت للحصول علـى ملح زانثيت الصوديوم البوليمري , وقد استخدم هذا الملح للتفاعل مع كل من : - 1 - اورثو كلورو بنزيل كلورايد و| This research includes some new chemical modifications which have been done on Poly(vinyl alcohol) through the hydroxyl group which has been converted to xanthate group to obtain the polymeric sodium xanthate salt and the later has been used for the reaction with the followings : 1 - O - chlorobenzyl chloride and 1,3 - Dibromopropane to get xanthate esters also the xanthate salt was reacted with ammonium chloride to form the polymeric ammonium xanthate salt.2 - The reaction with iodine to form the polymeric crosslinked Dixanthate.3 - The reaction with diazonium salts prepared from aniline , P - nitro aniline , benzidine , 4,4 - methylene dianiline to form the diazoxanthate polymers. 4 - The reaction with some transition metal ions such as (Ni2+, Mn2+, Co2+) to form some polymeric complexes.The other part of the work includes the oxidation of Poly (vinyl alcohol) to get the oxidized form Poly(oxomethylene) which was reacted with hydrazines to prepare polymeric hydrazones and azine and also gallic acid has been used to esterify the poly(vinyl alcohol) to get poly(vinyl gallate) and phosphorus pentachloride to prepare polymeric trialkyl phosphate.Finally a thermal elimination experiment has been done on one of the polymeric xanthate ester to yield polyene.The polymeric products have been identified spectroscopically using the IR and UV technique , one of the products has been identified by NMR technique and some of the polymeric products have been analyzed for (C.H.N.S.) and also the magnetic susceptibility of some complexes have been measured.

تحضير عدد من المركبات الحلقية غير المتجانسة المشتقة من 2 - امينو - 6 - بروموبنزوثايازول وتقييم تاثيرها البيولوجي Synthesis of Some Heterocyclic Compounds Derived From 2 - Amino - 6 - Bromobenzothiazole And Evaluation Their Biological Activity

اسم المؤلف: خالد عبد العزيز عطية البدراني
اسم المشرف: خالد مطني محمد الجنابي احمد خضر احمد الخياط
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة لتحديد الدوال المدروسة مع عينات عمرية لنساء مصابات بالاجهاض للثلث االثاني من الحمل ومستويات تركيزالفيوكوز الكلي Total fucose (TF), والفيوكوز المرتبط بالبروتين protein bound fucose (PBF), والسكريات السداسية المرتبطة بالبروتين (PBH) protei | The study was done to determine the relationship between the causes of abortion in women during the second trimester of pregnancy and total fucose (TF) level , protein bound fucose (PBF) , protein bound hexose (PBHex) and other biochemical parameter , which include : thyroid gland hormones ( T3, T4 ,TSH ) and testosterone , progesterone and Prolactin as well as the estimation of the levels of cholesterol , triglyceride , high density lipoprotein( HDL) , low density lipoprotein ( LDL) , and very low density lipoprotein( VLDL) Samples of ( 53) patientshave been collected from Azadi hospital and General Kirkuk hospital who have suffered from abortion where the agesranged between ( 16 - 45) years divided into three age groups first age group( 15 - 24) years & second age group( 25 - 34) years & third age group( 35 - 44) years. also the studyincluded (40) healthy persons at same age groups regarded as control groups1. Significant increase in the levels of (TF & PBF ) and Significantdecrease in the levels of (PBHex in aborted women compared with non - pregnant women2. Significant increase in thyroid hormone (T3) for the first & third age group, and there is no significant difference for the second age group in aborted women compared with non - pregnant women. Significant increase in thyroid hormone (T4) for the first & third age group, and Significant decrease for the second age group in aborted womencompared with non - pregnant women. Significant decrease for the first & third age group and Significant increase for the second age group in thyroid hormone (TSH) in aborted women compared withnon - pregnant women.3. Significant increase in Testosterone hormone level For all age Groups in aborted women compared with non - pregnant women And Significant decrease in progesterone hormone level For all age Groups in aborted women compared with non - pregnant women. 4. Significant increase in Prolactin level in aborted women compared with non - pregnant women.5. Significant decrease in( cholesterol, triglyceride, LDL and VLDL) level in aborted women compared with non - pregnant women. 6. Significant increase in the levels of ( HDL ) for the first age group, and there is no significant difference for the second& third age group in aborted women compared with non - pregnant women.

تحضير وتشخيص عدد من معقدات البلاديوم (??) والبلاتين (II) مع مزيج من ليكاندات الثايويوريا او الحلقات غير المتجانسة الحاوية على الامين مع السكارين او الثايوسكارين Synthesis And Characterization of Some Palladium (??) And Platinum(II) Mixed Ligand Complexes of Thiourea Or Heterocyclic Amine And Saccharin Or Thiosaccharine

اسم المؤلف: نور عبد المجيد ضياف الدوري
اسم المشرف: صبحي عطية محمود الجبوري مظهر يونس محمد المهيدي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء العضوية
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تتناول هذه الاطروحة تحضير المركبات الحلقية غير المتجانسة ذات الحلقة الخماسية مثل معوضات الثايادايازول و3,2,1 - ترايازولين والثايازولدين - 4 - اون والحلقة الرباعية مثل الازتدين - 2 - اون والحلقة الثلاثية الاوكسازردين, فضلا عن تحضير الحلقة السداسية البرمدين | The thesis deals with hetero cyclic compounds with five member rings like thiadiazole substituted 1,2,3 - triazoline and thiazoldine - 4 - one, four member ring like azetidine - 2 - one and three member rings oxazirdine. Synthesis including six member ring compounds like pyrimidin - 2,4,6 - trione in addition to synthesis seven member ring compound like oxazepine are synthesized. In the present work 4 - bromo aniline is used as precursor for the synthesis of the required compound; the 2 - aminobenzothiazole - 6 - bromo (K1) is synthesized from the reaction of 4 - bromo aniline with potassium thiocyanate in presence of bromine, the later (K1) was reacted with ethyl chloroformate to give ethylcarbamate (K2),which is used for the synthesis of urea derivatives (K3 - 8).through (K2) reaction with substituted aniline. Pyrmidin - 2,4,6 - trione (K9 - 14) is synthesized from the reaction of malonic acid with urea derivatives in acetyl chloride.Schiff bases (K15 - 20) are prepared through the condensation of 2 - aminobenzothiazole with substituted benzyldehid. Seven member ring are synthesized by cyclaziation of Schiff bases (K15 - 20) by using malic anhydride in absolute ethanol to give 2 - aryl - 3 - N - 6 - bromobenzothiazole - 5 - 7 - dione oxazepene (K21 - 26). four member ring is prepared from the reaction of Schiff bases(K15 - 20) with chloro acetyl chloride in 1,4 - Dioxane in the presence of tri ethyl amine to give azetidine - 2 - one(K27 - 32). Thiazoldine - 4 - one(K33 - 38) is synthesized from the reaction of Schiff bases(K15 - 20) with thioglycolic acid in the presence of Zinc chloride. The Oxazirdine(K74 - 79) is also prepared from the reaction of Schiff bases(K15 - 20) with 3 - chloro per benzoic acid in pyridine. 2 - (2 - chloroacetamide) - 6 - bromobenzothiazole(K39) is prepared from the reaction of 2 - aminobenzothiazole - 6 - bromo (K1) with chloro acetyl chloride. The compound (K39) is used in the preparation of substituted aryl amino acetyl - 2 - amino - 6 - bromobenzothiazole (K40 - 46) through its reaction with substituted amine. The thiazoldine - 4 - one - 2 - imine (K47) is also synthesized from the reaction of compound (K39) with potassium thiocyanate. The thiazoldine - 4 - one - 2 - imine (K47) is reacted with substituted benzeldehyd to give 2 - (5 - (aryldin) - 2 - imino - 4 - oxo - thiazoldin - 3 - yl) 6 - bromobenzothiazole (K48 - 53).The 2 - (6 - bromobenzothiazole - 2 - ylimino) thiozoldine - 4 - one(K95) is prepared from the reaction of 2 - acetylamino - 6 - bromobenzothiazole(K39) with ammonium isothiocyanate in ethanol 96%. The thiazoldine - 4 - one(K95) is used in the preparation of 2 - (6 - bromobenzothiazole - 2 - ylimino) - 5 - (sub.Methyl) thiozoldine - 4 - one(K96 - 100) through its reaction with various amine and formaldehyde.The aminobenzothiazole (K1) is also used for the preparation of thiosemicarbazide (K54) by its reaction with carbon disulphide. The substituted 1,3,4 - thiadiazole (K55 - 60) is synthesized from the reaction of thiosemicarbazide (K54) with various of carboxylic acids in the presence of phosphorous oxychloride. The aminobenzothiazole (K1) is used in the preparation of aryl ( benzothiazole - 2 - ayl ) dithiocarbamate (K61 - 65) through its reaction with carbon disulphide and arylhalid or alkylhalid in ethanol.The 2 - azido - 6 - bromobenzothiazole (K66) is prepared from the reaction of sodium azide with diazonuim salt ( prepared from the reaction of benzothiazole (K1) with sodium nitrate , hydrochloric acid ). 1,2,3 - triazoline (K67 - 71) are synthesized through the reaction of 2 - azidobenzothiazole (K66) with various olefin in ethanol. The treatment of aminobenzothiazole (K1) with phenyl isothiocyanate gives (6 - bromobenzothiazole - 2 - yl) - 3 - phenylthiourea (K72) which is converted to (6 - bromobenzothiazole - 2 - yl) - 3 - phenyl - 2 - thioxydihydropermidine - 4 - 6 - one (K73) through its reaction with malonic acid in dry. Benzene. The 2 - hydrazinobenzothiazole (K80) is prepared from the reaction of 2 - aminobenzothiazole (K1) with a mixture from hydrazine hydrate and hydrochloric acid in ethylene glycol. Pyrazoline compounds (87 - 92) are synthesized from the reaction of chalcons (K81 - 86) ( which are prepared from the condensation of substituted benzaldehyde with acetophenone in a base medium ) with hydrazino (K80). The hydrazino (K80) is used in the preparation of 2 - amino( - 6 - bromobenzothiazole)isoandole - 1,3 - diaone (K93) and 1 - (2 - amino - 6 - bromobenzothiazole)pyrroline - 2,5 - di - one (K94) through its reaction with phathalic anhydride and malic anhydride in ethanol. For furthur work, the preparation of Schiff bases (K101 - 110) carried out. from the condensation of substituted benzaldehyde with hydrazino (K80) in the presence of glacial acetic acid in ethanol. The 3 - ( - 6 - bromobenzothiazole - 2 - ylamino) - 2 - (sub.aryl) - 5,7 - di - one oxazipene (K111 - 120) are synthesized by cyclazition of Schiff bases (K101 - 110) by using malic anhydride in methanol. Schiff bases (K101 - 110) are also used in preparation of 1 - ( - 6 - bromobenzothiazole - 2 - ylamino) - 4 - (sub.aryl) - 3 - chloro - 2 - oxo - zetidine - 2 - one (K121 - 130) through its rection with chloro acetyl chloride in presence of tri ethyl amine in 1,4 - Dioxan. The 3 - (6 - bromobenzothioazol - 2 - ylamino) - 2 - (substituted aryl)thiozoldin - 4 - one (K130 - 140) is prepared from the reaction of thioglycolic acid with Schiff bases (K101 - 110) in presence of zinc chloride in dry. Benzene. In order to show the antibacterial activity of prepared compounds (k11,k23,k41,k56,k61,k62,k89,k97,k112,k118,k126,k137,k139) are evaluated against four types of common bacteria (Bacillus subtillis, Staphylococcus aureus, Eschershia coli, Klebsiella peneuomina). The result of biological study are compared with standered antibiotic (Ciprofloxacine & Gentamycin). The structure of the synthesized compound are confirmed by I.R, 1H - NMR & 13C - NMR spectra and Some chemical physical data.

تحضير وتشخيص مركبات غير متجانسة حلقية متعددة من مشتقات الازو اوقواعد شف Synthesi And Identifecation of Heterocyclic Multiple Ring Compounds of Azo Derivatives And Schiff Bases

اسم المؤلف: ولاء فاضل عبد ضفير
اسم المشرف: فائز عبد الحسين عبد الرماحي
الموضوع العام: علوم الكيمياء
السنة: 2013
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: تتضمن هذه الرسالة تحضير وتشخيص عدد من معقدات البلاديوم (??) والبلاتين (II) مع مزيج من ليكاندات الثايويوريا او الحلقات غير المتجانسة الحاوية على الامين مع السكارين او الثايوسكارين. وحضرت معقدات من النوع [M(L)2] حيث ان : M = Pd (??) , Pt (??) , L = PTUH ( | Work in this thesis includes synthesis and characterization of some palladium(??) and Platinum(II) mixed ligand complexes of thiourea or hetrocyclic amine and saccharin or thiosaccharine.Complexes of the type [M(L)2] were prepared, {M= Pd(??) , Pt(II) , L= PTUH}where : (PTUH) = {N - Pheny1 - N - (2 - thiazoyl)thiourea} by treatment of the appropriate ligand with Na2PdCl4 or K2PtCl4 to give square planer complexes, in which thiourea anoin ligand behave as a bidentate coordinate to metal through the S atom of thioamide group and the nitrogen atom of thiozolComplexes of the type trans - [MCl2(L)2] L =ABI , AT , M = Pd(?? ) , Pt(??)ABI = 2 - amino Benzimidazol وAT = 2 - aminothiazolwere prepared by treatment of the appropriate ligand with Na2PdCl4 or K2PtCl4 to give square planer complexes , in which benzimidazol and thiazol behave as monodentate coordinate to Pd(??) metal through the N atom while the Palladium thiazol complex showed two isomer the N and S - bonded isomer.Palladium (??) or Pt(II) complexes of the type trans - [Pd(sac)2(L)2] were prepared by treatment of trans - [PdCl2(L)2] with Nasac. Sac anion ligand behaves as a monodentate coordinate to Pd (??) metal through the N atom.Thiosaccharinate complexes of the type trans - [Pd(tsac)2(L)2] (L=ABI, AT) were prepared in which (L) behaves as a monodentate which coordinate to Pd(??) metal through the cyclic N atom while the thiosaccharin anion behaves as a monodentate ligand coordinated to palladium metal through the sulfur atom. The PTUH ligand was characterized by infrared spectra and (1H n.m.r).The prepared complexes were characterized by molar conductances, Elemental analysis, Infrared spectra, 1H n.m.r data also the structure of trans - [Pd(PTU)2] and cis - [Pt(PTU)2] were determined by single crystal x - ray diffraction.The complex trans - [Pd (PTU)2] crystallizes in the monoclinic space group p 21/c with a= 12.510(17) ? , ? = 5.6963 ?, C=15.322(2) ? ?=90° , ?=90.066(17) ° , ?=90° and Z=2 Molecules per unit Cell. The complex cis - [Pt(PTU)] crystallizes in orthorhombic space group with a=7.3021(5) ?, b=11.8025 (9) ?, C=25.6282(19) ?, ?=90 ?, ?=90(17) °, ?=90 and Z=4 Molecules per unit Cell.

تحضير ودراسة السلوك البلوري السائل ل الفا - بيتا (4 - n - الكوكسي - 6,5,3,2 - رباعي مثيل - 4? - اوكسي - ازوبنزين) ايثان Preparation And Study The Behavior of The Liquid Crystalline ? - ? (4 - N - Alkoxy - 2,3,5,6 - Tetra Methyl - 4 - Oxy - Azobenzene) Ethan

اسم المؤلف: نور محمود عبد الحسين التميمي
اسم المشرف: ساجدة هادي رضا
الموضوع العام: علوم الكيمياء
السنة: 2013
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: تضمنت هذة الدراسة تحضير مشتقات حلقية غير متجانسة مثل 2 - امينو - 4 - فنيل ثيازول(2 - Amino - 4 - phenyl thiazol)، والاوكسازبين(Oxazepine)، والتريازول(triazol)، والاميدازوليدين(Imidazolidine). ابتداءا من (2 - Amino thiazol) و(Acetophenon) كمركبات اساس | This Study include synthesis of some heterocyclic derivatives such as (2 - amino - 4 - phenyl thiazol) , (oxazepine) ,(tetrazole) and (Imidazolidine) ,starting from (2 - amino thiazol) and (acetophenon) This Work is divided in to three Parts : Part one : Include Foure StepsThe first step include synthesis of 2 - amino - 4 - phenyl thiazol from (acetophenon),(thiourea ),(Iodine) ,while second step repersents the formation of Azo derivatives of (2 - amino - 4 - phenyl thiazol) ,while third step includes the formation of schiff base derivatives through reaction of azo compound with (3 - hydroxybenzaldehyde) The fourth step includes the reaction of prepared shiff base with compound (? - alanine) These steps are explain in diagram (1)Diagram No.1Part two : Includes two stepsFirst step includes the formation of schiff base derivatives of (2 - amino thiazol) through reaction of (2 - amino thiazol) with several compound , while second step includes reaction of several compounds with prepared schiff base to formate five and seven ring Theses steps are explain in diagram(2) Diagram No.(2)Part Three : Includes two stepsThe first step includes reaction of (acetylaceton) and (isatine) with (2 - amino thiazol) to formate new schiff base , while second step includes reaction several compound with prepared schiff base to formate five and seven ring.These steps are explain in Digram (3) Diagram No.3The sequence of reaction steps are followed up by (TLC) technique , and by busing solvents (methanol and benzene(1 : 4)) and ethyl acetate.All compounds are identified by (FT : IR) ,and some compounds by H1 - NMR and (C.H.N.S)

تحضير الكاشفين DPIDBSA وMBDPI واستعمالهما في الدراسة التحليلية للايونات Co(II) , Ni(II) , Cu(II) بالطرق الطيفية The Preparation And Use of The Two Reagents DPIDBSA And MBDPI In An Analytical Study of Ions Co(II) , Ni(II) , Cu(II) By Spectroscopic Methods

اسم المؤلف: زينب جاسم خضير الربيعي
اسم المشرف: سامي وحيد راضي الحسناوي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: تم تحضير مركبات دايمرات ازوبلورية سائلة بالصيغة الاتية : no.on n = 2 - 7و تشخيصها بالطراق الطيفية المتمثلة بطيف الاشعه تحت الحمراء وطيف الرنين النووي المغناطيسي للبروتون بالاضافة الى التحليل العنصر الدقيق وقد تبين من خلال التحليل الطيفي والتحليل العنصري | A new series of liquid crystal compound has been synthesized : no.on n=2 - 7 The identification of this new series had been done by IR and HNMR spectra in addition to C.H.N analysis. By using a hot stage polarizing microscope, it was found that the members n=2,3 show pure nematic phase and members n=4 - 7 show smectice (sc ) in addition to nematic phase. The effect of the number of carbon atoms on the side chains of the these compounds with TN - I shows odd - even effect transition temperatures was recognized. The TN - Sc show odd - even odd effect. The brodeniris groups (CH3) in terminal benzene rings decrease the transition temperature and has less effect on dimenshing the liquid crystalline properties than the monomers.

تحضير وتشخيص معقدات بعض العناصر الانتقالية مع ليكاندات نتروجينية ودراسة فعاليتها الحيوية Preparation And Identification Complexes of Some Transition Metales With Nitrogeneus Ligands And Study Its Biological Activity

اسم المؤلف: علي ابراهيم علي بكر الجبوري
اسم المشرف: نهلة عبد الحميد عبد الجبار
الموضوع العام: علوم الكيمياء
السنة: 2008
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمن البحث تحضير كاشفين جديدين هما الكاشف 3 - ((4,5 - diphenyl imidazole) diazenyl) benzene sulfonic acid ويرمز له (DPIDBSA) والكاشـــف2 - ((3 - methoxy phenyl) diazenyl) - 4,5 - diphenyl imidazole ويرمز له (MBDPI) وذلــــك من مفاعلة ملـح الديازونيـوم ل | This thesis included the preparation of the two new reagents 3 - ((4,5 - diphenyl imidazole) diazenyl) benzene sulfonic acid (DPIDBSA) and 2 - ((3 - methoxy phenyl) diazenyl) - 4,5 - diphenyl imidazole (MBDPI) by reacting adiazonium salt solution of (3 - aminobenzene sulfonic acid) and (3 - methoxyaniline) with (4,5 - diphenyl imidazole) in alkaline ethanoic Solution.The identity of these reagents have been characterized by spectral methods such as(UV - Vis) , FTIR , another physical properties (m.p.) and elemental analysis.The ionization constant of the reagent (DPIDBSA) was determine using spectroscopic method , the pKa was equal to 9.9.Six chelating complexes of the above reagents were synthesized with metal ions) Co2+, Ni2+, Cu2+). The two wavelength of maximum absorption for the two reagents were found (422nm) and (416nm) respectively in ethanol and for the complexes formed between these ions with these reagents were found at (476, 492, 504nm) and (455, 458, 496nm) for cobalt(II) , nickel(II) and copper(II) respectively in aqueous medium.It has been prepared after fixing the optimum condition of concentration and acidity function, through the study of UV - Vis spectrum for reacting of metal solution and two reagents solution. For wide range of pH (5 - 11) and concentration which obey to Beer - Lambert Law.The structures were determine according to the mole ratio method and continuous variation method which is obtained from the spectroscopic studies of the complex solutions. The ratios of (metal : reagent) are equal to (1 : 2) for all the complexes ions.The stability of complexes in the solutions was also studied at the optimum conditions.Diagnosis the solid prepared complexes by UV - Vis spectrum in ethanol solution showed high chromic shift from as compared with free reagents in visible region to all the complexes prepared.Micro elemental analysis for all the complexes were prepared and the percentage of Co(II) and Cu(II) were determined , using flame atomic absorption spectroscopy, it was noticed a great accord between theoretical and particle ratio.The infrared spectrum of chelating complexes also studied and it's compared with the two reagents spectrum. They give notice change with free two reagents spectrum. These showed new bands that were not found original in two reagents spectra but other bands have been changed in shape, in trinity and location. This may indicate that a coordination between the metal ions and the two reagents prepared.The Conductivity measurements for solutions at (1×10 - 3M) in ethanol solution have shown non - ionic character for all chelate complexes.From the above observations, it's suggested stereo shapes for complexes, that show the two reagents (DPIDBSA) and (MBDPI) behave as bidentit reagent, we can conclude that the proposed geometrical structure of all chelate complexes are octahedral.The study also included using spectrum method for determination stability constant of complexes in the thermal rang (25 - 45C?) for complexes with reagent (DPIDBSA) while the thermal rang was (10 - 30 C?) for complexes with reagent (MBDPI), and calculating ?G , ?H and ?S for complexes.The bacterial activity of the ligand and it's complexes were studied toward two type of bacteria : 1 - Pseudomonas. aurginosa 2 - StaphylloCoccus. aureusThe complex of Ni(II) with reagent (DPIDBSA) and the complexes of Co(II), Ni(II) and Cu(II) with reagent (MBDPI) and metal ions solution showed high bacterial activity on Pseudomonas. aurginosa while the solution of two reagents and all chelate complexes prepared also the aqueous solution of metal ions don't showed any activity toward the two type of bacteria (StaphylloCoccus. aureus) (G+ve).

دراسة بعض المتغيرات الكيموحيوية على مرضى ضغط الدم

اسم المؤلف: منال عدنان ابراهيم
اسم المشرف: نزار احمد ناجي
الموضوع العام: علوم الكيمياء
السنة: 2011
الموضوع الدقيق: علوم الكيمياء
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: يتضمن البحث تحضير مشتقات جديدة للقاعدة النتروجينية البيورينية (ثيوفلين) باضافة مجموعة ازو (Azo group) الى هذه القاعدة حيث تتصل بالطرف الاخر لمجموعة الازو الحلقية حلقة بنزين معوضة بمجاميع مختلفة مثل (SO3H , Br , NO2) وقد حضرت اربعة مشتقات للثيوفيلين1 - SA | This study include synthesis of new derivatives of nitrogen bases purin (theophylline) by adding azo group to these Bases where connecting in the other terminal with Banzen ring substituted by different group like (NO3, Br,...) Four derivatives of the theophylline where these are SAT , BAT , 4NAT , 3NAT these derivatives were used as ligand because of is abitity to from helating complex , these derivatives were reacted with eight metal ions these are (Fe2+, Co2+, Ni2+, Cu2+, Zn2+, La3+, Ce3+) these complex were characterized by many methods as molarratio, measuring of electrical conductivity electronic spectra , which helped us to find the chemical structure of those complex this study also found that ratio of ligand metal was 2 : 1 this study also include the study of biological effect for these ligand and complexes on four deferent pathogenic species (staphylococcus aureus, streptococcus viridans ) ,(protens vulgaris, pseudomonas aeruginosa ) the two first species are gram positive while the other are gram negative , finally (by using disk diffusion method) it was found that these compounds show different activity of inhibition on other growth of the Becteria.

تطبيقات طريقة استخلاص سائل - سائل للفصل والتقدير الطيفي لبعض العناصر الانتقالية بواسطة معقدات عضوية جديدة Applcations of Liquid - Liqid Extraction Method For Separation And Spectrophotometric Determiination To Some Transition Metal Elements By New Organic Reagents

اسم المؤلف: احمد ابراهيم حمزة
اسم المشرف: شوكت كاظم جواد
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء الحياتية
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة لمعرفة تاثير مرض ارتفاع ضغط الدم على بعض المتغيرات الكيموحيوية في الدم, ومقارنتها مع القيم الطبيعية (مجاميع السيطرة) والبالغ عددهم (125) (47 اناث و72 ذكور) والذين تراوحت اعمارهم بين (21 - 70) سنة حيث تضمن البحث : دراسة 115 حالة مرضية للاش | The present study was carried out to determine the effect of hypertension on some biochemical parameters in the blood compared to that of normal values of healthy subjects in healthy control group(125) (47 females and 72 males) Their ages ranged between(21 - 70) yearsThe study included : - 1 - seventy hypertensive patients(30 females and 40 males)Their ages ranged between (30 - 80) years the following biochemical parameters were included : (Cho, TG, HDL, LDL, VLDL, GOT, GPT, SOD MDA, HbA1C ,LDH, Metall oendopeptidase , leptin )for both hypertensive patients and health subjects as a control. Results of this study have shown a significant increase(p?0.05) in the concentration of cholesterol, triglyceride ,LDL,VLDL compared with control group while high density lipoprotein showed a significant decrease (p?0.05) compared with control groupThe estimation of LDL/HDL ratio showed a significant decrease (p?0.05) compared to that of healthy subjects The study also included the effect of hypertension duration on BMI and age in relation to the concentration of (Cho, TG ,LDL,VLDL,HDL)The study showed increase in the concentrations of (Cho, TG ,LDL,VLDL) while a decrease in the concentrations of high density lipoprotein for all patients compared with that of healthy subjects (control group).A clinical study of Metallo endopeptidase on the serum of healthy and hypertensive patients was carried which has been shown that the activity of this enzyme in healthy subjects does not affect by sex, age, and smoking while there is significant increase in the activity of Metallo endopeptidase in the serum of the hypertensive patients for both sexes at different ages compared with that of control group while there was an increase in the activity of Metallo endopeptidase in relation to the duration of disease the result also demonstrated a significant increase in the activity of lactate dehydrogenase in hypertensive patients compared with that of control group.ALT and AST enzyme levels have been estimation in this study which showed a significant increase in the level of AST in hypertensive patients for both normal weight and overweight compared with that of control group, while ALT level showed no significant difference in hypertensive patients for both normal weight and overweight compared with that of control groupAs for Leptin the study has showed a significant increase in the concentrations of leptin hormone in control group of healthy subject (over weight BMI?25) compared with normal weight(BMI?25) for the same group. the concentration of leptin in all hypertensive patients showed an increase level in relation to age &BMIThis study also included the estimation of SOD and MDA in both hypertensive patients and healthy subjects (control group).It showed a significant decrease in the activity of SOD as the duration increases and there was a significant increase in the level of MDA(P?0.05)in hypertensive patients compared healthy group.Finally the level of (HbA1C) was also studied which no significant difference in hypertensive patients compared with that of control group, while there was a signi

استخدام تقنية كروماتوغرافيا الغاز باستعمال اطوار سائلة ثابتة لدراسة كفاءة فصل بعض مركبات الازو المشتقة من الباراكريزول Use Gas - Chromatography Technique By Using Stationary Liquid Phases For Study of Separation Efficiency For Some Azo Compounds Derivative From P - Cresol

اسم المؤلف: وداد ابراهيم يحيى خزاعل
اسم المشرف: قاسم كاظم الاسدي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: حضر كاشفين عضويين جديدين هما2 - [3 - Acyl methyl phenyl )azo] - 4,5 - diphenyl imidazol (3 - AMePADPI) 1 - [(2 - Pyridyl azo)] - 2 - naphthol (PAN) وقد استخدما في فصل واستخلاص والتقدير الطيفي لعناصر النحاس(II)، النيكل(II)والبلاديوم(II) على هيئة ايونات موج | Synthesized two organic reagent was 2 - [(3 - Acyl methyl phenyl)azo] - 4,5 diphenyl imidazole (3 - AMePADPI) and 1 - [(2 - pyridyl azo)] - 2 - naphthol (PAN), which is used for separation , extraction and spectrophotometric determination Copper(II) ,Nickel(II) and Palladium(II) as Cations according to solvent extraction method ,dependence on measurement absorbance of ion pair complex extracted at ?max as well Calculation distribution ratio (D). This Study include limitation of optimum conditions for Complex formation and extraction such as pHex. and the experimental shows optimum pH for extraction Copper(II) with (3 - AMePADP) (pHex=8) and (pHex=9) with (PAN) but for Nickel was(pHex=11) with both organic reagent as well (pHex=9) for palladium (II) with both organic reagents. The study about metal ions concentration effect on extraction methods demonstrate 40µg Cu2+ suitable concentration giving higher absorbance for ion pair complex extracted to organic phase and higher distribution ratio (D) with both organic reagent , also for Nickel(II) was 80µg Ni2+ with (3 - AMePADP) and 50µg Ni2+ with (PAN) , but for palladium(II) was 20µg Pd2+ with(3 - AMePADPI) and 15µg Pd2+ with (PAN). Kinetic energy has important role in extraction. method according to Solvent extraction , and this study show effect shaking time of two immiscible phase on qualification `of extracted and illustrate 15 min was suitable shaking time for Copper(II) and Nickel(II) with both organic reagent and 5 min for palladium(II) with both organic reagent to obtaining higher absorbance of ion pair complex extracted to organic phase and distribution ratio (D). Organic solvent effect study appear there is not any linear relation between dielectric constant (?) of organic solvents and distribution ratio (D) that’s is mean there is not any effect for polity of organic solvent on extraction method but there is an effect for organic solvent structure which is participate in the structure of ion pair complex extracted by formation ,Tight ion pair or loose ion pair as well experiment result illustrate dichloro methane organic solvent (DCM) was the best organic solvent in extraction Copper(II) ,Nickel(II) and Palladium(II) by organic reagent (3 - AMePADPI) and PAN. Study about determination more probable structure of ion pair complex extracted (stoichiometry ) by performance four spectrophotometric method for extraction Cu2+ , Ni2+ and Pd2+ by (3 - AMePADPI) and PAN under optimum conditions and all experiment show the structure of ion pair complex extracted was (1 : 1) (metal : ligad) [Cu(3 - AMePADPI)]2+SO42 - . , [Cu(PAN)]+HSO4 - .[Ni(PAN)]+Cl - . [Ni(3 - AMePADPI)]2+2Cl - . [Pd(3 - AMePADPI)]2+2Cl - . , [Pd(PAN)]+Cl - . Declination of distribution ratio (D) frequently by reason of the organic reagent not gratify the coordination shell of metal ion and in this case water molecule participate to saturate the coordination shell and increase partition the complex to aqueous phase and increase dissociation of complex and decrease distribution ratio(D) as well probable to formation ion pair complex in structure of [M(L)]n+(OH) where M=Cu2+ , Ni2+ and Pd2+ and L = (3 - AMePADPI) or PAN this complex favorite partition to aqueous phase and decrease distribution ratio. Thermodynamic study include Temperature effect on extraction efficiency the experimental results demonstrate the reaction was exothermic for Copper(II) with both organic reagent (3 - AMePADPI) and PAN but the Complextion reaction of Nickel(II) and Palladium(II) with organic reagent (3 - AMePADPI) and PAN endothermic reaction , after calculation thermodynamic data ?Hex , ?Gex , ?Sex show entropy values was high that is mean complexation reaction is entropic in region. The study about Interferences effect on extraction method of Cu2+ , Ni2+ and Pd2+ by (3 - AMePADPI) and PAN to clarify metal cations of first group in periodic table Li+ , Na+ and K+ giving enhancement in distribution ratio in arranging Li+ >Na+>K+ by reason of high affinity of these ions to water and the thickness hydration shell increase with diameter decrease , this properties these ions being to contribute to destroy hydration shell of Cu2+ , Ni2+ and Pd2+ and increase chances of association with organic reagent and increase distribution ratio (D) , but metal cations of second group in periodic table Mg2+ , Ca2+ has more charge density than metal cation of first group and has less thickness in hydration shell and the effective behavior on extraction method was less , but anions able to participate in electrostatic combination with cation complex and giving different effects by differ in molar volume , stereo structure and charge density. The study about synergism by used tributyl phosphate (TBP) and Methyl iso butyl Ketone (MBK) in the extraction the experimental results shows TBP and MIBK giving enhancement in distribution ratio (D) by participate molecular of these solvents in the structure of ion pair complex extracted install f water molecular in coordination shell of metal cation as well as the results show there is one molecular of TBP or MIBK participate in ion pair complex extraction [Cu(MIBK)(PAN)]+HSO - 4 , [Cu(MIBK)(3 - AMePADPI)]2+SO42 - [Cu(TBP)(PAN)]+HSO - 4 , [Cu(TBP)(3 - AMePADPI)]2+SO42 - [ Ni (MIBK)(PAN) ]+Cl - , [ Ni (TBP)(3 - AMePADPI)]2+ 2Cl - [ Ni (MIBK)(PAN) ]+Cl - , [ Ni (TBP)(3 - AMePADPI)]2+ 2Cl - [Pd(MIBK)(PAN)]+Cl - , [ Pd(MIBK)(3 - AMePADPI)]2+2Cl - [Pd(TBP)(PAN)]+Cl - , [ Pd(TBP)(3 - AMePADPI)]2+2Cl - The study about of effect of ethanol in aqueous solution on extraction method of metal in aqueous solution on extraction method of metal cation Cu2+ , Ni2+ and Pd2+ by (3AMePADPI) and PAN the results show foundation of ethanol in aqueous solution with metal cations giving increase in distribution ratio and this increasing continue until reached optimum concentration of ethanol after this value distribution ratio (D) decrease. This study include used organic reagent (3AMePADPI) and PAN for spectrophotometric determination of Copper(II) ,Nickel(II) and Palladium(II) in different environmental and vital samples.

تحضير وتشخيص مركبات خماسية وسباعية غير متجانسة الحلقة لمشتقات الامينو بنزوثيازول Synthesis And Identification of Five And Seven Membered Ring Heterocyclic Compounds of Amino Benzothiazole Derivatives

اسم المؤلف: علي فتاح ناصر الحسيني
اسم المشرف: فائز عبد الحسين عبد الرماحي
الموضوع العام: علوم الكيمياء
السنة: 2012
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: تضمن الجزء الاول من البحث تحضير اربعة كواشف عضوية جديدة هي مشتقات ازو لمركب الباراكريزول وقد تم تشخيص الكواشف المحضرة من خلال اطياف الاشعة فوق البنفسجية - المرئية (UV - Vis) فضلا عن قياس اطياف الاشعة تحت الحمراء IR)) وتم اجراء قياسات نسب العناصر الدقيق ( | The first part of this study included perpetrating four new organic reagents which are derivatives of P - cresol. Its identification was done by UV - Vis spectrophotometer, IR and C. H. N. Depending on the results, we found the correspondence between the theoretical calculation and the experimental ones with a way to suggest the final structures of the prepared reagents. The purity of these reagents was tested through thin layer chromatography.The prepared reagents are : 1. 2[(4 - Methyl phenyl )azo] - 4 - Methyl phenol (MePAMP)2. 2[(4 - Chloro phenyl )azo] - 4 - Methyl phenol (CPAMP)3. 2[(4 - Methoxy phenyl )azo] - 4 - Methyl phenol (OMePAMP)4. 2[(4 - Nitro phenyl )azo] - 4 - Methyl phenol (NPAMP)The second part deals with the study of chromatographic behavior of organic prepared reagents dissolved in ethanol according to gas chromatography on stationary liquid phases as capillary columns with different polarities as zebron (FFAT) which is characterized with high polarity, silica fused (BP10) with a medium polarity and poly phenyl siloxine (OV - 5) that appears with low polarity.Gas chromatography was equipped with a flame ionization detector (FID) and the nitrogen as carrier gas with flow rate 30cm3min - 1 at different column temperatures ranged 100C increments depending on columns maximum operation temperature, column inlet temperature and detector temperature were higher than the separation column (25,50) 0C respectively.This investigation attempts to find the optimum conditions for the sequential separation were defined for the azo compounds of all capillary columns such as injection, applied pressure inlet of column, gas flow rate as well as the conditions of the efficient separation.The order of elution and resolution of compounds on various stationary liquid phases were normal chromatographic behavior which is decrease in specific retention volumes with increase of column temperature through the relationship between logarithm of specific retention volume for the studied compounds against reciprocal of absolute column temperature which is observed generally linear relation for all compounds on different liquid phases by using (Clausius - Clapeyron) , then calculate the thermodynamic parameters ?H0 , ?S0 and ?G from the slope and intercept respectively the negative values of partial molar enthalpy ?H0 of solutions indicate to highest interaction between liquid phases and separated compounds. The results show that the zebron (FFAT) consider the high negative value of ?H and the reaction was exothermic, on other hand the highest negative value of ?s means less random of solutes on some liquid phase , so it was more selective towards to prepared azo derivatives of p - cresol. Also calculated separation factor (RS),number of theoretical plate (N), equivalent highest of one theoretical plate (HETP) respectively for mixture of studied compounds on various liquid phases.The precision and accuracy of the prepared organic reagent (MePAMP) from 0.06% to 1.44% for (CPAMP) from 0.91% to 1.5%, (OMePAMP) from 0.03% to 1.42% and finally for (NPAMP) from 0.06% to 1.6%

تاثير العكبر العراقي على مجاميع النتروجين الفعالة (RNS) لدى الجرذان المصابة باعتلال الكلى السكري The Effect of Iraqi Propolis On Nitrogen Reactive Species In Diabetic Nephropathy Rats

اسم المؤلف: امنة ناظم زغير العمري
اسم المشرف: فردوس عباس جابر
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: تضمنت هذه الدراسة تحضير مشتقات حلقية غير متجانسة مثل الامينوبنزوثايازول(aminobenzothiazole) والبايرازول (pyrazole)، والاكسازيبيــــن (oxazipine) , والايميدازوليدين (Imidazolidine) ابتداء من (4 - amino acetophenone) (A0) و(benzidine) (B0) والمركب(2 - ami | This study includes synthsis of new heterocyclic derivatives such as (Thiazole), (Pyrazole), (Oxazipine), and (Imidazolidine), starting from (4 - amino acetophenone) (A0), (benzidine)(B0) and (2 - amino benzothiazole (C).This work is divided into three parts : Part one : Includes synthesis 2 - aminobenzothiazole derivatives (A) and (B) from (4 - amino benzothiazole) (A0) and (benzidine) (B0) respectively ,as starting materials. These steps are explained in diagram (1).diagram (1)Part two : includes two stepsThis part includes two steps : - The first step includes the formation of Schiff bases derivatives for 2 - amino benzothiazole derivatives (A) and (C).While the second step includes synthesis seven 1,3 Oxazpine rings derivatives by reaction with (phathalic anhydride).In addition to, synthesis (Imidazolidine) derivative (A11) from the reaction with ? - Alanine. These steps are explained in diagrams (2) and (3).diagram (2) diagram (3)Part three : includes two steps The first step includes preparation Azo derivative (A12) by reaction of (acetyl acetone) with the compound (A) (6 - acetyl - 2 - amino benzothiazole) , then (A12) was entered the reaction of cycliczation with hydrazine hydrate or their derivatives to formate various five pyrazole rings derivatives. These steps are explained in diagram (4).diagram (4)The Sequence of reactions steps are followed up by (TLC) technique, and by using solvents (methanol or acetic acid and benzene ( 1 : 4 )). All compounds are identified by (FT - IR) ,and some compounds by 1H - NMR and (C.H.N.S).

تحضير، وتشخيص ليكاندات ازو جديدة ومعقداتها ودراسة تطبيقاتها Synthesis, Characterization of New Azo Ligands And Their Complexes With Application Study

اسم المؤلف: زينب عبد الهادي حسن علي
اسم المشرف: عباس علي صالح الحمداني
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء الحياتية
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة في البيت الحيواني التابع لكلية الطب البيطري/جامعة القادسية على ستين جرذا من الذكور ذات وزن يتراوح بين (156 - 160) غم قسمت على اربع مجموعات : المجموعة الاولى (السيطرة), المجموعة الثانية (المصابة بداء السكري) بعد 24 يوما من بداية التجربة, | This study was conducted in the house of the Faculty of Veterinary Medicine Animal/University of Al - Qadisiya on 60 a rat of males of the weight of the ranges between (156 - 160) gm. divided into four groups : the first group (control), second group (diabetes) after 24 days from the beginning of the experiment, the third groups (Pre - treatment) by local EEP for 24 days and then was to stimulate diabetes where once, the fourth group (Post - treatment) by local EEP is that to stimulate diabetes after 24 days from the beginning of the experiment. doses extracted from local EEP be 300 mg/kg of body weight.At the end of the experiment was sacrificed animal blood serum samples collected from rats under anesthesia to measure changes biochemical , as well as the extraction of kidney samples for examination PCR - SSCP for candidate genes in diabetic nephropathy and examination microscopically for kidney samples in the four groups. The results obtained PCR - SSCP technology a surge in certain sites in genes (GLUT1 and nephrin promoter) in diabetes infected groups (G2, G3, G4) compared to control group (G1) where he found and local EEP not corrected of mutations found in both two gene signature, which indicates an extracted from local EEP is not an effective impact in reducing genotoxicity for STZ but an effective impact on the reactive nitrogen species where found a decreases in peroxynitrite concentration in treatment groups through disclosure of 3 - nitrotyrosine by ELISA technology. As well as the decline in the level of nitric oxide radical in the serum (P<0.05).As reveal the incidence of kidney failure by measuring the level of each of creatinin and uric acid in serum. It was noted at the end of the search low moral in body weight, and an increase in the level of moral glucose in blood and increasing the level of uric acid and creatinin, in the serum (P<0.05), for the group infected with diabetes. While groups that treated by local EEP processing had a clear impact in reducing the level of glucose, Nitrotyrosin, nitric oxide, Uric acid and Creatinine. conclusion can be local EEP has characteristics of local anti - oxidization also through its impact in reducing sugar level in blood and its impact on the moderate on kidney functions through the reduction of creatinine and uric acid concentration in blood through improving of histological changes in kidney rats that suffer from diabetes resulting from STZ as well as to the impact of immunological.

دراسة تخليق ومقارنة نظرية لتفاعلات الاسترة لمشتقات البنزين ثنائي هيدروكسيل ونواتج البلمرة The Study of Synthesis And Theoretical Comparison Esterification Reactions of Benzene Diol Derivatives And Polymerization Products

اسم المؤلف: هيفاء عدنان عبد الامير
اسم المشرف: سعدون عبد الله عودة عباس عبد علي الصالحي
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء العضوية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: تضمنت الرسالة تحضير ليكاندات ازو جديدة] 2 - هيدروكسي - 3 - ((5 - ميركبتو - 4,3,1 - ثايادايازول - 2 - يل) دايازينيل) - 1 - نفثالديهايد[ (HL1) المشتق من 5 - امينو - 1،3،4 - ثايادايازول - 2 - ثايول مع 2 - هيدروكسي - 1 - نفثالديهايد. و3] - ((1،5 - ثنائي مثي | In this work new azo ligands [2 - Hydroxy - 3 - ((5 - mercapto - 1,3,4 - thiadiazol - 2 - yl)diazenyl) - 1 - naphth aldehyde] (HL1) derived from 5 - amino - 1,3,4 - thiadiazole - 2 - thiol and [2 - hydroxy - 1 - naphthaldehyde. And 3 - ((1,5 - Dimethyl - 3 - oxo - 2 - phenyl - 2,3 - dihydro - 1H - pyrazol - 4 - yl) diazen yl) - 2 - hydroxy - 1 - naphthaldehyde] (HL2) derived from 4 - amino - 1,5 - dimethyl - 2 - phenyl - 1H - pyrazol - 3(2H) - one and 2 - hydroxy - 1 - naphthal dehyde have been prepared. And it’s metal complexes of with VO2+, Cr3+, Mn2+, Co2+, Ni2+ and Cu2+ have been prepared with ligands. The ligands were characterized by physic - chemical spectroscopic techniques [(C.H.N.S.), FT - IR, UV - Vis, 1H and 13C - NMR, Mass and TGA DTA curve]. And characterized complexes by Elements micro analysis (C.H.N.S.), FT - IR, UV - Vis, Mass and TGA DTA curve, Flame atomic absorption, Magnetic susceptibility, Chloride containing and Molar electric conductivity.The spectral data suggested that the ligand (HL1) as a neutral bidentate is coordinated with metal ions through the nitrogen atom of azo group and oxygen atom of phenolic group for all complexes, the proposed geometry that the Mn2+, Co2+ and Ni2+ complexes have tetrahedral geometries, and the Cr3+ complex have octahedral geometries and the VO2+ complex have square pyramidal geometries, and Cu2+ complex have square planer geometries, molar ratio ligand : metal (1 : 1).The (HL2) as a neutral tridentate ligand is coordinated with metal ions through the nitrogen atom of azo group, oxygen atoms of phenolic group and carbonyl group of and for all complexes only with VO2+ complex is bidentate, the proposed geometry that the Mn2+, Co2+, Cu2+ Ni2+ and Cr3+ complexes have octahedral geometries, and the VO2+ complex have square pyramidal geometries, molar ratio ligand : metal (2 : 1). The effect of the time on the stability for the solution of complexes has been studied and the steady of the stability for all the metal complexes through the time has been noticed.Hyper Chem - 8 program has been used to predict the structural geometries of the compounds in the gas phase. The total energy, dipole moment, electrostatic energy, heat of formation, and binding energy at 298?K, was used to evaluate the vibrational spectra of the free ligands and compare the theoretically calculated wave numbers with the experimental values. From previously information we can suggest the stable geometries for all compounds and measured their bond length between their atoms in molecules.

دراسة فيزيائية لتشخيص سطح البوكسايت والبوكسايت المعدل لامتزاز مادة التتراسيكلين عليهما عند درجات حرارة مختلفة Physical Study of Bauxite And Modified Bauxite Surfaces Identification For Tetracycline Adsorption On Them At Different Temperatures

اسم المؤلف: اسراء محمد راضي
اسم المشرف: تقي الدين عبد الهادي حمدان
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تضمن البحث تحضير وتشخيص استرات وبوليمرات مختلفة جديدة عن طريق تحضير مركبات الكيلية اوروماتية حاملة لمجاميع الهيدروكسيل عن طريق مفاعلة الكليسيرول مع (الريسورسينول , الكاتيكول , الهايدروكوينون ) بشكل منفصل.تم اجراء دراسة نظرية لنواتج الالكلة وبعض نواتج ال | This research includes the synthesis and Identification of new esters and polymers via new alkyl Aromatic containing hydroxyl groups. These compounds was prepared by reacting of glycerol with (resorcinol, catechol, hydroquinone) separately.A theoretical study For the products of alkylation and Polymers was conducted and compared with results.This Work includes the following : - first step : - Alkylation of cyclic compounds (resorcinol, catechol, hydroquinone) with glycerol to produce.2 - (2,4 - dihydroxyphenyl)propane - 1,2,3triol (H1) 2 - (2,5 - dihydroxyphenyl)propane - 1,2,3triol (H2) 2 - (3,4 - dihydroxyphenyl)propane - 1,2,3triol (H3)The resulting compounds were Identified by different techniques (FT - infrared spectra IR, NMR spectrum magnetic (1H - NMR, 13C - NMR) and Elemental analysis (CHN).Some physical properties of these compounds were studied.Step Two : - This step in clndes the preparation of ester compounds (Es1 - Es6) via reacting (H1, H2, H3) with Dicarboxylic Acid (malonic, Succinic) The resulting compounds were identified by different techniques physical properties of these compounds were studied Step Three : - Compounds (H1,H2,H3)were polymerized to produce new polymers (p1 - p9) via reacting with anhydride (maleic , phallic and succinic) by melting reaction (200 - 250) C.These Polymers were studied and Identified by different chniqnes including (FT - infrared spectrum, DSC, DLS, and studying solubility in different organic solvents, and measuring the percentage of swelling.Step Four : - The theoretical simulation of alkylation reaction of compounds (resorcinol, hydroquinone and catechol) with glycerol in existence of silicate aluminum were condncted. The transitional situation of these reactants and estimated energy values that leads to the suggestion interactive pathways, where studied. The prepared compounds (H1, H2, H3) were found haning a low value of total energy ( - 390.240 , - 390.232, - 390.251kCal \ mol), respectively, The study also these compounds possass less ? gab values (1.515,1.23, 0.68ev) respectively which was calculated density function calculations of DFT (minimal - STO - 3G).The comparison between the theoretical and obtained values of these compounds were conducted.The theoretical simulation of polymerization reaction (H1, H2, H3) to produce the polymers (p1,p4,p7)were done.The third is the most possible be cause it has the lowest values of total energy( - 126.625, - 126.491 , - 125.814 kCal\mol), respectively, and also has the lowest ?gab values (8.31,7.03.7.088ev).Polymers (p1,p4,p7) are theoretical produced by ring closure reaction and reaction and the possible energy values of these reactants are ( - 222.444, - 222.443, - 190288.29 kCal \ mol) calculated by semi - empirical calculations PM3.in conclusion, these polymers are formed through condensation reaction but not cyclic closure reaction.

تحضير وتشخيص بعض المشتقات الجديدة للمركب بارا - برومو انيلين ودراسة فعاليتها البايولوجية كمضادات (HIV) Preparation And Identification of Some New Derivatives of P - Bromoaniline And Study In Vitro Anti - Hiv Assay

اسم المؤلف: رعد سعد جهاد
اسم المشرف: نجم عبود لعيبي المسعودي نبيل عبد عبد الرضا
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: بهدف التوصل الى ايجاد سطوح انتقائية طبيعية وذات فعالية عالية في امتزاز بعض المواد الدوائية , اجريت دراسة متكاملة لانظمة الامتزاز للمادة الدوائية التتراسيكلين ( Tetracycline ( في درجات حرارية مختلفة على سطح البوكسايت والبوكسايت المعدل )البوليمر(.حيث تم ف | In order to reach to find a natural selective surfaces and highly effective in the adsorption of some pharmaceuticals, it has been a comprehensive study of the adsorption systems for the pharmaceutical substance Tetracycline in different conditions of temperature, on the surface of bauxite and modified bauxite. In this study the bauxite has been activated and used to prepare two complexes : bauxite - urea and bauxite - melamine, these complexes were merged and polymerized with to prepare the complex bauxite polymer - urea - melamine - formaldehyde (modified bauxite).The complexes bauxite - urea and bauxite - Melamine were characterized by X - ray diffraction (XRD) and infrared spectroscopy (FT - IR), while the surface of bauxite and modified bauxite are characterized before and after the adsorption by X - ray diffraction techniques (XRD), infrared spectroscopy (FT - IR), atomic force microscope (AFM) and scanning electron microscopy (SEM), where measurements showed that the presence of two types of minerals included in the structure of bauxite which they are Gibsite and Buhimite in addition to small amounts of other minerals.(UV - visb.) Technique was used to investigate the adsorption quantitatively on the surfaces of bauxite and modified bauxite at the following temperatures (293,298,303,308,313,318 K).Search has been expanded to include also the study of adsorption kinetics of the drug substance (tetracycline) on surfaces mentioned above. It has been found that the surfaces of bauxite and modified bauxite used in the study have a ranking below in its ability to adsorption of drug substance : Bauxite> PolymerResults of the study also showed the applicability of Frendilh equation model for adsorption of drug substance on the surface of the above - mentioned bauxite and applicability to Langmiur equation for the adsorption of drug substance on the surface of modified bauxite. The isotherms of adsorption takes shape (S2max) at low temperatures and then start to turn into shape (L2max) at high temperatures in the adsorption of tetracycline on the surface of bauxite, while taking shape (Lmax)at low temperatures and then start to turn into shape (Smax) at high temperatures when the adsorption of drug substance took place on the surface of the modified bauxite.Thermodynamic quantities Have been calculated, it’s found that the adsorption of drug substance on the surface of bauxite and modified bauxite is endothermic when the adsorption constant calculated at greatest concentration while the adsorption of drug substance on the surface of bauxite was endothermic and exothermic on the surface of modified bauxite if the adsorption constant calculated at infinite dilution.The kinetic study of the adsorption of the drug substance on the above surfaces according to the developed Lagergreen equation then the rate constant of the process has been calculated at temperatures (293,298,303,308,313,318 K), through these values the activation energy value and the value of Arhiniuos coefficient have been calculated adsorption process, it was found that the value of activation energy and the value of the Arhiniuos coefficient follow the order below : Polymer> BauxiteAlso the surface area of the surfaces of bauxite and modified bauxite follow the order : Bauxite> Polymer

تحضير ودراسة طيفية لمعقدات مزيج الليكاند لايونات بعض العناصر الانتقالية

اسم المؤلف: عباس سامي عبد
اسم المشرف: عبد الله محمد علي حبيبان مسلم حسن محمد
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: تضمنت الدراسة تحضير عدد من المشتقات الحلقية غير المتجانسة بالاضافة الى بعض المشتقات ثنائية الاريل والتي تعد ذات اهمية في مجال الكيمياء الطبية ,ونواة لتحضير بعض المشتقات الكيميائية الاخرى للمركب بارا - بروموانيلين والتي درس بعضا منها كمضادات للـ(HIV). وك | A new series of heterocyclic derivatives together with new biaryl analogues of biological interest have been synthesized starting from p - bromoaniline. Most of the new synthesized analogues have been tested for their anti - HIV (anti - human immunodeficiency virus - AIDS) activity.The thesis included the preparation of four types of compounds which have been use for further reactions as followings : 1. Preparation of the analogue R1 and its derivatives from treatment of p - bromoaniline with chloroacetylchloride. Reaction of R1 with KSCN or NH4SCN afforded the analogues R2 and R3 bearing benzothiazole backbone, respectively, while treatment of R1 with thiourea, hydrazine hydrate and piperazine gave R4, R5 and R7, respectively. In addition, treatment of R5 with p - toluenesulphonyl chloride (TsCl) yielded R6, meanwhile, fusion of R7 with maliec and phthalic anhydrides gave R8 and R9, respectively (Scheme 1).2. Preparation of the analogue R10 and its derivatives from treatment of p - bromoaniline with NH4SCN in the presence of bromine. Nucleophilic substitution of bromro residue of R10 by ( - SCN) group under microwave irradiation (MWI) afforded R11. Fusion of the latter with maliec, phthalicand succinic anhydrides gave R12, R13 and R14, respectively. In addition, treatment of R10 with p - cyanophenylboronic acid, via Suzuki coupling reaction and under MW, furnished the analogue R21(Scheme 2).3. Preparation of the analogue R15 and its derivatives,via diazotization reaction, from reaction of p - bromoaniline with acetylacetone. Treatmet of R15 with hydrazine hydrate or phenylhydrazine afforded R16 and R17, respectively.Furthermore, treatment of R17 with substituted arylboronic acids, via Suzuki coupling reaction and under MW, gave R23, R24 and R25 (Scheme 3).4. Preparation of the analogue R15 and its derivatives from treatment of p - bromoaniline with dimethylaminobenzaldehyde to give the azomethane derivative, which has been subjected to reflex with maliec and phthalic anhydrides by using ethanol to give the analogues R19 and R20, respectively. Additionally, treatment of R18 with substituted arylboronic acids, via Suzuki coupling reaction and under MWI, gave R27 and R28 (Scheme 4). The structures of the new synthesized analogues have been assigned from their 1H, 13C NMR and the C.H.N. analysis. In addition, most of the compounds have been identified from their 2D NMR : HSQC, HMBC, COSY and ROESY spectra.The thesis included the biological active study of the most new synthesized derivatives against Human Immunodeficiency Virus (HIV - 1 and HIV - 2) (AIDS), which carried out at Rega medical institute college of medicine, Katholiek University, Leuven, Belgium. The study showed that five analogues exhibited remarkable anti - HIV activity, since the analogues, R6, R8, R13, R26 and R28 showed EC50> (3.19, 2.11, 3.41, 2.31 and 3.72) µg/mL. In conclusion, compound R8 being the agent of choice for further pharmacological evaluation by its structural medication which might optimizeits potential activity to be drug in the future for treatment of AIDS.

هرمون الانتي مولرين كدالة لمتلازمة تكيس المبايض في امصال النساء العراقيات Serum Anti - Mullerian Hormone As A Marker of Polycystic Ovary Syndrome In Iraqi Women

اسم المؤلف: شهد فوزي عبيد عبد الواحد الخفاجي
اسم المشرف: بشرى فارس حسن غريد خليل محمد علي
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: يتضمن البحث تنقية المحاليل المائية المخففة من الملوثات العضوية صبغة الرودامين وصبغة الكونغو الاحمر بطريقتين الطريقة الاولى كانت امتزاز هذه الصبغات على سطح البتونايت ضمن Al2O3، ZnO،TiO 005 ( جزء بالمليون استعلمت المركبات الثانوية 2 - مدى من التراكيز ) 05 ) | The present work deals with the purification of diluted aqueous solutions from organic pollutants Rhodamine B (RhB) and Congo red (CR) dyes with two methods. The first one was adsorption these dyes on bentonite in range (50 - 250)mgl - 1, Nanocompounds,TiO2, ZnO, Al2O3 and quaternary ammonium salts Hexadecyl tri methyl ammonium bromide (HDMAB), long chain hydrocarbon compounds Sodium dodecyl sulfate(SDS) in different amounts (0.01 - 0.1)g/10g of bentonite were used to modify the adsorption capacity to remove the RhB and CR dyes from aqueous solutions. Both bentonite and modified bentonite are firstly characterized using SEM, AFM and FTIR techniques.The effect of dyes concentration, contact time, effect of initial dye concentration and contact time, adsorbent dosage, and amount of modifiers on the percentage removal have been studied. The modified bentonite with SDS. TiO2 , ZnO increased the percentage removal(R%) of RhB dye from 80% by natural bentonite to 99.3%,98.9% and98.7% respectively, the other dye CR modified bentonite with HDMAB,TiO2 ,ZnO, increased the R% from 81.3% to 99.6%, 99.0% and 98.8%,while adding Al2O3 did not success to increase the R% of RhB and CR on bentonite surface The study exhibits that Langmuir and Freundlich models gave geed fitted to the experimental adsorption at 25°C.The second method deals with advanced oxidation process by using photo - Fenton catalyst(Fe2+,H2O2 and UV light) to degradates of two dyes RhB and CR, the effect of Fe2+ concentration,H2O2 concentration , initial dye concentration and effect of pH at different interval time have been studied.results indicated that simultaneous utilization of UV irradiation with Fentons reagent increase the degradation degree of RhB and CR dyes quickly lose their color, indicating that the dissolves organics have been oxidized, the maximum color removal were obtained at pH 2.0,250 mgl - 1of Fe2+,300 mgl - 1of H2O2for RhB at 240 minute while for CR maximum removal were at pH 3.0,200 mgl - 1of Fe+2,350 mgl - 1of H2O2 at 270 minute.The photo - Fenton degradation process was monitored by HPLC chromatogram of RhB and CR dye solutions. The intensity of the peaks are gradually decreased with irradiation time.The irradiation time after three hours show no HPLC peaks detected, the results are in a good agreement with the results obtained from the UV visible spectrum.In this study semi - empirical methods are used to calculate the molecular orbital energies. This calculation let to suggest the best surface active material which can be used to modify the adsorption efficiency for RhB and CR on Iraqi bentonite surface. The theoretical study results are compared to experimental results achieved in experimental studies on some organic pollutants and modified bentonite by SDS and HDMAB. Using SDS led to the best adsorption efficiency for RhB while HDMAB lead to best efficiency for CR dye. The enthalpy of formation, dipole moment and energy of molecular orbital HOMO and LUMO energies levels were calculated for the two dyes and the two modifiers.

دراسة كيميائية حياتية لانزيم اللاكتيت ديهايدروجنيز (LDH) ومتناظراته المنقاة جزئيا من ادرار المرضى المصابين باورام البروستات Biochemical Studies of Lactate Dehydrogenase And Its Isoenzymes Partially Purified From Urine of Patients With Prostate Tumors

اسم المؤلف: عمر علي كنوش الجبوري
اسم المشرف: فراح غالي الصالحي نزار احمد ناجي
الموضوع العام: علوم الكيمياء
السنة: 2008
الموضوع الدقيق: علوم الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمنت الرسالة ثلاثة فصول. يحتوي الفصل الاول على مقدمة لنبذة تاريخية للمواد البلورية السائلة وصفاتها الفيزيائية وبعض الامثلة لتطبيقاتها,وكذلك الخصائص الثرموديناميكية للمزيج الثنائي والثلاثي للمركبات البلورية السائلة. وتحتوي المقدمة ايضا على شرح مختصر لتق | This thesis consisted of three chapters. First chapter contained an introduction to explain the historical view, physical properties, application and thermodynamic characterization of binary and tertiary system mixtures of liquid crystalline materials. Also it contained an introduction to Nanotechnology and nanosheets like graphene oxide and its functionalization and a summary about the dielectric permittivity and conductivity. The second chapter explained the experimental part including the synthesis of graphene oxide (GO) and its functionalization and general synthesis procedure of eight liquid crystalline compounds, which were outlined as follows : 1. N1,N4 - Bis(4 - subst. - benzylidene) benzene - 1,4 - diamine [3a - d] 2. N4,N4? - Bis(4 - subst. - benylidene) biphenyl - 4,4' - diamine [5a,b] 3. 3,3' - dimethyl - N4,N4? - Bis(4 - subst. - benzylidene)biphenyl - 4,4' - diamine [7a,b] The binary mixtures were prepared from a non - polar compound N1,N4 - bis(4 - methylbenzylidene) benzene - 1,4 - diamine and N1,N4 - bis(4 - bromobenzylidene) benzene - 1,4 - diamine as polar compound. The tertiary mixtures were prepared by mixing the mole fraction of the eutectic point (60%A) mixture [D] from the binary system and considered as the first compound A, the second compound was 3,3' - dimethyl - N4,N4? - bis(4 - bromobenzylidene)biphenyl - 4,4' - diamine as compound B.The tertiary system mixture at (13%B) showed the lower eutectic point, each concentration of the eutectic points in the binary and tertiary systems was mixed with graphene oxide and graphene oxide functionalized with polyaniline. The third chapter described the characterization of the prepared GO nanosheets with different functional groups.These nanosheets were characterized with multiple techniques (FT - IR , X - ray diffraction, SEM and AFM). The prepared liquid crystalline compounds were characterized by using FT - IR infrared and the liquid crystalline properties of compounds [3a - d], [5a,b],[7a,b] , the binary, tertiary systems and the mixtures with graphene oxide (GO) and GO functionalized nanosheets were examined with hot - stage polarizing microscopy, at the concentrations of the eutectic points , measured the dielectric permittivity and conductivity ?ac at the concentrations of the eutectic points. The addition of the nanosheets caused lowering of the transition temperatures of eutectic points in the binary and tertiary systems. It is worth noting, that in the two mixtures was appeared a new unknown (enantiotropic smectic ) phase.

تقويم فعالية الخميرة Candida albicans من المسح المهبلية للنساء في حيوية النطف واحداث العقم

اسم المؤلف: رقية يحيى عبد الشهيد الطفيمي
اسم المشرف: زيدان خليف عمران المعموري فارس ناجي عبود الهادي
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الاحياء المجهرية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: The present study aimed to identify some of the molecular dynamic qualities and the type of Candida albicans and determine its virulence factors using some of the phenotypic and molecular techniques and their impact on the semen and causing infertility.The collection of 173 swab of the vagina and the cervix was where 97 women from women with primary infertility, including 78 women with positive and 19 women with a scanning negative.kmaamlh control and 76 women with secondary infertility, including 49 with positive screening women and 27 women with a scanning negative.kmaamlh control, women who Rajan unit infertility in Babylon, a maternity hospital and children and private clinics in the province of Babylon.The use of agricultural methods to isolate and diagnose 127 isolation dating back to Candida vaginal as well as the use of CHROMO agar medium test and test tobacco Agar to distinguish between certain types of Candida, was detected on some virulence factors such as the composition of the Germ tube and spores Alclamadah and production of enzymes case of fat (Alphusfullaypez) and the formation of membrane It was vital to draw your DNA candidiasis and the use of PCR technique where the starters used by the general whiteners, especially for the purpose of diagnosis isolates of Candida albicans and genetic profiling of yeast Candida depending on the variation in the ITS region area. Showed isolate and diagnose types of eggs in women with infertility initial results of 48 women infected with C.albicans by (61.53%), while 30 women is infected Non - C.albicans by (38.46%) either in women with secondary infertility showed the 29 women infected with C.albicans by ((59.18% and 20 women is infected non - C.albican by (40.81%). the results showed the center CHROMO agar medium isolates of Candida species C.albicans was once a green color and isolates C.tropicalis with blue color and with C.krusei color pink and showed C.glabrata violet and C.parapsilosis that showed white.And C.albicans isolates showed C.albicans result is positive for the production of germ tube and spores Alclamadah as well as the center of tobacco Acar which they appear yeast C.albicans white colonies free of filamentous structures, a test of this kind without other types of Candidapositive test.. While the production of enzymes showed a case of fat test (Alphusfullaypez) as a result of the positive isolates C.albicans and C.krusei The results showed that the incidence of candidiasis in women with infertility first was more ratio than the unemployed in secondary infertility. It was the incidence of type C.albicans is the largest in all of the women with primary infertility and secondary infertility women initial rate of 61.53% and 59.18%, respectively, followed by injury type C.glabrata by 17.9% in women with infertility first and 18.36% in secondary infertility. Distributed cases of four age groups and was the highest rates (47.91% (in women with infertility and the first (55.17%) in the women's secondary infertility is located within the age group (30 - 21) years old. In the case of a period of infertility and distributed cases into three periods and was the highest rate of infection is the period (5.1), where the percentage (81.81%) in infertile women was less than the rate of infection is the period (15 - 11), where the ratio of (6.49%) in infertile women. The results showed that the rate of infection C.albicans were higher in women with and who not to say on treatment by (65.33%) of either women with and who took up treatment (53.84%). As well as the incidence is higher in women infertile is Mentzmat appeared menstrual cycle by (63.75%) The women infertile women with regular menstrual cycle and to have a lower rate (55.31%). The incidence of rural women by (67.56%) higher than the women of the city that are represented (58.49%).It was three concentrations preparation 3×107, 5× 107, 7×108cfu/ml of all isolated from C.albicans and raw leach ate Khmer and observe their effect on semen and then finding the value of MED50 effective dose)) concentrations C.albicans way to draw a dose - of responsiveness was found that the concentration curve (107× 5 cfu/ml) top influential focus on movement and Sperm Viability. It was the influence of the C.albicans test on semen Concentration 107× 5cfu/ml over time (after 30 - 60 minutes) and a leaky yeast and after the screening device Alkazh Computer aided sperm analysis (CASA) where he found the impact of the C.albicans on sperm movement, Rapid progressive (a), Slow progressive (b) and Sperm Viability (V) over time after the text of the clock and watch.The pair initiator year ITS4 - ITS5 in the diagnosis of all isolates representing the total isolates succeeded as a return to form of the genus Candida spp. Where the results of the polymerization 520 bp. The pair initiator Specialist in the diagnosis of Candida yeasts belonging to the type C.albicans and succeeded when he polymerization products 344bp, while the rest of the species is C.albicans did not show any polymerization products.Showed genetic profiling products for the ITS using a pair of initiator ITS3 - ITS4 where showed variation in the ITS region area for the pair in the public initiator profiling C.albicans under study

فحص عوامل عنق الرحم باستخدام فحصي اختراق النطف واتصال النطف بمخاط عنق الرحم للازواج العقيمين Examination The Cervical Factors By Using Sperm Penetration Test And Sperm Cervical Mucus Contact Test In Infertile Couples

اسم المؤلف: الاء عمران مطلك الحسناوي
اسم المشرف: فارس ناجي عبود الهادي بشرى جابر الربيعي
الموضوع العام: علوم الحياة
السنة: 2014
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: The present study was conducted in Infertility unit / Babylon Hospital of Gynecology and Children in a period 21/1/2013 to 15/1/2014. The study involved communiqués tests for males and females complaining from unexplained infertility , in which seminal fluid analysis were normospermia. The study include 45 seminal fluid specimens used in connecting test (SCMCT) and penetrating test (SCMPT) with the specimens of cervical mucus of their wives. Cervical mucus aspirating in day 12 - 14 of menstrual cycle. The study aimed to evaluate the husband's sperm activity and concentration in vitro with cervical mucus. Seminal fluid analysis were achieved and then semen specimens used to performed two in vitro tests : SCMCT and SCMPT. sperm parameters ( sperm concentration and sperm motility grade a, b, c, and d) were evaluated in each mentioned test and compared the results with the values of sperm parameters in seminal fluid analysis (control). The statistic results showed 60% of the study specimens of SCMCT was negative and 40% positive, while in percentage of positive results was 33% and 67% negative in penetrating test. The results revealed a significant (p<0.001) decrease of sperm concentration and grade a and b sperm motility, a significant (p < 0.001) increase of sperm motility grade c and immotile sperm grade d in connecting test with cervical mucus compared to control. The results of penetrating test showed significant (P< 0.001) decrease of sperm concentration in the brim, medium and distal region of cervical decrease (p<0.001) of sperm concentration in both medium and distal region compared to brim region, and a significant (p < 0. 001) decrease in distal region compared to medium region ; A significant (P < 0.001) decrease of grade a + b motility percent in all three regions of cervical mucus area compared to control, while no significant differences (P > 0. 05) between brim, medium and distal region of cervical area ; Only grade C sperm motility in distal region showed a significant decrease (P < 0. 001) compared to control and both brim and medium regions. The results revealed significant increase of grade d (P<0.001) in brim and medium region (P < 0.01) compared to control, while there was a significant decrease (P< 0. 001) in distal region compared to control, brim and medium regions. The correlation (r) study of sperm concentration and sperm motility ( grade : a + b, c and d) with age and infertility period in SCMCT showed non significant (P > 0. 05) correlation, except the correlation between a + b grade sperm motility and age it was noticed a significant negative correlation (P < 0. 05) and positive correlation(p> 0.05) between grade c sperm motility and age. The study of linear correlation of sperm parameters in penetrating test showed a significant(P<0.05) negative correlation between grade a+b sperm motility and age in brim and medium region of cervical mucus area. Except this, there are no significant correlation (P>0.05) between sperm concentration and sperm motility for all grades (a + b, c and d) with age and infertility period in both brim and medium regions It was concluded that both test : SCMCT and SCMPT were necessary to diagnosis the causes of infertility when there were normal finding of both seminal fluid analysis and female criteria. mucus area compared to sperm concentration in control, also a significant

دراسة تاثير البروبايويك في تكوين الغشاء الحيوي وانتاج البروتيز لبكتريا Pseudomonas aeruginosa المعزولة من اخماج الحروق والجروح Study The Effect of Probiotic On Biofilm Formation And Production Protease Enzyme By Pseudomonas Aeruginosa Isolated From Contaminated Burns And Wound

اسم المؤلف: علا عبد الكريم كاظم النعيمي
اسم المشرف: منيرة جلوب اسماعيل العبادي ضيماء محمود ابراهيم
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الاحياء المجهرية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: he study includes the collection of 70 burns and wound swabs from patients of different hospitals, in Baghdad area, for the period from November 2013 to February 2014. 2) 31 isolates characterized as Pseudomonas aeruginosa 9 (45%) from wound and 22 (78.57%) from burn swabs, depending on the characteristics of the colonies phenotypic and microscopic when grown in differential selective media, as well as biochemical tests todiagnose isolates, Then the identification of these species were confirmed by using the system (GN I Card) using Vitek 2 device complementary step.3) The study includes sensitivity test towards 16 antibiotics for each species by using the system (AST Card) using Vitek 2 device, and the isolates ware Multi drug resistance, As results all isolates were resistant by 100 % for each of Piperacillin, Ticarcillin, Ticarcillinclavoulanic acid, Cefazolin, Ceftriaxone and Tigecycline. All strains were less resistance to Ceftazidime with percentage 50%. 4) All the isolates of Pseudomonas aeruginosa with percentage %100, have ability to produce protease enzyme.5) This study was use tow methods of biofilm formations seen in P. aeruginosa, Micro - titer plate method (MTP) and Tube method (TM), Results revealed that MTP was found to be more sensitiveand specific method for biofilm detection than TM. 6) Well diffusion method revealed the inhibitory effect of bacteria Lactobacillus acidophilus, Lactobacillus rhamnosus GG and its supernatants in the growth of bacteria Staphylococcus aureus and P. aeruginosa, and was the supernatant of L. rhamnosus GG isthe largest inhibitory effect on the growth of S. aureus and P.aeruginosa with inhibition diameter 32 and 34 mm respectively, while the inhibition of growth by supernatant of L. acidophilus diameter 25 and 27 mm respectively. 7) Estimated the amount of protein in each of the biosurfactant and bacteriocine producers of L. rhamnosus GG bacteria concentration of 74, 54 Mg/mL respectively, while their concentration in bacteria L. acidophilus 44, 40 Mg / mL, respectively.8) Found that the bacteriocine product of bacteria L. rhamnosus GG and L. acidophilus GG have inhibitory effect on ability of P. aeruginosa to produce the enzyme protease, and the absence of this effect in the Biosurfactants the product of these two types.9) The biosurfactant product from L. rhamnosus GG showed inhibitory effect greater than the effect of the biosurfactant product from L. acidophilus to inhibition (production of biofilm and adhesion to epithelial cells).10) studied the suspension's effect of L. acidophilus and L. rhamnosus GG in contrived injuries wounds in mice contaminated with P. aeruginosa, Positive results have been shown to be affected by the contaminated bacteria injuries wounds.

دور الجبرلين والسالساليك والبوتاسيوم في تقليل التاثيرات الضارة لملوحة التربة في صنفين من الحنطة الناعمة Triticum aestivum L. The Role of Gibberellien And Salicylic And Potassium In Reduce The Harmful Effrcts of Soil Salinity In Two Wheat Cultivars Triticum Aestivum L.

اسم المؤلف: هدى نافع كريم
اسم المشرف: وسام مالك داود
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: نفذت هذه الدراسة في قسم علوم الحياة - كلية التربية للعلوم الصرفة للموسم الشتوي 2014 - 2015 لبيان دور الرش بالجبرلين وحامض السالساليك والبوتاسيوم في زيادة تحمل صنفين من الحنطة للاجهاد الملحي.تضمنت الدراسة رش الجبرلين وحامض السالساليك والبوتاسيوم بالتراكيز | This study carried out in the department of Biology - College of Education for pure science in winter season 2014 - 2015 to indicate the role of spray by of gibberellien and salicylic acid and potassium in increased tolerance of two wheat cultivars to salt stress.The study included spray of gibberellien and salicylic acid and potassium with the concentrations of 200, 100 and 3000 mg.Liter - 1 on the vegetative of two wheat varieties Rashid and Diglha to increase the tolerance to the two levels of soil salinity and which are 3 and8 ds.m - 1.Through study of some morphological and physiological traits (germination rate, speed germination coefficient, number of tillers, flag leaf area, plant height, chlorophyll content, proline content, sodium and potassium rate securities, number of spikes, number of spikelet, spike length, grain protein ratio, weight of 1000 grain and grain yield).The results showed that increasing the level of soil salinity led to obtain significant decrease in the most of the traits, the study also showed adiscrepancy between the two cultivars, it was the product growth indicators Rashid best of Diglha and for most of the traits. Where spraying potassium gave the best results for most of the traits through reduce the negative impact of salt stress on plant wheat more than spraying gibberellien and salicylic acid. The study showed that the treatment of spraying potassium it was superior in most of the traits results and of these qualities is the description of the number of tillers where recorded 19.3 branch. Plant - 1 and recipe flag leaf area where the 28.20cm2 and the recipe chlorophyll content 88.181 spad and prescription rate securities where sodium ratio 0.151% and in the number of spikes reaching 14.8 spike. Plant - 1 and the average number of spikelet which is 21.0 spikelet. Spike - 1 and the percentage of protein in grain 18.1% and grain yield reaching 11.497 gm. Planter - 1.

دراسـة بيئيــة للافقريات القاعيـة في هور الدلمج - وسط العراق An Ecological Study of The Benthic Invertebrates In Al Dalmage Marsh - Middle of Iraq

اسم المؤلف: ميسون حسن مشجل السراي
اسم المشرف: هيفاء جواد جوير
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - اللافقريات
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: استهدفت الدراسة الحالية التنوع الاحيائي لمجتمع لافقريات القاع في هور الدلمج / وسط العراق فضلا عن بعض الخصائص الفيزياوية والكيمياوية لمياه الهور، اختيرت ست محطات لجمع العينات وذلك للمدة من بداية كانون الثاني وحتى كانون الاول 2013. استخدم تحليل التوافق CCA | Benthic invertebrate diversity on the Al - Dalmage marsh in the middle of Iraq, in addition to the some physical and chemical properties was the goal of the present study, for a period from January to the end of December 2013. Six stations along the eastern side of the marsh were chosen for monthly samples collection.The results showed water temperature ranged from(9 - 34.1)?C. The pH values were neutral but tends to near alkaline and ranged from (7.2 - 9).The Electrical conductivity values varied from (22735 - 2330) ?s/cm, according to the values of salinity (1.5 - 14.6) ‰ the marsh was classified as mesohaline (TDS) which showed high values ranged from (1820 - 17762) mg/L.This study showed that the marsh were well oxygenated due to the dissolved oxygen values which ranged from 7 - 12 mg/L, the study recorded values to BOD5 were ranging from (1.5 - 3)mg/L, and the marsh classified as very hard according to the total hardness values from (6980 - 825) CaCo3 mg/L. The high perecentage of organic matter in the sediment was 2.7 %. The results showed the station were characterized by sediment texture varied from silt clay sand sediment in the stations 1, 4, 5 , silt clay in St(2) and sand silt in St(3), sand clay silt in St(6).A total of 21286 individual benthic invertebrates was sorted, which represents which 78 taxonomic units, including 9 taxa. The Crustacea was the dominate group representing 29% of the total number of benthic invertebrates. It was noted that there were obvious differences in the total number of sorted individuals in which varied in each location and each month. The highest total number recorded in was st (2) was 4360 including 73 taxonomic units, while the highest total number recorded in April was 2624.The results of The relative abundance index showed that the species insects : Polypedilum sp Were more abundant in St(2 - 6), and dominant in St(6), while the Seinura sp were dominant in St(6), while the other taxonomy units varied from less abundant to rare abundant. Also the results of constancy index showed The which were considered "constant " However the other taxonomy units varied from "accessory " and" accidental" taxonomy units in study stations.The Shanon - Weiner index of totall benthic invertebrates varied from (1.2 - 3.8) bit/Ind, The uniformity index of benthic invertebrates varied from(0.7 - 1), these high values indicate that there is no ecological stress on benthic invertebrates in the study area.The Results of Jaccard Presence - community of similarity showed the highest degree of similarity to be 96% which recorded between St(1) and St(2).The values of the index of spcies richness varied from 1.3 - 15 with the greatest values recorded in April while lower values were in October.Six species of Turbellarian Platyhelminthes that were recorded, from which Stenostomum leucops, Stenostomum bryophilum, Stenostomum unicolor, Gyratrix hermaphrodites, Macrostomum sp, Dalyelliidae, which were considered as new records for Iraq, with Gyratrix hermaphrodites as the most abundant species and representing 25% of the total number of Turbellarian. It was noted that there were obvious differences in the total number of sorted individuals which varied in each location and each month, the highest total number recorded in St 3 was 400, while the highest total number recorded in November was (198).The present study result showed that three species of Nematoda were recorded incuding Seinura sp, Alaimus sp, Dorylaimus sp, Seinura sp as the most abundent species representing 84% of the total number of Nematoda. Spatially the highest total number of 590 individuals was recorded in St (4) , while temporally, the highest total number of 366 was recorded in October.One unidentified species of Gastrotricha was recorded for the first time in Iraq, 102 Ind were sorted these were considered "constant" recording to constancy index 63.8% which were sorted from all stations.A total of 2319 individuals of Rotifera was sorted, these were identified as 15 species that included Philodina sp, Rotaria citrinus, Dipleuchlanis sp, Euchlanis sp, Notholca sp, Ttriploeuchlainis sp, Colurella sp, Lepadella sp, Lecane sp, Proales sp, Cephalodela sp, Synchaeta sp, Hexarthra mira, and finally Brachionus sp which was recorded the highest number of individuals 540 individuals.A total of 1888 individual Annelida were sorted representing 12 species including nine species belonging to the family Naididae (three belong to the sub family Naidinae and six belonging to Tubificoid worms), two species belonged to Aleosomatidae including Aeolosoma hemprichi, Aeolosoma variegatum, and finaly one specie belong to Hirudinea which was Glossiphonia heteroclite, with three 3 ind in all study.The family Aleosomatidae recorded the highest percentage of 58% of the total number of Annelida.The sub family Naidinae including Paranais litoralis, Dero (Aulophorus) furcata, Stylaria lactustris.The highest frequency of 23.6% was recorded by P. litoralis.The Tubificoid worms represent six species which were Limnodrlius hoffmeisteri, Limnodrlius profundicola, L. claparedeianus, L udekemianus, Tubifex tubifex, Branchiura sowerbyi. This study also isolated 6238 individual Crustacea, these were identified as 15 species that included five species belonged to Cladocera, four order belong to copepod, which were recorded the highest percentage 30% of the total number of Crustacea, in addition to Macrobrachium nipponense from Decapoda, Sphaeroma annadalei anndalei from Isopoda, Ostracoda, Amphipoda, Conchostracha. It was noted that there was obvious differences in the total number of sorted individuals which varied in each location and each month, The highest total number recorded in st (2) was 1480, while the highest total number of 730 was recorded in April. The study finds 4297 individual insects groups, were sorted represent seven order includes larvae of Ephemeroptera, Trichoptera, Odonata, (Zygoptera, Anisoptera) Diptera (Culicidae, Chironomus sp, Polypedilum sp) Lepidoptera larvae Hemiptera (Corixidae, Nepa cinerea), and adult of Coleoptera (Dysitidae, Hydrophilidae Elmidae, Curculionidae, Coleoptera larvae), the Diptera larvae were recorded the highest percentage 55 % of the total number of insects groups, and Nepa cinerea was considered as new records for Iraq.This study showed two class from Mollusca, 1956 Ind were sorted, including Gastropoda and Pelecyopoda.The Gastropoda which were recorded the highest percentage 94% of the total number of Mollusca, these were identified to physa acuta, Lymnaea sp, Melonoides tuberculata, Melnopsis nodosa, Theodoxus sp, physa acuta which was the greatest percentage 41% of the total number of gastropoda. pelecyopoda which were including Pseudodontopsis euphraticus, Tigridis Unio, Corbicula fluminea, Corbicula fluminali

دراسة تشخيصية جزيئية ودمية وكيموحيوية لانواع الاكريات Eimeria spp. في الدجاج المصاب طبيعيا وتجريبيا في محافظة الديوانية Molecular Diagnosis Study And Haematological And Biochemical of Coccidiosis Eimeria Spp. In Natural And Experimental Infection Chicken In Al - Diwanyia City

اسم المؤلف: خالد ثامر مطر الشيباني
اسم المشرف: خيري عبد الله داود العكيلي
الموضوع العام: علوم الحياة
السنة: 2014
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة في البيت الحيواني التابع لقسم علوم الحياة / كلية التربية / جامعة القادسية للمدة من 1/9/2013 ولغاية 1/9/2014، للتحري عن انواع طفيلي الاكريات المتطفلة على الدجاج المصاب طبيعيا وعزل الطفيلي من الحالات المصابة الواردة الى المسستشفى البيطري | The study conducted in The animal house of the Biology department, College of Education, University of Al - Qadisiyah during the period from 1/9/2013 to 1/9/2014. The study diagnosed the species of Eimeria parasites in naturally infected chickens in poultry farms. Eimeria oocysts was isolated from the infected chickens feaces in Veterinary hospital and Veterinary clinics.Then, the cases diagnosed initially in the laboratory by direct examining stool smears and the positive cases were recorded.Through this study, oocysts were isolated, and two species of Eimeria parasites were diagnosed (E.tenella and E.maxima) by using the technique of Conventional Polymerase Chain Reaction technique.There are 186 cases of infected chicken which examined, and the results showed that (186 out of 315)stool Samples(59%), include infected with two species of Eimeria parasites E.tenella was in (135 out of 186, 72.5%) while the species E.maxima was in(51 out of 186, 27.4%). The experimental study was conducting two experiments were done.The first experiment, depend on the experimental infection of E.tenella species which was used for two types of chicken, (Ross type which is foreign, and local breed).The second experiment, includes experimental infection with the species E.maxima also in two types of chickens that mention above. Symptoms and clinical signs of the first experiment on foreign chickens included were recorded it is noticed that infected the chickens with E.tenella have was dull, unorganized feather and loss of appetite in addition to bloody diahrreha, loss weight, emaciated and isolated. The Gross Lesions include congestion of cecum and an increase in their sizes while inside the cecum, many ulcerated lesions were noticed, filling cecum with mucus and blood, liver was congested and enlarged. Microscopicale examination recorded congestion was full with blood cells and necrotic tissues cecum and falling of cells in the cecum lumen. Many different stages of the parasites were noticed as schizonts, merozoites, gametes and oocysts Hematological parameters showed high significant decrease (p?0.05) in Hb (0.38±5.94 mg / 100ml) in the fourth week of infection, PCV (0.68±18.47%) in the fifth week and RBC was (1.58±0.02x106) in the fourth week. Also, the infection led to significant increase difference of WBC (30.19±0.95x103) in the seventh week of infection in comparison of uninfected chickens of the control sample. The biochemical parameters of blood serum showed that significant decrease (p?0.05) in glucose concentration (156.98±1.75mg / 100ml in the fourth week of infection), cholesterol concentration and total protein concentration (62.11±4.40, 1.92±0.92 mg / 100ml respectively in the fifth week of infection).Also, Uric acid increased significantly (p?0.05) to reach(10.19±0.52mg / 100ml) in the fourth week of infection in comparison of uninfected chickens of the control group. Average weight was showed the significant decrease (p?0.05) of the chickens quantity (368.88±3.01gr in the fourth week of the infection), and an increase the percentage of mortality(23.33±0.23% in the fifth week of infection), addition to the decrease of consuming food by bird (282.8±2.19gr in the fifth week of the infection) in comparison of uninfected chickens of the control group. While the results of local breed chickens in the first experiment were less severity than that with the foreign type (Ross) but the colour of the stool was brown mixed with blood. The Gross Lesions showed pathological changes in the cecum as congestion and bleeding. Moreover, ulcers areas were smaller and less in number in comparison with the infected foreign chickens by the same parasite. The microscopic pathological changes of E.tenella in the cecum showed hyperplasia in goblet cells and congestion of blood capillaries with less number of stages of the parasite in comparison with the foreign chickens. The hematological parameters showed significant decrease (p?0.05) in Hb concentration and percentage of PCV (7.13±0.31mg/100ml, 21.26±1.82% respectively in the fifth week of infection), while the RBC count was (2.05±0.12 x 106 in the fourth week of infection and significant increased (p?0.05) in WBC count was (30.63±0.38 x 106 the sixth week of infection) in comparison with the chickens of the control group. The biochemical parameters of blood serum showed the significant decrease (p?0.05) in glucose concentration (169.60±2.16mg/100ml in the fifth week of infection), cholesterol concentration and total protein concentration (70.89±2.01, 2.25±0.39mg/100ml respectively in the fourth week of infection). Uric acid increased significantly (p?0.05) to reach (7.62±0.90mg/100ml) in the fifth week of infection in comparison with the control group. Average of the weight was significant decrease (p?0.05) (190.28±3.81gm), high increase in the average of mortality (10±0.20%), and high decrease in the consuming food average (413.4±3.91gr) in the fourth week of infection in comparison with the uninfected control group. The second experiment of the foreign chicken which infected experimentally by E.maxima showed asymptoms and clinical signs were nearly similar in the foreign chickens that infected with E.tenella, but mild in severity is average. The symptoms include fatigue, fallen wings, loss of appetite, mucus diarhea mixed with blood. The Gross Lesions showed severe changes in the infected part of intestine as congestion and filling of intestine with mucous secretion of bad odour. While the microscopic pathological changes showed the tissues section of intestine were damaged, necrosis of intestine villi due to the large number of different stages of the parasite with hyperplasia of goblet cells. The hematological parameters showed significanty decrease (p?0.05) in Hb concentration, percentage of PCV and RBC count (7.55±0.61mg/100ml, 23.62±0.81% and 2.08±0.10x106 in the fourth week of infection) and significant increased (p?0.05)in WBC count (31.26±0.63x106 in the seventh week of infection) in comparison with the uninfection control group. The biochemical parameters of blood serum showed that there was the significant decrease (p?0.05) in glucose concentration (164.86±2.11 mg /100ml in the fifth week of infection), cholestrol concentration and total protein (77.14± 3.38, 2.24±0.36 mg/100ml) and significant increased (p?0.05) in Uric acid concentration (8.20±0.79mg/100ml) in the fourth week of infection in comparison to the control group. The results of productive characteristics refered to significant decrease(p?0.05) in the weight of chickens (479.28±0.23gr) and significant increase (p?0.05) in mortality (10±0.11%) during the fifth week of infection. Also, there was significant decrease (p?0.05) in the consumed food by birds (368.5±2.10gr) during the fourth week of infection in comparison to the chicken of the control group. While the results of local breed chicken in the second experiment, the symptoms and clinical signs showed no sign of disease, and the chickens were active in spite of presence of infection and the releasing of Oocysts. The Gross Lesions showed the inflammation and congestion, onlargment of the infected part of small intestine, little mucous and liquid inside the lumen.As far as microscopic changes are concerned, the tissue examination showed some necrosis and damage of the villi ends and an increase in the size of the goblet cells. Hematological parameters showed to the significant decrease (p?0.05) in Hb concentration and percentage of PCV (7.86±0.45 mg/100ml, 23.60±0.53% respectively during the fifth week of infection), RBC count (2.10±0.13 x 106 in the fourth week of infection) and significant increased (p?0.05) in WBC count (32.98±0.58 x 106 during the sixth week of infection) in comparison with the control group. The biochemical parameters of blood serum showed that there was the significant decrease (p?0.05)in glucose concentration and cholestrol concentration (170.60 ±2.01, 79.70±2.69 mg/100ml respectively in the fourth week of infection), total protein concentration (2.42±0.31mg/100ml in the fifth week of infection) and significant increased (p?0.05) in Uric acid concentration (6.52±0.82mg/100ml in the fourth week of infection) in comparison to the uninfection control group. Average of the weight referred to significant decrease (p?0.05) of chickens (213.16±3.12 gr) and consuming food (481±3.21 gr) during the fourth week of infection.While there were no differnces in the percentage of mortality comparison with the uninfected chicken of the control group. Also, the results of the number of released oocysts showed significant increase (p?0.05)in number of released oocysts with stool by infected foreign ckicken(Ross) in comparison with the local breed chicken which infected by the same parasite.Also, the number of the dropped oocysts of E.tenella were higher than that of E.maxima.

دراسة بعض جوانب الاداء الحياتي لبعض الحشرات ذات الاهمية الجنائية في مدينة الديوانية A Study of Some Biological Aspects of Forensically Important Insects In Al - Diwaniya City

اسم المؤلف: عباس كاظم حمزة الشيباني
اسم المشرف: سعدي محمد هلال
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - الحشرات
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: The present study was aimed to identify the most forensically important insects species in addition to their distribution and abundance in the Al - Diwaniya province, also the succession pattern on carrion in urban and rural areas in different seasons was studied. The present study included some experiments on the effect of the quality and quantity of food on the development of some blow flies, the effect of rearing on food spiked with different concentration of Paracetamol and Amitriptyline drugs on some biologicalaspects of the blow flies, The result showed the following : ? When using fly sex - attractant poisoned bait used in the field, six dipterans flies were identified : 1 - Calliphora vicina 2 - Lucilia sericata 3 - Chrysomya albiceps 4 - Ch. Megacephala 5 - Sarcophaga africa 6 - Musca domestica the last species was the most abundant during all seasons of the year. However, when natural food bait was used, the same species of flies were recorded in addition to three species of beetles : 1 - Dermestes maculates 2 - Saprinus semistriatus 3 - Necrobia rufipes. the results also showed that the daily activity of different flies species was the varied according to ambient temperature during the day andthere was no activity recording for the flies during the night. ? The succession of insects on rabbit carrion in the urban and rural area in winter season showed that the most abundant fly species attacking the carrion during the active stage, these flies were : : 1 - C. vicina 2 - L. sericata 3 - Ch. albiceps 4 - Ch. megacephala in addition to S. africa, M. domestica and three beetles namely : 1 - D. maculates 2 - S. semistriatus 3 - N. rufipes especially during the late stage of decaying, and recoded fly : Eristalis aeneus (Diptera) accidentally appeared on the carrion. However, less number of fly species were recorded on rabbit carcass during summer season.? In general the present study showed fly species : C. vicina and L. sericata Their numbers in urban area were more than the rural area (urban species) while fly species S. africa was rural species. ? 4) skeletonization time of the rabbit carcass during summer season was three times faster than it was in winter season in both locations, urban and rural.? When C. vicina larvae reared on different animal tissues, the result showed that there were a significant differences between means of larvae weight and development time and in the emergence of adults from pupal stage, thus, the average weight of larvae was 2337 mg 2101 mg when reared on lung and liver tissues as a compared with 998.6, 1194 and 1278 mg when reared on kidney, brain and muscles after eight days of exp - Time. However the longest development period of larvae were : 10.6, 10.3 and 9.3 days and pupae 7.3, 7 and 6.6 days when reared on kidney, brain and muscles respectively, as a compared with : 7.3, 7.6 and 8 days(larvae) 5.3, 5.6 and 6 days (pupae) reared on lung, liver and heart respectively (P? 0.05).The highest emergence percentage of adult were 46.6% and 40% in the lung and liver tissues. ? Larvae of C. vicina reared on 25 and 50gm beef liver /10 larvae were 83.2 and 75.6 mg respectively compared with 67.1 reared on 100gm/10 larvae during the first four days of the experiment. However, the duration period of larvae and pupae were 10.3 and 8 days when reared on 100gm respectively, the highest emergence percentage of adults were 46% and 26.6% for larvae reared on 25 and 50gm of liver. ? Larvae of C. vicina reared on spiked liver with different concentration of Amitriptyline were significantly different to those in the control treatment, the highest means weight of larvae was 1615.3 and1474 mg when reared on liver spiked with 1.25 and o.125mg ofamitriptyline/25gmliver/5larvae respectively the lowest weight mean of larva was 1112 and 1264.6mg when reared on liver spiked with 0.025 and 0.0mg(control) respectively. The development period of larvae and pupa of C. vicina were 14.6 and 10.3 days respectively when reared on liver spiked with 1.25mg of Amitriptyline compared with 9.6 and 6.3 days in the control treatment(p>0.05).The highest percentage of adults emergence 40% was in the control treatment compared with only 13.3 when larvae reared on liver spiked with 1.25mg.amitriptyline. ? Larvae of C. vicina reared on beef liver spiked with different concentrations of Paracetamol showed different results. The highest mean weight of larva was 1735.3mg when reared on beef liver spiked with 25mg/5 larvae compared with 867.3mg in the control treatment, the development period of larvae and pupae were 12.6 and 8.6 days respectively as a compared with 9.3 and 6.3 days in the control treatment. The percentage of adults emergence was 46.6% in the control treatment compared with 13.3% in the highest concentration of drug ? The results also showed that there is a significant increase in the mean weight of larvae reared on different tissues of rabbits oral dosage with lethal dose of Amitriptyline, in the contrary weight of larvae reared on tissues of rabbits orally dosage with lethal dose of Paracetamol were decreased(p>0.05) as a compared with untreated rabbit tissues (rabbit was not dosage - control).

دراسة تصنيفية حياتية مقارنة لانواع من الجنس Euphorbia L. (Euphorbiaceae) في العراق A Comparative Biosystematic Study of Some Species of The Genus Euphorbia L. (Euphorbiaceae) In Iraq

اسم المؤلف: ازهار طاهر صليبي
اسم المشرف: عذية ناهي سلمان المشهداني
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تناول البحث الحالي دراسة تصنيفية مقارنة لثلاث وعشرين مرتبة تصنيفية تعود جميعها للجنس Euphorbia L. من العائلةEuphorbiaceae النامية في العراق، تضمنت الجوانب المظهرية العامة والدقيقة ودراسة حبوب اللقاح والمركبات الكيميائية والبيئة والتوزيع الجغرافي فضلا عن ا | The current research deal with twenty - three taxa belong to the genus Euphorbia L., Family Euphorbiaceae grown in Iraq. The study included the gross general morphological and micromorphological characters, the Pollen grains also studied and the chemical compounds, Ecological and geographical distribution and taxonomic treatment have done.Also botanical key was putted to separate the species. General survey for the Phytogeographical districts where the taxa spread in, and the result was a large crowds of samples, and new locations of taxa distribution were recorded. The specimens studied, and correct the mistake naming, specimens were identified and reidentified some miss identified specimens in the Iraqi herbaria. A comparative morphological study was undertaken to all plants parts of taxa appeared from habit and duration of taxa to the quantitative and qualitative attributes the members of the vegetative and floral parts included the roots, stems, leaves, stipules, flowering parts and fruiting parts and drew charts diagrams, tables and accompanying with natural images for different morphological characteristics, as well as the field images. This study showed that all species was herbs, shrubs and succulent and semisucculent annual and perinnal, the major taxonomic importance was for flowering parts includeing the specific Inflorescence, installation of a cupped and its regularity on the branches of the plant, glands forms, numbers, presence or lack of appendages, bractes and bracteoles shapes, dimensions and color fruits shape, indumentum and seeds forms, dimension and her surface sculpturing; and the presence or lack of caruncle, as well as the qualities of roots, stems and leaves, and the morphological characteristics of all plant parts mentioned above have a taxonomic importance in identification and separation of the studied taxa. The study of the micromorphological characters of hairs, leaves epidermal cells and the stomatal complex which included anomocytic, paracytic, anisocytic and tetracytic, have a taxonomic importance of supporting the morphological characters in separation and identification of the genus taxa.The pollen grains have a taxonomic importance because their different in shape, dimensions of polar and equatorial view, the wall thickness and their ornamentation. They are mostly of Tricolporate except two species were Hexacolporate, also the differences in their shape in the polar and equatorial view.They were spheroidal, ovoid and oblate - spheroidal in the polar view and oblate, spheroidal, subprolate and oblate - spheroidal in the equatorial view.The ornomentation they were reticulate, microreticulate and foveoate.The chemical study also importance in separation of the genus taxa four compounds Flavonoids diagnosed in all the studing species but different in concentrations, by using HPLC, they are Myriscetin, Quercetin, Kaempferol and Coumarin esculetin and this confirms that there are a common evolutionary link between the species in terms of their chemical properties, which suggests belonging species to the genus Euphorbia.Through field surveys and information installed on the herbarium samples, the taxa where distributed on their growth areas, and maps have been drawn for taxa distribution in the Iraqi natural geographical districts. the species of Euphorbia were distributed in all Iraqi districts especially in LCA, MSU, MRO, and DWD and some species were farmed in gardens and nurseries either to the beauty of their bractes colors or because their acceleration to the environmental changes such as succulent species, As well as wild species were spread in mountainous areas, oak, nuts forests, in orchards, cultivated fields, flat plains and desert areas in loam soils, clay, gravel, and sand. Through this study some new taxa where founded in Iraq and they are E. cyparissias Kunth ; E. maculata L. ; E. serpens L. ; E. tirucalli L., and this study suggests to recorded them for the first time in Iraq.

تاثير بعض العوامل البيئية على نمو الاحياء الدقيقة في بعض القاعات الانتاجية لمصنع ادوية سامراء The Effect of Some Ecological Factors on The Growth of Microorganisms in Some Production Units in Sammara Drug Industry (SDI)

اسم المؤلف: خالد محمد عباس
اسم المشرف: حميد سلمان خميس المهداوي
الموضوع العام: علوم الحياة
السنة: 2008
الموضوع الدقيق: علوم الحياة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تم دراسة الظروف الطبيعية الموجودة في القاعات الانتاجية لمصنع ادوية سامراء من خلال العوامل البيئية التي شملت الحرارة، والرطوبة النسبية. وشدة الاضاءة واعداد حجم الدقائق العالقة في الهواء وتاثيرها على الاحياء المجهرية الموجودة في القاعات الانتاجية حيث تم اخذ | The natural environmental conditions existing in the production units of Sammara drug company have been studied. Environmental factors included, temperature, relative humidity, light intensity as well as number and size of suspended particles in the air. From December 2006 through June 2007. 87 sampling visit was made during which 384 swabs were collected from three production buildings : Ibn - Hayan, Ibn - Sina and Al - Zahrawy. Results showed that at different temperature levels during this study dominance of bacterial colony over fungal colony in two buildings Ibn - Hayan and Ibn - Sina, was observed, whereas the dominance of fungal colony over bacterial colony in Al - Zahrawy building was noticed. While the effect of relative humidity on microorganisms showed that in Ibn - Hayan building at low relative humidity (41 - 53%) the dominance of bacterial colony over fungal colony whereas the dominance of fungal colony on bacterial colony at relative humidity (53 - 62%). While in Ibn - Sina building bacterial colony dominante fungal colony except at high relative humidity (63 - 73%), where the fungal colony dominance. The same pattern have shown in Al - Zahrawy building at low relative humidity less than 51% while fungal colony exceeded bacterial colony at high relative Humidity. Result of the effect of light intensity showed that the low light intensity have greater effect on fungal colony than bacterial colony this clear in Ibn - Hayan and Ibn - Sina buildings whereas increases in light intensity showed the reverse while the low light intensity in Al - Zahrawy building shown different effects which the dominance of fungal colony over bacterial colony. This perhaps reflects the different species of fungal colony in production units.The effect of the number and the size of 0.3 micron of particulates on bacterial and fungal colony was also examined. It has been noticed that the dominance of bacterial colony over fungal colony until the number of particulates 49000/foot3 in Ibn - Hayan building, while fungal colony appeared in most swabs in Ibn - sina building, but dominancy for bacterial colony. While in Al - Zahrawy building the swabs showed clear appearance for fungal colony, but some swabs shown high bacterial growth. The effect of 0.5 micron particulates showed that the dominance of bacterial colony with increased number of particulates in Ibn - Hayan building. The same pattern was shown in Ibn - Sina building, while in Al - Zahrawy building it has been the dominances of bacterial colony until 15000/foot3, but with increase in number fungal colony appear very clear. The following bacteria and fungi were identified during the course of this study; Staphylococcus, E.coli and a low genera of fungi like Penicillium, Aspergillus, Mucor. It has been shown by the collected swabs that the contamination with bacteria and fungi of drug production units never exceeded the standard limits set by the company except in very rare occasions the high contamination rate occurred in the hands of workers and delivery boxes in Ibn - Sina building.

دراسة بيئية وسكانية للقوقع الارضي Candidula gigaxii (L.Pfeiffer, 1850) (Pulmonata : Hygromiidae) في مواقع مختارة من محافظة بغداد Ecological And Population Study of The Land Snail Candidula Gigaxii (L.Pfeiffer, 1850) (Pulmonata : Hygromiidae) In Selected Locations From Baghdad Province

اسم المؤلف: بشرى محمد كاظم ديوان البيضاني
اسم المشرف: عماد الدين عبد الهادي المختار
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: Few studies on terrestrial snails in general, and garden snails in particular, existin Iraq. The group being important apparently for its wide - spread distribution in various habitats. One species of this group which has been previously recorded in Baghdad, is the garden snail Candidula gigaxii, class : Pulmonata, family : Hygromiidae.Available samples of the land snail C.gigaxii were collected from four locations within Baghdad province; a Taji, the Army Canal area, the Zafaraniyah, and Al - Jadiriya district, the study period of June 2013 to May of 2014.Environmental measurements were recordedat each site. Results showed that air temperature range was 10 - 34? C, soil temperature range was 5 - 26? C, pH range of the soil was between 4 - 8.9 and the content of the soil organic matter was between 0.3 - 2.0%.Snail samples were divided into seven size - classes according to the dimension of the shell and these were <2, 2 - 4, 4 - 6, 6 - 8, 8 - 10, 10 - 12, >12 mmPercentages of each size class were calculated. Having measured shell dimensions, shell growth index (Ia) was also calculated. The range of growth index value for this snail was 1.9 - 3.86 where the highest value was recorded at the Taji site in January 2014 which was probably attributed to low temperature range and high soil moisture and organic matter content.Results also showed that C. gigaxii favored soils with moderately high pH values and rich in organic content. Soil moisture appeared to be a limiting factor for growth; and a loamy soil texture for existence of the studied species. Average highest population density of living snails and empty shells were 44 and 32 individuals / m2 respectively. The overall population density was also calculated for the purpose of obtaining realistic population density of the species.

تاثير الاصابة بالاكياس المائية Hydatid cysts على مستويات مضادات الاكسدة في مصول المصابين The Effect of Hydatid Cysts Infection On Antioxidant Levels In Serum of Infected Individuals

اسم المؤلف: مريم ماجد محمد النصراوي
اسم المشرف: نغم ياسين كاظم البياتي
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: اجريت الدراسة الحالية في محافظة ديالى اذ تم جمع 100 عينة من اشخاص مصابين وغير مصابين بداء الاكياس المائية للفترة من 2013/10/1 الى 2014/8/10 من مناطق مختلفة تابعة لمحافظة ديالى والتي شملت (حمرين، المقدادية، قزانية، بعقوبة)، وقد توزعت العينات بواقع 54 من ا | The present study was carried out in Diyala province during the period from 1/10/2013 to 01/08/2014 in different areas including : Hamrin, Muqdadiyah, Kasaniya, and Baquba.Blood samples were collected from one hundred individuals who are at risk of hydatid cyst infection (veterinarians, shepherds, farmers, butchers and housewives).The diagnosis of hydatid cyst infection was carried out by Echinococcus IgG ELISA kit. It was shown that the total rate of infection was 16% (6% for male, and 10% for female). The study revealed that the highest percentage of infection was in individual live in urban compared with those who live in rural area.The mean concentrations of antioxidants ; glutathion, catalase and superoxide dismutase were measured in addition to measure the mean concentration of the oxidants.The results showed the presence of malondialdehyde in the serum of studied individuals. The results showed a decrease in the level of glutathion catalase and super oxide dismutase in infected individuals (0.0048±0.0596mmol/L, 0.0220±0.0260mmol/L, 0.0024±0.04430 mmol/L, respectively) compared with non - infected individuals (0.0237±0.2719mmol/L, 0.0024±0.0879mmol/L, 0.0428±0.3069mmol/L, respectively) while there was an increase in concentration of malondialdehyde (0.2245±2.915mmol/L) compared with non - infected (0.025±0.8042mmol/L). There was no significant differences in the concentrations of all these parameters according to age, sex and location of the cysts. The results showed that there was no correlation between each of catalase and superoxide dismutase and the malondialdehyde whil there was a negative correlation between glutathion and malondialdehyde. The study concludes that the infection of hydatid cyst leads to a decrease in antioxidants and to an increase in oxidants which may indicate that there was a damage caused by tissue infection.

انتاج وتوصيف متعدد السكريات الخارج خلوي Lactobacillus plantarum من بكتريا Exopolysaccharide المعزولة محليا ودراسة فعاليته البيولوجية Production And Characterization of Exopolysaccharide (EPS) From Locally Isolated Lactobacillus Plantarum And Studying Its Biological Activity

اسم المؤلف: بيداء مهدي عباس الغانمي
اسم المشرف: ناجح هاشم كاظم الظويهري
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: كربلاء
الصفحات الاولى:
المستخلص: Twenty - five isolates of Bacillus spp. Were isolated from 15 soil samples collected from different places in the Holly city of Kerbala, 13 isolates lactobacillus spp. Were isolated from 15 milk products and 7 isolates pseudomonas spp. The isolates were screened for their ability to produce Exopolysaccharide.The results showed that isolate number 3 (Lactobacillus lac 3) was found to give the highest production of the polymer, the isolate has been identified as lactobacillus plantarum. The optimal cultural and environmental conditions for EPS production were been identified which include using the production medium (simplified synthetic medium) containing date juice (5%) as a carbon source and yeast extract (0.2%) as a nitrogen source, the media was enhanced with a total concentration 0.9% of magnesium sulphate and potassium phosphate as mineral salts. The primary pH was adjusted to 6.5 and the inoculum size was 3%(v/v), isolates were grown under anaerobic condition at 35 Co for 24 h and the EPS extracted with ethanol 95%. Two steps were used for partial purification of the polymer as follows, the first step by using TriChloroAcitic acid (TCA) solvent and the second step by dialysis. The yields were (77.4 and 63.8)% for the two purification steps respectively. The biological activity of the EPS extraction from L. plantarum has been tested against some species of G+ve and G - ve bacteria and some fungal. The results showed that EPS extrac exhibits an inhibitory activity against Stenotrophomonas, Bacillus cereus and Proteus bacteria with an inhibition zone diameter of 23, 21, 19 mm respectively. While, there was no inhibitory effect against fungi. Antioxidant activity has also been tested, where IC50 value against ABTS free radical at 100 Mg / ml. The characterization of partially purified EPS is investigated by using Fourier Transform Infrared Spectroscopy (F.T.I.R). The molecular weight of the polymer was also measured by using viscometer and the molecular weight obtained by this technique was 2.3 *105 Dalton. The EPS extraction from selected isolate showed two spots when separated by Thin Layer Chromatography (TLC) which is analyzed as a glucose and galacto

دراسة تصنيفية لحشرات عائلة الخنافس الرواغة Staphylinidae : Coleoptera في بعض محافظات العراق

اسم المؤلف: كاظم عادل هادي
اسم المشرف: سعدون ابراهيم اسماعيل
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - الحشرات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:

تاثير المستخلصات المائية والكحولية لنباتات ليمون البصرة والرمان والبلوط على البكتريا المسببة للاسهال The Effect of Aqueous And Alcoholic Extracts of The Plants (Aurantifolia Varacidica, Punica Granatum, And Quercus Robur) On The Bacteria Causing Diarrhea

اسم المؤلف: نور جبار احمد علي
اسم المشرف: نجم عبد الله جمعة الزبيدي
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: اجريت الدراسة في محافظة ديالى للمدة من 17 اب 2014 ولغاية 15 شباط 2015, اذ اخذت اربع عزلات جرثومية جاهزة بعد عزلها من حالات مرض الاسهال وهي Proteus mirabilis وKlebseilla pneumonia وEscherichia coli وSalmonella typhimurium0تناولت الدراسة تاثير مستخلصات نب | This study was conducted in Diyalaprovince during the period that lasted from 17 August, 2014 to 15 February 2015, four ready bacterial isolates were taken after isolating them from diarrhea disease cases and then they were diagnosed by the bactriology in the bacteriology lab/ Baqubah teaching hospital.The isolates were : Salmonella typhimurum, Escherichia coli, Klebseilla pnumonia, and Proteus mirabilis. The study investagated the effect of the plants extracts of Punicagranatum, Quercusrobur, and aurantifoliavaracidica Citrus on the bacterial isolates that caused diarrhea.The bacterial isolates showed a various sensitivity toward the plants extracts. The sensitivity of isolates against extracts were to alcoholic extract, hot aqueous extracts cold water extracts of all the plants used in the study The study showed that plant extract ofQuercusroburwas the more effect on the growth of the bacterial isolates Punicagranatum extractsand extract of Aurantifoliavaracidica respectively. The high inhibition zone concentration were at 100 and 80 mg /ml. The isolates that had moer sensitivity toward the plants extracts were : Klebseilla pnumonia, Salmonella typhimurum, Proteus mirabilis and Escherichia coli respectively. The study investigated with the qualitative and quantitative of active compounds found in the plants extracts used in the study. The result showed that the plant were rich of many secondary metabolic compounds like : (Taninat, clycosides, flavonoids, alkaloids, pheonols and saponins) Also, the present study showed the toxid effect of the aqueous and alcoholic extracts on the red blood cells. it showed also that there was cytotoxic of the cold and hot aqueous extract for all the plants used in the study. The result showed the resistant of the bacterial isolates against some antibiotics such as Ciprofloxacin, Cefotaxime, Amikacin, trimethoprim, Gentamicin and Nalidixic acid. The study showed that the bacterial isolates had a highest ratio of resistance against the antibiotics Amikacin, Trimethoprim, and Cefotaxime

دراســــة الفعالية التضادية لجرثومة Bifidobacterium spp تجاه جرثومة Staphylococcus aureus المقاومة للمثيسلين Studying The Antagonistic Activity of Bacteria Bifidobacterium Spp Against Bacteria Methicillin Resistance Staphylococcus Aureus

اسم المؤلف: انغام نجاح هادي الخفاجي
اسم المشرف: سهام جاسم الكعبي
الموضوع العام: علوم الحياة
السنة: 2014
الموضوع الدقيق: الاحياء المجهرية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: النجف
الصفحات الاولى:
المستخلص: تضمنت هذه الدراسة التحري عن الفعالية التضادية لجرثومة Bifidobacterium spp تجاه عزلات سريرية لجرثومة Staphylococcus aureus المقاومة للمثيسلين، ودراسة تاثير تلك المواد على عوامل الضراوة المنتجة من قبل S.aureus المقاومة للمثيسلين مثل الغشاء الحيوي Biofilm وا | This study included the investigation of Bifidobacterium spp antagonistic activity against Staphylococcus aureus isolates, and the effect of these antimicrobial agent on virulence factors produce by MRSA (Methicillin Resistance Staphylococcus aureus) such as Biofilm and Slime layer. One handered different samples were collected to isolate Bifidobacterium spp and 50 clinical isolates of Staphylococcus aureus from clinical specimens in AL - Najaf AL - Asharaf governorate during the period of (10/10/2013 - 20/1/2014) by the cultural characteristic colonies, microscopic for cells, biochemical tests and polymerase chain reaction PCR technique to detect 16SrDNA, the results showed that 13 isolates belong to Bifidobacterium spp and there are divergent gene content between these isolates and they have been bearing lm26/ lm3 gene. Carbohydrate fermentation test was used to distinguish the species of Bifidobacterium, the results revealed that the B.bifidum is more predominant than the other species; B.thermoacidophilum, B.adolescentis, B.breve, B.longum. Antibiotics susceptibility test to Staphylococcus aureus using antibiotic disc diffusion assay showed that Methicillin Resistant Staphylococcus aureus formed 70% and 30% of isolates were sensitive to the same antibiotics, also the ability of MRSA isolates to produce Biofilm and Slime layer was investigated by tube method and Congo red agar, then 10 isolates of Staphylococcus aureus were selected as efficient isolates according to the resistance of Methicillin and the high ability to produce biofilm and Slime layer. The antagonistic activity of Bifidobacterium spp was extracted and tested against these MRSA isolates, the results showed that the most isolates of Bifidobacterium spp were effective against Methicillin Resistant Staphylococcus aureus (MRSA), as well as the inhibition of growth and formation of Slime layer by using the wells and disc diffusion agar assay. The inhibition zone was between (10 - 30)mm, and the ability of bacteriocin production of Bifidobacterium spp against MRSA have been conducted by well diffusion broth method, B.bifidum3 was greater than other species in producing bacteriocin with asignificant increase (P<0.05). Furthermore the impact of bacteriocin production to inhibit the development and formation of biofilm was investigated, the results showed that the bacteriocin has ahigh activity against MRSA. The bacteriocidal and bacteriostatic effect of bacteriocin was conducted by using spectrophotometer, the results showed that these effects were bacteriostatic in the beginning of the growth MRSA while it was lethal during other time and 40 minutes is the period needed for killing MRSA bacteria.

دراسة وبائية للانماط الجينية لطفيلي الاميبا الحالة للنسيج والجيارديا الامبيلية في منطقة الفرات الاوسط العراق

اسم المؤلف: صبا فاضل علي مهدي معلة
اسم المشرف: علي حسين مكي الكبيسي
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: كربلاء
الصفحات الاولى:
المستخلص: This study was conducted on the 1350 stool samples from diarrhea - suffering patients in three provinces of middle Euphrates region : Karbala, Babel and Al - Najaf (450 samples in each province). Patients ranged in age from 1 to more than 60 years and from both sexes and different regions who were attended to some hospitals, dispensaries and private laboratories in these provinces during the period from the first of May 2013 till the end of April 2014. All collected fresh samples were examined microscopically by wet - mounts method for G. l a mbl i a and E n ta m oeba histolytica detection One third of positive samples in microscopic examination (which was selected to be representative for all positive samples) from each province and ten of negative one as control group were submitted to the nucleic acid (DNA) extraction. Molecular diagnosis of G. l ambl i a and E. h i s to l yti ca were performed using PCR reaction with amplification of the 532 - bp and 355 - bp fragments from the internal transcribed spacer region1 ITS1 for each parasite respectively. The eluted DNA of each positive sample in ITS1 test with its specific primer was also submitted to a traditional PCR and RT - PCR techniques for detection two genes in G. l a m b l ia { Glycoprotein A Repetitions Predominant (GARP) and Adenosine Triphosphate Guanine Tri Phosphate (ATP/GTP) } and two genes in E. histolytica {Acetatekinase (ACK) and Methionine GammaLyase (MGL)} using PCR and RT - PCR techniques. Five positive PCR products in ITS1 test of G. la m blia were used for sequencing. Based on the results of this study, microscopic examination showed that the total percentages of infection with G. l am bl ia were (14.7, 17.3, 16) % and with E. histolytica were (15.1, 13.3, 16.7) % in Karbala, Babel PDF created with pdfFactory Pro trial version www.pdffactory.comand Al - Najaf respectively. The infection with G. l am bli a and E. histolytica was more frequent in males than in females and the prevalence of both parasites in rural areas was higher than the urban areas P < 0.05 in all studied provinces. The highest incidence of infection with G. lamblia occurred in age group 11 - 20 years (P < 0.01) and that with E. histolytica occurred in age group (1 - 10) years (P < 0.05) in all studied provinces. This study was revealed uneven percentages of infection with both parasites during different months of a year (P < 0.01), the highest rate of infection with G. lamb l ia and E. h i s t o l y ti ca were in summer. For the molecular diagnosis of G. l a mbl ia and E. hi s t ol y t i ca, using PCR technique, the prevalence of G. l amb l ia and E. his t o l y ti c a in middle Euphrates region were found to be 14.9 % and 12.8 % respectively. The infection with G. l a m b lia and E. hi stol y t i c a was more frequent in male (62.7, 63.8) % than in female (37.3, 36.2)%, the prevalence of the parasites in rural area (67.2, 69.0)% was higher than the urban area (32.8, 31.0) %, the highest incidence of infection occurred in age groups 1120 and 1 - 10 years with the percentages of (28.4, 29.3) %, the highest rates of infection were in August (20.9%) and July (19.0%) respectively. Significant differences were found between the rate of infection with both G. l a m bl i a and E. hi stol y t i ca and the different parameters (gender, residence, age gropes and months of a year). The results of detection the gens (GARP, ATP/GTP, ACK, MGL) by using PCR technique showed that the total percentages of positive samples were (55.0, 70.0, 45.0, 75.0) %, (62.5, 79.2, 47.0, 70.6) % and (65.2, 73.9, 61.9, 71.4) % in samples of Karbala, Babel and Al - Najaf respectively while those percentages by using RT - PCR were (60.0, 80.0, 50.0, 80.0) %, (66.7, 83.3, 58.8, 82.4) % and (65.2, 78.3, 66.7, 71.4) % respectively. For the detection of genes in G. l am bl ia, sensitivities of 91.8 % and 97.8 % and specificities of 94.6 % and PDF created with pdfFactory Pro trial version www.pdffactory.com81.4% for PCR and RT - PCR respectively were observed when compared to each others, While Sensitivities of 89.9 % and 98.6% and specificities of 97.3 % and 81.8 % for PCR and RT - PCR respectively for the detection of genes in E. hi sto l y t i c a were observed when compared to each others. Multiple sequence alignment analysis and phylogenetic analysis results of this study demonstrated that the G. l ambl ia in Middle Euphrates region - Iraq isolates had nucleotide homology sequence identity percent of 99% with Giardia intestin a l i s (AF199448.1) Australia isolate and with USA isolate Giardia microti

تاثير الاضافة الارضية والتغذية الورقية بالبوتاسيوم في بعض صفات النمو والحاصل للذرة الصفراء (Zea mays L.) Effect of Potassium Application By Soil And Foliar Fertilizer In Some Growth And Yield of Maize Zea Mays L

اسم المؤلف: هشام هاشم صالح الزبيدي
اسم المشرف: وسام مالك داود
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: نفذت هذه التجربة في المشتل التابع لمديرية زراعة محافظة ديالى خلال الموسم الخريفي لعام 2014 في تربة ذات نسجة طينية رملية بهدف معرفة تاثير الاضافة الارضية والتغذية الورقية بالبوتاسيوم في بعض المؤشرات المظهرية والفسلجية للذرة الصفراء Zea mays.L.. تضمنت التجر | This study has been achieved in a nursery that belongs to the Directorate of Agriculture of Diyala governorate in autumn 2014. The soil in which the corn is grown was Sandy clay. The aim of this study is to know the effect of Potassium application by Soil and Foliar in some morphological and Physiological Parameters of Corn (Zea mays L.) Buhooth 106. The randomize complete block design (RCBD) was conducted in this study with three replications Ground addition 80, 40, 20, 0 kg. k.ha - 1 and foliar applications (0, Spray with water, 3000 and 4000 mg k.L - 1) as Potassium sulfite (41.5% K). The results show that there are differences in the third level (40 Kg.K.ha - 1). The differences are in the Plant height (162.4 cm) , Leaf Area (518. Dsm2) , Stem diameter (10.7 cm) , Weight of 100 grains (22.7 g) , grain yield of plant (107.2 g.plant - 1), number of Leaves per plant (12.8) , ear Length (20.0 cm) number of grain per ear (641.8). number of rows per ear (16.5), dry matter of green plant (46.2.g.plant - 1) Chlorophyll index (48.7 Spade unit) and concentration of protein and Potassium in the leaves. Using K Foliar application treatment was 4000 mg.L - 1 caused Significant difference in the plant high (159.1 cm), Leaf Area (505.1 dsm2) , Steam diameter (10.7 cm) , weight of 100 grain (21.8 g) , grain Yield of plant (109.7 g.plant - 1), number of Leaves (13.0), ear Length (20.4 cm) , number of grain Per ear (633.4) number of rows per ear (16.7) , dry matter yield per plant (39.5) chlorophyll content (50.7) and concentration of protein (2.62%) and concentration of Potassium in Leaves (1.75%) The interaction between the Level 40 Kg.K - 1 as ground addition and 4000 mg.L - 1 as Foliar application gives the best results in all parameters.

التغيرات الدموية والكيموحيوية والنسجية في الدجاج المحلي المصاب تجريبيا بالقمل العاض وعلاقته بنقل طفيلي مقوسات كونداي في الدجاج Haematological, Biochemical And Histopathological Changes In Experimentally Infected Local Chickens With Biting Lice, And Its Relationship In Transmission of Toxoplasma Gondii In Chickens

اسم المؤلف: فاطمة ابراهيم محمد الليباوي
اسم المشرف: هادي مدلول حمزة الميالي
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: صممت الدراسة الحالية لمعرفة التغيرات الدموية والكيموحيوية والنسجية الناجمة عن الاصابة التجريبية بالقمل العاض Biting lice وكذلك لاثبات دور القمل في نقل طفيلي المقوسة الكوندية Toxoplasma gondiiمن الطيور المصابة الى الطيور السليمة للمدة من الاول من شهر تشرين | The current study was designed to showed the haematological, biochemical and histological changes caused by experimentally infection with biting lice, as well as to prove the role of lice in the transmission of Toxoplasma gondii parasite from infected to healthy birds for the period from November 2013 to June 2014. 30 bird were taken from the chickens local chicks Gallus gallus domesticus aged one week purchased from local markets of AL - Diwaniya city divided into three groups included of each 10 birds (two experimentally groups and one control group) it was hit by lice from naturally infected chickens and then measured blood, biochemical parameters and histological changes at the end of experiment about seven months. Then we collected 30 bird from adult local chickens Gallus gallus domestics at age greater than 4 months and infected with dense lice from markets of AL - Diwaniya city, All samples tested by serological test using Latex Agglutination Test to detects of Toxolasma gondii parasite, 17 samples were positive for Toxoplasma gondii parasite with percentage 56.66% and the highest proportion in the birds recorded at the standard 1/80 (41.17%) and the lowest proportion at standard 1/40, 1/640 reached (5.88%) for both. Four species of biting lice isolation after end of the experiment include, Menacanthus stramineus, Menacanthus cornutus, Menopon gallinae and Goniocotes gallinae at infected percentage 53.59%, 17.37%, 22.57%, 6.45% respectively. Results showed the blood parameters at end of the experiment significantly decreased in the number of red blood cells2.29(x106/mm3), packed cell volume 37.99%, Haemoglobin 9.52(g/dl) and Mean corpuscular Haemoglobin concentration 29.09(g/dl) while showed significantly increased in Mean corpuscular volume 143.23(µ/m3), Mean corpuscular Haemoglobin 47.32(pg) and blood platelets24.36(x103/mm3), and the results showed significantly increased in white blood cells count144.05(x103/mm3), percentageMonocytes 9.10%, Eosinophils4.82%, Neutrophils2.80% and significantly decreased in percentage Lymphocytes67.43%. The results showed biochemical parameters significantly decreased Glucose and Cholesterol concentration and significantly increased in uric acid and Total protein concentration and non - significantly increased in creatinin concentration. The pathological changes caused by infection in two group experiment showed abnormal behavioral changes in infected birds with lice such as instability, constant irritability as well as tweezing and the frequent use of the beak, legs and moving the wings as well as the lack of eating and decrease of weight. The results also show the occurrence pathological gross changes in the birds represented by molt of feather and appearance nacked areas free of feather as well as redness and inflammation of the areas of the skin as a result of wounds and scratches and haemorrhage as well as incidence of histological changes in each of (skin, muscle, liver, kidney, spleen, small intestine and lungs) represented by proliferation fibrous connective tissue in layer of the dermis and infiltration of inflammatory cells as well as hyperplasia in epithelial layer of the epidermis also appeared degeneration and necrosis of the muscle fibers where appeared free nuclei with infiltration of inflammatory cells out of the blood vessels in addition to the appearance bleeding within the muscle fibers in the liver there appeared congestion of central veins with loss of the geometric structure of the liver tissue and infiltration of inflammatory cells near the central vein with fatty degeneration of the liver cells as happened atrophy of the intestinal villi and crashing and alienation in the villi that lining the vertical cells. in the kidney, noted presence of severe bleeding in the renal tissue and necrosis of the cell lining of renal tubules twisted with atrophy of the renal glomeruli. in the spleen, the results showed atrophy an exhausted pulp white with severe proliferation in red pulp and incidence of hemorrhage and necrosis widely in the lymphoid tissue of the spleen. also the air sacs appeared in lungs full of red blood cells with a large clot inside a blood vessel. Finally, according to the results of molecular analysis of tissue of biting lice from species Menacanthus stramineus using conventional polymerase chain reaction PCR to the emergence of gene diagnostic B1(399bp) specific Toxoplasma gondii parasite in 12 sample of the total samples tested, about 22 samples percentage 54.54% which indicates presence of the parasite and the lice ability to transfer parasite within his body parts

التشخيص الجزيئي وخصوصية المضيف لداء الابواغ الخبيئة Cryptosporidiosis في بعض انواع الطيور البرية والداجنة ود راسة الاصابة التجريبية في الفئران البيض Molecular Diagnosis And Host Specificity For Cryptosporidiosis In Some Species of Wild And Domestic Birds And Study of Experimental Infection In White Mice

اسم المؤلف: اخلاص عباس مرهون الزبيدي
اسم المشرف: غيداء عباس جاسم الجبوري
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: The present study aimed to investigate of Cryptosporidiosis in some wild and domestic birds, and study some concerned aspect of it such as : Host specificity for Cryptosporidium spp., histo - pathological changes which parasite produced it and molecular analysis for this species. To attainment this purpose we applied our study in three major parts : The First part : Investigation of Cryptosporidium in birdsA total of 236 birds were collected from different regions of Al - Diwaniya province between May 2013 to June 2014, Birds included six species which are : 22 sample from Turkey (Meleagris gallopova), 60 from Quail (Coturnix coturnix) , 40 from Domestic chicken (Gallus gallus domesticus), 52 from Caged chicken(Gallus gallus), 32 from Common duck (Anas platyrhynchos) and 30 from Feral pigeon (Columba livia). Fecal and bile samples which took from birds were examined by used hot modified Zeihl - Nelseen stain.Results revealed that the birds were infected with two types of Cryptosporidiosis : Intestinal and Biliary Cryptosporidiosis (58.1% and 12.7% respectively).Our study recorded four species belong to Cryptosporidium be responsible for intestinal type which are : C.parvum, C.meleagridis, C.baileyi and C.galli, While just the first three species of them were be responsible for biliary type.Also results showed that no significant difference according to gender of birds in infection with two types of Cryptosporidiosis, while showed a significant difference to study's months in infection, the highest ratio of Intestinal type was in March and April (87.5% and 89.3% respectively) and the lower ratio was in July, it reached 27.8% ; While the highest ratio of biliary type was in April, it reached 39.3%.Also results revealed that all cases of Biliary type were light infection, while the severity of infection with Intestinal type was between heavy and light infection. Quail birds showed a significant difference in severity infection compared with other birds, it was higher in quail which reached 60.9% and lower in common duck(30.0%) and there was no heavy infection in feral pigeon. when reading of preparation histological sections from : intestinal, fabricious bursa and bile sac, the results showed a histological changes that parasite induced it which included : hyperplasia in infection's regions, necrosis and destroyed in infected cells with infiltration of inflammation cells.The second part : Experimental studyTo test a host specificity and to know how incidence of cross transmission of Cryptosporidium species which isolated from birds to human, therefore the laboratory mice were dosage with the four species of parasite and then we determinate of : susceptible of age group to infection, prepatent period and histological changes in experimentally infected mice.Result showed that cross transmission could happened for three species of Cryptosporidium that infected birds to lab. mice which are : C.parvum, C.meleagridis and C.baileyi with total ratio 30% and showed a significant difference compared with control group, and the results recorded a mortality ratio in infected mice (7.5%).The probability of mammalian infection by Cryptosporidium spp. which isolated from birds in our study represent the first record in Iraq. C.parvum and C.meleagridis showed loss of host specificity whereas C.baileyi was opportunist in his ability to infect another host beside their ordinary host (birds), while C.galli showed a high specificity for its host.The third part : Molecular studyThis part in our study studied for the first time in Iraq, which contains the diagnosis of Cryptosporidium species that infected birds and their genetic analysis through : DNA sequence analysis of species by used small subunit ribosomal RNA gene (18SrRNA), read of phylogenetic tree of these species and do comparison among genetic trees according to : original host (birds), experimental host (infected mice) and to their parasitic site in their ordinary host.The phylogenic tree of parasite species was drown by used MEGA6 program, the results of neighboring tree revealed two major branches : First branch include C.galli while the second branch include the other three species. Also genetic tree showed presence of two difference strains of C.parvum can infected the birds with neighboring ratio between them reached to 82% and the same thing was found for C.meleagridis but with neighboring ratio reached to 70%.The reading of phylogenetic tree showed that all species of studied birds can infection with isolated Cryptosporidium species excepting C.galli which just isolate from domestic chicken and C.meleagridis which found parasite only in turkey and quail.Results of genetic analysis of neighboring tree among species according to parasitic sites in infected birds showed similarity between species which isolated from fecal and bile, which are : C.parvum, C.meleagridis and C.baileyi, this result corroborate the ability of these species to transfer their infection from intestine to bile sac.The results of comparative concerned with isolated species from infected mice's fecal(experimental host) and from birds' fecal (ordinary host), results showed similarity among three species which isolated from mice's fecal with their analogous species isolated from birds' fecal which are : C.parvum, C.meleagridis and C.baileyi, while C.galli doesn't have ability to infect mice which dosage it.Finally the result of this study give evidence to ability of cross transmission for these three species from the class : Aves to the class : Mammalian, So this fact give to us a hygienic indication for probability of human infection with these species.

انتشار بكتريا Escherichia coli في المرضى في المرضى المصابين بالتهاب المرارة الحصوي في محافظة الديوانية Dissemination of Escherichia Coli In Patients With Cholecystitis Calculus In Al - Diwanyia Governorate

اسم المؤلف: احمد رزاق واجد الداوودي
اسم المشرف: سيوف خومان علوان الرماحي
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: The study aims to identify Escherichia coli bacteria, which causes calculus cholecystitis of molecular perspective. The study samples were gathered from 110 patients who undergone cholecystectomy in Diwaniya general hospital for the period October 2013 to April 2014. The sample included bile sap, gall bladder tissues and stone if available. The samples were cultured to identify their culture specifications.The results showed that chronic cholecystitis is the most common one, which has 55.5% then acute cholecystitis by 44.5%. The study results showed that age and sex have an influence on cholecystitis. The highest percentage of infection is the ages 36 - 45 for the two sexes. If the cases distributed according to the patient sex, there is a difference in cholecystitis between male and female, where females infections are 88.2% and males are 11.8%. The total isolated bacteria were 125 bacterial isolates of 52% of gall bladder tissues, 26.4% of bile and 21.6% of the stone. Escherichia coli had 34.4% of the total samples of 51.1%, 36.6% and 29.6% respectively of the above mentioned samples.As far as susceptibility for all Escherichia coli isolates towards 15 types of antibiotics by using disc diffusion for Kerby - Bauer method, bacteria had high susceptibility against ? - lactamases antibiotics where they had susceptibility against Ampicillin+ Clavulanic acid by 38.7% and 79% for Ampicillin. The least susceptibility was for Amoxicillin by 69.7%. Bacteria had no resistance for Imipenem where their susceptibility was 100%. Bacteria had weak susceptibility against Aztreonam by 13.9%. While with cephalosporins, susceptibility for Ceftazidime by 27.9% and for Cefotaxime by 20.9%. With Aminoglycosides, resistance to Gentamicin antibiotics was 34.8% and 30.2% for Amikacin. The results showed that resistance to Quinolones was 16.2 for Nalidixic acid while for fluoroquinolones resistance was 25.5% for Ciprofloxacin and 18.6% for Norfloxacin. Isolates ability to produce CTX - M, SHV, TEM and AMPC extended spectrum ? - lactamases enzymes was tested by investigating the existence of blaTem, blaAMC, blaCTX - M and blaSHV genes in these isolates through Polymerase chain reaction (PCR). There were 23/26 isolates (88.4%) showed their ability to contain blaAmpC gene, and 7/26 isolates (26.9%) contained blaSHV gene. There are 18/26 isolates(69.2%) contained blaTEM gene while 20/26 isolates (76.9%) contained blaCTX - M.Through using Quantitative Real Time - Polymerase chain Reaction (qRT - PCR), gene expression measurement for blaCTX - M, blaTEM and blaAmpC was measured by relative numbers. The results showed that gene expression measurement for ? - lactamases enzymes type AmpC produce by Escherichia coli was the highest if compared with ? - lactamases enzymes type TEM and CTX - M with different periods of incubation, which is T4h for 4 hours, T24h for 24 hours and T48h hours of incubation respectively. It is noticed that genes responsible for producing ? - lactamase enzymes type TEM, CTX - M and AmpC are changed during different periods of incubation through using Real Time - Polymerase chain Reaction (RT - PCR).

دراسة بعض الملوثات الصناعية وتاثيرها في الصفات التشريحية لبعض الانواع النباتية في قضاء سامراء Study of Some Industrial Pollutants And Their Impact in The Anatomical Characteristics of Some Plant Species in Samarra

اسم المؤلف: احمد يونس حمادي الكنعاني
اسم المشرف: طالب عويد الخزرجي ياسين محمد احمد الدليمي
الموضوع العام: علوم الحياة
السنة: 2012
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الكلمات الدلالية:
  • النبات - الامراض
الصفحات الاولى:
المستخلص: ان نمو النباتات في مواقع ملوثة قد يعرض صحة المستهلك للخطر سواء اكان انسان? او حيوان?، لذلك انجز هذا البحث لتقييم التلوث بالعناصر الثقيلة في مياه المخلفات الصناعية للحي الصناعي في مدينة سامراء وفي التربة والنباتات الواقعة على مجرى هذه المياه الجارية في ساق | The growth of plants in contaminated sites may expose consumers' health at risk, whether a human being or animal so accomplished this research to assess the pollution heavy elements in the waters of industrial waste of the neighborhood's industrial city of Samarra, in soil and plants located on the course of this running water in a stream length of 800 m even downstream Tigris River, as they are put waste industrial district as well as sewage water into the river is directly without treatment, as the study was to take part of the water and soil of that region as well as four types of plants that grow where is the tail of the seven, mint, sugar cane and corporal parents, study Some qualities Physical and chemical soil and water in addition to study some changes anatomical got to plants due to pollution, and that by dividing the study area into four zones as is the region (1) part near the industrial district and region (2) is located just 200 meters from the site of No. (1) towards the river, followed by site number (3), which is 200 m from the site of No. (2) The region (4) is located near the bank of the river and about 200 m from the site number (3) and samples were taken control of the West Bank of the Tigris River, was measurement of both pH and electrical conductivity and salinity in addition to measuring some heavy elements (iron, copper, cadmium) of soil and water, as well as the measured requirement vital for oxygen and the degree of turbidity of the water, also included the study to measure some heavy elements (iron, copper, cadmium) in plant and study the anatomical changes that occur due to the pollution produced by the launch of industrial waste. The results of the study that there is variation among study sites for each of the regions of the east bank of the river (the contaminated samples) and the West Bank of the river (the control) for most attributes Physical and chemical water and soil as well as for changes anatomical plants between contaminated samples and the control and in general has The results are within the limits permitted by the World Health Organization, the results indicate the high concentration of copper in the soil compared with iron and cadmium as the highest concentration has 10 ppm at the site (1), while the concentration of sample control 0.17 ppm The iron was higher focus him in the soil is 5.2 ppm in both locations (3) and (4), while the concentration of sample control 3.3 ppm The cadmium was the highest concentration has 0.43 ppm at the site (2), while the concentration of sample control 0.15 ppm and these concentrations are all not exceeding the allowable limit for the World Health Organization (for cadmium 1.5ppm of iron 120ppm copper 40ppm) respectively, and the results showed variation in pH between the soil and water for study sites on the one hand and sample control on the other hand, as shown soil samples to pH moderate among the four sites studied, where ranged pH between 7.26 - 6.33 The sample control was pH 8.64 As for water, the results showed basal water sites studied ranged pH between 6.8 to 5.8 which is comparable to Las pH for sample control 8.5, As for connectivity electrical has emerged variation between samples studied and sample control for soil and water and showed samples of soil and water at the site (2) the extent of the variation connectivity electrical them at the sites (3, 2, 1) and which are all higher than in the sample control, with varied degrees connectivity for soil samples between 14, 200 - 2860 Maekerosemins / cm The sample control 2300 Maekerosemins / cm The degree connectivity for water samples 2810 - 2450 Maekerosemins / cm The sample control of water was connectivity 1457 Maekerosemins / cm, for salinity, the results showed an increase in salinity of soil samples and water compared to a sample control ranged salinity in the soil between 8.92 - 1.79 g / l, while a control sample was salinity 1.438 g / l The salinity in the water was between 1.759 - 1.532 g / l The control sample was 0.907 g / l The results showed that the sample at the site (2) the degree of salinity have is higher than the rest of the other samples in soil and water. Results showed high copper for iron in the water was the highest percentage of copper in the signatories (4), (3) 0.05ppm The sample control has, (2.1) compared to a control sample, where he was between 55 - 20 mg / L, while a control sample 3.8 mg / liter, while for water Ekorh has ranged between four samples where Ekorh was water between 12.36 - 2.97 naphthalene The control sample was Ekorh water 2.1 Naphthalene. The results showed that the concentration of iron was high in most plants for copper and cadmium, as was the highest concentration of iron in the plant reeds 24 ppm as was assembled in the root zone of the plant which is within the limits permitted by the World Health Organization while the highest concentration of iron in the area of control of the plant reed it reached 17.5 ppm as it was assembled in the root also Copper was the highest concentration in the plant sergeant cock 0.89 ppm as it was assembled in the root while the focus was in control very few samples The cadmium is 0.1 ppm in all plants is within the allowable limits by the World Health Organization, while in the side anatomical has emerged is a difference between the samples studied and samples of control, as happened increase in the dimensions of the vascular bundles of the leg, as well as an increase in the thickness of the crust in the samples studied compared a sample of control as well as an increase in the thickness of the tissue foundation and a decrease in the number of packets Vascular plant roots as well as increase the thickness of the securities, an increase of pollution in the studied plants compared to a control sample..

تاثير بعض العوامل البيئية في مجتمع الهائمات القشرية لنهر دجلة وجزيرة بغداد السياحية - العراق The Effect of Some Environmental Factors In Crustaceans Plankton Community of The Tigris River And The Island of Baghdad Tourist - Iraq

اسم المؤلف: اعتدال فليح حسن العامري
اسم المشرف: صباح فرج عبد الاحد
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - اللافقريات
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: The present study was conducted to investigate the effect of the water body type on the density of crustaceans zooplankton of the cortical Cladocera and two orders of copepod (Cyclopoida, Calanoida), addition to the physical and chemical effect of lake of Baghdad Tourist Island and Tigris river within the water of the lake near the site and electric and know the effect these characterties on density of crustaceans Zooplankton and for doing this study. We choose five places, tow on Tigris river and three places on the Island in AI - Fahhama in north of Baghdad The samples of water were collected every 15 days all these stations from beginning of December 2013 to May 2014. This study had corrected the temperature of air and water and the pH, electrical conductivity. and Dissolved oxygen, BOD5, NO?¯, PO?¯ and the density of Crastaceans Zooplankton. This study showed that the temperature of the air was nearly in the river and the lake and that because of their being in the same geographs area.The temperature was between (16°c - 34°c)in Tigris while it was (11.9°c - 33°c)in the lake Hydrogen Ions, it was (7.3 - 7.9) in the river and (8.18.8)in the lake because that were a lot of water plants and phytoplankton. This study shows that water of the river and the lake in the areas of study have a good of air and that was shown by recording the heigh values of oxygen. The values of dissolved oxygen (DO) was between (8.11 - 11.5) mg\L in river between (7.9111.37)mg\L in lake and showed from the study that the values were few. It was less than 5mg\L it was (0.33 - 2.6) mg\Lin the river and (0.64 - 3.55) mg\L in the lake. The values electrical conductivity of water in all the placed the study in the permissible range the water, it isn't over than 1500?s\cm. The electrical conductively records were between (851 - 1184) ?s\cm in the river, and it was (755 1270) ?s\cm in the lake. From the other hand nutrients, the phosphor records between (0.025 - 0.0563)mg\Lin the river and in the lake between(0.00310.0429)mg\L The Nitrate records its values highs in the month of winter because of the rain and it was increased in the river, it was (0.345 - 0.9135)mg\L compare with the lake, it was (0.028 - 0.626)mg\L in the places of the study that were appearance of two clear increases in the density of Zooplankton one was in winter and the other was spring.The density of zooplankton in the lake much more than it was in the river. The density of the zooplankton belong to Cladocera between (0.019 - 0.307) ind.\L in the lake and the density of the Calnoida was between (0.003 - 0.065)ind. \L in the river and (0.0078 - 3.37) ind. \L in the lake. The results shows differences if there are changes in places and month on most of physical and chemical biological characteristic the measured during the period of this study. The kind of water body effects on most characteristics and soon the density of crustaceans zooplankton.the results of the study mention the binding morale relation between the density of zooplankton the values of electrical conductivity and value of BOD(Biological Oxygen Demand) while there isn't any morale relation between the density of zooplankton and the value of Hydrogen Ion and Nitrate and dissolved oxygen that because the value of these changes was near to be equal in all the places that eayses the reduce of its effective on the average of density of these organism. The study shows that Baghdad lake have the environmental ingredients makes the lake natural protected to forming and breeding a fish in the lakes in addition that it is a place for Tourism.

تاثير عصارة نبات البروكلي في متلازمة تعدد الاكياس المبيضية المستحدثة في الجرذ الابيض Effect of Broccoli Plant Juice On Induced Polycystic Ovarian Syndrome In Albino Rats

اسم المؤلف: رقية احمد صالح
اسم المشرف: نهلة جاسم محمد الشاهري
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - الفسلجة
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: The goal of present study was to investigate the benefits of broccoli as anti androgenic plant in protection and treatment for reproductive hormonal and metabolic disturbance, which combined with polycystic ovarian syndrome (PCOS). Three experiments for 3 PCOS models were done. First Experiment : The prepubertal female rats at 21 days old, were injected with Testosterone (T) subcutaneously for 39 days (first model). The females of this experiment were divided into 6 groups (8 rats each) as follows : Group 1 was injected with sesame oil. Group 2 was injected with T hormone. Group 3 was injected with T hormone with orally gavaged of broccoli juice. Group 4 was injected with sesame oil, and at the end of the last injection was orally gavaged with distilled water for 30 days. Group 5 was injected with T hormone, and at the end of the last injection was orally gavaged with distilled water for 30 days. Group 6 was injected with T hormone, and at the end of the last injection was orally gavaged with broccoli juice for 30 days. Second Experiment : The prepubertal female rats at 21 days old, were injected with Letrozole (L) subcutaneously for 39 days (second model).The females of this experiment were divided into 6 groups with the same style of the first experiment. Third Experiment : it was achieved by the injection of pregnant rats prenatally (days 16 to 19 of gestation) with 1 mg of T hormone subcutaneously (third model), and then the female offspring were divided into groups (8 rats each) as follow : The first offspring group : The female rats offspring at 21 days old (their mothers were injected with sesame oil from 16th to 19th day of gestation) were orally gavaged with distilled water until 60 days of age. The second offspring group\ gavaged with distilled water : The female rats offspring at 21 days old (their mothers were injected with T hormone from 16th to 19th day of gestation) were orally gavaged with distilled water until 60 days of age. The second offspring group\ gavaged with broccoli juice : The female rats offspring at 21 days old (their mothers were injected with T hormone from 16th to 19th day of gestation) were orally gavaged with broccoli juice until 60 days of age. The third offspring group : The female rats offspring at 21 days old (their mothers were injected with T hormone from 16th to 19th day of gestation and orally gavaged with broccoli juice) were orally gavaged with distilled water until 60 days of age. Females of all groups were sacrificed after 24 hours from the last treatment to undertake weight, histological, hormonal and metabolic study for each group. the results of present study showed the symptoms that reported PCOS of the three female experiments such as ovarian cyst, hyperandrogenemia, hormonal and metabolic disturbance, etc. Also a well improvement has been noticed in all syndrome symptoms on females gavaged with broccoli juice for all three rats PCOS experiments, these results indicate that broccoli juice has got a protective and curative role against this syndrome.

دراسة بكتريولوجية لاخماج المسالك البولية للنساء الحوامل والمصابات بارتفاع ضغط الدم وداء السكري في منطقة تكريت Bacteriological Study of Urinary Tract Infections Among Pregnant, Hypertensive, And Diabetic Women in Tikrit Region

اسم المؤلف: اسراء عز الدين ابراهيم
اسم المشرف: عبد الكريم فتاح عمر
الموضوع العام: علوم الحياة
السنة: 2010
الموضوع الدقيق: الاحياء المجهرية
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: النساء المتزوجات والحوامل والنساء المصابات بداء السكري وضغط الدم المرتفع ومدى مقاومتها للمضادات الحيوية لقد اشتملت الدراسة على 411 عينة ادرار من المريضات المراجعات لمستشفى تكريت التعليمي و100 عينة ادرار كمجموعة ضابطة للفترة من تشرين الثاني2008 ولغاية ايلو | This study aimed to isolate and identify the bacterial causative agents of urinary tract infections among married, pregnant, diabetic and hypertensive women and to determine the susceptibility of isolated bacteria to different antibiotics. The study included 411 urine samples for women attended to Tikrit Teaching Hospital, besides 100 urine samples used as a control group. The study carried out for the period from November 2008 to September 2009.E. coli was the most isolated bacteria at the rate of 31.8 % from married women followed by Staphylococcus saprophyticus 18.18 % and Staphylococcus aureus 15.90%. In the pregnant women, S. saprophyticus was the most isolated bacteria 48.10 % followed by E. coli 20.25 % and S. aureus 12.65 %, and in the diabetic women, S. saprophyticus was the common isolated bacteria 32.07 % followed by E. coli 28.30 % and S. epidermidis 15.09 %. In the hypertensive women, S. saprophyticus 30.35% was the common isolated bacteria followed by E. coli 25.0% and S. aureus 19.64 %. In the case of diabetic pregnant women, and in the hypertensive pregnants S. saprophyticus was the most isolated bacteria, (80 % and 75 % respectively), while E. coli 44.4% was the common isolated bacteria among the diabetic hypertensive women. Out of all isolates, S. saprophyticus 35.13 % came in the first rank followed by E. coli 26.64% and S. aureus 12.74% while Klebsiella oxytoca and Serratia odorifera (0.38% for each of them) were the lowest isolates. Urinary tract infection was common among urban patients 57.49%.The isolated bacteria showed different susceptibility to the antibiotics used in this study. S. saprophyticus isolates showed high sensitivity to Amikacin, Nitrofuratoin and Cefolaxime (the resistance rate for these antibiotics were 11 %, 12.1 % and 12.1 % respectively). While these isolates showed high resistance to Streptomycin 76.9 %, Nalidixic acid 67 % and Cephalexin 69.29 %. E. coli isolates showed low resistance rate to Amikacin 9.28 %, Ciprofloxacin 10.1 %, whereas showed high resistance rate to Cephalexin 47. %, Streptomycin 84 % and Ampicillin 82.6 %. The isolates of S. aureus showed low resistance to Ciprofloxacin 18.2 %, Carbencillin 18.2 % and Amikacin 15.2 % and high resistance for Ampicillin 18.8 %, Nalidixic acid 75.8 % and Cephalexin 72.79 %. Other isolated bacteria showed a different percentages of susceptibility to antibiotics Serratia odorifera, Proteus vulgaris and Enterococcus faecalis showed a significant resistance to antibiotics, while S. epidermidis isolates showed low percentages of resistance to Ciprofloxacin 9.1 %, Amikacin 18.2 % and Gentamicin 9.1 %. For S. saprophyticus the minimal inhibitory concentrations (MIC) resulted from Ciprofloxacin, Gentamicin and Cefotaxime were 8 - 32, 8 - 64 and 4 - 8 ?g/ml, and for E. coli the MIC results were 2, 8 - 16 and 16 - 64 ?g/ml. The MIC results were 2 - 8, 8 - 128, 32 - 256 ?g/ml for S. aureus, while the MIC results were 8 - 32, 16 - 64 and 16 - 128 ?g/ml for Klebsiella pneumoniae.

دراسات وراثية خلوية ومظهرية لثلاثة انواع من شبوطيات المياه العذبة العراقية (Barbus luteus, Cyprinion macrostomus, Chondrostoma regius) Three Species of Iraqi Freshwater Cyprinidaes (Barbus Luteus, Cyprinion Macrostomus, Chondrostoma Regius)

اسم المؤلف: اسماء سامي ابراهيم
اسم المشرف: ندى عبد المجيد الانصاري طه ياسين الدوري
الموضوع العام: علوم الحياة
السنة: 2008
الموضوع الدقيق: الحيوان - الوراثة
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: هدفت الدراسة الحالية التعرف على الطراز الكروموسومي ونظام تحديد الجنس والتمييز بين الجنسين مظهريا في ثلاثة انواع من اسماك المياه العذبة العراقية ممثلة بسمكة الحمري Barbus luteus والبنيني كبير الفم macrostomus Cyprinionوالبلعوط الملوكي Chondrostoma regius | These present studies were carried out to determine the karyotypes & the system of sex determination between the two sexes as well as the sexual morphological characteristics of three species of Iraqi fresh water fish Barbus luteus, Cyprinion macrostomus, & Chondrostoma regius that were fished from Tigris river at Baghdad during 2005. The cytogenetic studies revealed that the chromosome number of Barbus luteus is 2n = 148 & the karyotype of males is (80m + 52sm + 16st) while the females has (80m + 51sm + 17st). The chromosome number of Cyprinion macrostomus is 2n = 50 the males has (6m + 24sm + 12st + 8t) while the females has (6m + 23sm + 13st + 8t). The chromosome number of Chondrostoma regius is 2n = 48 and the karyotype is (14m + 30sm + 4st). Sex chromosomes were identified in Barbus luteus & in Cypinion macrostomus for the first time , the sex is determined by ZZ / ZW system, the female was considered as heterogametic (ZW) while the male was considered as homogametic (ZZ) , & the chromosome Z was represented as submetacentric chromosome & chromosome W as small subtelocentric chromosome. In spite of the difference in their chromosome number , the ratio between red blood cell diameter & it's nucleus was approximated in these species. The differences among these species in both of the diameter of cell and the nucleus didn't match with the differences at the polyploidy levels or with the difference in chromosome number within the same level. The liver & intestine were recommended as new sources for chromosomal studies , because of the good ratio of dividing cells (71.4 % & 58.2 %) respectively from the whole dividing cells in kidney that was considered as a control. The crude aqueous extract of fresh convolvulus arvensis leaves showed good effect in arresting the cell division of fish at metaphase , the concentration (0.4, 0.6, 0.8, ) mg / gm arrested kidney cells of carp fish at the metaphase in ratios 71.1 % , 88.1 % , 94 % respectively from the colchicines treated kidney cells (control). Positive significance correlation was found (r = 0.9518) between the percentages of arrested cells at metaphase & the concentrations of crude extract. Comparison between the females and males of the three species revealed that in Barbus luteus the distance from head edge to the anal orifice & from head edge to the dorsal fin were larger in males than females. The females have dark colored fins with reddish ventral aspect of head & body in comparison with the males during the whole months of study. So , they were considered as permanently sexual dimorphism characteristics. But , during the spawning seasons (May & June ) a more brighting color of male with reddish coloration of both sides of body were noticed in comparison with female with a golden orange corneal coloration in both sexes. Thus, they were considered as temporary sexual dimorphism characteristics. In Cyprinion macrostomus the distance from the head edge to the anal orifice was larger in females than males. The colors of anal & caudal fins were darker in females than in males during the whole monthes of study.So , they were considered as perminantly sexual dimorphism characteristics. While, during the spawning seasons ( May , June , July & August) , the gill operculum was of orange color only in male that extend to the end of pectoral fin. So , this was considered as a temporary sexual dimorphism characteristic. In Chondrostoma regius the distance from the head edge to the dorsal fin & from the dorsal to caudal fin as well as the pectoral fin base length were larger in females than in males during the whole months of study it was considered that they are permanently sexual dimorphism characteristics. Differential characteristics were not noticed during the spawning season (February & March). The permanently sexual dimorphism & the general characteristics were not affected by the differences of standard length , weight , age & season , because they were observed in fishes of different lengths , weights & ages & during the months of study 2005. But , the seasons affect the development of temporary characteristics in Barbus luteus & Cyprinion macrostomus , because these characteristics were observed during the spawning season only. Aging of Barbus luteus was accompanied by growth increase as indicated by the mean of standard length during May , July, August, September & December & by the mean of weight during May , August, September, October & December. A positive correlation was found between standard length & weight during the months of study , with the exception of January. While aging of Cyprinion macrostomus & Chondrostoma regius was not accompanied by growth increase as indicated by the means of standard length & weight , but a positive correlation between standard length & weight was found during the studied months. Same growth type were observed in the three species of fish , it was allometric in two sexes.

تاثير مستخلصات المركبات التربينية والقلوانية والفينولية الخام لنبات الزريج Chrozophora tinctoria L. في بعض جوانب الاداء الحياتي لحشرة الذبابة المنزلية Musca domestica L.(Diptera : Muscidae) مع عزل وتشخيص المركبات الفعالة باستعمال تقنية الكروموتوغرافيا الس The Effect of Crude Extract For, Terpenoids Alkaloids And Phenolic Compounds of Chrozophora Tinctoria L. On Some Biological Aspects of House Fly Musca Domestica L. (Diptera : Muscidae) And Isolation And Identification of Active Compounds By Using High Per

اسم المؤلف: اسيل كريم جبار السلطاني
اسم المشرف: هادي مزعل خضير الربيعي
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: اجريت سلسلة من التجارب المختبرية في مختبر بيئة الحشرات/كلية العلوم للبنات/جامعة بابل خلال عام 2014 - 2015 تضمنت اختبار فعالية مستخلصات المركبات التربينية والقلوانية والفينولية الخام لنبات الزريج Chrozophora tinctoria في بعض معايير الاداء الحياتي لحشرة الذ | A series of laboratory experiment were conducted in the laboratory of insect /college of Science for women /University of Babylon during the year 2014 - 2015 The present study conducted to evaluate the activity of crude extract of Terpenoid, Alkaliod and Phenolic compounds of Chrozophora tinctoria on some biological aspect of Musca domestica and histological study for effect crude phenolic compound on ovaries as well as isolation and identifaction of active compounds in these extracts.The extract of crude terpenoid compound was more effective than crude alkaloid and phenolic compound in different critirra of biological perphormance. The mortality rates of eggs in the extract of terpenoid alkaloid and phenolic compound at concentration 1mg/ml were (90, 63.7, 39.6)? respectively compared with (0.4, 0.8, 0.8)% in the control tretmentsThe mortality rate of first larval instar was (57.64, 57.00, 26.85)% respectively when treated with crude terpenoid, alkaloid and phenolic compounds at concentration 1mg/ml compared with (0.8, 0.8, 0.8)% in the control treatment.The mortality rate of pupae was 18.06% when treated with crude terpenoid extract at concentration 1mg/ml compared with 0.4% in the control treatment. The cumulative mortality rates of immature stage when treated with crude terpenoid, alkaloid and phenolic compound were (100, 100, 42) % at concentration 1mg/ml compared with (15, 14, 12)% at the control treatment.Developmental period of immature stage was 36.6 days when treated with crude alkaloid extract at 0.25 mg/ml compared with 10.2 days in the control treatment.The pupal weight and female productivity were reduced from 0.1gm, 122.6 egg/female in control treatment to 0.556 gm, 0 egg/female respectively when treated with crude alkaloid extract at 0.25 mg/mlThe different concentration of crude terpenoid, alkaloid and phenolic compound were effective in the performance of eggs deposition, the nummber of eggs decreases in crude extract terpenoid, alkaloid and phenolic compounds at the concentration in same space was (0) egg/femal for all extracts at concentrion 1mg/ml comparted with (117, 118, 106) egg/femal in the control treatment, while was (0) egg/femel when treated in different concentration of terpenoid, alkaloid alone of consentration 1mg/ml compared with (120, 122) egg/femel in the control treatment.The number of eggs was (37) egg/femel when treated with phenolic compounds at same concentration compared with (120) egg/femel in the control treatment.The study included the effect extracts activity for crude phenolic at concentration 1mg/ml in histological structure for insect overies, The length and diameter of ovary and ovares follicles at (24, 96) houres after emergency while the length and diameter of ovary was (625, 468.75)µm respectively at 24 houre at concentration 1mg/ml compared with (652.173, 565.217)µm in the overy of femel in the control treatment. The length and diameter of ovaries follicles were (116.66, 72.22)µm respectively in the femel overy for control treatment, while was not distingwish for follicles female which were produced from treatment. while in (96) hour after emergency the length and dimeter of ovary (1114.285, 971.428)µm respectively when treated with extract compard with (1688.88, 1481.48)µm for overy of female in control treatment.Isolation and identification of active compounds in the crude extract of terpenoid, alkaloid and phenolic compounds, of Chrozophora tinctoria by using high performance liquid chromatography (H.P.L.C), Five compounds isolated from crude terpenoid extract was Teter methyl hydrazine compound which had retention time(1.333) mintue which was the first compound, while seven compounds isolated from phenolic compounds The gallic acid compound had retention time 1.34 mintue, which was the first compound isolation.Two compounds were isolated from crude alkaloid compounds which were berberine and isoquinoline, berberine compound had retention time 2.51 mintue which was more concentration than other compound.

دراسة تصنيفية لبعض اجناس العائلة المركبة Asteraceae في العراق Taxonomical Study of Some Genera From Asteraceae In Iraq

اسم المؤلف: اشواق فالح خزعل العجيلي
اسم المشرف: عبد الكريم خضير البيرماني
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: تناول هذا البحث دراسة تصنيفية مقارنة لستة اجناس تعود للعائلة المركبة Asteraceae وهي Chrysanthemum L. وGazinia وGerbera وLeontodon L. وTagetes L. وZinnia L. وتميز كل جنس من تلك الاجناس المذكورة باحتوائه على نوع واحد فقط في العراق وهيL. Chrysanthemum coro | The present investigation comprises systematic study for six genera belong to Asteraceae as follow : Chrysanthemum L., Gazinia, Gerbera, Leontodon L., Tagetes L. and Zinnia L. Each genus of those genera described as containing only one species in Iraq, Chrysanthemum coronarium L., Gazinia splendens Gaertn, Gerbera jamisoni F.Gmel, Leontodon laciniatus L., Tagetes patula L. and Zinnia elegans L. respectively. The study was conducted in the laboratory research of plant taxonomy / College of Science women / Babylon university for the period January 2015 until August 2015.The study included morphological, anatomical, palynological and chemical characteristics as well as numerical taxonomy have been done for all species. The importance of taxonomic to studying variations in roots, stems, leaves, inflorescences, involucre bracts, flowering and fruiting parts and Indumentum were discussed. Results showed that many of the vegetative and reproductive characters have the importance taxonomic value for isolating genus from each other such as presence and absence of the stem and the nature of the basal and cauline leaves in addition the present of leafy stipule as well as the nature of Indumentum.Anatomical characters of leaves epidermises and the cross section of the stem, leaf blade, petiole and peduncles, in addition leaves venation have been studied and their taxonomic importance were assessed.The study also found the pollen grain was tricolporate in general, but the presence of spine or not had an important taxonomic to isolate Gerbera jamisoni by smooth surface compared to the rest of the species, while possible to isolate Gazinia splendens and Leontodon laciniatus by the presence of the bridges in pollen surface. On the other hand it has been the study of chemical content in each of the leaves and flowering heads of the species studied using Gas Chromatography technique (GC) to detect the terpenoid compounds, The presence of compound Nerolidol, Terpinolene in the species.. Gerbera jamisoni, Zinnia elegans emphasized the importance taxonomic chemical content at the level of species and genera.The species were numerically treated on the basis of number of selected characteristic from various studies to obtain the similarity and differences ranges between different species. Dendrogram was drawn for this purpose. As a result of preceding observation this study confirmed the diagnosis of six genera within Asteraceae family in Iraq. Finally all the taxa were treated taxonomically, and the key was prepared for all the taxa studied.

دراسة تصنيفية مظهرية لبعض انواع عائلة قفازات الضفادع من رتبة متشابهة الاجنحة Homoptera : Cercopidae من بعض محافظات العراق Taxonomic Morphological Study of Some Species of Froghoppers, (Homoptera : Cercopidae) From Some Iraqi Governorates

اسم المؤلف: حلا تايه عمران
اسم المشرف: حسن سعيد جاسم الاسدي
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - الحشرات
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تضمن البحث دراسة تصنيفية مظهرية لخمسة عشر نوعا تابعة لاربعة اجناس لعويلتيCercopinae، Aphrophorinae لعائلةCercopidaeمن رتبة متشابهة الاجنحة Homoptera جمعت من مناطق مختلفة في العراق تم الاعتماد على النوعCercopis vulnerata(Rossi, 1807) نموذجا للعائلة.وهذه ا | The present study comprisers taxonomic morphological of 15 species belong to four genera of the two subfamilies Cercopinae and Aphrophorinae, belong to the family Cercopidae of the order Homoptera, it has been regarded the speciesCercopis vulnerata(Rossi, 1807) as typical sample of the families.The species studied in were : Family : Cercopidae West wood, 1838Sub family : Cercopinae West wood, 1838.Genus : Cercopis Fabricius, 1775.**Cercopis vulnerata (Rossi, 1807)Sub family : Aphrophorinae Amyot&Serville, 1843.Genus : Aphrophora Germar, 1821.**Aphrophora alni(Falle'n, 1805).**Aphrophora major (Uhler, 1896).**Aphrophora oblique(Uhler, 1896).**Aphrophora salicina(Goeze, 1778)**Aphrophora straminae(Kato, 1932).**Aphrophora forneri(Haupt, 1919).**Aphrophora intermedia (Uhler, 1896).*Aphrophora triticasp.nov.*Aphrophora asadisp.nov.Genus : Phileanus Stal, 1864.Phileanus spumarius (Linnaeus) 1758.Genus : Neophileanus Haupt, 1935.** Neophileanus lineatus(Linnaeus, 1758).**Neophileanus campestris(Falle'n, 1805).**Neophileanus longiceps(Puton, 1895).**Neophileanus exclamationis(Thunberg, 1874). *New species for the science.**New recorded to the Iraq insect fauna of Homoptera.

تاثير حامض الهيوميك والاوكسينات في نمو نبات حشيشة الليمون Cymbopogon citratus L. وتراكيبه الافرازية ومكوناته الفعالة Effect of Humic Acid And Auxins on Growth of Lemon Grass Plant (Cymbopogon Citratus L.), Secretors Stractures And Its Active Constituent

اسم المؤلف: ايوب جمعة عبد الرحمن علي البياتي
اسم المشرف: جميل ياسين التميمي شاكر مهدي صالح
الموضوع العام: علوم الحياة
السنة: 2012
الموضوع الدقيق: النبات
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: اجريت تجربة حقلية باستخدام اصص بلاستيكية في كلية التربية - جامعة تكريت بهدف دراسة تاثير حامض الهيوميك والاوكسينات في الصفات المظهرية والتشريحية لنبات حشيشة الليمون ومحتواه من المادة الفعالة, نفذت التجربة العاملية وفق التصميم العشوائي الكامل CRD وبثلاث مكر | Afield experiment was conducted using plastic pots on lemon grass to study effect of Humic acid and Auxins in growth, anatomical characteristics and its content of active constituents this plant in Tikrit University - College of Education, using the factorial experiment in CRD.The first factor was humic acid as organic acid fertilizer and two ways for applied, The first spraying with Lighumus 18 concentration 1.5 ml/2L of water(H1).The second addition Liqhumus 18 with irrigation water 1.5 ml/2L of water(H2)In addition to the treatment control(without Liqhumus 18(H0). The second factor two type of growth regulators(IAA And IBA) and their mixture as follow : 1 - spray growth regulator IAA 150mg/L(A1).2 - spray growth regulator IBA150mg/L(A2).3 - spray the mixture (IAA+IBA) 150mg/L(A3).4 - (Control) spraying with water. The data analysis ststistical using analysis of variance test (ANOVA) and compared between the treatment using Duncan test at 5% level of probability, and results of the experiment were as follow : 1 - The treatment (H2A3) was superior in plant hight(150.92cm), leaf area(3278.0cm2), number of leaves/plant(49.16)and shot dry weight(153.86 g) While the lowest value of plant high were(127.17cm)leaf area(1341.0cm2), leaf number/plant(29057)and shot dry weight (98.58gm)in the control treatment.2 - The treatment (H2A3) was superior significantly in all plant elements content : Nitrogen(2.78%), phosphorus(0.388%), potassium(2.95mg/l), Iron (87mg/i), Copper(16.8mg/l)and Zinc(15.8mg/l)whereas control treatments gave the lowest value were (1.31%), (0.29%), (1.05mg/l), (47.66mg/l), (12.0mg/l)and(3.10mg/l)respectively.3 - The treatment (H2A3)gave high number of oil cell in the leaf blade(5.88)cell, leaf mid rib(5.88)cell and leaf sheath(6.88)cell while less value were in the treatment(H0A2)which gave(3.22)cell in leaf blade and(2.66)and(3.66)cell on midrib and sheath respectively gave by control treatment4 - The treatment (H2A3) was superior significantly increased the volatile oil percentage by (1.04%), Specific gravity(0.9460), oil density(0.9260)and refractive index(1.4839).while less percentage were (0.68%), (0.8890), (0.8880)and(1.4820)respectively in the control.5 - The treatment(H0A3)was superior significantly in Citral a compound percentage by(32.87%), total citral(54.59%)and linalool(11.53) hn the leaf and sheath.in compare with treatments(H0A1), (H1A0)and(H1A2)which never contain Citral, while less percentage of total Citral was (2.06%)in the control.6 - The treatment(H0A1)was significantly increased compound Citral b compound percentage(27.82%) in the leaf and sheathwhile less Citral b percentage was(1.90%) in the control.7 - Superior the treatment(H2A0) significantly in Limonen compound percentage by(88.81%) in the leaf and sheathwhile less Limonen percentage was(21.72%) in the treatment(H1A1).8 - the treatment(H1A1)was significantly superior in Myrcin compound percentage by(35.83%) in the leaf and sheath in compare with(H1A0) which never contain Myrcin.9 - the treatment(H1A3)was significantly superior in Geraniol compound percentage by(36.14%) in the leaf and sheath in compare with(H0A3)and(H2A1) which never contain Geraniol.

تقييم الفعالية المضادة للاكسدة والمضادة لحيوية الاطوار المختلفة لذبابة المنزل Musca domestica L. للمستخلص المائي لمخلفات العنب Vitis vinifera L. Evaluation of The Antioxidant And The Activity Against The Viability of Various Stages of The Domestic Fly Musca Domestica L. For The Water Extracts of Grape Pomace Vitis Vinifera L

اسم المؤلف: محمد قاسم بلاسم الخيلاني
اسم المشرف: عبد اللطيف مولان محمد
الموضوع العام: علوم الحياة
السنة: 2015
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: لقد تم تحديد المحتوى الفينولي الكلي للمركبات الفينولية Total phenolic content والفعالية المضادة للاكسدة Antioxidant activity لمخلفات نوعين من العنب (Vitis vinifera) (ديس العنز والشدة السوداء) التي تم الحصول عليها بعد استخلاص عصير العنب وهي القشور والبذور | The total phenolic contents (TPC) and the antioxidant activity of the pomaces and their components (seeds and peels) of two Iraqi grape cultivars (Shadda Black and Des - Alanez) were determined. Four types of solvents were used in the extraction in order to select the best way of extraction of the phenolic compounds. In addition, the insecticidal activity of the water extracts of the pomaces, seeds and peels against different stages of the life cycle of housefly, Musca domestica, was evaluated via studying the effects of the water extracts on egg hatching, the development of the first instar (L1) larvae into pupae and adult flies, and on the viability of the third instar (L3) larvae and pupae. The results of the present study showed that the extracts prepared in the 5% HCl solutions contained the highest (P<0.05) amounts of phenolic compounds followed by those prepared in hdyro - ethanolic solutions (50% with water, v/v), then the extracts prepared in boiling distilled water, while those prepared in normal distilled water (at room temperature) showed the lowest amounts of phenolic compounds. A similar trend of activity was observed for the antioxidant activity via the ability to scavenge the synthetic free radical (2, 2 - diphenyl - 1 - picrylhydrazyl; DPPH). This correlation between the total phenolic contents of the grape pomaces, seeds, and peels and their antioxidant activities clearly indicates that the phenolic compounds are the main contributors for the antioxidant activity. It is important to mention that the TPC of the pomaces, seeds, and peels of the Des - Alanez cultivar were significantly higher (P<0.05 - 0.001) than their counterparts of the Shadda cultivar.The insecticidal activity was evidenced by the ability of the water (boiling) extracts of the pomaces, seeds, and peels of the two cultivars to inhibit the hatching of the housefly eggs at very low concentrations. At 150 microgram (µg)/ml, the crude water extracts from the powdered pomaces, seeds, and peels were able to inhibit completely the hatching of the eggs (100% inhibition) when compared with the eggs in the control group (exposed to water only). The water extracts of the pomaces, seeds, and peels of the two cultivars showed inhibitory effects against the viability of the L3 larvae as evidenced by their ability to paralyze or kill the larvae and this ability increases significantly with increasing the exposure time (P< 0.05) and concentration (P< 0.05). The results also revealed that the ability of extracts of the seeds of the two cultivars to paralyze or kill the L3 larvae was significantly higher (P< 0.5 - 0.001) than the extracts of the pomaces and peels, especially at the higher concentrations.The results of the current study also showed the capacity of the water extracts of pomaces, seeds, and peels of the two cultivars to affect the development of pupae into adult flies and this capacity depends on the exposure time and the by - product and increases significantly (P< 0.05 - 0.001) with increasing the exposure time. Moreover, the ability of the seeds extracts from both cultivars to inhibit the transformation of the pupae into adult flies was significantly higher (P< 0.001) than the ability of the extracts of the pomaces and peels, and at all the exposure times.Concerning the results of the last series of the laboratory experiments which are considered the most important experiments in this study because they simulate field conditions, two treatment placement locations were selected, top of the manure and bottom of manure (under about 5 cm of manure). For top treatment, 50 grams of manure were placed in the plastic cup and then 5% or 10% of the powdered pomaces, seeds or peels were sprinkled on the top of the manure. For bottom treatment, the same amounts of powdered by - products were sprinkled on the bottom of the cup and then 50 g of manure were added to the cup. A similar quantity of untreated manure was used as a control. The results of these experiments showed that the powdered pomaces, seeds, and peels have the ability to inhibit the development of the larvae into pupae and adult flies and this ability depends on the location of the products and the grape cultivar. The results also revealed that the addition of the powdered materials of both cultivars on top of the manure inhibited significantly more (P<0.05 - 0.001) L1 larvae from reaching the pupa and adult stages in comparison with their counterparts which had been added at the bottom of the manure. Contrary to our expectations, the powdered pomaces, seeds and peels of both cultivars showed inhibitory effect against the L1 larvae when added on bottom of the manure which may indicate that the phenolic compounds present in the powdered materials can mix and bind with the ingredients of the powdered by - products and affect the growth and development of the larvae into pupae and adult flies.It can be concluded that the grape pomaces and their ingredients, which are usually thrown in the bin, represent very good sources for phenolic compounds that have the ability to scavenge the free radicals and have insecticidal activity against different stages of the housefly, Musca domestica.

تقييم كفاءة بعض المستخلصات النباتية وعقار الميترونيدازول Metronidazole في حيوية الاميبا الحالة للنسيج Entamoeba histolytica خارج الجسم الحي In vitro مع دراسة جزيئية لتحديد بعض الانواع التابعة لها في محافظة بابل Evaluation of Some Plant Extracts And Metronidazole Drug In Vitro of Entamoeba Histolytica Viability And Molecular Study For Some Species Determination In Babylon Province

اسم المؤلف: سحر عباس حسين المعموري
اسم المشرف: هادي مزعل خضير الربيعي احمد خضير عبيس الحميري
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: اجريت الدراسة الحالية للمدة من تشرين الاول 2013 ولغاية تموز 2014 في كلية العلوم للبنات / جامعة بابل, اذ تم الحصول على طفيلي الاميبا Entamoeba من عينات المرضى المصابين والمراجعين لمستشفيات بابل للاطفال والولادة ومستشفى ابن سيف للاطفال والمركز الصحي الحسين | The present study was conducted during the period from October 2013 till July 2014 in the College of Science for women, Babylon University, the Entamoeba stool samples were collected from patients that attending to Babylon Maternity and pediatric hospital, Ebn - Saiff hospital and Abi - Gharaq and Al - Mussaib of primary health center, Babylon province. The parasites were detected by direct smear method, 130 stool samples were collected that contain blood and mucus. The overall percentage incidence of E. histolytica (80.8%). No significance differences of infection rates in males and females and the highest rate of infection was in (1 - 10) year age group for males and females (82.9% and 39.1% respectively) while the lowest infection rate was in (51 year and more) for males and females (33.3 %, 6.7 % and respectively).Three plants extracts (cooled and Boiled) water (Euphorbia helioscobia, Eucalyptus gloubules and Mytrus comminus) evaluated at the culture media (Beef liver infusion media) that grown with E. histolytica. The results revealed the E. helioscobia boiled water extracts the efficient extracts to killed the all parasites in the second day from experiment beginning with 10 mg/ ml concentration and the next efficient plant extracts (boiled water) its E. globules and M. commines was the third day with 5 mg / ml concentration. The Metronidazole showed to killed all parasites in the third day with 1 microliter / ml. and from this present study showed that the successful growth of E. histolytica in culture media for some day and finished (Killed) at the fiveth day from experimental beginning.Isolation and identification of some terpenoid compounds were detecting in the present study belong E. helioscobia plant extracts (Camphene, ???pinene, Euphornin, ?? caryophyllene, Myrecene and ??humulene) by (HPLC).Molecular study was conducted to determined three species of Entamoeba by using Polymerase chain reaction for ten stool samples that primarily detected with Amoebic dysentery by direct smear method and the following results for molecular study, the highest overall percentages its E. dispar with (7/10) mean 70% whereas the E. histolytica and E. moshkoviskii its (6/10) mean 60 % for each one, as well as existence the double infection or tertian infection with these species for Entamoeba.

التشخيص الجزيئي لبعض انواع الفطر Trichoderma وتقييم فعاليتها ضد الديدان الثعبانية لعقد الجذور Meloidogyne javanica في محافظة واسط Molecular Diagnosis of Some Species of Trichoderma And Evaluation Their Activity Against Root - Knot Nematode Meliodogyne Javanica In Wasit Province

اسم المؤلف: حمزة عباس ياسر
اسم المشرف: محمد جبير حناوي هادي مهدي عبود
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: واسط
الصفحات الاولى:
المستخلص: نفذت هذه الدراسة لعزل وتشخيص الانواع المستوطنة للفطرspp Trichoderma في محافظة واسط وتقييم فاعليتها ضد نيماتود العقد الجذرية Meloidogyne javanica (Treub) في مختبر الفطريات في قسم علوم الحياة - كلية العلوم - جامعة واسط فضلا عن دراسة تاثير هذه الانواع في بعض | This study has been conducted to isolate and identify some nation species of the fungus Trichoderma spp in wasit province and evaluate the activity of them against Root Knot nematode Meloidogyne javanica (Treub) in the laboratory of Biodepartment - College of science - University of wasit, and study the effect of these species in growth criteria of tomato plant in greenhouses of Ministry of Technology and Science, and diagnosed by PCR technology. Soil samples had been collected from soil and plant roots (solanaceae, cucurbitacece) infected with Meloidogyne javanica in fields and greenhouses in eight locations in wasit province (Kut center, Alahrar, Alhay, Alnuamania, , Badra, algardhia, sheikh saad and Aldijaily) for the period from 5/11/2013 to 22/12/2013.The results had been revealed that there are 15 isolates of 25 isolates contain Trichoderma spp, by the purification we got 7 a local isolates of the fungus Trichoderma belong to four species of Trichoderma which were T.harzianum، T.hamatum، Trichoderma sp1 and Trichoderma sp2.Results showed All tested isolate high efficiency in parasitism the eggs of nematode and the reduction of the percentage of hatching eggs and the more effective isolate was the T. harzianum3 (T6) from sheikh saad location comparing with the other tested isolates and the percent of parasitism was 97%, and significant differences with all isolates and the results showed a clear reduction in the number of larvae emerging comparing with the control.The results showed that the isolates T.hamatum1 (T1), T.harzianum2 (T3)، T.hamatum2(T7) exist high percent of parasitism which were 92.2% , 90.8% , 90.4% respectively It was not a significant difference between them, while the isolates T.harzianum1 (T2)، Trichoderma sp1 (T4)، Trichoderma sp2 (T5) were 80.4%, 77.5%, 84.6% respectively.The result also showed that the filtrate of isolates (100%, 50%, 25%) had good effect on egg hatching (destruction) comparing with the control and the more effective concentration was 100% Compared to other concentrations and the filtrate of isolate T. harzianum3(T6) was more effective comparing with other filtrate of isolates and the mortality of eggs were 96.7%، 75.5، % 56.3% at the concentration 100%, 50%, 25% respectively The Trichoderma sp2 (T5) was least effective isolate compared with other isolates, as the proportion of parasitism was 76.4%، 59.7%، 38.6% at the concentration 100%, 50%, 25% respectively. With regard to the effect of fungus in tomato plant growth criteria the results also showed that the isolate T. harzianum3 (T6) enhanced the growth of the length of stem and root of tomato plant growing in greenhouses and the lengths of stem and root treatment with T. harzianum3 (T6) were (19.7, 21.3) cm respectively Followed by the the control which were (16.1، 15.4) cm respectively while the lengths of stem and root of treatment plants with the fungus and nematode together were(14.4، 11.1) cm respectively and least length of stem and root of treatment plants with nematode only were (9.6، 6.2) cm respectively.The results of the polymerase chain reaction (PCR) revealed a Positive results by using SCAR primer in this technique to two isolate of fungus Trichoderma (T. harzianum and T. hamatum) through success in the amplification process to 7 isolate of the fungus as given expected band (837 base pairs) which back to the species T.harzianum, while the species T.hamatum the size of band was (450 base pairs), the recording of two species using this technique is the first in Wasit province and Iraq.

تقييم الواقع البيئي لمعمل بابل /2 للبطاريات Assessment Study For The Environmental Situation of Babylon\2 Batteries Plant

اسم المؤلف: منال مالك سعدون الموسوي
اسم المشرف: سهير ازهر الكاظمي
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: البيئة
الدرجة: ماجستير
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: In this study was investigated the quantity and quality of industrial water from (Babil/2 batteries plant in Baghdad) and estimate the amount of air pollutants for some factory sections and estimate the amount of solid waste resulting from the industry and study the impact of these pollutants on the environment and public health.The first target of this study is investigated the physical and chemical characteristics of the discharged water from sections shipping and ficus where the sample water collocated was two samples per month for 6 month was taking during period from Novembers 2013 to May 2014. Some measurements were conducted laboratory and others on site, the result showing the following values of the variables rates for the shipping and ficus sections before treatment and respectivelyResults of the study showed that there is a significant increase inThe concentrations in sulfate and TDS, heavy metal When reached after treatment for the same variables and respectivelypH 9.9, EC 1524.9 ?s/cm, TSS 166.4mg/l, TDS 611.7mg/l, Cl - 64.46mg/l, (SO4)+2 486.8mg/l, BOD 49.2mg/l, COD 220.4mg/l, Pb+2 0.55mg/l, Zn+2 0.09mg/l, Cd+2 0.01mg/lpH 8.2, EC 1191.6?s/cm, TSS 68.1mg/l, TDS 927.6mg/l, Cl - 76.95mg/l (SO4)+2, 722.6mg/l, BOD 4.4mg/l, COD 29.2mg/l, Pb+2 0.04mg/l, Zn+2 0.03mg/l, Cd+2 0.01mg/lFrom the results of the study showed that there is a no significant increase in the concentrations in sulfate and TDS, but increases slowly. In the water of charging department reached the concentration of same variables and respectivelyThe second aims of this study a steamed the concentration and rate of air pollution (Total Suspended Particles, heavy metal, Oxides and gases) collected the sample of outstanding minutes analysis made to know and identify the concentration of heavy metal for same factory section and compared those with local and global determinants also the concentration of air emitted was measured.Results of the study showed that there is a significant increase in the concentrations of the outstanding minutes compared to the allowable limits as it reached the highest concentration in the Department of Shipping 3313.46?g/m3. The lowest concentration was in the section of the Aggregation 0.8155?g/m3. Where the concentration of heavy metals, especially lead element exceeded the permissible limits as it reached the highest concentration in Ficus section 3.53?g/m3 the lowest concentration in the assembly department which is 0.36 ?g/m3 concentration of CO gas in the department of Ficus, Shipping, assembly, queries reachedpH 1.6, EC 12058?s/cm, TSS 148.3mg/l, TDS 10122mg/l, Cl - 76mg/l(SO4) +2 3838mg/l, BOD 23.55mg/l, COD 203.5mg/l, Pb+20.55mg/l Zn+20.46mg/l, Cd+2 0.022mg/lrespectively.(21.7, 3.9, 2.44, 2.84?g/m3), the concentration of CO2 was 231.8, 187.6, 219.4, 225.4?g/m3.In the department of Ficus, Shipping, assembly, respectively queries either NO2 was 0.12?g/m3 in sections of Ficus, Shipping and queries, 0.16?g/m3 in the assembly department. The H2S appeared only in sections Ficus, Shipping with concentration 0.02?g/m3, 0.18?g/m3 respectively, either gas SO2 only appeared in the shipping department and was only 0.01 ?g/m3.The last part of these study was to calculate the amount of solid waste for a period of study in terms of total solid waste generated by the plant was 37.004 tons for eight months and included this waste pastes lead and lead plates and scrap processing units either the amount of recycling of batteries that are broken in the foundry of lead in Khan Dhari amounted to 354.832 tons for eight months, and the output of 181.1 tons. In this study we foxed on the problems in these factory that effected the process of industry and we found liquid wastes in the factory is not efficient in reducing the concentrations of all the variables treatment and gaseous emissions generated in the factory, there are no have any significant treatment of solid waste recycled and are utilized as it emerged that the Babil / 2 battery plant on a large degree of pollution sulfate and TDS with regard to liquid waste. The minutes and the outstanding lead with respect to gaseous pollutants to the current study that recommended a set of recommendations that would work to eliminate or minimize the causes of pollution and thus access to good results.

تاثير الملوحة في نمو ونشاط بكتريا الازوتوباكتر واثرهما في نمو نبات الحنطة Triticum aestivum L. The Impact of Salinity On The Growth And Activity of Azotobacter. Spp And Their It Imfuces On The Growth of The Plant Wheat (Triticum Aestivum L.)

اسم المؤلف: اية خالد كريم
اسم المشرف: فارس محمد سهيل
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: النبات
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: الخلاصة اشتملت الدراسة تنفيذ خمس تجارب, فضلا عن عزل بكتريا الـ Azotobacter وتنقيتها وتوصيفها وذلك من خلال جمع 16 عينة تربة من رايزوسفير محاصيل عدة من مناطق مختلفة من محافظة ديالى.كانت اربع تجارب مختبرية نفذت بهدف قياس اقل تركيز مثبط MIC من الـ NaCl في نم | The study imvolved implementation of five experiments, as well as the isolation, purification and classification of the bacteria (Azotobacter) and through the collection (16) soil samples from Rhaizosphre several crops from different regions of the province of Diyala. The four laboratory experiments carried out to measure less inhibitory concentration MIC in the growth and the number of bacteria Azotobacter and fixation of atmospheric nitrogen and produce GA3 from bacteria. Fifth experiment pot experiment to study the effect of two types of bacteria Azotobacter and interference with water drainage in the growth and yield plant wheat (Triticum aestevium L.) type (Aba 99).Isolate and diagnose the bacteria Azotobacter : The screening showed and diagnostic results that 11 isolation is a subsidiary of the type A.chroococcum, and 5 isolates belonging to the sensitization A.vinelandii.The isolates (A10, A2, A6, A8) was chosen from A.chroococcum and (A9, A5, A16, A14) was chosen from A.vinelandii was chosen as local isolate used in laboratory experiments based on the measurement of the soil salinity isolated ones, and selected isolates A10, A8, A5, A14 local isolate used as biofertility to the experience of pots because of their ability to nitrogen fixation by measuring the amount of nitrogen fixation in the third experiments. Laboratory experiments : The first and second experiment : Two trials were conducted Laboratory by using randomized complete block design (RCBD), each experiment included (120) experimental unit for each lap. Resulted from (8) isolates bacterial and five Trakizmn salt NaCl (0, 1, 3, 5, 7)% and (3) replicates, and incubated for three periods lap (1.3, 6) days to calculate the (MIC) in the growth and cell numbers bacterial. The results showed that the number of bacteria cells A.vinelandii rate increase all isolates A.chroococcum regardless of the concentrations of NaCl and extended incubation. Although isolates (A16, A14) isolated from soil salty surpassed isolates (A9, A5) isolated from soil is salty, and isolates (A8, A6) A.chroococcum of bacteria isolated from soil salty surpassed isolates (A10, A2) isolated from non - saline soil. The highest values of the numbers of bacteria are isolates A8, A16, amounting to (11.13, 11.0) * 104.cfu g - 1 dry soil. The increase in the concentration of NaCl led to a decrease significantly in the growth and the number of bacteria Azotobacter cells as the decline amounted to 17.13%, 45.52%, 59.50%, 76.99% at concentrations of 1%, 3%, 5%, 7%, respectively, and recorded the lowest numbers in the values of focus 7%, reaching 3.80 * 104. Cfu g - 1 dry soil. The growth and numbers of bacteria Azotobacter increased treatment effect when increasing the extended cuddling and all concentrations of NaCl. In a period of one lap on all isolates were grown in 1% NaCl concentration of the MIC for all isolates focus is 1%, while the two lap 3 days, all isolates growing focus recorded (3%, 5%) excluding A16 isolation of bacteria A.vinelandii was able to focus on growth until 7%, so the damper the MIC for this isolation focus is to concentrate 7%, while the rest of the isolates the MIC have 5%, which indicates that this isolation is more resistant to salinity of the isolates.The third experiment : The results showed that the rate of nitrogen fixation bacteria Azotobacter between (0.008 - 0.04%), but an increase in local concentrations led to a decline in moral decline as nitrogen fixation rate of 50.0%, 77.5%, 95.0%, 98.0% at concentrations of 1% salinity, 3%, 5%, 7% respectively.All isolated of bacteria Azotobacter can nitrogen fixation in the all salinity level. although A.chroococcum isolates isolated from non - saline soil surpassed isolates isolated from soil salty and all levels of salinity. Fourth experiment : A laboratory Conducted experiment by using a randomized complete block design (RCBD), included the experiment (12) experimental unit. Resulted from (4) bacterial isolates and three concentration of salt NaCl (0, 3, 5)% to calculate the MIC in the production of bacteria gibbereline Azotobacter. The results showed that the production rate of bacteria gibberline Azotobacter and all isolates ranged from 0.996 - 3.6 mg. L - 1, regardless of the concentration of added NaCl. And increasing salinity levels have led to a reduction in the production of Aljprlin, recorded A8 isolation from A.chroococcum isolated from soil salty higher values in the production of Aljprlin and all levels of salinity Experiemet of pots : The experiment was Carried out in the College of Agriculture, University of Diyala in the soil of a fusion sand using a design full sectors randomized (RCBD) in the winter season of the year (2013 - 2014). The experiment included on (60) experimental unit, resulting from the overlap between the four isolates bacterial treatment compared without the addition of bacterial vaccine and four concentrations of water drainage. The results showed that the addition of the vaccine bacterial gave a significant increase in plant height, dry weights of grouped shoot and root, leaf area, chlorophyll content, holds grains, protein and the concentration of elements of N and decrease the concentration of Na elements, Cl and proline.The addition of the vaccine bacterial and all isolates used led to a significant increase in plant height, dry weights of grouped shoot and root, leaf area, chlorophyll content, holds grains, protein and the concentration of elements of N, and decrease the concentration of Na elements, Cl and the preparation of bacteria Azotobacter in the soil compared to non - bacterial vaccine in addition to all the concentrations of water drainage. The isolates were isolated from soil salty gave an increase in traits higher than isolates isolated from non - saline soil.

دراسة نسجية مقارنة للامعاء بين طائر الحمام الضاحك وطائر الرفراف Comparative Histological Study of Intestine Between Laughing Dove And Kingfisher

اسم المؤلف: علي نديم جواد الشباني
اسم المشرف: عدنان وحيد البديري
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: هما طائر الحمام الضاحك او فاختة النخيل Laughing dove من الطيور اكلات الحبوب وطائر الرفراف Kingfisher من الطيور اكلات اللحوم اعتمادا على طبيعة الغذاء. تضمنت الدراسة فحص مظهري ونسجي للامعاء لكلا النوعين في ثلاثين طائرا بالغا تتراوح اوزانهم بين 96.6 ± 0.87 | The study was designed for the purpose of identifying the tissues structure in the intestines of two Iraqi wild birds, Laughing dove, granivores birds and Kingfisher of birds carnivores birds depending on the nature of the food. The study included morphological and histological of intestines of both types in thirty adult birds their weights ranging between 96.6 ± 0.87 grams in the laughing and 101.8 ± 0.49 grams of Kingfisher. These birds were obtained by caught from different areas in AL - Qadisiya province regardless of their sex and then divided into two groups, every group included fifteen birds represent the order of studied birds. Five birds for the purpose of studying the morphological structure and another ten for the purpose of examining the histological structure, from each group. Birds were Seduced and opened by the abdominal area carefully. The intestines of the birds were visually described, both the small and the large intestine. Both birds intestines were separated from their bodies.Then, the weights of birds were accounted. After that, the ratio of birds intestines was recorded according to birds bodies. The results of morphological structure have showed that there are similarities in the parts and position of intestines in both studied birds.Also, it has been showed that the ratio of weight of both small and large intestines to the body was higher in kingfisher bird 2.23% and 0.42% compared with that ratio in laughing dove 1.94% and 0.52%. The intestine of laughing dove was longer than that of kingfisher.The duodenum forms single loop that encircles pancreas in both birds. There is no diverticuli vitelini that separates jejunum and ileum. It has been found that there were couple of cecaea in laughing dove bird and not found in white breasted kingfisher. The results of histological study has showed that the wall of intestine in both birds consists of four main layer different in their thickness which are mucosa layer, submucosa layer, muscularis layer and serosa layer.The mucosa layer consists of simple epithelium, lamina propria and muscularis mucosae layer.The three parts of intestine duodenum, jejunum, ileum have similarity in their histological structure in that the mucosa layer modified into a lot of villi which were longer and thicker and contain more branches in its base parts in kingfisher compared with that of laughing dove birds which was shorter and thinner, The villi were covered with a lot of columnar cells and brush border that have goblet cells which their number increase toward the of digestive canal. It has been noted that there was differences in layer thickness that form intestine wall.The mucosa layer was thinner compared with other layer. The villi of ceacae were short and flat, the villi of rectum were short in both birds.The cloaca villi were longer and clearer of laughing dove that of white breasted kingfisher. It has been concluded that the difference of food type that the birds have can have clear effect in both morphological and histological structure of intestine ; namely, the thickness of layers that forms their walls.

دراسة تاثير المستخلص المائي لنبات الحناء Lawsonia inermis كمضاد للاكسدة في ذكور الجرذان البيض المعرضة للاجهاد التاكسدي A Study Effect of Henna Aqueous Extract Lawsonia Inermis As Antioxidant in Exposed Oxidative Stress White Male Rats

اسم المؤلف: سعدية جمال قادر السامرائي
اسم المشرف: صالح محمد رحيم العبيدي منيف صعب احمد ساجت الجنابي
الموضوع العام: علوم الحياة
السنة: 2012
الموضوع الدقيق: الحيوان
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: صممت هذه الدراسة لمعرفة تاثير المستخلص المائي لنبات الحناء Lawsonia inermis كمضاد اكسدة في ذكور الجرذان البيض المعرضة للاجهاد التاكسدي المستحدث ببيروكسيد الهيدروجين مع ماء الشرب طيلة مدة التجربة البالغة 30 يوما، بالاضافة الى فيتامين C المعروف كمضاد قوي لل | The study was examined the effect of aqueous extract of the Lawsonia inermis antioxidant in Albino male rats which exposed to oxidative stress induced hydrogen peroxide with drinking water for the duration of the experiment of (30 days), compared with vitamin C, known as strong anti - oxidant.1. The results showed that hydrogen peroxide led to a high moral (p <0.05) in the level of Glucose and Cholesterol, Triglycerides (TG) and low lipoproteins - lying density cholesterol (LDL - C) and lipoproteins low - lying density cholesterol is very (VLDL - C) and evidence Atherosclerosis, phospholipids and Malondialdehyde (MDA) peroxynitrite radical (ONOO - ) , Urea and Total count of white blood cells (WBCs), as well as significant decrease at the level (p <0.05) in the level of high - density lipoproteins cholesterol (HDL - C) and the level of, Glutathione (GSH), and Ceruloplasmin (CP), Uric acid, Albumin, serum Creatinine in the blood of Albino male rats exposed to oxidative stress.2. Resulted in treatment of male rats, eggs exposed to stress oxidative vitamin C (concentration of 250 mg \ kg of body weight) to a significant decrease (P ? 0.05) compared with the group treated with H2O2 only in the total count of white blood cells and the level of glucose, cholesterol, Triglerids and lipoproteins and low density cholesterol and very low - lying density of cholesterol and signs Atherosclerosis and Phospholipids, Urea, and the Malondayaldehid Peroxynitrite radical, while the moral high concentrations in high - density lipoprotein cholesterol, uric acid, Albumin, Creatinine, and, Glutathione and Ceruloplasmin.3. As well the treatment of animals exposed to stress oxidative Palmstkhals water plant henna to a significant decrease compared with the group treated with H2O2 only in the total number of white blood cells(WBCs) and concentrations of glucose, cholesterol, Triglycerides (TG), lipoprotein and low density lipoprotein choesterol LDL - C, and low density is very VLDL - C, phospholipids, levels of evidence Altasd, Urea, and the Malondayaldehid MDA and Peroxynitrite radical, (ONOO - ) while the moral high concentrations in high - density lipoprotein choesterol, HDL - C, Uric acid, Albumin, and, Glutathione and Ceruloplasmin.4. That the treatment of Albino male rats group water plant henna led to a significant decrease in the concentration of Malondayaldehid Peroxynitrite radical (ONOO - ) compared with the control group, while did not show significant difference (P> 0.05) in the concentrations of Glucose, total cholesterol, Triglycerides (TG), lipoprotein, high - density cholesterol lipoprotein HDL - C, and low density cholesterol lipoprotein LDL - C, and low density cholesterol is very VLDL - C, phospholipids, Atherogenic indices levels I, II and III, Uric acid, Creatinine, Albumin, Ceruloplasmin, Urea, peroxynitrite radical and total (WBCs) number of white blood cells compared with control group. It is clear from the current study that aqueous extract of henna, vitamin C role of great importance to reduce the emergence and development of atherosclerosis induced proxaid hydrogen as anti - oxidation which removal of free radicals, and contain the extracted compounds in particular have an impact on physiological and biochemical events occurring in the body and without side effects makes it possible to make use of the prevention and treatment of many different conditions, which may reflect the preventive role of this extract against free radicals.

التحري عن عوامل الضراوة لبكتيريا اشيريشيا القولون المعزولة من المرضى المصابين بالتهاب المجاري البولية وقياس نمط بعض الحركيات الخلوية لديهم Detection of Virulence Factors of Escherichia Coli Bacteria Which Isolated From Patient With Urinary Tract Infection And Measuring Some Cytokines In Them

اسم المؤلف: رواء ماجد محمد البو صالح
اسم المشرف: ميثم غالي يوسف
الموضوع العام: علوم الحياة
السنة: 2014
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: تضمنت هذه الدراسة جمع 100 عينة من اعمار مختلفة للمرضى المصابين بالتهاب المجاري البولية الذين راجعوا مستشفى الديوانية التعليمي ومستشفى الولادة والاطفال في مدينة الديوانية , خلال المدة من تشرين الثاني 2012 الى نيسان 2013 للتحري عن بكتيريا Escherichia coli ا | groups of patient with pyelonephritis, whose visited Al - Dewaniya teaching and Woman s and children hospital in Al - Dewaniya city during the period from November 2012 to April 2013 for detection the isolates of Escherichia coli. The results showed that 56% of bacterial isolates were E.coli and 44% isolates belonged to others bacterial types. These results indicated that the females were more infected 67.86%(38\56) with pyelonephritis than the males 32.41(18\56). Always our result were pointed that the age of 30 - 39 old years have beeninfected with pyelonephritis and present the high percentage infection 30.36% comparison with others age groups (1 - 9, 10 - 19, 20 - 29, 30 - 39, 40 - 49, 50 - 59, 60 - 69, 70 - 79) , with percentage of (1.79%, 7.14%, 14.29%, 30.36%, 19.64%, 10.71%, 12.50%, 3.57%) respectively. The resistance of E.coli isolates to the four generation of Cephalosporin antibiotics were showed the following state : - The first generation of Cephalosporin antibiotic were indicated to Cephalothin 76.6%, Cefazolin 71.4%, Cephlexin 69.7% and Cephadroxil 66.1%. - The second generation of Cephalosporin antibiotic were indicated to Cefaclor 59.0%, Cefonicid 60.8%, Cefprozil 50.0%, Cefoxitin 64.2% and Cefmetazole 55.3%. - The third generation of Cephalosporin antibiotic were indicated to Ceftriaxone 32.2%, Cefotaxim 35.7%, Ceftazidim 37.5%, Cefixim 42.9%, Cefdinir 35.7% and Ceftizoxim 30.4%. - The fourth generation of Cephalosporin antibiotic were consisting of one antibiotic only like Cefepime with percentage of 39.3% The results concerned the virulence factors genes showed that the gene irp2 witch responsible for taking the iron from the blood, whereas the gene pap responsible for the production of P - type Pilli, afa gene responsible for the production fimbriae, iha gene responsible for production of capsule and the gene tst responsible for toxic shock. The result of PCR for the E.coli DNA showed that all the thirty isolates of this bacteria contain the gene irp2, while the others genes pap, afa, hly, and iha were presented the following percentage 36.6%, 30.0%, 96.6% and 10.0%respectively, whereas the gene tst didn’t recorded any isolates concerting. So in this study was to measure immune factors related to the urinary tract infection is in general and pyelonephritis in specially, has been measure some of cytokines which (Interleukin - 8, Interleukin - 6, Tumor necrosis factor - ?), they found increase in these factors in sera of patients with pyelonephritis compared to healthy persons.

تاثير التلوث البيئي على بعض النباتات النامية في مناطق ملوثة بالعناصر الثقيلة في محافظة نينوى The Effect of Environmental Pollution on Some Plants Growing in Polluted Sites By Heavy Metals in The Province of Nenivah

اسم المؤلف: حسين صابر محمد علي الراشدي
اسم المشرف: يحيى داؤد وهب المشهداني خليل ابراهيم بندر النعيمي
الموضوع العام: علوم الحياة
السنة: 2009
الموضوع الدقيق: البيئة
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الكلمات الدلالية:
  • البيئة - التلوث البيئي
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة في جامعة الموصل / كلية التربية /قسم علوم الحياة، لتحديد بعض المناطق الملوثة بالعناصر الثقيلة (Cu, Zn, Cd) في محافظة نينوى، وتاثيرها على النمو والقيمة الغذائية وتراكمها في الاجزاء المختلفة للانواع النباتية المختلفة المزروعة في هذه المواقع | this study is conducted in the University of Mosul - College of Education department of biology to identify some of the areas polluted with heavy metals (cu, zn, cd) in the Province of Nineveh, and their effect upon the growth and the nutrition value and its accumulation within the different planted species in these areas. Furthermore, the effect of soil treatment with cadmium, zinc, and copper have been studied with different concentration on the physiology growth and response and the nutritious value of the safflower, fenugreek, coriander, and flares and its ability to accumulate the heavy metals in its different parts as a technique of treating polluted soil with heavy elements through plants.The results showed that the upper Maximum recorded value of cadmium and copper in the soil of Hawi ALkanisa area reached 1.509, 15.900 mg/kg soil respectively and zinc in the soil of Hamam Alaleel area which reached 181.470 mg/kg.The most polluted area with heavy metals was Hawi ALkanisa, Alshora, Hamam Alaleel and Aldanadan in comparison with the other areas and this affected negatively on the growth and nutrient value of vegetables (Malva sylvestris, Beta vulgaris, Apium graveolens, Menthae piperitae, Raphanus saltivus, and Lepidium sativum) planted within these area where it had been noticed the decrease of these plants growth and its neutrinos value with respect to plants content of nutritious mineral elements such as calcium, magnesium, potassium, chloride, and sodium with concentration of proteins and carbohydrate and the occurring of an increase in the concentrations of heavy metals (cu, zn, cd) in the different plant parts in comparison with the growing plants in other less polluted areas.It became clear that the most resistant plants to the effects of these elements was the Raphanus sativus which belongs to the plant family Cruciferae known of its role in removing and treating polluted soil with heavy metals.The study in the plastic greenhouse showed that soil treatment with cadmium within concentrations (1, 2, 3) mg/kg and with zinc in concentrations (150, 300, 450) mg/kg and with copper in concentrations (50, 100, 150) mg/kg of soil caused decreasing the growth of safflower, fenugreek, coriander, and flares plants, and decreasing its protein, carbohydrate, and potassium concentration in the different plant parts. Moreover, it caused increasing peroxidaes and Superoxide dismutase enzymes in the Shoot and increasing heavy metals concentration in the different plant (the Shoot and Root group and grains)of the four plants.Also increasing these elements concentration was directly proportional with increase concentration in soil, and the study showed that the most tolerant plants for elements effect was safflower in comparison with the other plants.

دراسة تصنيفية مقارنة لانواع الجنس Heliotropium L. (Boraginaceae) في وسط وشمال العراق Comparative Taxonomical Study of The Genus Heliotropium L. (Boraginaceae) in Mid And North of Iraq

اسم المؤلف: محمد عدنان هاشم ال ابليش
اسم المشرف: طالب عويد الخزرجي عقيل حسين العاصي
الموضوع العام: علوم الحياة
السنة: 2012
الموضوع الدقيق: النبات
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: صلاح الدين
الصفحات الاولى:
المستخلص: تضمن البحث الحالي دراسة مقارنة مظهرية وتشريحية وكيميائية ووراثية لثمانية انواع تابعة للجنس Heliotropium L. (Boraginaceae) في وسط وشمال العراق هي H.bacciferum Forssk., H.ellipticum Ledeb. H.europaeum L., H.lasiocarpium Fisch., H.noeanum Boiss., H.ramosissi | The current research study is a comparative morphological, anatomical, chemical, genetical of the genus Heliotropium in mid and north of Iraq between eight species belonging to the genus of the family Boraginaceae, and the study included some morphological characteristic of the roots, stems, leaves, flowers (calyx, corolla, stamens, pistils), inflorescence, fruits and pollen grain shows that there are clear differences between the species under study. The study included aspects of anatomy and the differences included the qualities of epidermis leaf and stem and stomata as well as study transverse sections of roots, stems, leaves and petiole and peduncle, fruits, Nutlets and seeds, also studied the system of Venation in the leaf where he studied the type of venation as well as study the direction of midrib, thickness, branching as well as the study of secondary veins, Arrangement, Aerioles and Veinlets that showed clear differences between species.The study showed that pollen grains in the species are Tricolporate in all species except H.bacciferum it contains four grooves and pollen grains of contain Psaudotricolporate found in all species except H.lasiocarpium was completely absent of false grooves have distinguished this species by this character, showed the study of pollen grain Psaudotetracolporate in species H.bacciferum only and did not appear in the rest of the species. the study noted that there are variations evident in the two axes equatorial and polar as well as in the length of the groove, width, the rate of the thickness of the wall of pollen grain, the rate of diameter germination aperture in all species. The study showed clear difference between species in dimensions of upper and lower epidermis leaf, as well as a study stomata index on the surfaces of upper and lower leaves where show that all species were the lower surface more than the upper surface in density of stomata and Trichomes were studied in all parts of plants under study it was observed that there is variation in the distribution of hair and their locations as well as the lengths of hairs and thickness of the walls and shape of apex and base. Studied species in pathway of photosynthesis showed that two species are C4 plants H.noeanum, H.suaveolens either species H.bacciferum, H.ramosissimum, H.lasiocarpium was belong of intermediate C3 - C4 species while the rest were from C3 plants after analysis qualities and similarities of these qualities were very important to isolate the species from each other because present of bundle sheath, thickness of leave in cross section, thickness of cuticle, thickness of chlorenchyma and collenchymas tissues, frequency of stomata and it distribution, the number of aerioles and veinlets density and size. Has also been studying the chemical content of alkaloids and found that there are six alkaloids isolated for the first time from inflorescences for plants belonging to the genus Heliotropium were isolated using the technique liquid chromatography for identified six alkaloids compounds (indicine and supinine, indicine - N - oxide, heleurine, heliotrine and lindelofidine), which included the study of compounds Alkaliods type, concentration and percentage and the pyrrolizidine alkaloids that have a biological importance of cure tumors and cancers. The study showed high percentage of heliotrine in four species of Heliotropium H.bacciferum, H.ramosissimum, H.europaeum, H.noeanum were (48%, 54%, 51%, 54%) while heleurine was high percentage in two species H.suaveolens, H.supinum were (33%, 56%), while the study showed lower percentage of indicine - N - oxide in three species H.ramosissimum, H.noeanum, H.supinum were (2%, 4%, 1%). The current research identified for the first time on the content of the Glycosides from inflorescences in eight species of Heliotropium from mid and north of Iraq. These species are H.bacciferum, H.ellipticum H.europaeum, H.lasiocarpium, H.noeanum, H.ramosissimum, H.suaveolens, H.supinum by using the liquid phase chromatography diagnosis of six compounds (heliotrope, isopyrrolidine, isorhamnetin, naringenin, quercetein, triterpene) results showed that plant species studied vary their content of these compounds, with absent of naringenin in the species H.noeanum while absent of triterpene in species H.ellipticum, H.europaeum, H.supinum. They also showed the studied differences in concentrations glycosides and percentage of species as shown H.europaeum, H.lasiocarpium, H.noeanum, H.ramosissimum, H.supinum, H.suaveolens lower concentrations (12 - 37 mg / ml) and percentages (1 - 9%) for quercetein compared to the rest of the species studied and the species H.europaeum, H.lasiocarpium, H.noeanum, , H.supinum, H.suaveolens were higher concentrations (99 - 442 mg / ml) and percentages (26 - 51 %) for heliotrope compared to other species. These results indicate the possibility of the adoption of the content glycosides for inflorescence criterion for the separation between species as well as use for medical purposes, especially pyrolizidine and isopyrrolidine important in the treatment of tumors and cancer. Studied the genetic variation through the study of random variation indicators RAPD for eight species of the genus Heliotropium, and using 14 primer showed variation between the species under study and were divided into two groups are : 1. Group A : Included only two species H.bacciferum, H.ramosissimum where the genetic distance between these two species (0.249) where the two species are similar in genetic traits and genetic content in the absence of many bands of the primers and appear in the other. 2. Group B : Included six species of the genus Heliotropium under study and was less genetic distance between H.ellipticum, H.europaeum where (0.105) and this is a great similarity in appearance bands between the two species in some of primers, then the following two species were also two other, where he was the closest genetic distance between the two species H.lasiocarpium, H.noeanum where (0.153) and was very close two species of H.ellipticum, H.europaeum were was (0.125). The data were analyzed and characteristics after into the program (NTSYSpc) to study morphological and anatomical, chemical, genetic and find a genetic distance inter - species on the basis of similarity So was isolated species to groups and based on a large number of morphological characteristics and anatomical, chemical, genetic possible distinguish species from each other and show the variation at the level of species belonging to the genus Heliotropium.

دراسة ادلة التنوع الاحيائي لتقييم مجتمع العوالق الحيوانية في نهر الكوفة - العراق A Study of Biodiversity Indices To Assessment The Zooplankton Community In The Kuffa River - Iraq

اسم المؤلف: حسين عليوي حسن الكرعاوي
اسم المشرف: مهند رمزي نشات
الموضوع العام: علوم الحياة
السنة: 2014
الموضوع الدقيق: الحيوان - اللافقريات
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: اجريت هذه الدراسة على نهر الكوفة في وسط العراق والتي هدفت الى التعرف على التنوع الاحيائي للعوالق الحيوانية من خلال قيم بعض ادلة التنوع الاحيائي وكذلك والتعرف على نوعية المياه من خلال قياس بعض الخصائص الفيزيائية والكيميائية لمياه النهر وكذلك من خلال قيم دل | The Present study was carried out on the AL - Kuffa River in the middle of Iraq to know biodiversity of zooplankton by through some of biodiversity indices values and to know water quality by through measurement some physical and chemical characteristics of water as well as by through the Canadian Water Quality Index (CCME WQI) values. The samples of the study have been collected monthly for water and zooplankton for the period from March 2012 till February 2013 at four selected stations in the river; the first is located in Al - Kufel city, the second in Al - Kuffa city, the third in Aboskeer city and the four after Al - Mushkab city. The study was achieved by measurement of some physical and chemical properties of water were analyzed based on the importance of these parameters the parameters studied included Air temperature, water temperature, pH, water current velocity, turbidity, total suspended solids, electrical conductivity, salinity, total dissolved solids, dissolved oxygen, percentage of saturation, biological oxygen demand, total alkalinity, total hardness, calcium, magnesium, chloride, sulphat, phosphate and nitrate. The study also included biological aspects using density, Rrelative abundance index (Ra), Constancy index (S), Species richness index (D), Shanon - Weiner index (H), Species uniformity index (E) and Jaccard presence - community were also employed to determine the values of species composition, density and zooplankton biodiversity in the study area. The results showed clear consensus from air temperature and water temperature in all study locations.Air and water temperature ranged from 6 to 41 ?C and 7 to 34?C respectively, the Water current velocity values were fluctuated according to the different water levels during the study period and ranged from 0.19 to 0.71 m/sec, while the (TSS) values were low and ranged from 3.54 to 52.05 mg/l, and turbidity 1.69 to 55.76 NTU, the pH values were neutral tend to light alkaline and ranged was ranged from 7.1 to 8.7, The electrical conductivity values varied from 810 to 1810 ?s/cm, according to the values of salinity 0.51 to 1.158 ‰ the water of the river was classified as Oligohaline, (TDS) showed medium values ranged from 440.4 to 977 mg/l. This study showed that river were well oxygenated the dissolved oxygen values ranged from 5.5to12.2mg/l and high percentage of saturation recorded from 72 to 148 %, The study recorded values to the BOD5 were ranged from 0.9 to 6.4 mg/l.The study showed that the water of the river was classified as slight alkaline and bicarbonate ions were dominant throughout the study period according to the values of total alkalinity from110 to 210 mg CaCo3/l, and the river water classified as very hard according to the total hardness values from 237.9 to 538.2 mg CaCo3 /l., While the concentrations of calcium and magnesium were from 73.19 to134.1 and from10.46 to 55.59 mgCaCO3/L respectively, The chlorid and sulfate values were from117.6 to 244.5 mg/l and136.9 to 528.14mg/l respectively, The nutrients showed clear fluctuation in their concentrations, nitrate values were varied from 3.55to36.43?g/l and phosphate values were from 0.15 to 2.89 ?g/L.. In the current study about 164 Taxonomic units of zooplankton were identified, the rotifer was dominate group including 92 taxa to rotifera, 35 taxa belonging to cladocera and 37 taxa to copepod. The Zooplankton showed high density in river 29470 ind /m3 during April 2012 while lower1100 ind/m3 in December 2012 also the rotifer recorder density from 425 to 17925 ind/m3, cladocera density from 25 to 4850 ind/m3 and copepod density from 300 to 15450 ind/m3 the high values were in spring and autumn while lowest values were recorded in summer and winter. The results of relative abundance index showed that the species rotifera : Keratella cochlearis, K.valga, Euchlanis delatata while the cladocera Alona rectangular, Bosmina longirostris, Chydorus sphaericus, Simocephalus vetulus and the copepods : nauplii were more abundant in the kuffa river. also the results of Constancy index showed fourteen taxa belonged to zooplankton which were considered "Constant" at stations However the other taxonomy units varied from "accessory" and "accidental" taxonomy units in study stations he Values of the index of Species richness of Rotifer varied from 3.42 to18.26 and Cladocera varied from 0.9 to8.13 and Copepod from1.46 to 6.13 with greatest values were recorded in April While lower values in September and June The highest percentage of similarity 70.58% for Zooplankton were reported from stations 3 and 4 in and lowest similarity reaching 50.30% from stations 2 and 3. the Shanon - Weiner index of total Zooplankton varied from 1.81 to 4.13 bit/ind while the Shanon index of Rotifer from 1.85 to 3.78 bit/Ind, Cladocera varied from 0.001 to 3.03 bit/Ind and Copeoda varied from 0.35 to 2.71 bit/Ind with greatest values were recorded in April 2012 and September 2012 While lower values in and June 2012 and January 2013, The uniformity index of Rotifer varied from 0.01 to 0.9, Cladocera from 0.01to 1 and Copeoda from 0.14 to 0.88 These high values indicate that there is no ecological stress on zooplankton in the study area. The results of the Canadian Water Quality Index (CCME WQI) for aquatic life showed that the water quality of River Kuffa in the study area obtained good to marginal level (90.93 - 62.76) the highest value was recorded at station 1 through April 2012 and lowest value was recorded at station 2 through July 2012

التغيرات الفسلجية لضربين من الباميا Abelmoschus esculentus (L.) Moench بتاثير حامض الدبال والزولفاست Physiological Changes To Varieties of Okra Abelmoschus Esculentus (L.) Moench By Effect of Humic Acid And Zolfast

اسم المؤلف: ندى سالم عزيز الموسوي
اسم المشرف: عبد الامير علي ياسين
الموضوع العام: علوم الحياة
السنة: 2013
الموضوع الدقيق: النبات - الفسلجة
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: القادسية
الصفحات الاولى:
المستخلص: نفذت هذه الدراسة في كلية الزراعة/ جامعة القادسية خلال المدة من 10/4/2011 حتى 15/10/2011. الهدف منها دراسة الاستجابة لضربين من الباميا (الحسيناوية والبتيرة) لطريقتي اضافة حامض الدبال ومستحضر الزولفاست (الرش الورقي ومع ماء الري) وبتركيزين لكل منهما (الموصى | This study was conducted in Agriculture College, AL - Qadisiya University during the period of 10/4/2011 till 15/10/2011. The aim of the study was studying response of two okra varieties (Al - Husenawyia and Al - Pteira) humic acid and zolfast application methods (foliar and addition to irrigation water) and this concentration (recommended and doubled) on growth and productivity as well as leaf mineral and fruit medicinal active constituents.The humic acid and zolfast formulas were added by the use of hand sprayer or with irrigation water with the recommended and doubled concentrations for humic acid and zolfast as foliar spraying were 1 ml.L - 1 and 2 ml.L - 1 if doubled respectively while when used with irrigation water 4.8 ml.L - 1 and 9.6 ml.L - 1 if double for humic acid 7.2 and 14.4 ml.L - 1 for zolfast if doubled.The design of the experiment was Randomized complete blocks in a factorial arrangement (2×2×5) in three replications. The RLSD at 0.05 was used as a method to compare means separation treatment effect was evident. The results showed : 1 - Al - Husenawyia variety was superior in total leaf area, vegetative fresh and dry weights, root fresh and dry weights, P% and content addition to specific leaf weight, relative growth rate, fruit length, number of fruit/plant, fruits yield compared to Al - Pteira. Percentage of protein, carbohydrates, total soluble solids, caprylic, lauric saturated fatty acids and all the unsaturated fatty acids. Mucilage, folic acid and oil refractive index were also higher with Al - Husenawyia compared to Al - Pteira had higher stem diameter, fruit fresh and dry weight, K%, boron content and percentage of saturated fatty acids (Myristic, Palmatic, Stearic, Arachidic and Behinic). Ca% was the same for both cultivars.2 - Foliar application method of humic acid and zolfast showed beneficial effect on and all parameters studies except root fresh and dry weight and percentage of saturated fatty acids increased with irrigation water (except Lauric acid which was increased with foliar application). Methods of application did not affect stem diameter, Ca% in leaves and fruit total soluble solids.3 - Although the double recommended concentrations of humic acid and Zolfast reduced saturated fatty acids significantly their recommended concentration lowered saturated fatty acids (Caprylic, Myristic, Palmatic, Stearic, Arachidic and Behinic) compared to control treatment. Percentage of fiber was lower with the use of zolfast compared to humic acid and control. While K% was lowered when zolfast used in the double recommended concentration. No significant difference were found between the recommended concentrations of humic acid or zolfast in stem diameter, total leaf area, relative growth rate, vegetative dry weight, root dry weight, P%, Ca%, boron content, fruit length, number of fruit/ plant, fruit dry weight, mucilage, carbohydrates%, folic acid, oil%, percentage of saturated fatty acids (Caprylic, Myristic, Palmatic and Arachidic) and unsaturated fatty acids (Oleic and Linoleic) and the percentage of unsaturated fatty acids/saturated.4 - The interaction between cultivars and methods of application revealed that foliar application of both humic acid and zolfast reduced saturated fatty acid (Caprylic, Myristic, Palmatic, Stearic and Arachidic) significantly of both cultivars, compared to their addition to irrigation.5 - The interaction between cultivars and substances of application (humic acid and zolfast concentrations revealed that both cultivars had different response in some traits of studied to applied concentrations of humic and zolfast. Al - Husenawyia variety had higher vegetative fresh weight, root dry weight and fruit of mucilage content with the double recommended humic acid. While Al - Pteira variety had higher TSS% and Lauric acid% when used the double recommended concentration of zolfast.6 - The interaction between methods of application and concentrations of application substances showed superior effect on some studied parameters. Foliar application method was superior on addition to irrigation application with all concentrations except root fresh and dry weight and saturated fatty acids% (except Lauric acid) which were increased when added to the irrigation water to all concentrations of application substances. The same interaction did not revealed significant difference in stem diameter, Ca% and fruit fresh and dry weight.7 - The three way interaction factors studied in the experiment revealed an increase in growth parameter of both cultivars when humic acid and zolfast were added in their higher concentration (double recommended) by foliar application expect root fresh and dry weight and saturated fatty acids% (except Lauric acid) which were increased when added to the irrigation water. Al - Husenawyia variety was higher in all parameters with the use of higher concentration of humic acid and zolfast when applied with irrigation water or foliar application. The three way interaction revealed no significant difference in stem diameter, vegetative dry weight, Ca%, fruit fresh and dry weight, TSS%, percentage of oil and unsaturated fatty acids (Linoleic and Myristoleic).8 - Results of electrophoresis analysis revealed that the use of the doubled recommended concentration of humic acid and zolfast with irrigation water participated in building higher protein molecules in fruits to both cultivars. While the double recommended concentration of humic acid and zolfast did not show this trait when foliar applied.