تحضير وتشخيص مركبات غير متجانسة حلقية متعددة من مشتقات الازو اوقواعد شف == Synthesi And Identifecation of Heterocyclic Multiple Ring Compounds of Azo Derivatives And Schiff Bases
Author name:
ولاء فاضل عبد ضفير
Supervisor name:
فائز عبد الحسين عبد الرماحي
General topic:
Chemistry
Specific topic:
Chemistry
Degree:
Master
University:
University of Kufa - College Of Science - Chemistry Department
Language:
Arabic
University location:
Najaf
First pages:
25T1458 - p.pdf
Abstract:
تتضمن هذه الرسالة تحضير وتشخيص عدد من معقدات البلاديوم (??) والبلاتين (II) مع مزيج من ليكاندات الثايويوريا او الحلقات غير المتجانسة الحاوية على الامين مع السكارين او الثايوسكارين. وحضرت معقدات من النوع [M(L)2] حيث ان : M = Pd (??) , Pt (??) , L = PTUH ( | Work in this thesis includes synthesis and characterization of some palladium(??) and Platinum(II) mixed ligand complexes of thiourea or hetrocyclic amine and saccharin or thiosaccharine.Complexes of the type [M(L)2] were prepared, {M= Pd(??) , Pt(II) , L= PTUH}where : (PTUH) = {N - Pheny1 - N - (2 - thiazoyl)thiourea} by treatment of the appropriate ligand with Na2PdCl4 or K2PtCl4 to give square planer complexes, in which thiourea anoin ligand behave as a bidentate coordinate to metal through the S atom of thioamide group and the nitrogen atom of thiozolComplexes of the type trans - [MCl2(L)2] L =ABI , AT , M = Pd(?? ) , Pt(??)ABI = 2 - amino Benzimidazol وAT = 2 - aminothiazolwere prepared by treatment of the appropriate ligand with Na2PdCl4 or K2PtCl4 to give square planer complexes , in which benzimidazol and thiazol behave as monodentate coordinate to Pd(??) metal through the N atom while the Palladium thiazol complex showed two isomer the N and S - bonded isomer.Palladium (??) or Pt(II) complexes of the type trans - [Pd(sac)2(L)2] were prepared by treatment of trans - [PdCl2(L)2] with Nasac. Sac anion ligand behaves as a monodentate coordinate to Pd (??) metal through the N atom.Thiosaccharinate complexes of the type trans - [Pd(tsac)2(L)2] (L=ABI, AT) were prepared in which (L) behaves as a monodentate which coordinate to Pd(??) metal through the cyclic N atom while the thiosaccharin anion behaves as a monodentate ligand coordinated to palladium metal through the sulfur atom. The PTUH ligand was characterized by infrared spectra and (1H n.m.r).The prepared complexes were characterized by molar conductances, Elemental analysis, Infrared spectra, 1H n.m.r data also the structure of trans - [Pd(PTU)2] and cis - [Pt(PTU)2] were determined by single crystal x - ray diffraction.The complex trans - [Pd (PTU)2] crystallizes in the monoclinic space group p 21/c with a= 12.510(17) ? , ? = 5.6963 ?, C=15.322(2) ? ?=90° , ?=90.066(17) ° , ?=90° and Z=2 Molecules per unit Cell. The complex cis - [Pt(PTU)] crystallizes in orthorhombic space group with a=7.3021(5) ?, b=11.8025 (9) ?, C=25.6282(19) ?, ?=90 ?, ?=90(17) °, ?=90 and Z=4 Molecules per unit Cell.
