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تحضير وتشخيص مشتقات جديدة ين 4,3,1 - اوكسادايازول و 4,2,1 ترايازول ومعقداتها مع بعض ايونات العناصر الانتقالية Preparation and Characterization of new Derivatives of 1,3,4 - Oxadiazol and 1,2,4 - Triazole and its complexities with some transition metal ions

مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: ابراهيم عبود فليفل
اسم المؤلف: امنة نعيم هليل الركابي

تاثير المستخلص الفيولي لدرنات السعد المستدير ومركب التايورين على بعض المعايير الكيموحيوية في اناث الجرذان المصابة باحتشاء عضلة القلب Effect of Tubers Cyperus rotundus Phenolic Extract and Taurine Compound on Some Biochemical Parameters in Induced Myocardial Infarction in Female Rats

مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: محمد عجة عودة خالد كاطع الفرطوسي
اسم المؤلف: علياء ماجد مناي الكناني

استخلاص وعزل وتشخيص المركبات متعددة الفينول اكاسيتين كلايكوسيدات من بذور نبات الحلفا السبخبة ودراسة الفعالية الحيوية للمستخلص كمضاد فطري وبكتيري Extraction, Isolation and identification of poly phenols compounds (acacetin glycosides) from Cladium Mariscus seeds and study of their biological activity of extract as antifungal and antibacterial agent

مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2018
الموضوع العام: علوم الكيمياء
اسم المشرف: حسام محمد كريدي محمد تركي خثي
اسم المؤلف: رحاب حاتم بريج الشمري

تحضير وتشخيص ودراسة بايولوجية لمشتقات جديدة من 4,2,1 - ترايازول ومعقداتها مع بعض العناصر الانتقالية Preparation, Characterization and biological study of some new 1,2,4 - Triazole derivatives and theirs complexes with some transition metals.

المستخلص: he work listed by this thesis covers the preparation and characterization ofsome new derivatives of 1,2,4- Triazole as ligands which are : | 1-N : ( 2-ethyl-5-{[(3-phenyl-5-sulfanyl-4H-1,2,4-triazol-4-yl)imino]methyl}benzene-1,4-diol). (L1)2-4-({2-[(4-methylphenyl)amino]ethylidene}amino)-5-phenyl-4H-1,2,4-triazole-3-thiol (L2)3-5-methyl-4-{[1-(5-methylfuran-2-yl)ethylidene]amino}-4H-1,2,4-triazole-3-thiol (L3) | Those ligands were used to prepare some complexes such as L1,L2,L3with the chlorides of transition metal(FeCl3.6H2O,COCl3. 6H2O,CrCl3.6H2O,CuCl2.6H2O,NiCl2.6H2O)To characterize the structure of prepared ligands and their complexes, | elemental analysis (C.H.N),Infrared Spectroscopy (IR), NuclearMagnetic Resonance Spectroscopy(1H-NMR),Mass Spectra,Magneticsensitivity and Molar conductivity techniques were applied . The resultsshowed that ; | 1- The complexes of [Fe(III) , Co(III) , Cr(III)] for all ligands haveshown octahedral configuration. | 2- Complexes of [Ni(II) , Cu(II)] with all ligands have shown square | planer configuration.Testing the biological activity for ligands and their complexes by using spread method and measurement inhibition zone by using (DMSO) as asolvent showed a positivity results; By the appear laeg inhibition zonesagainst E-coli and S. aureas species of bacteria.
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: ابراهيم عبود فليفل
اسم المؤلف: احمد كامل عجيل الزيدي

تحضير وتشخيص ودراسة بايولوجية لبعض مركبات ثنائية الازو الجديدة ومعقداتها واستخدامها كوثبطات لتاكل سبيكة الفولار الكاربوني في الوسط الحامضي Synthesis,Characterization and Biological activity Study of Some Bis - Azo Dyes and their Complexes and the use of Bis - Azo dyes as Corrosion Inhibitors for Low Carbon - Steel in acidic media

المستخلص: As it used for dyes (A1,A3) P-Phenylenediamine ,while using for dyes (A2,A4) O Phenylenediamine. | here is X for dyes (A1,A2) 3-ethoxy salicylaldehyde ,while representing for | dyes 3-methoxy salicylaldehyde. | he prepared copmpounds were identified by FT-IR spectroscopy, CHN analysis, 1H-NMR spectroscopy and GC-Mass spectroscopy.Also, determination of melting pointsWhere,XIn the recent study, four azo dyes compounds were prepared (A1-A4) and tested as The inhibition efficiency of the synthesized compounds was studied , using | weight loss method in acidic solution by corrosion rate determination for | carbon steel without and with different concentratins | ) 1 , 5 , 1 , 5 ( M | of inhibitor at different immersion times (1-5) hrs ,303K and static condition | .The inhibition efficiency of synthesized compounds was calculated ,the | optimum concentration ( 5 M ) and immersion time (5 hrs) were | determined at the same conditions.The compounds have agood corrosion | inhibition with efficiency percentage of (86.47-88.26%) for azo dyes. | The effect of temperature variation on the corrosion rate for different | concentrations (1 -5 M) of the prepared compounds was studied | by using weight loss method at four temperature degrees (303, 313,323 and | 333)K and (1-5) hrs. | The experimental results of temperature effect indicated the following : | 1-The rate of corrosion inhibitors increased with the rise of temperature, while | the corrosion rate decreased with increasing of inhibitor concentration at the | certain temperature.For example ,the corrosion rate for carbon steel in the | presence of A2 inhibitor increased from 39.22mpy at 303K to 464.75mpy at | 333K.while the corrosion rate decreased from 70.50mpy at concentration of | 1 M to 39.22 mpy at concentration of 5 M at constant | temperature of 303K. | 2-All inhibitors had high inhibition efficiency in reducing the corrosion rate.The | inhibition efficiency was decreased by increasing the temperature ,for example | inhibition efficiency for A2 inhibitor was decreased from 88.26% at 303K to | 85.44% at 333K. | 3-The adsorption of the molecules on the metal surface obey Langmuir | isotherm.The adsorption constant and free energy of adsorption were | calculated for the studied inhibitors.The results showed that the adsorption | constants were decreased with increasing the temperature and the negative | value of free energy indicated that the adsorption process is spontaneous. | 4-Thermodynamic functions H and S and the activation energy Ea were | determined.The results indicated that the activation energy for acidic solution | without inhibitor (16.21 KJmol-1 )was less than of the activation energy value | with the presence of inhibitor s, (17.08-31.07 KJmol-1 ) for azo dyes .The | positive value of enthalpy indicated that the metal dissolution process is | endothermic , while the negative value of entropy reflected the reducing in the | entropy value and formation stable layer on the metal surface. | Electrochemical method (Tafel plot) was used to evaluate the inhibition | efficiency for the azo compounds using carbon steel corrosion in 0.5M HCl | solution. The percentages of inhibition efficiency were 86.84%, 93.68%, 86.70 | and 93.06% for the inhibitors A1, A2, A3 and A4, respectively, at 303K and | concentration of 5 x 10-3M. Tafel plot results indicated that the prepared azo | dyes compounds are the doublet inhibitors type. | Studying of the growth inhibition against three types of pathogenic bacteria | namely for some pigments lecture(A1,A2) and their Nickel(II) complexes by | using diffusion method and measurement inhibition zone by using (DMSO) as a | solvent , using in this study three types from bacterial two its Gram negative | bacterial strains, Escherichia coli, Pseudomonas Aeruginosa and the other is Gram positive bacterial strains , Staphylococcus aureus , We notice that the biological activity against this bacterial showed a positivity results. | Ciprofloxacin were used as standard bactericide and compared inhibition this | bacterial with Ciprofloxacin.corrosion inhibitors in acidic medium ,0.5M HCl. These compounds have general chemical structure :
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: ساجد حسن كسار حسام محمد كريدي
اسم المؤلف: اسراء عبد الكاظم جاسم الشمري

تحضير وتشخيص ودراسة الفعالية البايولوجية لمشتقات جديدة من 4.3.1 اوكسادايازول ومعقداتها مع بعض العناصر الانتقالية Preparation , characterization and biological activity of a new1,3,4 - oxadiazole derivatives and some of their transition metal complexes

المستخلص: The work described in this thesis is mainly concerned with preparation and characterization of three ligands (L1-L3) derived from 1,3,4-Oxadiazole .The study deals with reaction of these ligands with transition metal salts as (CrCl3.6H2O , CoCl2.6H2O , NiCl2.6H2O , CuCl2.2H2O) .The ligands and their complexes were characterized by the elemental analysis (C,H,N), Infrared spectroscopy (IR) , Proton Nuclear Magnetic Resonance Spectroscopy (1HNMR), Mass spectra and molar conductivity. However, the ligands and some of their were studied by using hyperchem7.5 program in order to know their geometry and proving their shapes and hypridizaion which were notice the chromium complexes is octahedral (oh), the hypridization is d2sp3 with the three ligands while the shapes of the complexes (cobalt(II), Nickel(II), Cupper (II) ) is four coor-dinated is square planar and the hypridizaion is sp3. | Antibacterial activity was carried out against Escherichia coli, Staphylococcus aureus, Streptococcus pyogenes and Klepsiella pneumonia, and with test compounds at four concentrations of (5, 2.5, 1.25, 0.625mg/ml). Azithromycin and Cefoaxime were the standard drugs utilize. Some of these compounds showed good efficacy, while others ranged from medium to small. | The hemolysis activity of the compounds was tested at different concentrations (5, 2.5, 1.25, 0.625mg/ml) and the results showed high percentage of hemolysis for all these compounds and these gave a conclusion about the contraindication use of these compounds in vivo .
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2018
الموضوع العام: علوم الكيمياء
اسم المشرف: ابراهيم عبود فليفل احمد حسن محمد
اسم المؤلف: ايمان حسين شويل التميمي

تحضير وتشخيص قواعد شف ومعقداتها المشتقة من 4 - امينوانتيبايرين واستخدامها في استخلاص ايون النيكل الثنائي Preparation and Characterization of Schiff Bases and their Complexes Derived from 4 - Aminoantipyrine and using them in the Extraction of Nickel (II) Ion

المستخلص: The study includs the preparation and charazchtion of three new compounds of the schiff bases are : | 1- L1 is prepared from the condensation of 4-amino antipyrine with Penzaal acetone . | 4,4'-((1Z,1'E)-(1-phenylbutdiylidene)bis(azanylylidene))bis (1,5-dimethyl-2-phenyl-1Hpyrazol-(2H)-one)3 | 2- L2 is prepared from the condensation of4-amino antipyrine with Asetayl acetone | 4,4'-((1Z,1'E)-pentane-2,4-diylidenebis(azanylylidene))bis(1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)- one | 3- L3 is prepared from the condensation 4-amino antipyrine with Slsldehid as a first step then it is is reactance output with 3.4-di amino toluene . | 2,2'-((1Z,1'E)-( (3E,3'E)-3,3'((4-methyl-1,2-phenylene)bis(azanylylidene)) bis(1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazole-4-yl-3- ylidene))bis(azanylyidene))bis(methanylylidene))diphenol | The ligands were characterized by using Elemental Analysis (C.H.N), Infrared Spectroscopy (FT-IR) ,Uv-visible Spectroscopy , Nuclear Magnetic Resonance Spectroscopy (1H-NMR) , Mass Spectra . It is appeared that prepearing ligands are tetra chelatingagents kind (N2O2) for the ligands L1 and L2 and kind (N4) for the ligand L3. The complexed are prepeared from reaction the prepearing ligands with some transitional elements (Ni+2 , Co+2 , Cu+2) and the ligends and their complexes were characterized by methods of spectral analysis,Uv-visible Spectroscopy,Infrared Spectroscopy (FT-IR) , Mass Spectra and the Molar Electrical Conductivity .And from the result that we know the complexes are octahedral and their general formula [M(L) Cl2] , whereas M = Ni+2 , Co+2, Cu+2 . The study includs an extraction of nickel(II) ion from its aqueous solutions using solvent extraction technique by employing the reagent L3. The optimum extraction conditions are studied to obtain a better distribution ratio of values for (D) to reach the best percent extrected (%E) to extract nickel (II) ion . It is noted that the best values of distribution ratio (D) and the best percent extrected (% E) extracting nickel ion duo with the reagent L3 at the time of shake (15) minutes .The best extraction to nickel(II) ion with reagent L3 at temperature (25C°). As it turns out from this study that the best acidic function nickel(II) ion extraction in the aqueous phase with reagent L3 in the organic phase | when the (PH=9),also the study shows that the best values of distribution ratio (D) and the percent extrected (% E) for nickel(II) ion extraction when its constriction was (120 μg/ml) | (4.5×10-4 M ).The reagent L3 concentration (1× 10-4 M) . Chloroform was the best organic solvent for an extraction process for nickel(II) ion with reagent L3.The reagent L3 also is used for extraction Ni+2 from water of the Euphrates River City of Nasiriyah and the distribution ratio (D) =4.81 and the precent of extrected =%82 as it becomes out the reagent has high efficiency for extrected from the sample .
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2015
الموضوع العام: علوم الكيمياء
اسم المشرف: ساهر عبد الرضا علي حيدر عباس مهدي
اسم المؤلف: اسراء جرجيس نعمة

تحضير وتشخيص بعض مركبات النايترون الجديدة ودراسة الفعالية البايولوجية لها SYNTHESIS And characterization OF Some new Nitrones Compound and The study of biological effectiveness

المستخلص: This study was included the preparation of a series of compounds heterogeneous Nitrones. Novel compounds were resulting from the reaction between azo compounds and hydroxylamine compounds through several steps. | the first step was synthesis of a new azo compounds for 2-aminopyridine includes (2a, 2b, 2c, 2d) by configuration the diazonium salt, which in turn enters the reaction of duplication with these aldehydes (2-nitro benzaldehyde, 4-dimethylamino benzaldehyde, 4-chloro benzaldehyde and 4-hydroxy benzaldehyde) respectively. | The second step was included the preparation of hydroxylamine compounds, (N-phenyl hydroxylamine and N-p-toluidine hydroxylamine) were reduced depending on the methods published in the literature. | The third step included the reaction between N-phenyl hydroxyl amine and azo compounds to gave nitrones compounds first set (3a, 3b, 3c, 3d) respectively. | Also we prepare nitrones compounds by the reaction between azo compounds with N-p-toluidine hydroxylamine to give Nitrones compounds second set (3e, 3f, 3g, 3h). | It has been identified the both novel azo-aldehydes and nitrones compounds by using infrared spectroscopy (FT-IR), spectrum NMR proton (1H-NMR), spectrum NMR carbon (13C-NMR) and mass spectrometry (Mass Spectra ) as well as we measured the Melting point for the preparing compounds. | We also Study the effectiveness of biological compounds of the prepared compounds inhibited the growth of some bacteria positive and negative gram, it has shown some compounds to be effective in killing or inhibition of these germs. | next table shows the compounds prepared in this study.
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: ماجد حمود مزيعل
اسم المؤلف: زهراء حميد كامل

تحضير وتشخيص بعض مركبات N - Oxide جديدة ودراسة فعاليتها الحيوية Synthesis and characterization of some novel N - Oxides and Study their Biological activities

المستخلص: In this study, we prepared a series of nitrones compounds resulting from the interaction of azo dyes prepared which contain Carbonyl edge with hydroxylamine compound . | It was prepared a series compounds of azo dyes (A1, A2, A4, A5) have been prepared by the reaction between 2- amino pyrimidine with diazonium salts which contain benzaldehyde derivatives(4-hydroxy benzaldehyde, 4- chloro benzaldehyde, 4-dimethylamino benzaldeyde, 2- nitro benzaldehde). While the compound A3 was prepared by the reaction between 6-amino-2-mercaptopyrimidin-4-ol with 4-hydroxy benzaldehyde.It was also prepared two groups of Nitrones, the first | group includes the compounds (B1, B2, B3, B4, B5) resulting by the reaction between azo dyes prepared (A4, A2, A5, A1, A3) respectively with N-phenyl hydroxylamine. | On the other hand the second group includes the compounds( C1, C2, C3) resulting by the reaction between azo dyes (A4, A2, A1) respectively with NParatolyl hydroxyl amine Those compounds have been confirmed the authenticity | of the molecular structures of the compounds prepared | using the TLC, infrared spectroscopy and 1H-NMR | spectrum and 13C-NMR spectrum. | It has also been study the toxicity by the calculation of the median lethal dose LD50 of one of the prepared Nitrone compound B1 on laboratory rats , the result was that the prepared compound was non toxic at the used doses ( 34.2-136.8 ) . | We also study the biological activity of the prepared compounds ( Alaldehydes and Nitrones ) by observing its effect on negative and positive bacteria of gram dye
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: ماجد حمود الصافي محمد عجه عوده
اسم المؤلف: نور عبد الخضر سلمان الاميري

دراسة وظائف الكبد وصورة الدهون والاجهاد التاكسدي في مصول النساء قبل وبعد استئصال المرارة في محافظة ذي قار / العراق Study of Liver Function, Lipid Profile and Oxidative Stress in Sera of Women Pre and Post Cholecystectomy in Province of Thi - Qar/ Iraq

المستخلص: The present study has been designed to evaluate and compare changes in patients pre, post and long periods for cholecystectomy on BMI, liver function (Aspartate Amino Transferase (AST), Alanine Amino Transferase (ALT), Alkaline Phosphatase (ALP), Total Bilirubin (TSB), Total Protein (TP), lipid profile (Total Cholesterol (TC), Triglyceride (TG), High Density Lipoprotein (HDL), Low Density Lipoprotein (LDL), Very Low Density Lipoprotein (VLDL)), oxidative stress (Malondialdehyde (MDA), Nitric Oxide (NO)) and antioxidant state (Albumin (Alb), Ceruloplasmin (CP)). | The study includes (192) subjects : (64) normal subjects (control) and (128) patient’s cholecystectomy, their age range (20-69) years, the patients were divided in to three groups : (64) patients pre and 24 hr post operation cholecystectomy, (64) patients after long periods for cholecystectomy, as well as the patients were divided by age into two groups : a premenopausal group and a postmenopausal group. | The results show that there were a significant decreased in the concentration of serum (AST, ALT, TSB, DB, InB, HDL and Alb) in group pre in comparison with each of post (short and long terms) and control groups (p≤0.05). It was found no significant differences in the concentration of serum (AST, ALT, TSB, DB, InB, HDL and Alb) between each of post (short and long terms) groups (p≤0.05). Also it was found significant differences in the concentration of serum (AST, ALT, TSB, DB, InB, HDL and Alb) between each of post (short and long terms) and control groups (p≤0.05). | -----------------------------INDEX--------------------------------- | XII | While the results showed a significant increase in the concentration of serum (ALP, TP, TC, LDL, NO, MDA and Cp) in all patient groups in comparison with control groups (p≤0.05). It was found no significant differences in the concentration of serum (ALP, TP, TC, LDL, NO, MDA and Cp) between each of post (short and long terms) groups (p≤0.05). Also it was found significant differences in the concentration of serum (ALP, TP, TC, LDL, NO, MDA and Cp) between each of post (short and long terms) and control groups (p≤0.05). | Also the results showed a significant increase in the concentration of serum TG and VLDL in all patient groups in comparison with control groups (p≤0.05). It was found no significant differences in the concentration of serum TG and VLDL between each of post (short and long terms) groups in the group A (p≤0.05). But it was found a significant difference in the concentration of serum TG and VLDL between each of post (short and long terms) in the group B (p≤0.05). Also it was found a significant difference in the concentration of serum TG and VLDL between each of post (short and long terms) groups and control groups (p≤0.05). | The correlation between nitric oxide and each of (ALP, TP, TC, TG, LDL, VLDL, MDA and Cp) in these patient groups were positive. Whereas the correlation between nitric oxide and each of (AST, ALT, TSB, BD, InB, HDL and Alb) in these patient groups were negative. | The above reviewed results lead to conclusion that cholecystectomy causes variant alternations in serum hepatic function and lipid profiles and causes variant effects in serum oxidative stress. Also, age has no effect on each of (ALT, TSB, DB, InB, ALP, TP, TG, VLDL, NO, MDA, Cp and Alb), while age has effect on each of (TC, LDL and HDL). Besides, there are no effect of the period after cholecystectomy on all studied parameters except TG and VLDL.
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2018
الموضوع العام: علوم الكيمياء
اسم المشرف: رائد معلك الصالح مهند عبد الرضا الشريفي
اسم المؤلف: سمى يعقوب يوسف

تحوير فجوة طاقة ثاني اوكسيد التيتانيوم بواسطة تفاعلات الحالة الصلبة مع صوديوم بوروهيدريد والمنيوم ليثيوم هيدريد وتحديد فعالية التحفيز الضوئي Modifying The Band Gap of Nano Titanium Dioxide By Solid State Reactions With Aluminum Lithium Hydride and Sodium Borohydride and Determining Their Photocatalytic Activity

المستخلص: This study includes preparation of nanoparticles of titanium dioxide using sol-gel method and then, the band gap was modified by solid state reaction with (AlLiH4،NaBH4) reductive compounds. Modification reduced the band gap separating | energy levels between valance band (VB) and conduction band (CB), therefor; facilitating the transfer of excited electrons from (VB) to (CB). Absorption of the energy from incident photons having the same or larger energy than the energy of the | band gap promote the formation of the couple (electron - hole) . The resulting (e--h+) couple acts to produce (OH.) radicals. OH. radicals hav a high capability to destroy organic pollutants that adsorbed on surface of the photocatalytic TiO2. | The optical properties measured using UV-visible spectrophotometer (Absorbance (A), energy band gap (Eg) and absorption coefficient ( α ) . TiO2 and TiO2- solid state reaction showed clear blue shift of the absorption band gap which were (2.8ev, 2.7ev, 2.25ev, 2.0ev) to )TiO2- NaBH4(550 ) ,TiO2-NaBH4 (750 ) , TiO2-AlLiH4 (500 ) and TiO2 -AlLiH4 (750 )) respectively. The structure of prepared TiO2 nanopowders were identified using XRD, particle size distribution varied appreciably in comparison with crystallite size (D) calculated from Sheerer formula which was in a good accordant compared with ASTM results , the particle size and their distribution were characterized using (AFM) . To the surface forms and compositions diameters of nanoparticles)SEM) was implemented . The energy dispersive X-ray (EDX) microanalysis was utilized to investigate the chemical composition of the whole samples. | Photocatalytic reaction was studied by using UV-Vis spectrophotometry. | In photocatalytic reaction the effect of the catalyst on photocatalytic rate of decomposition of methylene blue dye through the use of catalyst TiO2 and TiO2- solid state reaction (TiO2 - NaBH4 (550 ,750 )) and (TiO2 - AlLiH4 (500 ,750 )) . Using constant weight of the catalyst and dye. The most effective weight was found (1*10-4 M). At best weight the influence of many factors on rate of decomposition of dye were studied the impact of change pH varies (4.5, 7.1 and 9.4) found that the highest percentage in the decomposition of the MB was in the acidic media than in neutral and then alkaline. The effect of temperature variation from (20, 30, 40ºC) and found that increased rate of decomposition with increasing the temperature of the MB. Activation energy (Ea) for each reaction was calculated by using the equation of Arrhenius equation between (5.73-11.31) kJ mol-1 . | A series of dark reactions with absorbance measurement by UV-Vis spectrophotometry, within different periods of time with the change of pH and temperature. The results indicate that no degradation of the methylene blue dye although all the factors affecting in photocatalytic present except UV-light .
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: محسن عريبي الدخيلي ابراهيم عبود فليفل
اسم المؤلف: سراج علي رحيم

التحقيق في اثار الحجامة الرطبة على بعض المؤشرات البايوكيميائيه في ذي قار محافظة / العراق Investigation of The Effects of Wet Cupping Therapy on Some Biochemical Parameters in Thi - Qar Governorate/ Iraq

المستخلص: This study was designed to determine the effect of cupping to treat or reduce a lot of blood variables such as diabetes, liver failure, lipid profile and status of Oxidative and antioxidant , where we have in this study to take blood samples from the volunteers before they activate cupping therapy and then we have to take more samples within 14 days and comparing the results obtained were as follows : The results of the blood glucose concentration decreased significantly (P≤0.05) post cupping when compared with a pre-cupping, while there is no significant decrease in the level of glucose in the blood serum of a group post cupping compared with the control group (P≥0.05 ). In addition, the group pre-cupping showed a significant increase (P≤0.05) in the glucose in the blood serum when compared with the two sets of post-cupping and the control group. It can be seen the results of MDA serum showed a decrease (P≤0.05) in the group post cupping, compared with a pre-cupping, while non-significant in the serum level of MDA in the group post cupping compared with the control group (P≥0.05). While the group pre cupping significant (P≤0.05) MDA in serum when compared with the two sets of post-cupping and control. Summary | XIV | Cp serum levels showed high significant increase (P≤0.05) in | serum Cp can be observed in the two groups pre and post cupping when comparing this with the control group, In addition, the total post-cupping has shown a significant decrease (P≤0.05) in serum Cp compared with a pre-cupping. | As well as the results showed Alb serum significantly increased (P≤0.05) in Alb serum can be observed in the two groups pre and post cupping when compared with the control group, as a group post the cupping showed that there was a significant decrease | (P≤0.05) in Alb serum compared with a pre cupping. | Liver function tests showed a significant decrease in the group post cupping, compared with a pre cupping (P≤0.05), while significant difference was observed liver enzymes levels (ALT, ALP and AST) in the serum can be observed in a post-cupping compared with the control group (P≤0.05). Moreover, the group pre-cupping showed a significant increase (P≤0.05) in levels of ALT, ALP, AST serum when the two groups to be compared with the postcupping and the control group. | Fat results in the serum showed little change, but did not reach the moral (P≥0.05) in the proportion of fat in the blood serum levels of lipoproteins among all groups studied. | In the end we can say that cupping is not used for treatment once and for all, but it's used to treat Alternatively, or in a more identification used to treat complementary.
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: محمد عجة عودة
اسم المؤلف: زهراء طالب مشلول

طريقة كروماتوغرافية طيفية جديدة - لتقدير عقار اللوراتادين في بعض المستحضرات الصيدلانية Anew Chromatographic - Spectrophotometric Method for Determination of Loratadine in Some Pharmaceutical Preparations

المستخلص: Due to the medicinal significance of Loratadine, ethyl4-dihydro-11H benzo [5,6] cyclohepta [1,2-b] pyridin-11ylidene (-1-piperidinecarboxylate) has been devoted to this message To create a new chromatographic-spectral method for estimating the pure drug and the drug found in a number of its pharmaceuticals. | The letter included a detailed explanation of a new chromatographic-spectral method for estimating amounts of pure and commercial loratidine. The principle of this method is to break down the double bond present in the loratadine by the potassium permanganate oxidant factor of 0.05 molar and convert it into two ketone-containing compounds : 8-Chloro-5,6-dihydro-11H-benzo [5,6] cyclohepta [1,2-b The second compound is ethyl-4-oxopiperidine-1-carboxylate (B). It has been shown that the two compounds (A and B) can be separated by TLC, FTIR, separated and completely isolated by column chromatography technique. After the separation, the compound (A) was given a stable colorant complex with 4-amino acid benzoic acid ester, in a acidic medium, While the compound ( B ) did not give a stable complex. The results showed a study of changing the conditions of the process of analysis and separation of the two compounds and their diagnosis and the formation of the resulting complex and applications of the method and discussed with the use of different quantities of many types of acids and strong and weak rules and indicate their impact on the intensity of the complex complex color and the optimal conditions were selected for his way of work.
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2019
الموضوع العام: علوم الكيمياء
اسم المشرف: محمد تركي خثي
اسم المؤلف: صفاء حكيم ناصر الغزاوي

تخليق وتشخيص لبعض المركبات الحلقيه الغير متجانسه كالبيتا لاكتام والكاما لاكتام وفق تفاعل كانيكوزا SYNTHESIS AND CHARACTRIZAITION OF SOME NEW HETROCYCLIC COMPOUNDS INCLUDING ? & ? LACTAMS BY USING KINUGASA REACTION

المستخلص: This study is concerned with the synthesis and characterization of the some β- lactams 3(a-f),as in (Table.2). These compounds 3(a-f) were prepared by reacting phenylactylene with the appropriate nitrones2(a-f), in the presence of triethylamine | in acetronitrel under nitrogen atmosphere at -10˚C. in moderate yield (50-70)% . The nitrones compound 2(a-f) were prepared by reacting aldehyde with appropriate N-phenyl hydroxyl amine 1 in the presence of Ethanol. | As in (Table.1) Also the N-phenyl hydroxyl amine 1 compounds were prepared by reduction of nitrobenzene with ammonium chloride in Zinc Powder in the presence of water.This study is concerned with the synthesis and characterization of mono-γ- | lactams and bis-γ-lactams These compounds were prepared by reaction phenylsuccinic anhydride with the appropriate schiff bases(imines), by using chloroform solvent and heated at temperature (51-61˚C) in moderate yields(70- 92)%, All this compound confirmed by using spectra data such as : , IR , 1H-NMR , 13CNMR , APT 13C-NMR , HSQC 1H-13C-NMR,Mass
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء العضوية
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: محمود شاكر مكطوف محسن عريبي الدخيلي
اسم المؤلف: دعاء هادي محسن العطار

تحضير بعض الفورمازنات والثايازوليدينونات الجديدة ودراسة فعالية بعض المركبات المحضرة في خفض سكر الدم

المستخلص: The thesis consists of three chapters. The first chapter is concerned with the introduction described the chemistry of Schiff bases , formazans and thiazolidinones compounds including importance , applications , synthesis and literature reviews.The second chapter describes the chemicals and solvents which were used in the synthesis of the new Schiff bases, formazans and thiazolidinones derivatives, physical measurements , synthesis methods of compounds and evaluation of anti - hyperglycemic activity. The formazans compounds[4a - 4h] were prepared by reacting diazonium salts amines[3a - 3c] with the appropriate Schiff bases[2a - 2h].Schiff bases themselves are synthesized by the condensation of different primary amines with various aromaticaldehydes. The thiazolidinones derivatives[5c,5e,5i,5j,5k] are synthesized by condensing thioglycolic acid with various Schiff bases[2a - 2h]. All the structures prepared [2a - 2k] , [4a - 4h] and [2c, 2e ,2i ,2j , 2k] were shown in scheme(1), and characterized on the basis of the spectral data : IR, Mass, 1H and 13C NMR. The third chapter deals with , the results and discussion. The IR spectra show an important absorption band at (1558 - 1689)cm - 1 attributed to azomethine (C=N) for Schiff bases, the IR spectra showed important absorption band at (1681 - 1597 )cm - 1 attributed to azomethine (C=N) and (1465 - 1558) cm - 1 to ( - N=N - ) for formazans derivatives. Also, the IR spectra show an important absorption band at (1689 - 1658)cm - 1 attributed to the thiazolidinones ring . The 1H - NMR spectra of formazans show aromatic protons at the range (7.07 - 8.49 )ppm and pyridyl protons as downfield signal at (8.22 - 9.15 ) hydrazide signal at 11 ppm. The 1H - NMR of thiazolidinones exhibit new signals attributed to - CH2 and - CH of thiazolidnones ring at δ (4.52 - 4.71) and (5.70 - 5.81 ) ppm, respectively .13C - NMR spectra of formazans exhibit that the a signal at 156 - 168 ppm (amide carbonyl) , thiazolidinones show a signal at (207.35 - 208 .60) ppm attributed to the C=O ring thiazolidinones.The mass spectra of the formazans compounds [4d ,4e, 4g , 4h] show a molecular ion peak. M+(354 .401 . 516. 498) m/z corresponding to the target compounds. Also, mass spectra of thiazolidinones compounds [5e, 5i] show molecular ion peak. M+ (356 , 369 ) m/z corresponding to the target compounds .This study is also concerned with anti - hyperglycemic activity ,and male mice (Mus musculus Balb/c ) weighing (25 - 35)gm were used for the study of the effects of formazan compound [4e] and thiazolidinone compound [5e] on the blood glucose levels of the animals.Animals are divided into seven different groups, Group (A) : negative control (normal) that is only treated with distilled water (D.W). Group (B) : positive control that is treated with alloxan (125mg/kg) B.W. only to induce diabetes. Group (C) : that is only treated with (DMSO) only. Group (D) : alloxan - induced diabetes mice that are treated with (75 mg/kg) of formazan derivative [4e]. Group (E) : alloxan - induced diabetes mice that are treated with (150 mg/kg) of formazan derivative [4e]. Group (F) : injected alloxan and thiazolidinone [5e] (75 mg/kg). Group (G) : injected alloxan and compound thiazolidinone [5e] (150 mg/kg) .The mice were treated for two weeks and used Colorimetric to Determination of serum Glucose Level by spectrophotometer. The results how that the determination of serum glucose concentration is in males mice groups (A , B , C , D, E , F and G ).A significant decrease can be observed among ( D, E, F and G) groups as compared with group (A) after treatment (2 week) with (75 mg /kg) and (150 mg /kg ) respectively of formazans [4e] and also treatment with(75 mg /kg) and (150 mg /kg ) from thiazolidinone [5e] . while groups (A , C ) do
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: حيدر عباس مهدي كريم سالم عباس
اسم المؤلف: هبة محمد داغر راشد

تحضير وتشخيص قواعد شف ومعقداتها المشتقة من الازاتين واستخدامها في استخلاص ايون النيكل الثنائي Synthesis and characterization of Schiff Bases and its complexes derived from isatin and using in extraction of nickel ion(II)

المستخلص: The present work include preparation of three ligands (schiff base) derived from condensation reaction isatin and 5 - Bromoisatin and 5 - Methyl isatin with (2 - aminoBenzylamine) ,to give the following ligands : (z) - 3 - (2 - ((z) - 2 - oxoindolin - 3 - ylideneamino)benzylimino)indolin - 2 - one (z)5 - bromo - 3 - (2 - ((z) - 2 - oxoindolin - 3 - ylideneamino)benzylimino)indolin - 2 - one (z)5 - methyl - 3 - (2 - ((z) - 2 - oxoindolin - 3 - ylideneamino)benzylimino)indolin - 2 - one The new complexes were prepared from the reactions of ligands L1,L2,L3 with the transition metal chlorides (NiCl2.6H2O,CoCl2.6H2O, CrCl3.6H2O).The prepared derivatives and Their complexes were studied and characterized by elemental analysis (CHN),Infrared(IR),Spectroscopy, Nuclear Magnetic Resonance Spectroscopy(1H - NMR),Mass Spectra , Molar conductivity techniques were used. The complexes of [Ni(II), Co(II), Cr(III)] for all ligands have shown octahedral configuration. Shiff base has been stadied by liquid - liquid extraction to words the metal ion Ni2+ from aqueous phase to organic phase .the study of condition o extraction shows that the optimum pH values for extraction was (pH= 8). the suitable concentration of (L3) was(1×10_2M).so the suitable concentration of Ni2+ ion in aqueous solution wich is giving highest distribution ratio (D) was(80μg/ml) .the optimum shaking time to reach the equilibria was(15 minute). The results show that D and (E%) depend on the structure of organic solvent used.the temperature effct that areduce in the efficiency of extraction with increase of temperature means that the reaction is exothermic .The (L3) use in the extraction of nickel from sample of tobacco . it was found that the efficiency of extraction is (E %= 98.98 ) .
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2016
الموضوع العام: علوم الكيمياء
اسم المشرف: ساهر عبد الرضا علي ابراهيم عبود فليفل
اسم المؤلف: الاء محمد علي عبد الامير

دراسة مقارنة لفرط الاكسدة ووظائف الكبد في النساء ذوات تضخم الغدة الدرقية قبل وبعد عملية الاستئصال Compartive Study for Oxidative Stress and Liver Functions in Women with Euthyroid Goiter before and after Thyroidectomy

المستخلص: Multinodular goiter defined as the palpation of multiple distinct nodules in the enlarged thyroid gland and it is one of the commonest thyroid diseases encountered in the practice of surgery. Treatment modalities are mainly antithyroid drugs and surgery. The most common surgery being performed for multinodular goitre is subtotal thyroidectomy for the reasons that it is comparatively easier to perform, less time consuming and has a lesser complication rate especially of damage to recurrent laryngeal nerve andparathyroids. Subtotal thyroidectomy involves removal of majority of the diseased thyroid tissue along with the isthmus leaving behind a remnant of roughly 4 - 8 grams on each side.This study was accomplished for evaluation the effect of thyroidectomy on thyroid hormones levels (T3, T4 and TSH) ,serum oxidant - antioxidants status( malondialdehyde (MDA) , ceruloplasmin (Cp), transferrin (Tf ) and albumin (Alb)) , also liver function tests (aspartate amino transferase enzyme (AST), alanine amino transferase enzyme (ALT), alkaline phosphatase (ALP) and total bilirubin (BIL)). Blood samples were obtained from (100) patients with euthyroid goiter, as well as (50) healthy subjects as a control group.The comparison is based on three variables : general comparison ]Group A (Control) : - Included fifty health subjects aged (15 - 60) years. Group B (preoperative) : - Included fifty preoperative patients aged (15 - 60) years. Group C (postoperative) : - Included fifty postoperative patients aged (15 - 60) years[, age ]each one divided into three groups : G 1(15 - 30),G 2 (31 - 40), G 3 (41 - 60)[and according to the time period after surgery ] Post - 1 group : (Less than month). Post - 2group : (From month to year). Post - 3 group : (More than year)[.The results showed that there was a significant increase in MDA, Cp, AST and ALT in all preoperative and postoperative patients in comparison with control group. Yet, Alb, Tf levels showed a significant decrease in all patients groups of preoperative and postoperative in comparison with control group. Also, MDA, Cp, AST and ALT showed a significant increase in postoperative patients in comparison with control group. But, ALP, Alb and BIL showed no significant increase in postoperative patients in compared to control group.While Tf showed a significant decrease in postoperative patients in as compared to the control group. MDA, Cp, AST, ALT, ALP and BIL was decreased in the postoperative group when compared to preoperative group. Yet, Alb, Tf showed a significant increase in postoperative patients group when compared to preoperative group .The results showed a significant increase MDA, Cp, AST, ALT, ALP and BIL in Pre - G1 in comparison with Cont - G1. But, Tf, Alb showed a significant decrease in Pre - G1 in comparison with Cont - G1. Also, MDA, Cp, ALT, ALP and BIL showed a significant increase in Pre - G1 in comparison with Post - G1. While AST showed no significant differences in Pre - G1 as compared to Post - G1. The results showed that there were a significant increase MDA, Cp, AST, ALT and BIL in Pre - G2 in comparison with Cont - G2. But, Alb showed asignificant decrease in Pre - G2 in comparison with Cont - G2. Tf showed a significant decrease in Post - G2 compared to Pre - G2, Cont - G2. While ALP showed no significant differences in all age groups as compared to Cont - G2.Also, MDA, AST and BIL showed a significant decrease in Post - G2 in comparison with Pre - G2. While ALT and ALP showed no significant differences in Pre - G2 as compared to Post - G2.The results showed that there were a significant increase MDA, Cp, AST, ALT, ALP and BIL in Pre - G3 in comparison with Cont - G3. But, Tf and Alb showed a significant decrease in Pre - G3 in comparison with Cont - G3. lso, MDA, Cp, AST and ALT showed no significant differences in Pre - G3 in comparison with Post - G3. While Tf showed a significant increase in Pre - G3 as compared to Post - G3, there were no significant differences in Alb in Pre - G3 and Post - G3 .According to The Time Period there were a significant increase in serum MDA ,Cp concentration in Post - 1and Post - 3 in comparison with Control group(P≤0.05), but there were no significant differences in serum MDA concentration between Post - 2 and Control group (P≤0.05). there were no significant differences in serum Alb, Tf concentration between Post - 1 , Post - 2, Post - 3 and Control group (P≤0.05). there was a significant increase in serum AST concentration in Post - 2, Post - 3 in comparison with control group (P≤0.05), but there were no significant differences in serum AST concentration between Post - 1 and Control group (P≤0.05), there were no significant differences in serum MDA, Cp, AST concentration between Post - 1 , Post - 2, Post - 3(P≤0.05) But, ALT and ALP showed a significant decrease in Post - 1 comparison with Post - 2 and Post - 3, there were no significant differences in serum ALT ,ALP concentration between Post - 1, Post - 2 and control group(P≤0.05), While there was a significant increase in Post - 3 comparison with control. BIL show a significant decrease in Post - 1 comparison with Post - 3.There were no significant differences in Post - 2, Post - 3 in comparison with control. But, BIL show a significant increase in Post - 1 in comparison with control.
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2014
الموضوع العام: علوم الكيمياء
اسم المشرف: رائد معلك حنون الصالح علي نايف عاصي
اسم المؤلف: الاء عبد فيصل

دراسة التاثيرات الانجابية لبعض العناصر النزرة على العقم عند الرجال في محافظة ذي قار - العراق Reproductive Effects of Some Trace Elements On Male Infertility, In Thi - Qar Governorate/Iraq

الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: ساجد حسن كزار ايناس صالح جواد
اسم المؤلف: ملاك حريز نعيم الخفاجي

تحضير وتشخيص وتقييم الفعالية البايولوجية لبعض مركبات الفورمازان المشتقة من قواعد شف ومركبات الازو الجديدة ومعقداتها مع الكادميوم الثنائي II Synthesis , Charactrization and Evaluation Biological Activity of some New Formazan Compounds Derived from Schiff Bases and Azo Compounds and Their Complexes With Cadmium(II)

المستخلص: The letter includes the preparation of twenty new derivatives of Formazan compounds that include Schiff bases associated with AZO compounds.The spectrum of spectroscopy (FT.IR) for all compounds, the NMR spectrum, the NMR spectrum of NMR and the CHIS for all compounds and the identification of some of their physical properties such as grade (TPC), and then to prepare four complexes (two of them for morphine and two forformas) as complexes with cadmium ion, to determine optimal conditions for complex formation and then to measure the molecular conductivity of the complex as well as the electronic measurements Wa For magnetic sensitivity. And then studying of biological activity. For some of these vehicles the research has included two main parts : section One : I attended and identified a group of derivatives (Schiff bases) and then were linked through the interaction of the nuts under certain conditions for the preparation of new Formazan compounds containing (Schiff bases - AZO compounds) on the same compound and then attended four complexes of two Schiff bases and two of the Lycandat Formazan The new vehicles have been identified above Section Two : This part of the work was studied by studying the vital effectiveness of some compounds. Schiff bases and Formazan compounds were selected to determine the effect of the active groups of the compound on inhibiting the biological activity of the microorganisms studied in this thesis
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: حيدر عباس مهدي
اسم المؤلف: محمد عبد الحسن شلال

تحضير وتشخيص بعض مشتقات قواعد شف والفورمازانات ومعقداتهما واستخدامهما في استخلاص ايون Cr+6 بطريقة استخلاص نقطة الغيمة Preparation and Characterization of some Schiff base and formazans derivatives and their Complexes and using them in the Extraction of (Cr+6) Ion By Mothed Cloud - Point Extraction

المستخلص: This study includes the preparation of ten ligands and it′s complexs : Ligand L4 (N - (4 - ((2 - (phenylcarbamothioyl)hydrazono)methyl)phenyl) acetamide) was prepared by the condensation of (4 - acetamido benzaldehyde) with (4 - phenylthiosemi carbazide). Ligand L5 (1, 3 - bis (2 - hydroxy - 3 - methoxy - (E) - benzylideneamino) eurea) was prepared by the condensation of (o - vanillin) with (carbohydrazide). Formazan F1 (1 - benzoyl - 3 - (2 - hydroxyphenyl) - 5 - phenylformazan) is prepared from coupling the diazonium salt with (L1) proportions Molar (1 : 1). Formazan F2 (3 - (2 - hydroxyphenyl) - 1 - nicotinyl - 5 - phenyl formazan) was prepared by coupling the diazonium salt with (L2) proportions Molar (1 : 1).Complexes were prepared for (L3), (F1) and (F2) by interaction with the salts of the elements NiCl2.6H2O, CoCl2.6H2O, CdCl2.6H2O, CrCl3.6H2O. The ligands and it′s complexes were characterized by using Elemental Analysis (C.H.N) Infrared Spectroscopy(FT - IR), Nuclear Magnetic Resonance Spectroscopy (1H - NMR) , Mass Spectra and Molar Electrical Conductivity and the results were identical to what is expected scientifically. The spatial shape of the complexes prepared is (octahedral). (ligand L1 and formazan F1) on distribution ratio values and percentage of extraction, where results showed that percentage values and distribution ratio in this way increase with increasing concentration of (L1 and F1) where he found that the best distribution ratio (D) and percentage (% E) to extract ion(Cr+6) when concentration (L1 & F1) is (5 * 10 - 4 M).
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: ساهر عبد الرضا علي
اسم المؤلف: بتول مهدي صالح

تحضير , تشخيص ودراسة بيولوجية لمشتقات جديدة من 4,3,1 - ثايادايازول ومعقداتها مع بعض ايونات العناصر الانتقالية Preparation , Characterization and biological study of new derivatives of 1,3 , 4 - Thiadiazole and their complexes with some transitional element ions

المستخلص: The present study involves preparation of three new ligands derived from the thiadiazole (2,5 - dihydrazineyl - 1,3,4 - thiadiazol) with 1H - indole - 2,3 - dione (Isatin) by the ratio (1 : 2). the ligands L1 and L2 were synthesized from the reaction between thiadiazole derivative with (Benzophenone) by the ratio (1 : 2). The ligand L3 was prepared from thiadiazole derivative and (3 - aminoacetophenone) by the ratio (1 : 2), the following are the structural formulas of the prepared ligands : Prepared the complexes of the transitional elements ions [Cr+3, Fe+3, Co+2, Ni+2 and Cu+2] with ligands (L1, L2 and L3), where the ligands and their complexes characterization by precision analysis of elements (C.H.N.), Infrared spectrum (FT - IR), proton Nuclear Magnetic Resonance (1H - NMR), Mass spectrometry, measurement magnetic sensitivity and measurement molarconductivity the results were practical exactly matching with the molecular and structural formulas of the proposed compounds. Hyperchem was used to draw ligands and their complexes and to show the distribution of electronic density. The data indicates that the configuration of the complexes {[CrL1Cl3], [FeL1 3] , [CoL1 3]}, {[CrL2 3], [FeL2 3] ,[CoL2Cl3]} {[Cr(L3)2Cl ]Cl, 3)2Cl2] and [Co(L )2Cl2]Cl} are octahedral , while the proposed configuration of the complexes {[NiL Cl2], 1Cl2]}, [NiL2Cl2] [CuL2Cl ]} ,{[NiL Cl2] and [CuL3Cl2 are square planer. A study was conducted testing the biological activity for the prepared ligands and their complexes against two types of bacteria (staphylococcus aureus) and (Escherichia coli) compared to the standard inhibitor (Ciprofloxacin), the obtained results confirmed the biological effectiveness of prepared preparations except for the third ligand higher than standard inhibitor (Cipro) towards the bacteria (Escherichia coli), the following complexes also showed (A5, C5, C4, C3 and C1) biological effectiveness towards the bacteria (Escherichia coli) higher than standard inhibitor (Cipro), while the rest complexes showed less effectiveness than the standard inhibitor (Cipro) ) 4and A 3, A2(A ) except the complexesEscherichia colitowards the bacteria (where don't showed any biological effectiveness. Also the study confirmed that ligands and their complexes did not show any biological activity towards the bacteria (staphylococcus aureus).
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: ابراهيم عبود فليفل
اسم المؤلف: نعيم عبد السادة بشير الخفاجي

استخلاص وتشخيص ودراسة كيموحيوية لبعض الزيوت الاساسية في نبات الرشاد البري في مدينة الناصرية / العراق

الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: العربية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: حسام محمد كريدي
اسم المؤلف: مريم ماجد كاظم الحسيناوي

تحضير وتشخيص وتقيم الفعالية البيولوجية لبعض مركبات الفورمازان المشتقة من قواعد شف الجديدة ومعقداتها مع بعض العناصر الانتقالية Synthesis, characterization and biological evaluation of some new Formazan compounds derived from Schiff Bases and their complexes with some transition Metals.

المستخلص: This thesis contains three chapters represents, the first chapter introduction and interested in studying the chemistry of schiff base and derivatives of formazan, their complexes in terms of their characteristics, importance and synthesis.The second chapter is interested in describing the chemicals and procedures used in the synthesis of the required compounds, and the study of physical measurements, synthesis methods of compounds and evaluation as well as the biological activity.In this research, four new derivatives of formazan (L3, L4, L5 - 4d), which synthesized from the reaction of Diazonium salt amine with suitable Schiff base (L1, L2 - 2d). The Schiff base can product of different primary amines with several aromatic aldehyde and synthesized both of the (Schiff bases, formazans) suitable complexes.The third chapter Results and Discussion, identified synthesized formazan derivatives as well as Schiff bases prefix and its complexes by appropriate spectral methods including of infrared spectroscopy (FT - IR) for all compounds, Nuclear Magnetic Resonance spectrum (1H - NMR) for all compounds Microanalysis (CHNS) for the majority of compounds as well as Mass spectra. For all complexes were recording certain physical properties, such as melting point (m.p.). Monitoring progress of the chemical reaction by using thin chromatography layer (TLC). We synthesis eight complexes (three from Schiff bases and five from formazan derivatives) were complexes with ions (Co, Ni, Cd), then measuring the molar conductivity of complexes. Then study the biological effectiveness for some compounds have been chosen complexes Schiff bases, as well as formazan complexes to determine the effect of active groups in these compounds to evaluate the efficiency ofXIthe compounds against different type of bacteria.The research also includes a test of biological effectiveness of the prepared ligands and their metallic complexes, where we study response inhibitory to the three types of bacteria, a gram positive type of bacteria (Staphylococcus aureuse) and gram negative type of the bacteria (Escherichia Coli and salmonella species) and compared with the standard inhibitor (Cipro).The biological effectiveness swohs positive results as it was noted The ligand L1, L2, L3, L4, L5 and Schiff base 4d Showed lower efficiency than the standard inhibitor trend three types of bacteria. The prepared complexes from ligands appeared high effective than the effectiveness of the ligands itself The formazan (L3, L4, L5 dna 2d) appeared high effective than the effectiveness of the prepared Schiff base
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: حيدر عباس مهدي
اسم المؤلف: اعراف محمود داود

تخليق وتشخيص بعض المركبات الاحادية والثنائية للكاما لاكتام والثايزوليدينون SYNTHESIS AND CHARACTERIZATION OF SOME MONO AND BIS ? - LACTAMS AND THIAZOLIDINONES COMPOUNDS

المستخلص: This study is concerned with the synthesis and characterization of mono, bis γ - lactams 3(a - h) and mono, bis Thiazolidinone 4(a - i). The structures of the prepared compounds are confirmed by the spectral data include FT - IR spectroscopy , 1H - NMR spectroscopy , 13C - NMR spectroscopy, Mass spectroscopy.Mono and bis γ - Lactams are prepared by reacting Phenyl succinic anhydride with the appropriate Schiff base , in dry chloroform. The obtained mono and bis γ - lactams 3(a - g) is in moderate yields (51 - 75%).The FT - IR spectra showed an absorption bands at (1636 - 1692 cm - 1) attributed to amide carbonyl group ( - N - C=O), and at (1699 - 1733 cm - 1) carboxylic group which attributed (COOH) . The 1H - NMR spectra of compounds 3(a - g),show signals of the aliphatic protons at rang (3.356 - 4.02) ppm and signals for aromatic protons at rang (7.202 - 8.218) ppm. The 13C - NMR spectra of compounds 3(a - e), show signal at rang (171.30 - 178.58) ppm which related amide carbon ( - N - C=O), and at rang (178.32 - 182.16) ppm carboxylic carbon (COOH).Mono and bis Thiazolidinones are prepared by the reaction of thioglycolic acid with Schiff base, in dry benzene. The produced Thiazolidinones 4(a - f) is in moderate yields (55 - 78%).The FT - IR spectra showed an absorption band at (1654 - 1691 cm - 1) attributed to carbonyl group which is related to ( - N - C=O). The 1H - NMR spectra show signals of the aliphatic protons at rang (4.2 - 7.1) ppm and signals for aromatic protons at rang (7.352 - 8.015) ppm. The 13C - NMR spectra show signals at rang (172.32 - 179.52) ppm which is related to amide carbonyl group ( - N - C=O).
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء العضوية
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: محمود شاكر مكطوف التميمي
اسم المؤلف: اصالة سلام جبر

دراسة مستويات مصل الهوموسيستين وعلاقته مع بعض انزيمات القلب في المرضى الذين يعانون من احتشاء عضلة القلب في محافظة ذي قار - العراق Study of Serum Homocysteine levels and Its Correlation with Some Cardiac Enzymes in Patients with Myocardial Infarction In Thi - Qar Province/Iraq

المستخلص: Myocardial infarction (MI) or acute myocardial infarction (AMI) is the medical term for an event commonly known as heart attack. An MI occurs when blood stops flowing properly to a part of the heart, and the heart muscle is injured because it is not receiving enough oxygen. Biochemical tests are restricted to monitoring cardiac enzymes activities. Therefore, introducing homocysteine test in hospitals for MI patients may provide a clearer picture on the patient condition and help in the disease management.The study was conducted during the period from October 2015 till August 2016. Sixty - three of the people who have a history of injury in the acute myocardial infarction are studied. The diagnosis is based on the clinical presentation and confirmed by ECG, and cardiac enzyme. Forty - eight of persons as healthy volunteers were selected as a control group.The results indicated the following : The proportion of patients male (57%) and females (43%), smokers (49%) and non - smokers (51%), most of them are females. The results also showed that (32%) live in cities, compared to (68%) live in rural areas, and patients Serum homocysteine was significantly higher in MI patients compared to the control group. Homocysteine levels were higher in smokers(p = 0.0001). and unemployed individuals(p < 0.0001)., as well as in individuals with family history of MI or CAD(p < 0.0001). High hypertensive, diabetic and obese individuals had also higher levels of homocysteine . Based on the results of this study suggested measuring the amino acid Homocysteine levels of security as one of the effective ways to diagnose patients with myocardial infarction in hospitals
الصفحات الاولى:
مكان الجامعة: ذي قار
اللغة: الانكليزية
الجامعة: جامعة ذي قار - كلية العلوم - قسم الكيمياء
الدرجة: ماجستير
الموضوع الدقيق: الكيمياء التحليلية الحياتية
السنة: 2017
الموضوع العام: علوم الكيمياء
اسم المشرف: محمد عجة عودة
اسم المؤلف: اديان سعد حمزة
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