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تحضير وتشخيص بعض مشتقات قواعد شف والفورمازانات ومعقداتهما واستخدامهما في استخلاص ايون Cr+6 بطريقة استخلاص نقطة الغيمة == Preparation and Characterization of some Schiff base and formazans derivatives and their Complexes and using them in the Extraction of (Cr+6) Ion By Mothed Cloud - Point Extraction
Author name:
بتول مهدي صالح
Supervisor name:
ساهر عبد الرضا علي
General topic:
Chemistry
Specific topic:
Chemistry
Degree:
Master
University:
University of Thi-Qar - College Of Science - Chemistry Department
Language:
Arabic
University location:
Dhi Qar
First pages:
25T1540 - p.pdf
Abstract:
This study includes the preparation of ten ligands and it′s complexs : Ligand L4 (N - (4 - ((2 - (phenylcarbamothioyl)hydrazono)methyl)phenyl) acetamide) was prepared by the condensation of (4 - acetamido benzaldehyde) with (4 - phenylthiosemi carbazide). Ligand L5 (1, 3 - bis (2 - hydroxy - 3 - methoxy - (E) - benzylideneamino) eurea) was prepared by the condensation of (o - vanillin) with (carbohydrazide). Formazan F1 (1 - benzoyl - 3 - (2 - hydroxyphenyl) - 5 - phenylformazan) is prepared from coupling the diazonium salt with (L1) proportions Molar (1 : 1). Formazan F2 (3 - (2 - hydroxyphenyl) - 1 - nicotinyl - 5 - phenyl formazan) was prepared by coupling the diazonium salt with (L2) proportions Molar (1 : 1).Complexes were prepared for (L3), (F1) and (F2) by interaction with the salts of the elements NiCl2.6H2O, CoCl2.6H2O, CdCl2.6H2O, CrCl3.6H2O. The ligands and it′s complexes were characterized by using Elemental Analysis (C.H.N) Infrared Spectroscopy(FT - IR), Nuclear Magnetic Resonance Spectroscopy (1H - NMR) , Mass Spectra and Molar Electrical Conductivity and the results were identical to what is expected scientifically. The spatial shape of the complexes prepared is (octahedral). (ligand L1 and formazan F1) on distribution ratio values and percentage of extraction, where results showed that percentage values and distribution ratio in this way increase with increasing concentration of (L1 and F1) where he found that the best distribution ratio (D) and percentage (% E) to extract ion(Cr+6) when concentration (L1 & F1) is (5 * 10 - 4 M).
