معالجة الماء من حقول النفط باستخدام محاليل ايونية في منظومة التعويم بالهواء المذاب == Treatment of Oilfield Produced Water Using Ionic Liquids In A Dissolved Air Flotation System
اداء الحماية الكاثودية لخطوط الانابيب == Performance of Cathodic Protection For Pipe Lines
ازالة الكبريت بالامتزاز من النفثا الثقيلة العراقية بواسطة 13X زيولايت == Adsorption Desulfurization of Iraqi Heavy Naphtha Using 13X Zeolite
دراسة الحركية ونمذجة تفاعل استرة حامض الاوليك باستخدام NaY زيولايت المحضر == Kinetic Study And Modeling of Olic Acid Esterification Over Prepared Nay Zeolite
استخدام المادة النانو مسامية SBA - 15 لازالة الملوث العضوي من المياه الصناعية == A Nanoporous SBA - 15 As Adsorbent For Removal of Organic Pollutants From Wastewater
عمليات التنافذ الامامي - العكسي لمعالجة المياه الملوثة بالزيوت == Forward - Reverse Osmosis Processes For Oily Wastewater Treatment
تاثير المحتوى المائي , درجة الحرارة وكلوريد الصوديوم على تاكل CO2 للصلب الكربوني (A106 B) في النفط العراقي == Effect of Water Content , Temperature And NaCl On CO2 Corrosion of C - Steel (A 106 B) In Iraqi Crude Oil
محاكاة لمعمل الاثلين في العراق باستخدام الاسبن بلسن والماتلاب == Simulation of Iraqi Ethylene Plant Using Aspen Plus And Matlab
دراسة استخدام الكاربون المنشط الحبيبي لازالة الفينول والباراكلوروفينول والبنزين من المياه المطروحة من مصفى بيجي == Study of Using Granular Activated Carbon For Removing Phenol , Parachlorophenol , And Benzene From Wastewater of Baiji Refinery
استخدام بعض المخثرات الطبيعية لازالة المواد العالقة من المياه == Using of Some Natural Coagulants To Remove Collide Particles From Water
معالجة واعادة استخدام المياه الناتجة من حقول نفط الاحدب العراقية == Treatment And Reuse of Produced Water From Al - Ahdab Iraqi Oilfields
معالجة واستصلاح الماء المصاحب للنفط العراقي باستخدام طريقة عمود التطويف وتقنية الاغشية == Treatment And Reclaiming of Iraqi Oil Field Produced Water By Flotation Column And Membrane Technology
Author name:
هدى كاظم حسن
Supervisor name:
ثامر جاسم محمد | قصي فاضل عبد الحميد
Abstract:
يتم انتاج كميات كبيره من الماء المصاحب النفطي من قبل شركة نفط الجنوب.يعتبر محتوى النفطي oil - water والاملاح الذائبه TDS من اخطر الملوثات والتي تتم معالجتها باحدث التكنلوجيا في السنوات الاخيره تم استخدام تقنية الاغشية لمعالجة الماء المصاحب النفطي.الهدف م | A large amount of oil field produced water is generated by South Oil Company. Oil - in - Water and TDS are the most serious pollutants for which current treatment technologies are often costly and ineffective in order to reuse water. In recent years, membrane process has been applied for produced water treatment.The aim of the present work is to treat produced water from oil well before being disposed in environment or reused as re - injection to oil well or agriculture water. Oil field produced water is very difficult wastewater to treat and its characteristics change as well to well. The sample test of this study was taken from dehydrator in the DSI/North Rumila/Southern Oil Company in Basrah /Iraq. The treatment process of produced water consists of two stages. The first stage as pre - treatment is achieved by continuous dissolved air flotation (DAF) to reduce the oil content. The second stages, as advanced treatment processes, are accomplished by microfiltration (MF) to reduce the turbidity and nanofiltration (NF) to reduce the salt content as TDS of produced water. The experimental work was carried out using dissolved flotation column is of Perspex glass (0.1 m I.D, 1.5 m height). The bottom of the column connected to a conical joint of QVF glass with a Teflon distributer. The effect of operating parameters (flow rate of produced water, pH, initial oil concentration, flotation time, alum dosage and surfactant of SLS) saturated pressure=5 Atm on the oil content or oil removal efficiency was investigated. The results showed that the oil removal efficiency increases with increasing the flow rate of produced water, the flotation time and coagulants dosage. The oil removal efficiency in DAF unit without coagulants is equal to (80, 94, 95%) for initial oil concentration (30, 50, 70 ppm), respectively at a flow rate 0.03 m3/h and pH=6. While flotation with coagulation, the results indicated that the removal efficiency is equal to 94% (residual oil content <10 ppm) at pH=5, alum dosage=560 ppm, and initial oil concentration=50 ppm, and the removal efficiency is equal to 89.6 at pH=6, alum+SLS dosage=80 ppm, and initial oil concentration=50 ppm. The kinetics of flotation column was studied and it was found that the order of the reaction is changing between zero to first order.The treatment of produced water by membrane technique was carried out by cross flow mode in hallow fiber microfiltration (MF) and nanofiltration (NF). The effect of operating parameter such as transmembrane pressure (TMP) (1, 1.5, 2 bars) with cross flow 20 mL/min, at room temperature, on the flux, rejection, and turbidity and TDS removal was studied. The experimental results by MF manifested that the permeation flux is (108, 156, 611 l/m2.h) and transemembrane pressure is 2 bar at initial turbidity (100, 200, 300 NTU), respectively. But NF, as a final treatment of produced water to reuse, was studied at different feed concentrations (82950, 75050, 67150 ppm) with different TMPS. According to the experimental results, the higher permeation of flux =15 (l/m2.h) at 82950 ppm and 2 bar, was obtained.The experimental results of the removal efficiency were represented in two and three dimensional graphs. An empirical correlation for R% as a function of different parameters (flow rate, pH, and oil concentration) was developed by aided computer using the following formula %R= a + c1*x1n1 + c2*x2n2 + c3*x3n3.
انتقال الحرارة في الغليان الحوضي باستخدام موائع النانو == Pool Boiling Heat Transfer Using Nanofluids
ازالة الكبريت من زيت الوقود باستخدام الاكسدة المعززة بالموجات الفوق الصوتية == Ultrasound - Assisted Oxidative Desulfurization of Fuel Oil
تخمين حركية تفاعل ازالة الكبريت للنفثا الثقيلة العراقية == Prediction of Kinetic Reaction of Iragi Heavy Naphtha Desulferization
فعالية عامل مساعد محضر ومحفز بمعادن مختلفة لعملية ازالة الكبريت بالهدرجة لزيت الغاز العراقي == Activity of A Prepared Catalyst Promoted By Different Metals For The Hydrodesulfurization of Iraqi Gas Oil
ازالة المحتوى الكبريتي من وقود الديزل بواسطة الاكسدة والاستخلاص بالمذيب == Desulfurization of Diesel Fuel By Oxidation And Solvent Extraction
تطبيقات الطرق العددية في التاكل الكلفاني للمعادن المزدوجة == Applications of Numerical Methods In Galvanic Corrosion of Coupled Metals
استخلاص الزيوت العطرية من قشور الحمضيات باستعمال التقطير البخاري بمساعدة المايكرويف == Extraction of Essential Oils From Citrus By - Products Using Microwave Steam Distillation
تاثير الحماية من التاكل بواسطة الليزر على سبائك الالمنيوم == The Effect of Laser Surface Melting Corrosion Protection On Al Alloys
تطبيق اللابفيو والخوارزمية الوراثية في السيطرة على مبادل حراري من نوع الصفائح == Application of LabVIEW And Genetic Algorithm For Controlling of Plate Heat Exchanger
تثبيط تاكل الحديد الكاربوني الواطئ في حامض الكبريتيك باستعمال كحول البولي فينيل ومستخلص نبات PIPER LONGUM == Corrosion Inhibition of Low Carbon Steel In Sulfuric Acid By PVA And Piper Longum Extracts
تحضير الكاربون المنشط من نوى التمر باستخدام كاربونات البوتاسيوم كعامل منشط في ازالة صبغة المثيلين الزرقاء == Preparation of Activated Carbon From Date Stones By K2Co3 Activation For Methylene Blue Dye Adsorption
ازالة الكادميوم من المياه الملوثة بالترسيب الكهروكيمياوي باستخدام حزمة من الانابيب الفولاذية متحدة المركز == Removal of Cadmium From Wastewater By Electro - Deposition On Stainless Steel Concentric Tubes Bundle