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معالجة مياه الصرف الصناعي لمصافي النفط بالاكسدة الانودية المباشرة == Treatment Of Petroleum Refinery Wastewater By Direct Anodic Oxidation

اسم المؤلف: انغام سامي حمزة

اسم المشرف: علاء نور غانم الموسوي

الموضوع العام: الهندسة الكيمياوية

السنة: 2016

الموضوع الدقيق: الهندسة الكهروكيمياوية

الدرجة: ماجستير

الجامعة: جامعة بابل - كلية الهندسة - قسم الهندسة الكيمياوية

اللغة: الانكليزية

مكان الجامعة: بابل

الصفحات الاولى: 📎 38T324 - p.pdf

المستخلص: مياه الصرف الصناعي لمصافي النفط الناتجة بصورة رئيسية من عمليات تكرير النفط الخام والصناعات التحويلية، مواد التشحيم والبتروكيماويات الوسيطة. هذه السوائل هي المصدر الرئيسي للتلوث البيئي المائي. تتكون مياه الصرف الصناعي من الزيوت والشحوم والمركبات العضوية ا | Petroleum refinery wastewater originating from petroleum industries primarily resulted in refining crude oil and manufacturing fuels, lubricants and petrochemical intermediates. These effluents are a major source of aquatic environmental pollution. The wastewaters are composed of oil and grease, toxic organic compounds along with many other minerals. In this study, wastewater of Al - Najaf petroleum refinery was used as electrolyte solution in the experiments, and the effect of some variables on the removal of organic material as a pollutant in term of COD were studied. The performance of anodic oxidation represented by COD removal was studied using 1 liter batch - mode parallel plate electrochemical reactor at constant initial COD concentration and fixed agitation speed of 250 rpm with the variation of operating conditions that were expected to have a major effect on process. These variables were : electrodes material (platinum, stainless steel, graphite, PbO2, and carbon felt), current densities (5, 15, 25) mA cm - 2 for carbon felt electrode and (10, 30, 50) mAcm - 2 for other electrodes, pH (4, 7, 10), temperatures (25, 40, and 55)?C and with electrolysis time up to 120 minutes. The results show that the direct anodic oxidation process gave the best COD removal percent of 84.88% and 86.27% at 50 and 25 mA cm - 2 current densities for PbO2 and carbon felt anode materials, respectively. The highest COD removal was predicted at pH 4 and the best temperature at 55?C for all electrode types. The reaction was followed by pseudo first - order kinetics rate. As well, it was studied the effect of current density on the current efficiency, instantaneous current efficiency, energy consumption, charge load with the time and calculated activation energy.