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معالجة عناصر الخارصين والنحاس والمنغنيز في مياه الفضلات الصناعية بطريقة الترسيب الكيمياوي == Treatment of Zinc ,Cupper And Manganese In Wastewater By Chemical Precipitation
Author name:
يوسف صالح عيسى
Supervisor name:
دريد فاضل احمد
General topic:
Chemical Engineering
Specific topic:
Chemical Engineering
Degree:
Master
University:
Tikrit University - College Of Engineering - Department Of Chemical Engineering
Language:
Arabic
University location:
Salahaddin
First pages:
38T306 - p.pdf
Abstract:
تهدف هذه الدراسة الى ايجاد تاثير المعالجة الكيمياوية بطريقة الترسيب الكيمياوي على كفاءة ازالة العناصر الثقيلة في مياه الفضلات الصناعية المطروحة لتصل الى النهر بالتراكيز المسموح بها. تتم عملية الترسيب الكيمياوي بالسيطرة على الدالة الحامضية لمياه الفضلات ب | This study aims to find the effect of chemical treatment by chemical precipitation on the efficiency of removing heavy metals from wastewater to be poured back to the river. Chemical precipitation is done by controlling the (PH) of wastewater by adding a suitable hydroxide ,different hydroxides were used like the hydroxides of sodium ,calcium and potassium 0.05N each and sodium carbons 0.1N in removing heavy metals of wastewater. The study has taken prepared samples contain different concentrations of heavy metals ions like cupper 2,4 and 6 ppm zinc 5,10 and 15ppm and manganese 2,5,8 ppm Jar taste is used to show the chemical precipitation. Fast and slow mixing periods were written down to get the velocity gradient (G) and (GT) The used materials were highly efficient to remove the ions of metals. The removed amount of metals was measured by (AAS) Atomic Absorption spectroscopy. The paper has also studied the effective factors on the efficiency of precipitation like the (PH) is (8,9,10,11) and The precipitation time is (0.5,1,2,3)h.The result show that the best precipitation efficiency when an ion is used alone in the solution (PH) is (10,11) precipitation time 2h hydroxides precipitation (0.05N) it removes about 98% of cupper ions when sodium and calcium hydroxides are used ,more than 96,66% when the potassium hydroxide is used.a complete removing appears of manganese ions when the calcium hydroxide is used more than 90% when the potassium hydroxide is used.77% when the sodium hydroxide is used more than 98.4% of zinc ions removed when the sodium and calcium hydroxide is used 95.9% of zinc ions is removed when the sodium carbons are used the best treatment condition appear when the (PH) is (9 to10) and precipitation time is 2h when an ion is used alone in the solution 98% of cupper and zinc ions are removing 90% of manganese ions.When the ions are mixed in the solution the best removing efficiency appears when the (PH) is (9 to 11) and precepitition time is 2h when the hydroxides and carbons are used a complete removing of cupper ions 90% of zinc ions and more than 98.2% of manganese ions.The time of reaction to get 10.5 PH using hydroxides is (25 - 30) second when sodium carbon's are used the reaction time to get 8.5 is (50) second for cupper and zinc ,(25) second for manganese.The reaction is zero order when hydroxides are used and first order when carbons are used in treating heavy metals.
