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دراسة تاكل الصلب الكربوني في محلول ملحي والمنتجات البترولية بوجود غاز ثاني اوكسيد الكربون == Studying of Carbon Steel Corrosion In Salt Solution And Petroleum Products In Presence of CO2
Author name:
نضال احمد شاكر
Supervisor name:
شذى احمد سامح | شروق طالب الحميري
General topic:
Chemical Engineering
Specific topic:
Chemical Engineering
Degree:
Master
University:
University of Technology - Department Of Chemical Engineering
Language:
English
University location:
Baghdad
First pages:
38T319 - p.pdf
Abstract:
يتضمن البحث دراسة سلوك التاكل للصلب الكربوني في محلول ملحي من (3.5wt%NaCl) ومشبع طبيعيا بالهواء بوجود غاز CO2 المستخدم في انابيب النفط. وتم تصميم منظومة القطب الاسطواني الدوار (RCE) لانجاز الدراسة.واجريت تجارب الاستقطاب في ظروف الجريان المضطرب باستخدام | The present work is to study the corrosion behaveior of carbon steel, in naturally aerated 3.5wt% NaCl (brine solution) and petroleum products in presence of CO2. A rotating cylinder electrode (RCE) system were used to study the potentiostatic polarization experiments, under turbulent flow conditions, using 3.5wt% brine solution as electrolyte at different temperatures (298, 308, 318 and 328)K and rotating speed of (0, 100, 200, 300 and 400)r.p.m. at each temperature.Similar experiments were carried out in 3.5wt% brine solution using CO2 gas at (32 ml/sec) flow rate.Corresponding experiments by weight loss were carried out in 3.5wt% brine solution with compunds of : - 1. Kerosene + 10V% brine solution.2. Gas oil + 10V% brine solution. At 328Kand flow rates of (0 and 400) r.p.m.3. Similar experiments were carried out in kerosene + 10V% brine solution at (298, 308 and 318)K and static condition speed of (0) r.p.m at each temperature.4. Experiments were carried out in pure kerosene at a temperature of (298 and 318) K and speed of (0) r.p.m.All above experiments were carried out with and without CO2 gas.The results indicated that the corrosion rate of carbon steel was increased in presence of CO2 gas.The anodic dissolution kinetics were activation control processes affected by temperature.The activation energy of carbon steel with CO2 gas system (2.87 - 1.8) Kcal/mol at different r.p.m. was lower than that without CO2 gas system of (11.4 - 1.7) Kcal/mol at different r.p.m.The corrosion potentials without CO2 gas were shifted to the noble direction with increasing flow rate at a constant temperature, whereas such potential were shifted to the less noble direction with increasing temperatures at a constant speed. However, the corrosion potential with CO2 gas was more noble than that obtained without CO2 gas.The corrosion rate is increased with increasing temperature and velocity. The results indicated that the corrosion rates of ( gas oil +10V% brine solution ) are higher than that of (kerosene +10 V % brine solution) with and with out CO2 gas, and the corrosion rate of pure kerosene is lower than that of (kerosene+10V% brine solution) with and without CO2 gas.In the presence of CO2 gas the results indicated that corrosion rate increases due to continuous dissoultion of iron ion and formation of weak carbonic acid. The carbonic acid accelarteed corrosion rate and affected carbonate and hydrogen ion, which increased the cathodic reactions on the metal surface.
