دراسة تاثير بعض متغيرات عملية الترسيب الكهروكيمياوي للنحاس على كفاءة العملية وخواص المسحوق المنتج == The Study of The Effect of Some Variables In Electrochemical Deposition of Copper Powder On The Efficiency of Process And Powder Properties
Author name:
ميادة نوار نصيف
Supervisor name:
فاروق منصور مهدي
General topic:
Chemical Engineering
Specific topic:
Chemical Engineering
Degree:
Master
University:
Tikrit University - College Of Engineering - Department Of Chemical Engineering
Language:
English
University location:
Salahaddin
First pages:
38T318 - p.pdf
Abstract:
يهدف البحث الى اجراء دراسة عملية لانتاج مسحوق النحاس باستعمال طريقة الترسيب الكهروكيمياوية مع دراسة تاثير عدد من المتغيرات التي تؤثر في كفاءة العملية والوقوف على طبيعة تاثير كل منها. تمت دراسة تاثير كل من كثافة التيار وزمن الترسيب ودرجة حرارة وسط الترسيب | The present study aims to produce copper powder by the electrochemical deposition method. In this work, the effect of current density, deposition period, electrolyte temperature, distance between electrodes, ratio of anode to cathode surface area and cathode rotation on the current efficiency and powder properties such as apparent density, grain size, grain size distribution and grain morphology on powder properties and current efficiency are studied. A deposition system composed of Perspex cell, two copper electrodes ( 96.8% purity), electrolyte composed of 90g/l CuSO4 and 120g/l H2SO4 as well as the electrical connections. Betts method was followed by this study.The automatic sieve shaker was used to determine the grain size, while the atomic spectroscopy was used to determine copper purity. Moreover, both optical microscope and SEM were used to estimate powder morphology. It is found that current efficiency is increased with increasing deposition time and electrolyte temperature. It is also found to be decreased with increasing current density, distance between the electrodes, ratio of anode to cathode surface area and rotation of cathode electrode. The results showed also that particle size is increased with increasing the distance between the electrodes and increased with increasing the ratio of anode to cathode surface area and cathode rotation. Further more, the obtained data indicated that the maximum and minimum achieved fine grain percent (
