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دراسة تصنيفية وبيئية لحشرات نصفية الاجنحة المائية وشبة المائية Heteroptera : Hemiptera في محافظة البصرة == Taxonomical And Ecological Study of Aquatic And Semiaquatic Insects(Heteroptera : Hemiptera) In Basrah Provience

Author name: اسماء عبد الزهرة سبع العيداني
Supervisor name: ضياء خليف كريم
General topic: Biology
Specific topic: Life Science
Degree: Doctorate
Language: Arabic
University location: Basrah
First pages:
Abstract: Present studies dealing with the taxonomical and ecological studies of the aquatic Hemiptera : Heteroptera in eight stations in Basrah provience ,which are : Al - Medina , Al - Qurna , Basrah center ,Shat Al - Arab , Al - Zubair , Abu Al - Khasib , Al - Faw and Sullein Marsh, collection was done twise monthly during the period from April 2012 to March 2013 .Results showed the presence of nine species belonging to aquatic Hemiptera , three belonging the group Gerromorpha and six the group Nepomorpha,as follows : Group : Gerromorpha(Popov,1971)Family : Gerridae ( Leach , 1815)1 - Aquarius nebularis(Schellenberg,1800)Family : Mesoveliidae(Douglast and Scott , 1867 )2 - Mesovelia vettigera( Horvath , 1895 ) ( apterous )M .vettigera( Horvath , 1895 ) ( macropterous )Family : Macroveliidae3 - Macrovelia hornii(Uhler , 1872 )Grouop : Nepomorpha(Popov,1968)Family : Nepidae ( Latreille , 1802 )4 - Nepa cinerea( Linnaeus , 1758 )Family : Corixidae ( Leach,1815 )Subfamily : Cymatianiae ( Walton , 1940 )5 - Cymatia bonsdorffii(Sahlberg , 1819 )Subfamily : Corixinae ( Leach , 1815 )6 - Sigara(Vermicorixa) latelaris ( Leach , 1815 )Family : Belostomatidae ( Leach , 1815 )7 - Lethocerus fakir(Mayr , 1852)Family : Notonectidae ( Latreille , 1802 )8 - Anisops sardeus(Herrich - Schaeffer , 1849)AbstractBFamily : Pleidae ( Fieber , 1851 )9 - Plea leachi(McGregor and Kirdaldy,1899)Among the collected species ,six were regarded as new records to the Iraqi fauna of this order,they were : A. nebularis,M. vettigera( macrpterous) , M . vettigera( apterous), Ma.hornii , N.cinerea , C.bonsdorffii andP.leachi.Study also deal with the measuring of some ecological aspects like air and water temperatures , salinity , pH and dissolved oxygen ,and their effected on the monthly distribution of the aquatic Hemiptera. Temperature was the most effective aspect in the monthly distribution of the insects ,as the lowest numbers were recorded in Summer months and the highest number were in Winter months , the ranges of the air temperatures were 9 - 43º C and water temperatures were 2 - 33º C .The highest concentrations of salinity was recorded in Al - Zubair , Abu Al - Khasib and Al - Faw reached to 35g/l in Al - Zubair in July , the pH ranges were the same in all stations and was alkalid , their ranges were 7.3 - 7.8 , about the dissolved oxygen it was low and same in all stations except in Sullein Marsh which reached to 11 mg/l in January .The concentration of some heavy metals in water also studied like Fe, Pb, Cu and Zn , the highest concentrations were to Fe and Zn in Basrah center and Al - Zubair, and the highest concentration for Fe in Al - Zubair reached to 6362.21μ/L in August, while highest concentration for Zn in Basrah center reached to 1365.92μ/L in July, while in the other stations the concentrations were lowest .The study also used the water boatmen Sigara latelaris(Leach,1817) as bioindicators of heavy metals pollution in the water of Basrah provience , and taken Sullein marsh as control , and measuring the concentrations of the heavy metals in insects tissues , water and sediments , the results showed that the insects collected from the water of the center of the city can accumulate Fe andAbstractCZn in their tissues and the highest concentrations reached to 3562.16 and 3778.12 μ /gm for Fe and Zn in July , while in the insects taken from Sullein marsh were 286.25 and 285.17 μ /gm .The concentrations of heavy metals in water and sediments of the city center were measured and the highest concentration was for Fe and Zn , and reached to 1569.91 and 1365.91 μ /L of the water of city center , while reached to 215.01 and 223.14 from the same metals in the water of Sullein marsh , the concentrations of the same metals were recorded in sediments of the city center and reached to 2865.16 and 1982.56 μ /gm for Fe and Zn , and the highest concentrations of the same metals in Sullein marsh were 418.57 and 393.74 μ /gm .

تقدير مستويات بعض العناصر النزرة وانزيم الكلوتاثيون بيروكسيديز في دم مرضى حصاة الكلى في محافظة البصرة - العراق == Estimation Levels of Some Trace Elements and Glutathion Peroxidase in The Blood of Patients Infected Kidney Stones in Basrah Governorate - iraq

Author name: نور حامد فيصل
Supervisor name: بيداء حسين علي العزاوي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: The current study aimed to find relationship between some of biochemical variables with kidney stone patients and study the effectiveness of antioxidants (Zinc Zn,Selenium Se,Glutathion peroxidase GPx) and Calcium Ca ,Magnesium Mg and Cupper Cu. The samples were collected from Lithotripsy center in Basrah General Hospital and samples were selected from 104 patients with stones (55male and 49 female) their age ranged between (12 - 67) and 70 healthy people (40 male and 30 female) their age ranged between (17 - 65).The result were : 1 - Highly significant decreasing in patients in the level of zinc (p˂0.01) compared with healthy people. 2 - Significant decreasing or increasing was observed in level of Cu in patients compared with healthy people.3 - Highly significant in patients in the level of calcium p˂0.01 compared with healthy people.4 - Highly significant decreased in level of Mg p˂0.01 in patient compared with healthy.5 - highly significant decrease was observed in Se in patients compared with healthy people p˂0.01 6 - highly significant decrease was observed in GPx in patients compared with healthy people p˂0.01 7 - Presence positive correlation between antioxidants (Zn,Se and GPx) and negative correlation between (Zn,Cu) and negative correlation between (Ca,Mg).

تحضير بعض صبغات الازو المشتقة من البروكائين ودراسة امتزازها بالكاربون المنشط المحضر من نوى النبق المحلي == Synthesis of some azo dyes derived from Procaine and study the adsorption of these dyes by activated carbon prepared from local Z.spina - christi fruits pits

Author name: عبد الله عبد اللطيف عبد الله الخلف
Supervisor name: طارق زباري جاسم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: Activated carbon was prepared from Ziziphus Spina - Chisti fruit pits, which is locally available in Iraq, the purpose of this study is to search for surface that are highly applicable for dye adsorption to treat the pollution of aqueous solution in nature.Four azo dyes were synthesized in our laboratory from the reaction of Prodain Hydrochloride with Cromotropic acid, Pyridoxal Hydrochloride, Pyridoxine and 4 - Amino - 5 - hydroxy naphthalene - 2,7 - disalphonic acid via diazonium ions. UV - Visible and FT - IR spectra, characterized these dyes (D1, D2, D3 and D4).The different variable affecting the adsorption capacity of the activated carbon prepared such as contact time, initial dye concentration in feed solution, pH of the medium, weight of adsorbent and temperature were investigated on a batch process mode.Spectroscopic technique was used for the measurement of dyes before and after adsorption. The optimum contact time to attain equilibrium is (6)hr, the maximum percentage removal for D1&D4 occurred at pH 4 while D2 at pH 11 and D3 at pH 6.1. Ar =II The experimental data of adsorption were fitted to two different isotherms, namely Langmuir and Freundlich these isotherms equation were applied at different temperatures. The results obtained showed that the Freundlich isotherm equation is better fitted to the experimental data than the Langmuir isotherm equation. The adsorption kinetic was found to follow the pseudo second order kinetic expression

تحضير وتشخيص ودراسة تحليلية - طيفية لبعض اصباغ السلفا الجديدة == Synthesis, Characterization and Analytical - Spectral Study of some New Sulfa Dyes

Author name: رجاء حسین فیاض
Supervisor name: اسعد عبود علي | فاطمة مھدي الجابري
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: Arabic
University location: Basrah
First pages:
Abstract: Including preparation of six new symmetrical azodyes of selfa compounds ( sulfaguanidine , sulfanilamide and sulfadiazine , A1 - A3 respectively ) and ( mercuration of sulfaguanidine , sulfadiazine and sulfanilamide , B1 - B3 respectively ) by oxidative - coupling reaction of sulfa compounds and their mercuration with oxidizing agent ( 1,2 - nephthaquinone - 4 - methoxy ) . The color of prepared azodyes were orange to orange - redish with melting points ranges ( 275 - 312 oC ). The azodyes were characterized by C H N , FT - IR , H NMR and TG analysis. The electronic spectra of azodyes were showed max. wavelength range ( 440 - 460 nm. ).The acid - base properties were studied at pH values in the range of ( 0.7 - 12 ), the electronic spectra of azodyes were scanned at wavelength range of ( 350 - 600 nm. ) . The isopestic point of each dye were fixed and the protonation and ionization constants were determined by half - height method. The effect of solvents of different polarities on the azodyes spectra was also studied . From that spectra it was found that most of solvents no effect except for polar solvent like DMF ,which showed a light red shift ( that may be for the hydrogen bonding between dye and solvent ) . From the relation of max. wavelength and dielectric parameter of each dye , it was found that linearity or slightly deviation of linearity in case of polar solvent . That means the major effect is dielectric constant of the solvent The second subpart : The ability of using all prepared azodyes as acid - base indicators ( strong acid with strong base and weak acid with strong base ). The results were compared with that obtained from the recommended method . It was found that no significant observed between the two methods by using of relative error .The last subpart : Including complex formation between two of studied azodyes ( A1 & A3 ) with Ni2+ by forming 1 : 2 ( M : L ) complexes by aid of molar ratio method.The optimum conditions were studied which including ( the effects of , time , pH , sequence of addition and interferences ). The spectra of two complexes showed a red shift from their azodyes . The obeyness of Beer's law , molar absorbtivity coefficient , sandel resistivity , relative error , relation coefficient and detection limit were all determined . The effect of foreign ions with concentrations of ( 1 - fold , 5 - fold and 10 - fold ) on the absorbance of the complexes was also studied . The overall stability constants ( β1 & β2 ) of Niazodyes complexes were determined by using corresponding solutions method which including half - height method . The complexes were also characterized by C H N and FT - IR .Part two : Including simple , easy and sensitive spectrophotometric method for the microdetermination of sulfa and mercurated salfa compounds in aqueous solution and pharmaceutical compounds .This method depends on the oxidative - coupling between the reagent hydroxyl nephthaline - 4 - sulphonic acid in strong acid medium by forming colored imine - quinone dyes in max. wavelength ran ( 480 - 510 nm.). The optimum conditions which including ( volume of reagent , volume and kind of the oxidizing agent , volume and kind of the acid , sequence of additions , time effect and temperature effect ) . The electronic spectra of the dyes were carried on in the range of ( 350 - 600 nm.).This method was applied pharmaceutical compounds ( Tablets and Creams ) that containing sulfadiazine .It was found there are no significant difference between results of this method and the composition of the sulfa drugs , that observed from calculated relative rror.By the aid of C.H.N. , FT - IR and stoichiometry ( molar ratio method ) of forming the complexes, the chemical structure of the complexes Ni2+ and A1 & A3 dyes were suggested .

دراسة التاثير المخفض - المضاد لفرط سكرالدم للمركبات الكيميائية الفعالة المعزولة من النبات الطبي العراقي شوك البحر == Study of Hypoglycemic Antihyperglycemic Action of Active Chemical Compounds Isolated from Iraqi Prosopis juliflora Medicinal Plant

Author name: جمال حربي حسين السعدي
Supervisor name: عباس دواس مطر المالكي
General topic: Chemistry
Specific topic: Analytical Biochemistry
Degree: Doctorate
Language: English
University location: Basrah
First pages:
Abstract: Diabetes mellitus is a disorder in glucose sugar metabolism process becauseof different reasons.leading to a great damage in body systems , therefore medicinalplants were used successfully to treat this disease .The current study was carried outIraqi prosopis juliflora to determine and investigate its hypoglycemic action in bloodof normalglycemic and alloxan induced hypoglycemic rabbits. Many generalextracts were prepared from Iraqi prosopis juliflora pod and leaves ,they are hotaqueous ,cold aqueous ,hot alcoholic ,cold alcoholic ,oils, ethyl acetate and dichloromethane extract .Moreover , some chemical families were isolated from this plantsuch as phenols ,glycosides , flavonoids , tannins ,alkaloids and saponnins.Preliminary qualitative tests were carried out for all prepared extracts thenhypoglycemic and fasted alloxan - induced hyperglycemic rabbits to know activitythese extracts in decreasing blood glucose levels in these rabbits . the resultsindicated that all extracts showed good decreasing in glucose level. Oil extractisolated from prosopis juliflora leaves showed very high activity to decrease blood glucose ,levels in normalglycemic and hyperglycemic rabbits ,where significant decreasing (P<0.05) was found at second and forth hrs , significant decreasing (P<0.01) at sixth hr. and high significant decreasing (P<0.001) at twenty forth hrs. ,whereas leaves glycosides has a great ability to decrease glucose levels in normalglycemic rabbits where a significant decreasing (P<0.01) was found at second and forth hrs., and a high significant decreasing (P<0.001) at twenty forth hrs., but in hyperglycemic abbits , a high activity was recorded and led to a significant decreasing ( P<0.01) at second forth hrs., and high significant lowering( P<0.001 ) at twenty forth .whereas ,leaves tannins extract was noticed to be the lowest affiecieney in reducing blood glucose levels ere it led to a significant lowering ( P<0.01) at twenty forth in normalglycemic rabbits , while a significant decreasing (P<0.05) was recorded at twenty forth in hyperglycaemic rabbits. Leaves ,4 - (2’ - Hydroxyethyl)phenol, Trans - phytol , 24 - Methylencycloartan - 3 - one β - hydroxylup - 20(29) - en 4 - (β - D - Glucopyranosyloxy)benzyl alcohol and Sti masterin (.Were isolated ,separated ,purified and identified by thin layer chromatography, column chromatography, gas chromatography, IR - spectroscopy ,1H,C13 - NMR ,Gas chromatography - mass spectroscopy .Also study of hypoglycemic action of four these chemical compounds isolated from leaves and pods p.juliflora , the glycosidic compound 4 - (β - D - Glucopyranosyloxy)benzyl alcohol recorded strong activity as hyperglycemic action and led to a significant decreasing ( P<0.05) at second hrs., and significant lowering( P<0.01)at fourth ,sixth hrs. and high significant decline (P<0.001) at 24 hrs in normalglycemic rabbits ,while in hyperglycemic rabbits a significant decreasing (P<0.05) at second hrs. ,significant lowering P<0.01 at fourth and sixth hrs and significant decreasing (P<0.001) at twenty forth hrs. The active compound 4 - (2 - - Hydroxyethyl)phenol showed a high hypoglycemic action were significant decline ( P<0.05) at second hrs, a significant decreasing ( P<0.01) at sixth and a high significant decreasing (P<0.001) at twenty forth hrs. in normalglycaemic rabbits ,while in hyperglycemic rabbits , a significant decline (P<0.05) was at second , a significant decreasing (P<0.01) at fourth and sixth hrs., and a high significant decreasing ( P<0.001) was recorded at twenty forth hrs..Also active compound24 - Methylencycloartan - 3 - one showed a significant decrease (P<0.05) at second hrs. , significant decrease (P<0.01) at fourth and sixth hrs., and a high significant decreasing ( P<0.001) at twenty forth hrs hyperglycaemic rabbits, while the compound α - tocopherol recorded a significant decreasing (P<0.05) at sixth hrs. , significant decrease (P<0.01) at twenty forth hrs. in hyperglycemic rabbits. The toxicity for some extracts and active chemical compounds isolated from leaves and pods was studied where no hemolytic for red blood cells was found .

تقدير بعض المغذيات في نماذج مختلفة بوساطة تقنية كروماتوغرافيا التبادل الايوني مصنع محليا == Determination of some nutrients in different Samples by Home - made ion exchange chromatography technique

Author name: نور عبد الحكيم عبد الرزاق عبد الله الباهلي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: This work includes three chapters. The first chapter focuses in general on chromatography and specifically on Ion Chromatography ( IC ) and recent application for some nutrient determination .The second chapter, Experimental parts, describes all parts of the homemade semi - automated IC system, procedure solution chemicals sampling and the optimu m conditions used in this study also illustrate.The last chapter , result and dissection demonstrates the application of IC system for determination of NO2 - NO2 - and PO4 3 - ions in details.Linearity's were in the range 2.5 - 12.5 , 2.5 - 12.5 and 7.0 - 35 mg/L with regression coefficient 0.9950 , 0.9960 and 0.9990 the ± RSD % equal to ± 0.45% , ± 0.56% and ± 0.51 % the recoveries were the range 100% , 96% and 95% which were found by standard additions method the sample throughput were 8.0, 6.0 and 3.0 sample/hour for NO2 - ,NO2 - and PO4 3 - ions respectively .The final parts in this chapter displays the application of the IC systemfor determination of NO2 - ,NO2 - and PO43 - ions in water some pharmaceutical preparations and soft drinks samples with simple eco and simultaneous method .

تحضير ودراسة تحليلية وتطبيقية لبعض الاصباغ الازوية المشتقة من المستحضرات الدوائية وتقدير ايون الفضة كمعقد == Preparation and Analytical and Application of Some Azodyes Derived From Pharmaceuticals drugs and Determination of Silver Ion as Complex

Author name: نهى وليد علي حسين
Supervisor name: اسعد عبود علي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: تم تحضير ثلاث صبغات ازويه وهي procaine hydrochloride and 8 - Amino - 1 - napthol - 3 - 6 - disulfonic acid disodium salt (L1)و صبغتين ازوتيتين جديدتين procaine hydrochloride and 4 - aminoantipyrine (L2) and Metoclopramide hydrochloride and 8 - Amino - 1 - napthol - 3 - 6 - disulfonic acid disodium salt(L3). درست هذه الصبغات طيفيا، وتم تشخيصها بتقنية الرنين النووي المغناطيسي للبروتون (1H NMR) وتقنية الاشعة تحت الحمراء (FT - IR)، وفي هذه التقنية بالتحديد تم تشخيص اهم المجاميع الفعالة الموجودة في الصبغات، واهمها مجموعة الازو ( - N=N - ) التي ظهرت عند (1526.86، 1500 ، (1497.45سم - 1 للصبغات (L1 - L3) على التوالي . كما ودرس التحليل الحراري للصبغات (L3 - L1) واظهر الثبات الحراري الى درجة حرارة (255.2،151.2 ،290) م˚ على التوالي وقد قيست درجات حرارة مراحل التفكك (الابتدائية، العظمى ،النهائية) وكذلك بينت درجة حرارة التفحم، ودرجة حرارة فقدان 50 % من وزن المادة .اما الدراسة الطيفية فقد تم من خلالها تحديد الاطوال الموجية العظمى للصبغات وهي (530) نانوميتر لصبغتين (L1،L3) و(360) نانوميتر لصبغة (L2 )، ودرس تاثير الاس الهيدروجيني في اطياف الامتصاص الالكترونية للصبغات المحضرة في المنطقة المرئية، بمدى من الاطوال الموجية (650 - 350) نانوميتر لصبغات (L3 - L1) باستعمال محاليل منظمة ذات قيم اس هيدروجيني مختلفة (2 - 12)، ومن هذه الاطياف تم حساب ثابت تاين مجموعة الهيدروكسيل ل (8 - Amino - 1 - napthol - 3 - 6 - disulfonic acid disodium salt) و4 - amino anti pyrine )) وثابت برتنة ذرات النيتروجين لمركبات (Procaine hydro chloride وMetoclopramide) باستعمال طريقة منتصف الارتفاع .كما وتم تعيين النقاط الايزوبستيه وميكانيكيات التاين والبرتنه المقترحة . وتم دراسة اطياف الاشعة المرئية لهذه الصبغات مع مجموعة مذيبات مختلفة القطبية ( الماء الخالي من الايونات ,الكحول الاثيلي، 4 - 1 دايوكسان ، رباعي هيدرو فيوران ، ثنائي مثيل سلفوكسايد ، الاسيتون، ثنائي مثيل فورمالديهايد) بمدى من الاطوال الموجية (650 - 350) نانوميتر لصبغتين (L1,L3 ) بمدى ((530 - 300 نانوميتر لصبغة (L2 )، واظهرت اطيافها حزمة امتصاص رئيسية اعزيت للانتقال *π π في مجموعة الازو باستعمال مذيبات مختلفة القطبية، حيث وجدت علاقة خطية بين الاطوال الموجية العظمى وثوابت العزل الثنائي وهذا يعني ان ثابت العزم الثنائي هو الذي يتحكم بانحراف حزم القمم . المحور الثاني : تضمن دراسة طيفية لمعقد الصبغة (L3) مع الفضة، وكان لون المعقد الناتج بنفسجي بعد ما كان لون الصبغة احمر. وقد تم تحديد الظروف المثلى لتكوين هذا المعقد منها تحديد الطول الموجي الاعظم، وكان (560) نانوميتر، وتاثير الاس الهيدروجيني بمدى من محاليل المنظمة (12 - 2) باستخدام المحلول المنظم الجامع وكان بقيمه (12) مستخدما المحلول الجامع كافضل محلول منظم . ودرس تاثير الزمن من ( 1440 - 1) دقيقة، ووجد عدم تغير في قيم امتصاص الصبغة مما يدل على استقراريه المعقد المتكون، فضلا عن تاثير تعاقب الاضافة اللازمة للدراسات الطيفية التي يتم من خلالها تحديد نسب التراكيب الجزيئية للمعقد المتكون اعتمادا على طريقة النسب المولية ، اذ اظهرت النتائج ان المعقد يتكون بنسبة (1 : 1) (فلز : ليكاند (.وكذلك تناولت الدراسة مدى انطباق قانون بير وحساسية الطريقة الطيفية للصبغة الازوية (L3) مع الفضة (I) وقيم معامل الامتصاص المولاري ( ) (104 2.2 ͯ) لتر.مول . 1 - سم1 - ، وقيم معامل الامتصاصية النوعي (a) (0.2037) مل .غم_1.سم_1، وحساسية ساندل (S)(4.909×10 - 3) مايكرو غرام.سم - 2 ، وقيم الانحراف المعياري (S.D) ( 0.00709)، وحد الكشف (DL) (0.0663) مايكرو غرام.مل - 1.اوضحت الدراسة تاثير تداخل بعض الايونات المهمة ( Li+ ،Na+ ،K+ ، +Mg2، Mn2+ ، Cd2+ ،Ba2+، Pb2+ ، Co+2، Ca2+ ، Cr3+ ، Zr4+ ، Ti+ ، Uo+2 ،VO2+ ، Cu2+ ، Fe3+) التي يمكن ان تتداخل وتؤثر في قيم امتصاص المعقد ولوحظ ان هناك تفاوت في شدة تداخلها. فقد وجد ان الايونات Ni2+، Cu2+ ،Fe3+ يمكن ان تتداخل وبشده , هذا يعني ممكن تكوينها معقدات مع الصبغة L3. اضافة الى ذلك تم حساب ثوابت تكوين هذا المعقد وذلك باستعمال طريقة المحاليل المتناظرة والمتضمنة طريقة نصف قيم دالة التكوين اذ وجد ان قيمة log β1 = (5.62) لمعقد الفضة مع الصبغة الازوية. ودرس طيف الاشعة تحت الحمراء للمعقد ومقارنته مع طيف الصبغة بدون وجود ايون الفضة ويلاحظ تاثر مواقع حزم الامتصاص وشدتها للمجاميع المهمة الموجودة في الصبغة مما يبين الارتباط بين ايون الفضة وجزيئة الصبغة المعنية. المحور الثالث : تم دراسة بعض التطبيقات لصبغات الازوية ومنها امكانية استعمال محاليل الصبغات (L3 - L1)، كدلائل ) حامض قوي - قاعدة قوية) و(حامض ضعيف - قاعدة قوية )، فقد وجد ان الاصباغ الازويه تعطي نتائج ممتازة وذات خطا نسبي واطئ مع تغيير حاد عند نقطة التعادل . كما ودرس تطبيق اخر وهو استخدام الصبغة (L3)، في تقدير ايون الفضة في بعض المستحضرات الصيدلانية مثل Floumizin Cream 1% ( w/w) , Hamazine Cream 1% ( w/w) وSulphative Cream 1% ( w/w) فقد وجد ان مستحضرين يعطيان دقة وضبط عاليتين وهذا ما نلاحظه في قيم الخطا النسبي . وكذلك امكانية استعمال الصبغات (L3 - L1)، في دراسة الفعالية البيولوجية مع صنفين من البكتريا احداها ذات صبغة كرام موجبة Staphylococcus Aureuse والاخرى ذات صبغة كرام سالبة Escherichia Coli واظهرت النتائج فعالية الصبغة (L2)، تجاه بكتريا Staphylococcus Aureuse وكذلك عوملت الصبغات مع نوع من الفطريات هي (Candida albicans) واظهرت النتائج فعالية عالية للصبغة (L2،L3)، تجاه الفطر. | The research work was divided into three parts : The first part : Involves the preparation of new azodyes L1 - L3( except for L1) . The dye (L1،L2) was derived from (8 - Amino - 1 - napthol - 3 - 6 - disulfonic acid di sodium salt) with Procaine hydro chloride (L1) ,and with (4 - amino anti pyrine )) (L2) and Metoclopramide with (8 - Amino - 1 - napthol - 3 - 6 - disulfonic acid di sodium salt) ( L3). They have been described by NMR and Visible , UV. spectroscopic spectra and fourier transform infrared spectra (FT - IR) which investigation of more important active groups such as ( - N=N - ) which appeared by (1497.45,1500,1526.86) cm - 1 for(L1 - L3) respectively.The Thermal analysis of the prepared azodyes (L1 - L3) showed their thermal stability in (255.2 ,151.2 and 290) C°,The intial maximum and final temperatures of dissociation of each stage were calculated . The acid - base properties were studied at different pH values (2 - 12) From these spectra , the isobestic points , the protonation and ionization constants of azo dyes were determined by using half - height method .The solvents effect were studied at different solvents polarities (Ethanol, THF, DCM, 1 - 4 Dioxane , Acetone, DMF ,Water) with in wave length rang (350 - 650nm) for (L1،L2( and (300 - 530) for (L2) it was found linearity relationship between λmax of the bands and dielectric constants for all solvents. This denotes that the dielectric constant of the medium is the main factor governing the band shift in such solvents.The second part : includes the study of spectra of complexes azodye (L3) with Silver (I) ion , to form colored complex . The complex was studied under optimum conditions for forming the such as selection of the max. wavelength (560 nm). The pH effect, time effect and the effect of sequence of addition, were studied . The stoichiometrey of formed complex was carried out by using of molar ratios method .The results showed that the complex is composed of (1 : 1) (metal : Ligand ).As well as, the study examined the applicability of the Beer’s law . The Beer's validity and sensitivity azo dyes (L3) with Silver (I) were calculated . The values of molar absorptivity ( ) (2.2×104) L.mol - 1.cm - 1, specific absorptivity (a) (0.2037) ml.g - 1.cm - 1,Sandell sensitivity (S) (4.909×10 - 3) g cm - 2, standard Deviation (S.D) (0.00709) and Detection Limit (DL) (0.0663) g ml - 1 were determined .The study of the interference of some important ions like ( Li+ ،Na+ ،K+ ، +Mg2، Mn2+ ، Ni2+ ، Cd2+ ،Ba2+، Pb2+ ، Co+2، Ca2+ ، Cr3+ ، Zr4+ ، Ti+ ، Uo+2 ،VO2+ ، Cu2+ ، Fe3+) were studied, at different concentrations (1fold, 5fold, 10 fold) . Some of above ions were found to be interfere or affect on the values of absorption complex like (Ni2+، Cu2+ ،Fe3+) . The stability constant (Log β1) of the complex was calculated by applying the corresponding solution method and found with value of (5.62) for silver (I) with Dye (L3) .Third part : Includes the study of some applications of dyes , like the ability of using deys (L1 - L3) as acid - base indicators for strong acid with strong base and weak acid with strong base under suitable concentrations . By using of azodye ( L3 ) as reagent for the deteminaion of silver content in some Pharmaceutical Reagents like ( Floumizin Cream 1% ( w/w) , Hamazine Cream 1% ( w/w) and Sulphative Cream 1% ( w/w). It was found that the first two cream drugs give good results with low values of relative standard error . The ability of using dyes, by established the biological activities of (L1 - L3) toward two types of bacteria (Staphyococcus Aureuse) and (Escherichia Coli) .The results showed the effectiveness of (L2) towards bacteria (Staphyococcus Aureuse). The study carried out on the dyes (L1 - L3) toward (Candida albicans) ,the results showed the effectiveness of (L2 - L3) towards fungi .

عزل وتشخيص بعض المركـبات الفعالة من وريقات نخيل البريم ودراسة تاثيرها المضاد لفرط سكر الدم == Isolation and identification of some Active Compounds from Phoenix dactiylifera (Breim) Leaflets and study of their Antihyperglycemic Effect

Author name: نهى اياد محمد العبيد
Supervisor name: عباس دواس مطر المالكي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: في هذه الدراسة تم استعمال وريقات نخيل البريم العراقي(Breim) Phoenix dactylifera لتقصي تاثيره المخفض لسكر الدم في الارانب الطبيعية والمصابة بفرط السكرالمستحدث بالالوكسان. تم تحضير (11 ) مستخلصا من وريقات هذا النبات وهي المستخلص المائي البارد والمائي الحار والمستخلص الايثانولي البارد والايثانولي الحار ومستخلص الدهون ، ومستخلصات الفينولات والقلويدات والفلافونيدات والكلايكوسيدات والصابونين والتانينات .تم اجراء الكشوفات الكيميائية النوعية الاولية للمستخلصات المحضرة وتعيين العوائل الكيميائية الفعالة الموجودة في وريقات النبات، تم استعمال مجموعتين من الارانب الصائمة الطبيعية والمصابة بفرط السكر وقسمت كل منها الى مجموعة سيطرة ومجموعة معالجة، ثم تم تسجيل تاثير المستخلصات في تخفيض سكر الدم في هذه الارانب، اذ اظهرت النتائج ان المستخلص الايثانولي الحار كان الاكثر تخفيضا لمستوى سكر كلوكوز الدم من المستخلصات العامة الاخرى في الارانب الطبيعية.سجل كل من المركبات القلويدية والفينولية المعزولة التخفيض الاكبر في مستوى سكر كلوكوز الدم مقارنة مع بقية المستخلصات في الارانب الطبيعية والمصابة بفرط السكر حيث ادت هذه المركبات الفعالة الى تخفيض عالي المعنوية (P<0.001 ) في الساعة الرابعة والعشرين , وانخفاض عالي المعنوية P<0.01)) في الساعة الرابعة والساعة السادسة , وتخفيض معنوي P<0.05)) في الساعة الثانية في الارانب الطبيعية الصائمة , وانخفاض بفارق معنوي (P<0.001 ) في الساعة السادسة والرابعة والعشرين , وانخفاض معنوي P<0.01)) في الساعة الرابعة , وانخفاض معنوي P<0.05)) في الساعة الثانية وفي الارانب المصابة بفرط السكر . اما التانينات فقد اظهرت التخفيض الاقل مقارنة مع بقية المستخلصات الاخرى . اظهرت نتائج التحليل النوعي لكروموتوغرافيا الطبقة الرقيقة ((TLC عن وجود مركب قلويدي في مستخلص القلويدات وعن وجود اربعة مركبات في مستخلص الفينولات وشخصت المركبات الفينولية والمركب القلويدي الفعالة المعزولة باستعمال كشف منصهر الصوديوم وكشف المجاميع الفعالة وطيف الكتلة - كروموتوغرافيا الغاز GC - Massوطيف الاشعة تحت الحمراء IR وطيف الرنين النووي المغناطيسي للبروتون (H1 - NMR) وطيف الرنين النووي المغناطيسي للكاربون (C13 - NMR ) ولذلك من هذا التشخيص وجد ان المركب القلويدي المعزول هو 2 - Methoxy - 4 - [(E) - (1H - tetraazol - 1 - ylimino)methyl]phenol اما المركبات الفينولية المعزولة هي 3 - hydroxy tyrosine , 4 - n - propylresorcinol , alpha - tocopherol , 2 - hydroxy - 5 - methylisophthaldehyde لقد سجل المركب الفينولي4 - n - propylresorcinol] تخفيضا عالي المعنوية في مستويات كلوكوز الدم، اذ اظهر تخفيضا بفارق معنوي عالي (P<0.001 ) في الساعة الرابعة والعشرين , وانخفاض معنوي P<0.01)) في الساعة السادسة وانخفاض معنوي P<0.05)) في الساعة الثانية والرابعة في الارانب الطبيعية ، كما سجل هذا المركب الفعال تخفيضا معنويا عاليا (P<0.001 ) في الساعة السادسة والرابعة والعشرين , وانخفاض معنوي P<0.01)) في الساعة الرابعة , وانخفاض معنوي P<0.05)) في الساعة الثانية في الارانب المصابة بفرط السكر . في حين اظهرت المركبات الفينولية الاخرى 3 - hydroxy tyrosine, 2 - hydroxy - 5 - methylisophthaldehyde , alpha - tocopherol تخفيضا معنويا عاليا في الارانب السليمة والمصابة بفرط السكر ولكن بنسبة اقل من المركب 4 - n - propylresorcinol . كما اظهرت الدراسة ان المركبات الفينولية الفعالة والمركب القلويدي الفعال ليس لها اي تاثير سمي في تحلل كريات الدم الحمراء في الانسان . | In this study Iraqi Phoenix dactylifera (Breim) leaflets were used to investigate their hypoglycemic action in normal glycemic and Alloxan - induced diabetic rabbits. Eleven extracts from this plant were prepared are cold aqueous, hot aqueous , cold ethanolic, hot ethanolic ,fats extracts, phenols, alkaloids, flavonoids, glycosides and tannins. Preliminary qualitative tests were carried out for prepared extracts and active chemical families were detected for plant leaflets. Two groups of fasted normal glycemic and fasted hyperglycemic rabbits and they were divided into control and treatment groups then hyperglycemic action in these rabbits were recorded. The results showed that the hot ethanolic extract was the highest hypoglycemic action than other extracts in normal glycemic rabbits. Phenolic and alkaloidic compounds isolated, recorded the great hypoglycemic action compound with other extracts in normal glycemic and hyperglycemic where these active compounds led to a decreasing with a a significant difference (P<0.001)at 24 hr , a significant decreasing (P<0.01) at 4 and 6 hr and a significant decreasing (P<0.05) at 2 hr in fasted normal glycemic rabbits , also a significant decreasing (P<0.001)at 6 and 24 hour ,a significant decreasing (P<0.01) at 4 hr and a significant decreasing (P<0.05) at 2 hr in hyperglycemic rabbits whereas tannins showed the lowest decreasing compared to other extracts . Thin layer chromatography (TLC)results showed presence of one alkaloidic compound in alkaloids extract and four phenolic compounds in phenols extracts . Action phenolic compounds and alkaloidic compound were identified by using sodium fuse , function groups test , gas chromatography ,mass (GC - Mass) spectrum technique ,infra - red (IR),proton nuclear magnetic resonance (H1 - NMR), carbon nuclear magnetic resonance (C13 - NMR) spectra . Therefore from this identification , it was found that the isolated alkaloidic compound is 2 - Methoxy - 4 - [(E) - (1H - tetraazol - 1 - ylimino)methyl]phenol whereas the phenolic compounds are 3 - hydroxy tyrosine , 4 - n - propylresorcinol , alpha - tocopherol , 2 - hydroxy - 5 - methylisophthaldehyde. the phenolic compound 4 - n - propylresorcinol recorded a high, a significant decreasing in blood glucose levels , where it showed a decrease with a , a significant difference (P<0.001)at 24 hr, a significant decreasing (P<0.01) at 6 hr and a significant decreasing (P<0.05) at 2 and 4 hr in fasted normal glycemic rabbits , also this active chemical compound recorded a high significant decreasing (P<0.001)at 6 and 24 hour ,a significant decrease (P<0.01) at 4 hr and a significant decrease (P<0.05) at 2 hr in hyperglycemic rabbits , while other the phenolic compounds 3 - hydroxy tyrosine, alpha - tocopherol , 2 - hydroxy - 5 - methylisophthaldehyde showed a significant decreasing in normal glycemic rabbits and hyperglycemic rabbits but it was less than the compound 4 - n - propylresorcinol , also the study showed that the active alkaloidic compound and active phenolic compounds have no toxic effect in hemolysis of blood red cells of human being.

تحضير وتشخيص ودراسة طيفية وكهربائية وحرارية لبعض مركبات البورفرازين الجسرية == Synthesis, Characterization with Spectroscopic and Thermal and Electrical Studies for Some of Bridged Porphrazine Compounds

Author name: مصطفى هاشم موكر
Supervisor name: نزار عبد الامير حسين
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: This study includes a preparation of some Tetrapyrazino Porphrazine Compounds and new Bridged Compounds with General Formula (MPzDCB)n ,(MPzCN)n where M is Fe(II) and Co(II) and VO(IV) .These compounds prepared by different method diagnosed by (elemental analysis (CHN), InFrared of spectrum , Nuclear Magnetic Resonance Spectroscopy , Electronic Absorption Spectrometry (u.v), X - ray Diffraction Measurements, Thermographimetric analysis , Finally diaynosed electrical Properties) .The Results showed for the analysis of microelements good Convergence between the theoretical and practical Values.For the Infrared spectroscopy compounds tetrapyrazino porphrazine (PzFe,PzCo,PzVO) We noticed the disappearance of C≡N Pack and its appearance as preparing the Bridged Compounds (MPzDCB)n and (MPzCN)n with frequency (2044) cm - 1 mean with less frequency . For spectrum visible and ultraviolet for pxepared Compounds by using (DMF) as a solvent showed two types of the first absorption packages within the range (600 - 700)nm celled Q band is due to transitions ( π - π*) and the second within the range (300 - 400)nm celled package B and attributed to the transitions ( π - π*) for the existence of bye bonds in Composite loops and (n - π* ) the presence of nitrogen atoms in the circle . As for Nuclear Magnetic Resonance Spectrum of the proton in the iron Compound (PzFe) we noticed appearance of chemical shift one when 8.3 PPm this return to the protons gasoline circled in the Compound .For Bridged Compound (PzFeDCB)n noticed the appearance of two chemical shift first at 7.9 PPm Located in the higher area return to proton circle in Compound and the second at 8.50 PPm Located in the low area , return of protons (DCB) this is consistent with the proposed structural formula .For x - ray from which achieved an account dimension between levels crystalline d - species by studying the x - ray deviation and through it can calculate the energy levels located around the Fermi level and through α that represents inverted dimension between crystalline level .AS for the weighted thermal analysis we noticed all prepared Compound have high thermal stability and high stability studied the electric properties of prepared Compounds was measured conductivity continuous stream and found electrical conductivity of increased Compounds with rising temperature indicating that semiconductor powersupply materials.

دراسة مستويات مضادات الاكسدة الانزيمية وايوني (الحديد والكلوريد) في دم مرضى الحساسية والربو في محافظة البصرة - العراق == Study of enzymatic antioxidants levels and (Iron & Chloride) ions in the blood of asthmatic patients in Basrah governorate/ lraq

Author name: مرتضى فراس حسن الكناني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: اجريت هـذه الــدراسة لـمعرفة تركـيز مـضادات الاكسدة الانزيمية (السوبر اوكسيد دسميوتيز SOD, الكلوتاثيون بيرواوكسيديز GPx والكتاليز (Catalase ومستوى ايوني (الحديد والكلوريد) لدى عدد من مرضى الربو في محافظة البصرة.شملت الدراسة 100 حالة من المرضى وكانت اعمارهم تتراوح مابين 7 - 67)) سنة55) من الذكور و45 من الاناث) تم تشخيصهم في مركز الحساسية والربو في محافظة البصرة, كذلك 60 حالة من الاصحاء ( 35من الذكور و25 من الاناث). تم تصنيف المرضى بالاعتماد على العوامل السريرية التالية (الفئات العمرية, عامل الجنس, التاريخ العائلي, عامل التدخين ونوع الغذاء}بروتينات, فواكة وخضراوات, توابل{). وقد اوضحت نتائج الدراسة ارتفاع تركيز انزيم فوق اوكسيد دسميوتيز (SOD) في دم المرضى ((224.511±9.502 U\ml مقارنة بالاصحاء (191.162±7.879) U\ml وبمعدل احتمال ((P˂0.05, ويزداد الارتفاع في تركيز هذا الانزيم بتقدم العمر وشدة المرض وعامل التدخين والتاريخ العائلي وبمعدل احتمال معنوي ((P˂0.05. بينما لوحظ انخفاض في مستوى انزيم الكلوتاثيون بيرواوكسيديز (GPx) للمرضى (2925.250±787.564) U\L مقارنة بالاصحاء (3502.331±1386.953) U\L, ويزداد انخفاض تركيز انزيم ((GPx بتقدم العمر وشدة المرض وعامل التدخين وبمعدل احتمال معنوي (.(P˂0.05كما تم قياس تركيز انزيم الكتاليز ( (CAT.في مصل دم المرضى فوجد انخفاض في تركيزه لدى المرضى (0.693±0.392) U مقارنة مع الاصحاء (1.456±0.244) U وبمعدل احتمال معنوي (P˂0.05), ويزداد هذا الانخفاض مع تقدم العمر والتاريخ العائلي وشدة المرض وبمعدل احتمال معنوي ((P˂0.05. اظهرت الدراسة ايضا انخفاض تركيز عنصر الحديد للمرضى (55.2433±5.5873) µg ̸100 ml مقارنة بالاصحاء (64.1231±24.9367) µg ̸100 ml وبمعدل احتمال (P˂0.01), ويقل هذا الانخفاض مع تقدم العمر وعامل التدخين وشدة المرض وبمعدل احتمال معنوي (P˂0.01). بينما اظهرت نتائج الدراسة لعنصر الكلور انخفاض في مستوى تركيزه للمرضى (290.4770±31.1280) µg ̸ L مقارنة مع الاصحاء ((298.4238±38.4793 µg ̸ L وبمعدل احتمال معنوي (P˂0.01), ويزداد الانخفاض في تركيزه مع التاريخ العائلي وعامل التدخين وبمعدل احتمال معنوي (P˂0.01). نستنتج مما ذكر اعلاه ان الاشخاص المرضى الذين يعانون من الربو تكون لديهم الاصناف الفعالة للاوكسجين ROS فعالة اكثر والتي تسبب اجهادا مؤكسدا مصحوبا بتناقص او زيادة في مضادات التاكسد والعناصر النزرة | The work described in this thesis is mainly concerned with studying the concentration of the enzymes antioxidants (Superoxide dismutase SOD, Glutathione peroxidase GPx and Catalase CAT.) as well as to know the levels of (Iron and Chloride) ions in asthma patients from Basrah governorate/Iraq. This study covers 100 case of sickness in which their ages between (7 - 67) year (55 male and 45 female) and all these cases were identified in Allergies and asthma center in Basrah/Iraq. However, the control group contain 60 volunteer (35 male and 25 female). The classification of these patients depend up on few factors such that (Ages, Sex, genetic history, smoking habit, living places and the type of their foods which covers {proteins, fruits & vegetables and spices}).This study shows that there is increasing in the concentration of the SOD in the blood (224.511±9.502) U/ml, as comparison with the healthy peoples (191.162±7.879) U/ml at rate (P˂0.05) and elevation in concentration increased by applying the factors above. However, we noticed a significant decreasing in GPx (2925.250±787.564) U/L as comparison with healthy peoples (3502.331±1386.953) U/L, and decline in concentration was increased by applying the factors mention above at rate (P˂0.05). As well as there is a decreasing in the concentration of CAT. (0.693±0.392) U as comparison with control group (1.456±0.244) U, and this decline in concentration decreasing increased by applying the factors mention above at rate (P˂0.05). Added to which the concentrations of Iron and Chloride were decreased at rate (P˂0.01) in the serum of blood of patients (55.2433±5.5873) µg ̸100 ml and (290.4770±31.1280) µg/ L respectively as comparison with healthy peoples (64.1231±24.9367) µg ̸100 ml and (298.4238±38.4793) µg/ L respectively. The rate of Iron and Chloride concentration was increased by applying the factors except the genetic factor.We conclude from the above that the asthma patients have the active oxygen species ROS more effective than healthy controls, which in turn caused an oxidative stress accompanied by a decrease or an increase in antioxidants and trace elements, and the effectiveness of those affected by the factors mentioned above.

تحضير ودراسة تحليلية - طيفية لبعض اصباغ الازو غير المتجانسة واستخدام احدها في استخلاص النحاس الثنائي من المحاليل المائية == Preparation and Analytical Study of Some Heterogeneous Azo Dyes and Using One of Them in Extraction of Cu(II) From Aqueous Solutions

Author name: لمياء عبد اللطيف رسن
Supervisor name: اسعد عبود علي
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: Arabic
University location: Basrah
First pages:
Abstract: The thesis involves three parts : The first part included synthesis eight new Azo dyes,derived of Procaine and Metoclpramide : LR1R = 3 - [ ( Procaine ) azo ] - 2 - hydroxyl indoleLR2R = 2 - [ ( Procaine ) azo ] - 4,5 - diphenyl ImidazolLR3R = 2 - [ ( Procaine ) azo ] - 3 - PhenylephrineLR4R = 2 - [ ( Procaine ) azo ] Imidazol, L5 = 2 - [ ( Metoclopramide ) azo ] Imidazol,LR6R = 2 - [ ( Metocopramide ) azo ] 3 - PhenylephrineLR7R = 3 - [( Metoclopramide ) azo ] 2 - hydroxyl indoleLR8R= 2 - [( Metoclopramide ) azo ] - 4,5 - diphenyl ImidazolThey have been described by C.H.N. and Visible spectroscopic spectra and the functional groups were characterized by I.R technique like azo group of (1558.48 , 1512.19 ,1581.63 , 1508.12 , 1521.84 , 1529.55 , 1517.98 , 1533.14 ) cm - P 1 P for azo dyes (LR1R LR2R , LR3R , LR4R , LR5R , LR6R , LR7R , LR8R) respectively The Acid - Base properties were also studied spectrophotometric using buffer solutions of pH values of (0.67 - 12) in the visible region, From the spectra obtained the protonation an ionization constants of azo dyes were determined by using Half - Height method ,the isopiestic point were also established ,which indicated the suggested mechanism for the ionization and protonation steps.The effect of solvents of different polarities was also studied on the spectra shift in the visible region. It was found that linearity relation between the dielectric constants of solvents and λRmaxR this denotes the dielectric constants at the mediumis the main factor governing the band shift, except for (LR6R) azo dye which give little deviation from linearity . The second part concerns with the ability of azo dye (LR8R) for forming complex with Cu(II) , The optimum conditions for forming stable azo dye - complex were studied like pH effect , kind of buffer solution , time effect and sequence of addition of reagents by aid molar ratios method and Continuous variation method It was found that stable complex was obtained with stoichiometry of 1 : 2 ( M : L ) From calibration curve of (L8) complex , : Sandell sensitivity 2.492× 10 - 3 μg cm - 2, Detection limit 0.00977 μg ml - 1, Standard deviation 0.00193, Correlation coefficient 0.994 , molar absorbitivity coefficient 2.547×104 L mol - 1cm - 1 , specific absorbtivity 0.4012 ml g - 1cm - 1 and obeyness of Beer's law linearity up to 3.20 ppm The effect the interference of some important cations and anions of concentration (1 - fold, 5 - fold and 10 - fold ), the stability of this complex was showed through determination of their conformation constants (stability constants) by use the corresponding solution method ,by aid of using half value method .this complex had been characterized by (FT - IR) according to the different of shift relativity abundance of same active groups bundle complex comparison with privately dyes ; the azo group ( - N=N - ) and (C=N) groups.,the percentage to metal (Cu) in the complex determine by using of result Atomic Absorption Spectroscopy where found approximate the same between theoretical and measurement.The third part : involved solvent extraction of Copper(II) ions from its aqueous solution by using L8 to organic solution. This study include limitation of optimum conditions for complex formation of highest observed absorbance of λmax at complex : such as (pHex=7) ,ions concentration Copper(II) 15μg effect shaking time of two immiscible phase 15 min .the distribution ratio (D*).and extraction percentage (%E) were determination.Organic solvent effect study appeared there is not any linear relation between dielectric constant (D) of organic solvents and distribution ratio (D*) that’s mean there is not any effect for polarity of organic solvent on extraction method but there is an effect for organic solvent structure which is participate in the structure of ion pair complex extracted by formation tight ion pair or loose ion pair as well experiment result illustrate chloroform organic solvent it was the best organic solvent in extraction .Thermodynamic study include Temperature effect on extraction efficiency the experimental results demonstrate the reaction was exothermic for Copper(II) with organic reagent (LR8R) endothermic reaction , after calculation thermodynamic data ΔHRexR , ΔGRexR , ΔSRex Rshow entropy values was high that is mean complexion reaction is entropic in region

دراسة حيوية لمستخلص اوراق نبات الدودنيا ضد مرض سرطان الثدي البشري == Biochemical Study of Dodonaea viscosa (L.) Jacq. Extracts on the Anti - Human Breast cancer

Author name: غزوان ذياب موسى العمري
Supervisor name: علي عبد الواحد عبد الحسين الشاوي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير ايمايدات حلقية ثنائية وبعض مشتقاتها الكبريتية ودراسة خواصها الطيفية والتركيبية , عمليا ونظريا باستخدام نظرية دالية الكثافة == IR, NMR, MS Spectra and Structure of Some prepared Bicyclic Imides and Their Thione Derivatives; Experimental and Density Functional Theory studies

Author name: عادل امعلا ضمد ال ازيرج
Supervisor name: ناجي علي عبود
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Basrah
First pages:
Abstract: The present work involved four parts : First step concerned with the preparation some N, N’ - alkyl (aryl) bismaleimic acidsvia reaction of twice molar amounts of maleic anhydride and hydrazine for compound(A1), and different alkyl and aryl - diamines for compounds A2 - A7. The reaction wascarried out via nucleophilic attack of amino group in maleic anhydride. The structureof the compound (2Z,2Z’) - 4,4’ - (ethane - 1,2 - diylbis (azanediyl)) bis (4 - oxobut - 2 - enoicacid) (A2) was also unambiguously confirmed by X - ray single crystal structureanalysis. The white crystal crystallizes in the monoclinic system, space group C2/cwith the cell dimensions a =7.108(3), b=7.370(2), c= 20.859(6) Å, β = 91.260(4)oand Volume = 1092.65(6) Å3.Molecule is stabilized by an intramolecular O—H…O hydrogen bond. In thecrystal, molecules are connected through intermolecular N—H…O hydrogen bonds.Intermolecular and intramolecular hydrogen bonds coexist to stabilize the structure.The geometry calculated of compounds A1 - A7 was optimized using a Densityfunctional theory DFT with B3LYP hybrid functional and 6 - 311G (d, p) basis set, andis in good agreement with the structure obtained by the X - ray single crystal structureof compound A2. Also the fundamental vibrational frequencies of vibrational bandswere evaluated.The second part of this study was the treatment of N,N - alkyl and (aryl)bismaleimic acid (A1 - A7) with suitable dehydrating agents lead to dehydration andcyclization producing the corresponding N,N - alkyl and (aryl) bismaleimide (AD1 - AD7).The structure of the compound 1,1’ - (sulfonylbis(4,1 - phenylene)) bis (1H - pyrrole - 2,5 - dithione) (AD7) was also unambiguously confirmed by X - ray single crystalstructure analysis. The colorless crystal crystallizes in the monoclinic system, spaceAbstractix0200040000CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2CH2phenyl4,4' - sulfonyldianilinedirect Aliphatic AromaticWavenumber cm¯¹Types of RCH str.CH2 - N strC=O strC - Ngroup P21/c with the cell dimension a =11.698(3), b=15.002(3), c= 20.053(6)Å andβ = 98.818(2)o Volume = 3478.07(13) Å3.FT - IR spectra show the position of the absorption bands vary with the type andlength of the link spacer (R) between the two maleimide rings on the compoundsAD1 - AD7.The absorption frequency of vinyl group increases with increasing methylene aliphatic chain spacer link between two maleimides ring, the correlation between some absorption bands and the type (direct link or aliphatic or aromatic) and length of aliphatic chain link spacer (R) between the two maleimide rings in the studied compounds AD1 - AD7 shown in the chart below.In the third part, a series of new bisthimalemide derivatives were prepared by thionation the compounds AD3, AD6 and AD7 with Lawesson’s reagent LR. Subsequent reaction of bismaleimimides AD3, AD6 and AD7 with Lawesson’s reagent afforded dithio derivatives.

تحضير وتقييم ودراسة الاطلاق المسيطر عليه للكيتوبروفين المحمل على بوليمرات ذات خاصية لاصقة للمواد المخاطية == Preparation, evaluation and study controlled release ketoprofen from mucoadhesive polymers

Author name: سرور وليد عبد الرضا الكناني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: We have used ketoprofen which is found in the local pharmacy and ketoprofen was separated and purified and then measured the melting point and (λ max) were determined for the purpose of ascertainig the purity of the material used.The microspheres were prepared with Sodium alginate by using Sodium alginate with Chitosan and without Chitosan and by using Calcium chloride a cross - linking agent, the microspheres and drug were characterized by IR and photomicrographs microscopy.In vitrostudy of drug release and kinetics of drug release were studied in simulated Gastric fiuid (SGF) and simulated Intensinal fluid (SIF). The results exhibit that the pH value effected on releaseing rate of drug from microspheres, also the samples gave ahigh release rate in pH=(8.2)(SIF) comparison with low values of pH=(1.2) (SGF) .Study The effect of different process parameters such as drug /polymer ratio and sodium alginate /chitosan ratio,on the morphology, size distribution and drug release. The microspheres diameters were found between (400 - 900) μm The rate of ketoprofen released was increased with the increasing of concentration of drug in the microspheresThe release of drug deareasing with increase of polymers. The coefficient of determination indicated that the release data was best fitted with zero order kinetics , Higuchi equation explains the diffusion controlled release mechainism.In this study Nine polymer hydrogel compound were prepared (GI - G9). semi Interpenetra ting polymeric hydrogel (IPNS). From synthuetic polymers Poly electrolyte with poly acrylamide The swelling146146characteristics were studied for all microspheres and semi - IPN hydrogels by determining the swelling ratio (Q)in three differnt pH, it was found that it . depending on components quantities and enoironments.We Niosomes loaded with ketoprofen were prepard and studied rate release drug in (pH=7.4) was studied with decreasing . The results showed that the releasing is increase of Cholesterol, Niosomes was succeeded in cover kp . also prepared gel of Niosomes and Carbopol934 by different concentration of Niosomes and Carbopol934 , The results showed that by ahigh release of drug deincreasing the concentration of Carbopol934 .In biological part , the results show that biological activities of the microspheres loaded with kp exceed biological activities against three types of fungal isolates including Candida albicans, and staphylocoecas aureus in comparison with activity of kp alone.The study consist on the toxicity of these materials which is shown that these materials are nontoxic.

دراسة الصفات الفيزيائية والكيميائية وتقدير الفينولات في المحطات (Hg,Cd,Pb) وبعض العناصر الثقيلة المختارة لمياه شط العرب == Study of physiochemical Properties Determination of phenols and Some Heavy Metals (Hg , Cd , Pb ) in the Selected Station of Shatt Al - Arab water

Author name: سارة كاظم حسین السیامر
Supervisor name: ناظم عبد النبي عواد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: The present study was concluded measurement of physical and chemical properties such as pH value, temperature, electrical conductivity, total hardness total solubility of salt, calcium and magnesium hardness, chloride concentration basal, concentration of dissolved oxygen, phosphates, nitrates, concentration of sodium and potassium in addition to, estimation of heavy metal and phenols to sample taken from shatt al - Arab of Qurna to Fao for period From December (2014) to June (2015). The study showed that the water temperature range between (18co - 20.4co) .The pH value were (7.8 - 8.9). Electrical conductivity range between (1118 - 27700ppm) the total hardness. Of studies water sample were (480 - 2600 ppm) Qurna E20. The concentration of lead were (1.8ppm) as the highest value plant (SH4) which located in FAo (marina boats) in plant (SH2) which located in AL Maakal. The study reveated That The highest value 0f mercury were in plant (SH4) which were (18nglmL)in plant which located in water project near The basra airport (F3) and (F5) plant located near Basra international airport The Salty were range (752 - 20000 ppm) in addition, Calcium and Magnesium concentration were (96 - 468ppm) and (43 - 846 ppm) respectively, chloride concentration (122 - 965ppm) while The basal were (l05 - 200 ppm), dissolve oxygen were (8.13 - 17.5 0). phosphates and nitrate were range between (0.10 - 0.62ppm) and (2.24 - 15.53ppm) respectively sodium and potassium concentration to studies sample were (120 - 8800ppm) ( 3.1 - l50ppm) revealed That highest value of cadmium element were in Abu - alkaseeb plant in Al - sankar (SH2B) were (0.099607ppm) while the lowest value were (0.0125819ppm) which were in plant before confluence of Tigris and Euphrates rivers about450m in sediment sample, The highest value of sodium and lead were(0.17Mg.g) and (2.1Mg.g) respectively in SH2B plant while lowest value of cadmium and lead were (0.11Mg.g) and (0.95Mg.g) respectively in F5plant lead element has highest value(2.5Mg.g) in plant SH2B while lowest value were (1.2Mg.g)in plant SH1which located in Al - Hartha before karma Ali river. This study showed that the concentration of phenols were range between (20 - 590ng\l) also, this study showed that Shatt - Al - Arab which consider as main source to water drinking in province of Basra , is currently asking for direct sewage and heavy water without treatment .

تحضير وتشخيص المعقدات الضمنية لبعض ادوية السلفا == Preparation and Characterization of Inclusion Complexes of Some Sulfa drugs

Author name: رؤى قاسم ابراهيم
Supervisor name: جبار صالح هادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: حضرت في هذه الدراسة ثلاثة معقدات ضمنية لثلاثة من ادوية السلفا هي السلفابروكسلين والسلفابريدين والسلفاميثوكسي بريدايزين مع β - سايكلودكسترين بنسبة مولية 1 : 1 وبطريقتين هما طريقة التجفيف بالتجميد Freeze drying وطريقة العجن Kneading . شخصت المعقدات المحضرة باستعمال تقنيات IR و1HNMR وXRD وDSC وTg وSEM .وقد اظهرت نتائج IR و1HNMR طبيعة التداخل بين جزيئة الضيف والمضيف وبينت بان الحلقة الاوروماتية لادوية السلفا توجد داخل فجوة - CD β الكاره للماء . سلفابروكسلين β - سايكلودكسترين معقد السلفابروكسلين - β سايكلودكسترين واظهرت دراسة XRD لمساحيق الادوية النقية ، وبمقارنتها مع المعقد الناتج ان الصفة البلورية لمعظم المعقدات تقل عند تكوين المعقد مقارنة مع السلفا النقية ، وحسبت احجام البلورات Crystal باستعمال معادلة Scherrer ووجد انها بحدود nanocrystalline. كذلك بينت دراسة DSC وTg ان الاستقرار الحراري للسلفابروكسلين يزداد عند تكوين المعقد وبينت نتائج DSC اثبات تكوين المعقد . وكذلك بينت صور SEM للمعقدات الناتجة ان معقد السلفابروكسلين ذات اشكال ورقية ، ومعقد السلفابريدين ذات اشكال قرصية ، اما معقد السلفاميثوكسي بريدايزين فانة يظهر باشكال صفائحية ذات حافات حادة .كذلك درس تاثير تكوين المعقدات على ذوبانية الطور Phase Solubility في المحاليل المائية وتصنف الادوية الثلاث بانها قليلة الذوبان جدا في الماء بحالتها النقية . واستعملت طريقة Higuchi وConnors في تكوين المعقد على الذوبان باستعمال تقنية uv وبينت النتائج ان الذوبانية تزداد لجميع ادوية السلفا المدروسة مع زيادة تركيز CDβ وتتبع للنوع AL للسلفاميثوكسي بريدايزين وAN للسلفابريدين والسلفابروكسلين وحسب ثابت استقرار المعقدات من العلاقة Kc=slope/(S_o (1 - slope)) ووجد انها للسلفابروكسلينM - 1 455.160 وللسلفابريدينM - 1 483.149 وللسلفاميثوكسي بريدايزينM - 1 164.01 والذوبانية تزداد بمقدار 3 - 4 مرات

دراسة الاطلاق المسيطر عليه لعقار الاندوميثاسين من مركبات الاباتيت المحضرة المحتوية على عنصري الكالسيوم والسترونتيوم == Studying Of The Controlled Relaesinng of Indomethacin Drug From Prepared Apatite Compounds Containing Elemantal Calcium And Strontium

Author name: رؤى حسين ناصر
Supervisor name: عبد الامير حسين تعوبي | زكي ناصر كاظم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: This work contains two parts, the first parts includes the preparation of different compounds of apatite and determine the ratios of strontium and calcium and phosphate in the compounds and the second part included the study of release of indomethacin drug from prepared compounds.Different compounds of apatite were prepared and identified such as a compound of calcium hydroxyapatite (Ca10 (PO4)6 (OH)2) which is prepared in three different methods .Hydroxyapatite Strontium compound (Sr10(PO4)6 (OH)2) and Strontium Fluorapatite compound (Sr10(PO4)6F2 ) and composite calcium Fluorapatite compound ( Ca10 (PO4) 6F2) and Strontium - Calcium hydroxyapatite compound ( Ca5Sr5(PO4)6(OH)2 ).All these compounds were identified by Infrared spectroscopy and X - rays, which confirmed the presence of the prepared compounds.Quantitative analysis of the percentage of calcium and strontium in the prepared compounds was conducted using flame atomic absorption spectroscopy. Also the amount of phosphate and then phosphorus was determined by UV - Vis. spectroscopy ( Phosphomolybedenum blue method.) The results showed that the concentrations of the elements mentioned above in the prepared compounds are within the acceptable range for its role in a property biological effectiveness for compounds.The other part has been singled out for studying the release of a indomethacin drug in a laboratory in the prepared compounds and which is used as an anti - inflammatory and analgesic for pain osteoporosis.Porosity tablets of the compounds loading with drug indomethacin for 24 hours and then studied the release of drug from tablets for 48 hours using visible spectroscopy UV function when acidic pH = 7.4 and a temperature of 37 ⁰ m. As the results showed that the release of indomethacin taking a different time for different times of the compounds that arrived at the level at which the release settled between (4 - 8) hours.

تحضير وتشخيص بعض المعقدات التناسقية لصبغات الازو المشتقة من الباراسيتامول ومركبات السلفا ودراسة فعاليتها ضد البكتريا == Synthesis And Characterization Of Some Metal Complexes For Azo Dyes Derived From Paracetamole And Sulpha Compound And Study Of Their Antibacterial Activity

Author name: رواء هشام يعقوب
Supervisor name: طارق علي فهد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: In this study, four ligands were synthesized from prepared by the coupling of 4 - acetamidophenol with some sulfa drugs (sulfadiazine Ld , sulfaguinidine, Lg ,sulfamethazine Lm and sulfapyredine Lp) with parasetamol .These ligands were characterized by elemental analysis, FT - IR. , UV - visible ,1H - NMR , 13C - NMR and mass spectroscopy. The chemical structure of these ligands are suggested as following : Lp={N - (4 - hydroxy - 3 - ((4 - (N - pyridin - 4 - ylsulfamoyl)phenyl)diazenyl)phenyl)acetamide} Ld=N - (4 - hydroxy - 3 - ((4 - (N - pyrimidin - 2 - )ylsulfamoyl)phenyl)diazenyl)phenyl)acetamide) Lg=N - (3 - ((4 - (N - carbamimidoylsulfamoyl)phenyl)diazenyl) - 4 - hydroxyphenyl)acetamideLm={N - (3 - ((4 - (N - (4,6 - dimethylpyrimidin - 2 - yl)sulfamoyl)phenyl)diazenyl) - 4 - hydroxyphenyl)acetamide} The ionization constant of the ligands were determined potentiometrically using the Irving - Rossotti technique at constant temperature 25 °C. The values of the average number of protons associated with the ligands nA at different pH values were calculated. The proton - ligand formation curves are obtained by plotting nA versus pH at constant temperature.Twelve complexes were prepared from above ligands with cobalt, nickel, and copper salts, with molar ratio 1 : 1 (M : L) . These complexes were identified by elemental analysis, FT - IR. spectra, Uv - visible spectra,atomic absorption,molar conductance and megnetice,susceptibility The results were lndicated that the found valaes of C,H,N for prepared complexes were clossed to their theoretical volues . IR Spectra showed that stretching vibration of azo group in the complexes were shifted in comparison with ligands inaddition to appearance of M - N and M - O stretching,UV - visible and magnetic studies gave in idea about geometry and coordination number of these complexes through location of electronic transition and number of unpaired electron in outer energy levels.Atomic absorption measurements explained that the reaction of the ligand with the metal complexes was 1 : 1 molar ratio ,also the perecentage of the metals in the prepared complexes was in good agreement with the theortical values.The molar conductance values of the coordination compounds of mentioned metal ions under investigation were determined using (1.0×10 - 3 mol. L - 1) DMF solvent, The molar conductance and magnetic values suggest the presence of a non - electrolyte.The magnetic moments of Ni(II), Cu(II), and Co(II), complexes were measured at room temperature .Based on the different characterization methods described above, the chemical structures of the prepared complexes were suggested as following.

دراسة الفولتامتري الحلقي والتخليق الكهروكيميائي والتوصيل الكهربائي لبعض مركبات التلوريوم العضوية == CYCLIC VOLTAMMETRY, ELECTROCHEMICAL SYNTHESIS AND CONDUCTEMETRIC STUDIES OF SOME ORGANOTELLURIUM COMPOUNDS

Author name: ديار محمد علي مراد
Supervisor name: علي زايد الربيعي | انيس عبد الوهاب النجار
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: تضمنت هذه الدراسة على جزئين ، فالجزء الاول يتعلق بدراسة السلوك الكهروكيميائي لمركبات ثنائي فنيل ثنائي التلوريد وبس(2 - امينو - 5 - مثيل فنيل ) ثنائي التلوريد وبس(2 - امينو - 5 - بروموفنيل )ثنائي التلوريد باستعمال تقنية المسح الجهدي الحلقي في مذيب رباعي هيدروفيوران وفي درجة حرارة الغرفة .بينت النتائج المستحصلة ان تلك المركبات تعاني انتقالا الكترونيا مفردا خلال عمليتين متعاقبتين اثناء عملية الاختزال .و استعملت تلك التقنية لتحديد مناطق الجهد المناسبة تمهيدا لاجراء التخليق الكهروكيميائي للتلوريدات العضوية غير المتجانسة : اثيل فنيل تلوريد ((1 ، بروبيل فنيل تلوريد ((2 ، بيوتيل فنيل تلوريد ((3، اثيل ( - 2 امينو - 5 - مثيل فنيل) تلوريد (4) ، بروبيل( - 2 امينو - 5 - مثيل فنيل) تلوريد (5) ، بيوتيل ( - 2 امينو - 5 - مثيل فنيل) تلوريد (6)، اثيل( - 2 امينو - 5 - برومو فنيل) تلوريد ((7، بروبيل ( - 2 امينو - 5 - برومو فنيل) تلوريد (8)، بيوتيل ( - 2 امينو - 5 - برومو فنيل) تلوريد (9). شخصت هذه التلوريدات العضوية غير المتجانسة بواسطة تحليل العناصر الدقيق واطياف تحت الحمراء . اما الجزء الثاني فقد تضمن قياس التوصيلية الكهربائية للمركبات : فنيل التلوريوم ثلاثي اليوديد و4 - ميثوكسي فنيل التلوريوم ثلاثي اليوديد و4 - كلوروفنيل التلوريوم ثلاثي اليوديد وفنيل التلوريوم ثلاثي البروميد وفنيل التلوريوم ثلاثي الكلوريد في مذيبي DMSO وDMFالنقيين وعند درجة حرارة 25 مo . اجريت التحاليل المتعلقة بنتائج التوصيلية الكهربائية بطريقة تقنية التقليل للحد الادنى باستعمال اربع معادلات نظرية للتوصيلية وهي معادلات Fuoss - Hsia (فوس - سايا) و) Pitts بتس) الموسعة والمحورة . اوضحت النتائج التحليلية لتلك المركبات بانها لا تتصرف كالكتروليتات قوية في كلا المذيبين وان تفككها ليس بالتفكك التام ، كما لوحظ وجود تفاوت في قيم التوصيلية الكهربائية وفقا˝ لطبيعة المجموعة المعوضة كونها دافعة او ساحبة وكانت حسب الترتيب الاتي : ومن ناحية اخرى قورنت قيم توصيلية المركب فنيل التلوريوم ثلاثي اليوديد مع المركبين فنيل التلوريوم ثلاثي البروميد وفنيل التلوريوم ثلاثي الكلوريد اذ كانت قيم التوصيلية الكهربائية وفق نمط الترتيب الاتي | The present study divided into two sections, firstly , the electrochemical behavior of diphenyl ditelluride ,bis(2 - amino - 5 - methyl phenyl)ditelluride and bis(2 - amino - 5 - bromo phenyl)ditellurid have been investigated by cyclic voltammatry in THF at room temperature. The results showed that all these compounds suffer of two single successive electron transfer through the reduction process. This technique was used to determine the best voltage regions in order to carry out the electrochemical synthesis of unsymmetrical organic telluride, i.e : ethyl phenyl telluride (1), propyl phenyl telluride (2), butyl phenyl telluride (3), ethyl (2 - amino - 5 - methyl phenyl)telluride (4), propyl(2 - amino - 5 - methylphenyl)telluride(5), butyl (2 - amino - 5 - methylphenyl) (6),ethyl(2 - amino - 5 bromophenyl)telluride(7), propyl(2 - amino - 5 - bromo phenyl) telluride(8) and butyl(2 - amino - 5 - bromophenyl) telluride(9). All mentioned compounds were characterized by CHN and IRspectroscopy. secondly, the electrical conductances of phenyl tellurium triiodide , 4 - methoxy phenyltellurium triiodide , 4 - chloro phenyltellurium triiodide , phenyltellurium tribromide and phenyltellurium trichloride have been measured in both DMSO and DMF solvents at temperature 25oC .The evaluation of conductance data was carried out by minimization technique using the theoretical conductance equations of the complete and modified forms of Pitts and Fuoss - Hsia . Analytical results showed that these compounds do not behave as strong electrolytes in both solvents , and that their dissociation are far from complete . The low conductances of these electrolytes may be attributed to the formation of ion - pairs. The presence of donating or withdrawing groups on benzen ring affect the electrical conductivity and the following trend was obtained : Finally ,the sequence of increasing the conductaces of the three studied phenyltellurium trihalides is given below :

تحضير ودراسة بايلوجية لبعض مركبات البايرزول == Preparation and biological study of some pyrazole compounds

Author name: خنساء صقر سعود
Supervisor name: نزار لطيف شهاب الدين
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:
Abstract: The present study includes the preparation of some pyrazolines derivatives includes their characterization and their biological activity.Chapter one the introduction shows the literature survey and related important reactions for pyrazolines .While chapter two shows the details of the preparation for each types in details 36 pyrazoline product were prepared from 6 types of (cha/cones) Benzalacetophenones and six different hydrazine ( hydrazinehydrate , phenylhydrazine, semicarbazide, thiosemicarbazide 2,4 - dinitrophenylhydrazine and phenylthiosemocarbazide ).Chapter three shows all the results which proved the chemical structures of some selected compounds by using I.R, 1H - NMR, 13C - NMR, CHN, and mass. Spectroscopy we found abnormal case in pyrazoline derivatives especially in the ring once have - CH2 like in (P1and P10) and compounds (P8 and P13) does not have the methylene protons this exception was happened due to modification in procedure. Finally the biological activity for some selected compounds were used and compared with standard drugs and its shows moderately to good activity.

تقديرات بيز لنموذج القياسات المتكررة احادي التصنيف == Bayesian Estimations of the One - Way Repeated Measurements Model

Author name: خولة عبد الرزاق وادي
Supervisor name: اميرة جابر محيسن
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

مصفوفات التجزئة للمشخصات المغزلية للزمر التناظرية == Decomposition Matrices Of The Spin Characters Of The Symmetric Groups

Author name: نزار محمد يعقوب
Supervisor name: سعيد عبد الامير تعبان
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

تحليل الاستقراريه لنموذج رياضي لتفاعلات النظام المناعي والسرطان == Stability Analysis For The Mathematical Modeling Of Cancer - Immune Response Interactions

Author name: نداء قاسم محمد
Supervisor name: مهند موسى عيسى
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

منهجية التفاضل التربيعي الجديدة المعتمدة على متعددات حدود برنستين وتحسين ADI-DQM لحل معادلات النقل == A New Differential Quadrature Methodology Based On Bernstein Polynomials And Improve ADI - DQM For Solving Transport Equations

Author name: فراس عامر سعدون السعداوي
Supervisor name: عبد الستار جابر علي السيف
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

تحليل الخطا بطريقة كالركن الغير مستمرة للعناصر المحددة لمسالة الحمل والانتشار == Error Analysis For The Discontinuous Galerkin Finite Element Method Of The Convection - Diffusion Problem

Author name: غازي عبد مفتن
Supervisor name: هاشم عبد الخالق كشكول | يحيى هاشم سليم
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

حول هندسة تنسر الانحناء الكونفورمي لمتعدد طيالا فايسماش - كري == On The Geometry Of The Conformal Curvature Tensor Of The Vaisman - Gray Manifold

Author name: فاتن احمد رجب
Supervisor name: حبيب مطشر عبود
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

المجموعات الضبابية والشريحة الجزائية في الانحدار شبه المعلمم البيزي == Fuzzy Sets And Penalized Spline In Bayesian Semiparametric Regression

Author name: عمار مسلم عبد الحسين
Supervisor name: اميرة جابر محيسن
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

توليد الحل المضبوط لبعض انظمة المعادلاتالتفاضلية الجزئية غير الخطية باستعمالطريقة التكامل الاول == Generating Exact Solution For Some Nonlinear Systems Of Partial Differential Equations By Using First Integral Method

Author name: عمار عبد الحسين راضي الصالح
Supervisor name: عبد الستار جابر علي السيف
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

طرائق ال B - spline المتبقي الموزون لحل مسالة الموجة المتساوية العرض المعدلة == B - Spline Weighted Residual Methods For Solving Modified Equal Width Wave Problem

Author name: عقيل عبد الواحد قاسم
Supervisor name: حميدة عودة مزبان
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

تعميم الاقواس - (k,n;f) من النوع (1,n) في pg(2,q) و الاقواس -(k,n) الموزونه من النوع (n-4,n) في pg(2,8) == A Generalization Of (k,n;f) - Arcs Of Type (1,n) In PG (2,q) And Weighted (k,n) - Arcs Of Type (n - 4,n) In PG (2,8)

Author name: زينب عبد الباقي عبد الجبار
Supervisor name: فؤاد كاظم حميد | حبيب مطشرعبود
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

حول تقريب دوال في فضاء البعدين باستخدام بعض المؤثرات الخطية الموجبة من النمط q == On Approximation Of Functions In Two Dimensional Space Of q - Type By Certain Linear Positive Operators

Author name: رفة فؤاد كاظم
Supervisor name: علي جاسم محمد الاسدي
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

المتفردات الحدودية للدوال الملساء في تحليل حلول التفرع لمعادلة دوفينك == Boundary Singularities Of Smooth Functions In The Analysis Of Bifurcation Solutions Of Duffing Equation

Author name: حسين خشان كاظم
Supervisor name: مظهر عبد الواحد عبد الحسين
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

حلول التفرع لبعض الانظمة من المعادلات التفاضلية اللاخطية == Bifurcation Solutions Of Some Systems Of Nonlinear Differential Equations

Author name: ابراهيم عبد علي شنان
Supervisor name: مظهر عبد الواحد عبد الحسين
General topic: Mathematics
Specific topic: Mathematics
Degree: Master
Language: English
University location: Basrah
First pages:

نقل البرم خلال نقطة كمية تحت تاثير مجال مغناطيسي == Spin Transport Through a Quantum Dot under Magnetic Field Effect

Author name: مهند محسن مرزوك
Supervisor name: جنان مجيد المخ
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

الضخ غير الاديباتيكي للشحنة الالكترونية في نقاط كمية مقترنة == Non-adiabatic electron charge pumping in coupled quantum dots

Author name: رجاء محمد عبد الله
Supervisor name: شاكر ابراهيم عيسى
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة نظرية لتوليد الطاقة الكهربائية وتاثرها باختلاف درجة الحرارة وخصائص الشكل الهندسي == Theoretical Study Of Electrical Energy Generation And Its Dependence On Temperature Variation And Geometrical Shape Properties

Author name: رسول رمضان عتاب
Supervisor name: جاسب عبد الحسين مشاري
General topic: Physics
Specific topic: Physics
Degree: Doctorate
Language: English
University location: Basrah
First pages:

دراسة التركيب النووي لنظائر الكادولينيوم (154 - 160Gd) الموشوهة بتطبيق انموذج IBM - 1 == Studied the Nuclear structure of Isotopes Gadolinium (154–160Gd) deformed application IBM-1

Author name: مسلم جاسم فعيل
Supervisor name: فالح حسين خضير
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة التصرف الحركي لليزرات اشباه الموصلات نوع النقاط الكمية الممتدة == Study of the dynamical behavior of the quantum dash semiconductor laser

Author name: محمد سالم جاسم الطائي
Supervisor name: جاسب عبد الحسين مشاري
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تصميم وتصنيع هوائي احادي القطب مستوي مطبوع ذات عرض الحزمة الترددية الفائقة (UWB) == Design And Fabrication Of Miniaturize Printed Planar Monopole Ultra Wideband Antenna

Author name: علي محمد عذاب
Supervisor name: علي عبد الصمد عبيد | احمد هاشم عبود
General topic: Physics
Specific topic: Physics
Degree: Doctorate
Language: English
University location: Basrah
First pages:

دراسة عملية ميدانية وانموذج يحاكي هيدروديناميكية ونقل الرسوبيات في نهر شط العرب == Study process and model simulates hydrodynamical and sediment transport in the Shatt al-Arab River

Author name: عادل جاسم محمد الفرطوسي
Supervisor name: نوري حسين نور الهاشمي | سامر عدنان رحمة
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة نظرية لليزر النقطة الكمية بوجود التغذية المرتدة باستخدام معادلة المعدل متعدةة التعدد == Theoretical Study of Quantum Dot Lasers with Feedback by Multi-population rate equation

Author name: ضياء صيوان بريسم
Supervisor name: رائد محمد حسن
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحديد تركيز غاز الرادون في لحوم الاسماك المحلية والمستوردة في محافظة البصرة/ جنوب العراق باستخدام تقنية كواشف الاثر النووي الصلبة == Determination of Radon Activity Concentration In local and Imported meat of fish in Basra Governorate/(Iraq)by using Solid State Nuclear Tracks Detectors Technique

Author name: ضرغام جبار سلمان الاسدي
Supervisor name: عيسى جاسم الخليفة
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة قوة التلاصق والخصائص الكهربائية لاغشية البوليمر بولي (انلين - مشترك - الكحول الاليلي) المرسب على قواعد مختلفة == Studying of Adhesion force and electrical properties of polymer poly ( Aniline – Co -Ally Alcohol ) films deposited on different substrates

Author name: شذى سامي عبادي
Supervisor name: حسين فالح حسين
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

التقنين الاشعاعي البيئي لمحافظة البصرة - العراق باستخدام تقنية التالق الحراري == Environmental Radiation Dosimetry For Basrah Governorate/(Iraq) by using Thermoluminescence Technique

Author name: ستار جبار بدر الدرويش
Supervisor name: رياض جاسب ابو الهيل
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة نظرية لبعض معاملات جهود المصيدة المستخدمة في تكثيف بوز - اينشتين == Theoretical Study of Some Factors of The Trapping Potential Used in Bose – Einstein Condensation

Author name: سامر كاظم غالب الخفاجي
Supervisor name: نوري حسين نور الهاشمي
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

قياس تركيز النظائر المشعة طبيعيا في بعض المواد الغذائية والاسنان المتوفرة في محافظة البصرة == Measurement of Natural Radioactivity in Some Food and Tooth Available in Basrah Governorate

Author name: سارة عبد الامير محمد
Supervisor name: عبد الرضا حسين صبر
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة التركيب النووي لانوية الرصاص (186Pb - 194) والبلوتونيوم (238 - 246Pu) باستخدام انموذج البوزونات المتفاعلة بصيغتيه IBM - 1 وIBM - CM == Study the Nuclear Structure of 186-194Pb and 238-246Pu Nuclei by Using The Interacting Boson Model IBM and IBM-CM

Author name: زينب نجم احمد شهاب
Supervisor name: فالح حسين خضير
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة الخواص البصرية الخطية والاخطية لصبغات عضوية == Studying of linear and nonlinear optical properties for organic dyes

Author name: رضاب خلف منشد
Supervisor name: قصي محمد علي حسين
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

نقل الالكترون المعتمد على الزمن خلال نقطة كمية المدعوم بالمجال الكهرومغناطيسي : بوجود وغياب القناة غير الرنينية == Time-dependent Electron Transport through a Quantum Dot Assisted by Electromagnetic Field: In the Presence and Absence of the Nonresonant Channel

Author name: حيدر موشنة عبيد
Supervisor name: جنان مجيد المخ
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة نظرية لليزرات الانبعاث السطحي ذات التجويف الشاقولي بالبلورة الفوتونية == A Theoretical Study of Photonic-Crystal Vertical-Cavity Surface-Emitting Lasers

Author name: حسين ناصر قاسم
Supervisor name: حسن عبد الله سلطان
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

نقل الالكترون خلال النقطة الكمية : التاثيرات الكهروحرارية وتاثيرات التبادل في نهجي كوندو ولاكوندو == Electron Transport Through A Quantum Dot: Thermoelectric Effects And Correlation Effects In Kondo And Non - Kondo Regimes

Author name: موسى كاظم شامر
Supervisor name: jenan majeed Al - mukh | shakier lbraheem easa
General topic: Physics
Specific topic: Electronics Physics
Degree: Doctorate
Language: English
University location: Basrah
First pages:

دراسة تركيز البورون لمصادر المياه في محافظة البصرة باستخدام تقنية طريقة القياس اللوني الكركومين == Boron Concentration Measurement in Water Using Colorimetric Curcumin Method in Basra Governorate

Author name: منتظر عدنان قاسم المياحي
Supervisor name: ثائر منشد سلمان
General topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة الخواص البصرية اللاخطية وانماط الحيود - الذاتي لاصباغ الازو == A Study of the nonlinear optical properties and Self-diffraction patterns of azo dyes

Author name: ختام عبد العادل وحید
Supervisor name: حسين علي بدران
General topic: Physics
Specific topic: Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تاثير المجال المغناطيسي الساكن على معايير الدم ومكواته الكيموحيوية ونسبة تحلل كريات الدم الحمر == Effect of Static magnetic Field on Hematological,Biochemical Parameters and on Lysis of Red Blood Cells

Author name: جابر خليل عبد الحسين الطوكي
Supervisor name: سناء كاظم خلف | عبد الرزاق نعيم خضير
General topic: Physics
Specific topic: Medical Physics
Degree: Master
Language: Arabic
University location: Basrah
First pages:

الجوانب الفيزيائية والكيميائية في الخليج العربي == Physical and Chemical Oceanography of the Arabian Gulf

Author name: مؤید حسن محمد البهادلي
Supervisor name: علي عبد الزهرة دعيبل | بهجت علي سعيد
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
Language: English
University location: Basrah
First pages:

تحضير ودراسة دواء مضاد للشمانيا مسند الى انظمة بوليمرية ذات الانحلال المقنن

Author name: ايمان سعد علي
Supervisor name: نادية عاشور الاسدي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تخليق ودراسة الفعالية البايولوجية لبعض مشتقات 1و2و3 - ترايازول الجديدة == Synthesis of some new 1,2,3 Triazole derivatives and Biological activity study

Author name: نازك حميد خضير الكطراني
Supervisor name: فائزة عبد الكريم ناصر
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص مركبات الثايواستر ودراسة صفاتها البلورية السائلة == Synthesis and Characterization of thio esters compounds and studying their liquid crystalline Properties

Author name: ميعاد خلف حضين الشريفي
Supervisor name: عهود جبار عبيد الحمداني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص وتقييم سقالات عظمية للبولي يوريثان والبولي يوريا فورمالديهايد كانظمة توزيع عقاقير == Preparation , Characterization and Evaluation of Bone Scaffolds For Polyurethane and Poly Urea Formaldehyde as Drug Delivery Systems

Author name: انسام خالد نعمة
Supervisor name: نادیة عاشور الاسدي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

التخليق المدعم بالاشعة المايكروية لبعض الدايهايدروبيردونات المشتقة من الكركمينات ودراسة صفاتها التركيبية == Microwave - Assisted Synthesis to some Dihydropyridones Based on Curcuminoides and Study to its Structural properties

Author name: ميثم نجم عبود
Supervisor name: بهجت علي سعيد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تاثير المجاميع الفينولية المعوضة للكركمينات غير المتناظرة على تحضير الجسيمات النانوية وتفاعلها مع الامينات المدعم بالاشعة المايكروية == Effect of substituted phenolic groups of asymmetric curcumines on preparation nanoparticles and their ractions with amines supported by microwave

Author name: مها عبد الجبار ناصر الاسدي
Supervisor name: بهجت علي سعيد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تخليق ودراسة تحليلية - طيفية لصبغات ازوية جديدة لمشتقات الايميدازول ومعقدات بعض الفلزات الانتقالية مع احدى الصبغات المخلقة == Synthesis and spectro - analytical study of new azodyes of imidazole derivatives and complexes of some transition metals with one of synthesized azo dyes

Author name: منتهى خليل حمزة غريب
Supervisor name: اسعد عبود علي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص بعض الصبغات الازوية ومعقداتها مع النحاس المشتقة من 5,1 - ثنائي هيذروكسي نفثالين ودراستها كمثبطاث لتاكل النحاس في الوسط الحامضي والقاعدي == Synthesis, Identification of Some Azo Dyes and their Complexes with Copper derived from 1,5 - Di Hydroxy naphthalene and Study as Corrosion Inhibitors for Copper in Acidic and Base media

Author name: علي منعثر عبد السادة النجار
Supervisor name: مؤيد يوسف كاظم العبادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص بعض قواعد شف ومعقداتها والبيتالاكتام المشتقة من بعض ادوية السلفا ودراسة فعاليتها البايولوجية == The Preparation and Identification of Some Schiff bases and their Complexes and ? - lactams derived from Sulfa drugs and the study of their Biologycal activity

Author name: علي غانم سوادي
Supervisor name: جبار صالح هادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص بعض منشطات السطوح البوليمرية الجديدة المشتقة من الاثلين ثنائي الامين رباعي حامض الخليك ودراستها ككواسر استحلاب وكمثبطات للتاكل == Preparation, Identification of some New Polymeric Surfactants derivative from Ethylenediamintetraacetic acid And Study As De - emulsifiers And Corrosion Inhibitors

Author name: علا جميل خلف محمد العلي
Supervisor name: محمود شاكر حسين
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص بعض معقدات العناصر الانتقالية الجديدة الحاوية على ليكاندات قواعد شف المشتقة من الببرونال ودراسة خصائصها الحرارية وفعاليتها البايولوجية == Preparation,Characterization Some Transition Metal Complexes Contains of Schiff base Ligands' Derived From Piperonal And Study of Thermal Properties And Biological Activity

Author name: عبد الجليل محمد عبد الجليل
Supervisor name: مؤيد يوسف كاظم العبادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة مقارنة باستخدام مستخلص اوراق نبات الكونوكاربس ومخلف البولي ستايرين المسلفن والبولي الكتروليت التجاري كمساعدات للتخثير في عملية تصفية المياه == A comparative study of the use conocarpus extract and waste polystyrene sulfonated and Commercial polyelectrolyte as coagulant aid in water purification

Author name: عباس كاظم جحيل
Supervisor name: نبيل محمد علي وادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتذخيص مركبات مذتقة من الجالكون ودرادة صفاتكا البلورية الدائلة وادتقرارها الحراري == Synthesis and Characterization of Chalcone Compounds and Study their Liquid Crystaline Properties and Thermal Stability

Author name: روزا عدنان سلمان
Supervisor name: عهود جبار عبيد الحمداني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

استخدام تقنية المسح الفولتائي الحلقي لدراسة بعض قواعد شف ذات المجاميع المختلفة == Using of cyclic voltammetry technology for study of some Schiff base derivative

Author name: رسل وداد محمد سعيد الطه
Supervisor name: طالب اسماعيل الصالح
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير ودراسة بعض مركبات الكركمين والجسيمات النانوية المشتقة منها == Synthesis and Study of Some Curcuminoids and Their Nano Particles

Author name: فايز عويد نعمة
Supervisor name: بهجت علي سعيد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص ودراسة طيفية وكهربائية لبعض معقدات البورفرازين رباعية البايرازين == Preparation and Identification with Spectroscopic and Electrical Study for Some Tetrapyrazinoporphyrazine complexes

Author name: رحين كرم زبوى
Supervisor name: نزار عبد الامير حسين
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

حالة الاجهاد التاكسدي ونمط الدهون في مرضى اضطرابات الغدة الدرقية == Oxidative Stress Status And Lipid Profile In Patients With Thyroid Gland Disorders

Author name: بشرى عبد المحسن عبد العزیز السالم
Supervisor name: عباس دواس مطر المالكي | كامل حسین السوداني
General topic: Chemistry
Specific topic: Biochemistry
Degree: Doctorate
Language: English
University location: Basrah
First pages:

تحضير وتشخيص ودراسه الفعاليه البايلوجيه لبعض مركبات الازو الجديده == Synthesis, Identification And Study The Biological Activity Of Some New Azo Compounds

Author name: انتظار كاظم محمد الايوب
Supervisor name: نزار لطيف شهاب الدين
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Basrah
First pages:

دراسة نظرية وعملية للتراكيب واطياف تحت الحمراء والرنين النووي المغناطيسي لبعض الهيدرازونات المشتقة من الالديهايدات باستخدام طريقة DFT == Theoretical and experimental Study of Structures IR and NMR of some hydrazones derived from aldehydes using DFT method

Author name: ساري حمد هلبان
Supervisor name: ناجي علي عبود
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة مستويات بعض العناصر النزرة (الزنك , السلينيوم , الكروم , المنغنيز) كمضادات اكسدة بمصل دم مرضى الربو في محافظة البصرة/ العراق == The study level some trace element ( zinc , selenium , chromium and manganese) as antioxidant in blood serum of asthma patient in Basrah / lraq

Author name: فرح مجبل جبر الجابري
Supervisor name: ساهرة غريب صياح
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير ودراسة تشخيصيه وتحليليه لبعض مشتقات الاسبرين الاحادي التعويض الجديدة == Synthesis and characterization studies and Analysis for some Aspirin of Mono - Substituted

Author name: ستار جبار احمد
Supervisor name: فاطمة مهدي نعمة الجابري
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص طيفي ودراسة الصفات الحرارية والفعالية البايولوجية لبعض المعقدات المشتقة من قاعدة شف والبنزاميدازول المشتقة من 4 - مثيل اورثو فنلين ثنائي امين == Preparation,Spectroscopic Characterization, Thermal Study and Biological Activity of Some Complexes Derived From Schiff base and Benzimidazole Derived From 4 - methylphenelendiamine

Author name: زهیر علي عبد النبي
Supervisor name: جبار صالح هادي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير ودراسة طيفية لبعض الصبغ الازوية المشتقة من 1 - هيدروكسي 2 - حامض النفثويك مع مشتقات السلفا دايزين ودراسة معقداتها مع الالمنيوم == Synthesis and Spectrophotometric Studies of Some Azodyes Derived From 1 - Hydroxy - 2 - naphthoic Acid and Sulfadiazine Derivatives and Studing their Complexes with Aluminum

Author name: حيدر عبد الستار جايد اليوسف
Supervisor name: اسعد عبود علي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة امتزاز بعض العناصر الثقيلة على سطحي مسحوق اوراق الكونوكاربس واليوكالبتوز وتطبيقها في معالجة مياه الصرف الصحي == Study of adsorption of some heavy metals on the surface leaves powder of both Conocarpus and Eucalyptus and their applications in the sewage water treatment

Author name: ايهاب اسعد مطرود
Supervisor name: ثريا منصور ابراهيم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

عزل وتشخيص بعض المركبات الفعالة من اوراق نبات البرهامة Albizia Lebbeck (L.) Benth ودراسة فعاليتها ضد البكتيريا المعزولة من مرضى المسالك البولية == Isolation and Identification of Some Active Compounds from Albizia lebbeck (L.)Benth Leaves and Study of Their Activity Against the Bacteria Isolated from Urinary Tracts Patients

Author name: اشواق عبود شنتة حافظ
Supervisor name: عباس دواس مطر المالكي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تحضير وتشخيص بعض الدايمرات الميزوجينية المتناظرة ودراسة صفاتها البلورية السائلة

Author name: ايمن غازي فيصل الابراهيم
Supervisor name: عهود جبار عبيد الحمداني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تقدير بعض العناصر الثقيلة في محار ورواسب ومياه شط العرب ومعالجتها بصخور البورسلينات == Estimation of some heavy metals in clams, sediments and water from Shatt Al - Arab and treatment rocks porcellanite

Author name: احمد يوسف حمود الشمري
Supervisor name: طارق زباري جاسم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Basrah
First pages:

عزل انواع من البكتريا المكسرة للنفط من مصب شط العرب وتحسين قابليتها على تكسير الالكانات الاعتيادية == Isolating oil degrading bacteria from Shatt Al- Arab estuary and improving their degradability for n-alkanes

Author name: فاضل نعمة عبد الرضا
Supervisor name: امین عبد الجبار السلمي | اسعد محمد رضا الطائي
General topic: Biology
Specific topic: Microbiology
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تاثير التهاب اللثة وانسجة حول السن وتسوس الاسنان في بعض المعايير الفسيولوجية == Effect of gingivitis, Periodontitis and Dental caries on some physiological parameters

Author name: شذى قاسم كاظم التميمي
Supervisor name: سامي جبر كاظم المالكي
General topic: Biology
Specific topic: Zoology - Physiology
Degree: Master
Language: Arabic
University location: Basrah
First pages:

The Role Of Mycoplasmas In Oral Cavity Diseases And The Efficacy Of Some Toothpaste And Antibiotics On Them

Author name: زهراء كاظم سعيد
General topic: Biology
Specific topic: Microbiology
Degree: Master
Language: English
University location: Basrah
First pages:

الديدان المتطفلة في بعض الطيور البرية في محافظة البصرة == Helminthes parasitized on some wild birds of Basrah province

Author name: سامية شمخي جبر
Supervisor name: بسم هاشم عبد الله
General topic: Biology
Specific topic: Microbiology - Parasites
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة انتشار طفيلي الابواغ الخبيئة Cryptosporidium في بعض مصادر المياه والخضروات والحيوانات في محافظة البصرة == The distribution of Cryptosporidium in Some Resources of Water, Vegetables and Animals in Basrah Province

Author name: سارة كامل ناصر
Supervisor name: عبد الحسين حبش عواد
General topic: Biology
Specific topic: Microbiology - Parasites
Degree: Master
Language: Arabic
University location: Basrah
First pages:

تاثير المطروحات السائلة لمحطة النجيبية الحرارية لتوليد الطاقة على مجتمع النواعم في نهر كرمة علي - البصرة - العراق == The effect of liquid effluens from ALNajibiyah thermal power plant on the molluscacommunity in Garmat Ali River Basrah ,IRAQ

Author name: حنان عبد الحافظ علي
Supervisor name: منال محمد اكبر الدركزلي
General topic: Biology
Specific topic: Zoology - Pollution
Degree: Master
Language: Arabic
University location: Basrah
First pages:

مقارنة الطرائق التشخيصية الوسط اللوني Chromogenic mediumوالانتشار بالاقراص DisK Diffusion المتسلسل PCR للكشف عن المكورات العنقودية الذهبية المقاومة للمثيسيلين في الردهات الجراحية في مدينة الناصرية == Comparison Of Chromogenic Medium, Disk Diffusion Test And Pcr Methods Forthe Detection Of Methicillin Resistant Staphylococcus Aureus (MRSA) In The Surgical Wards Of Al - Nasiriyah City

Author name: جواد رشید هویدي الزیدي
Supervisor name: امین عبد الجبار السلمي
General topic: Biology
Specific topic: Microbiology - Bacteria
Degree: Doctorate
Language: English
University location: Basrah
First pages:

الكشف عن دور المفطورات في اصابة الجهاز البولي في كلا الجنسين باستخدام طريقتي الزرع MDCS وتقنية PCR == Detection the Role of Mycoplasmas in Urinary Tract infection of both Sexes in Basra city by MDCS method and PCR

Author name: ايمان عبد الحسين غانم
Supervisor name: غيداء جاسم عبد النبي الغزاوي
General topic: Biology
Specific topic: Microbiology
Degree: Master
Language: Arabic
University location: Basrah
First pages:

انتاج جسيمات الفضة النانوية باستخدام بعض فطريات التربة وتقييم نشاطها الضد ميكروبي مختبريا == Production of silver nanoparticles using some soil fungi and in vitro evaluation of their antimicrobial activity

Author name: احمد كاظم حاجم الخفاجي
Supervisor name: توفيق محمد محسن
General topic: Biology
Specific topic: Biotechnologies
Degree: Master
Language: Arabic
University location: Basrah
Key words:
  • Nanobiotechnology+Fungi+Silver nanoparticles (AgNPs)+UV+Scanning electron microscopy (SEM)+ Antibacterial
First pages:
Abstract: اجريت هذه الدراسة في قسم علوم الحياة في كلية التربية للعلوم الصرفة وتضمنت الدراسة الحالية تطبيق_x000D_
لانتاج جسيمات الفضة النانوية باستخدام بعض الانواع nanobiotechnology تقنية النانو الحيوية_x000D_
الفطرية المعزولة من التربة في مناطق مختلفة من محافظة البصرة بعد ان نميت في وسط تخمري سائل في_x000D_
دوارق زجاجية لمدة عشرة ايام._x000D_
Macrophomina والفطر Curvularia tuberculata فقد اظهرت الانواع الفطرية المتمثلة بالفطر_x000D_
قابليتها على البناء Nigrospora sphaerica والفطر Humicola grisea والفطر phaseolina_x000D_
الحيوي لجسيمات الفضة النانوية بعد 42 ساعه من حضانة راشح الغزل الفطري المعامل مع ملح نترات_x000D_
وتم الكشف عن عملية البناء الحيوي بملاحظة التغيرات اللونية من الراشح الشفاف الى AgNO الفضة 3_x000D_
الذي اظهر قمم امتصاصيه UV الاصفر او البني او البني الغامق. واستخدم مطيافية الاشعة فوق البنفسجية_x000D_
الخاصة بجسيمات الفضة النانوية . )nm 430- عند الاطوال الموجية ) 420_x000D_
استخدم في الدراسة الحالية المجهر الالكتروني الماسح لغرض تحديد شكل الجسيمات النانوية وحجمها وقد_x000D_
100 نانومتر. - اظهرت صور المجهر الالكتروني الجسيمات النانوية باشكال كرويه بابعاد 8_x000D_
كما تم الكشف عن المجاميع الكيميائية المسؤولة عن البناء الحيوي وتغليف الجسيمات النانوية باستخدام طيف_x000D_
لكلا من رواشح الفطريات والجسيمات الناتجة بعد تحويلهما الى مسحوق وقد اظهر IR الاشعة تحت الحمراء_x000D_
الطيف وجود مجاميع الامايد وبقايا البروتينات وكذلك مجاميع الكاربوكسيل المسؤولة عن عملية الاختزال_x000D_
الحيوي للنترات وبناء جسيمات الفضة النانوية بالشكل الكروي._x000D_
اظهرت جسيمات الفضة النانوية المنتجة من الفطريات وبتراكيز واطئة جدا باستخدام طريقة الانتشار_x000D_
Esherichia فعالية تثبيطيه تجاه البكتيريا القياسية Well Diffusion Method بالحفر_x000D_
والسلالات المرضية Staphylococcus aureus (NCTC وبكتيريا ( 6571 coli(ATCC25922)_x000D_
كما اظهرت فعالية Salmonella typhi و Proteus mirabilis و Pseudomonas aeruginosa_x000D_
وتفاوتت الفعالية عند مستوى Candida albicans(ATCC تثبيطيه ضد الخميرة المرضية ( 10231_x000D_
. P? احتمال 0.05_x000D_
بتقدير Microtiter technique وحددت الفعالية الحيوية للجسيمات النانوية باستخدام تقنية المعيار الدقيق_x000D_
تجاه البكتيريا الموجبة والسالبة لصبغة كرام MFC و MPC والقاتل الادنى MIC التركيز المثبط الادنى_x000D_
S. 0.0097 )مايكروغرام\مل( تجاه بكتيريا - والخميرة المرضية والتي اظهرت تراكيز منخفضه 0.078_x000D_
كما اظهرت الجسيمات E. coli 0.312 )مايكروغرام\مل( تجاه بكتيريا - والتركيز 0.039 aureus_x000D_
كما تم خلال الدراسة C. albicans 1.25 )مايكروغرام\مل( تجاه الخميرة - النانوية التركيز 0.0195_x000D_
Disk الحالية اختبار الفعالية الحيوية لجسيمات الفضة النانوية باستخدام طريقة النشر على الاقراص_x000D_
تجاه Gentamycin ودراسة الفعالية المشتركة مع المضاد الحيوي التجاري Diffusion Method_x000D_
البكتيريا المرضية المختبرة وقد لوحظ زيادة الفعل التثبيطي تجاه جميع الانواع البكتيرية وسجل اعلى معدل_x000D_
ثم تلتها الانواع الاخرى. Ps. aeruginosa و E.coli تثبيط ضد بكتيريا

تاثير بعض مركبات الايض الثانوي المعزولة من الطحلب الاخضر ضد طفيليي Cladophora crispata (Kuetizings ,1843) Entamoeba histolytica(Schaudinn, 1903) في الفئران المختبرية نوع Giardia lamblia)Stiles, و) 1915 Balb/c سلالة Mus musculus (L, 1758) == Effect of Some Secondary Metabolic Compounds Isolated From Alga Cladophora crispate( Kuetizings ,1843) against Entamoeba histolytica(Schaudinn, 1903) and Giardia lamblia(Stiles,1915) Parasites in Laboratory mice Species Mus musculus (L, 1758) strain Balb

Author name: دلال فلاح محسن العقابي
Supervisor name: صبيح هليل المياح | احمد محسن عذبي
General topic: Biology
Specific topic: Microbiology - Parasites
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة التوزيع الجغرافي والتواجد السنوي لعض انواع عائلة الذباب الازرق diptera : calliphoridae والتشخيص باستخدام تقنية كروموتوغرافيا الغاز في البصرة

Author name: نادية كاظم ثامر
Supervisor name: ضياء خليف كريم
General topic: Biology
Specific topic: Zoology - Insects
Degree: Doctorate
Language: Arabic
University location: Basrah
First pages:

استخلاص المركبات السامة من الطحلب الاخضر المزرق Lyngbya aeruginosa Menegh. ex Gomont ودراسة تاثيراته النسجية المرضية على ذكور الفئران Albino mice mus musculus المختبرية == Extraction of Toxic Compounds From Blue Green Alga Lyngbya aeruginosa Menegh. Ex Gomont and Study of Its Histopathological Effects on male Albino mice mus musculus

Author name: اساور سليم محمد علي الطائي
Supervisor name: احمد محسن عذبي الجعفر | علي عبد اللطيف عبد الحسن العلي
General topic: Biology
Specific topic: plant - aquatic life
Degree: Master
Language: Arabic
University location: Basrah
First pages:

عزل وتشخيص الطحلب الاخضر المزرق Menegh. ex Gomont Lyngbya martensiana ودراسة تاثيراته المرضية النسجية على سمكة سيفية الذنب Xiphophorus helleri واجنتها == Isolation and identification of the blue green algae Menegh. ex Gomont Lyngbya martensiana and study of its histopathological effects on swordtail fish Xiphophorus helleri and its embroys

Author name: يسرى طارق ياسين الرديني
Supervisor name: احمد محسن عذبي الجعفر | علي عبد اللطيف العلي
General topic: Biology
Specific topic: plant - aquatic life
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة بيئية وحياتية للقشري Indomysis nybini Crustacea: Mysidacea في شط العرب وقناة شط البصرة == Ecological and Biological study of Indomysis nybini i (Crustacea: Mysidacea) in Shatt Al Arab and Shatt Al basrah canal

Author name: ندى مفيد عبد اللطيف البغدادي
Supervisor name: منال محمد اكبر | طالب عباس خلف
General topic: Biology
Specific topic: Zoology - Invertebrates
Degree: Master
Language: Arabic
University location: Basrah
First pages:

دراسة فرط الحساسية من النمط الاول للحوم الابقار والدجاج عند مرضى الحساسية وعلاقتها مع مستضدات كريات الدم البيض من الصنف الثاني == Study The Hypersensitivity Type I To Beef And Chicken Meat In Allergy Patients With HLA Class II Association

Author name: شيماء جبار ريسان عيسى
Supervisor name: فوزية علي عبد الله
General topic: Biology
Specific topic: Microbiology - Immunology
Degree: Doctorate
Language: English
University location: Basrah
First pages:

دراسة تشريحية مقارنة لبعض الاعضاء لنوعين من الاسماك العظمية المغذاة على الطحلب الاخضر المزرق (Agardh,1884) Nostoc carneum المنتج للسموم الكبدية Microcystins == Comparative study of some organs for two osteicthyes fishes fed on blue-green alga Nostoc carneum(Agardh,1884) producing microcystins

Author name: سجى جعفر طالب
Supervisor name: عقيل جميل منصور | عماد يوسف عواد
General topic: Biology
Specific topic: Zoology
Degree: Master
Language: Arabic
University location: Basrah
First pages:

الديدان المتطفلة في بعض الطيور المائية واهمية الحشرات في دورة حياة البعض منها في محافظة البصرة == Helminthes parasitized of some aquatic birds & the impotance of insects in the life cycle of some of them in Basrah province

Author name: التفات عامر عبد الله التميمي
Supervisor name: عبد الحسين حبش عواد | ضياء خليف كريم
General topic: Biology
Specific topic: Microbiology - Parasites
Degree: Master
Language: Arabic
University location: Basrah
First pages:

عزل وتشخيص الجراثيم من عينات سريرية وبيئية والكشف عن بعض العناصر الوراثية المسؤولة عن المقاومة للمضادات الحيوية والعناصر الثقيلة في محافظة البصرة == Isolationand Identification of Bacteria from clinical and Environmental Samples and Detection of Some Genetic elements Responsible for Antibiotic and Heavy Metals Resistance in Basrah Government

Author name: اسماعيل جمعة عباس
Supervisor name: ميثم ايوب الحمداني
General topic: Biology
Specific topic: Microbiology - Bacteria
Degree: Master
Language: Arabic
University location: Basrah
First pages:
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