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المنابع الثقافية للشعر العربي في القرنين الثاني والثالث الهجريين Cultural Sources for Arabic poetry In the second and third centuries AD

اسم المؤلف: سعد علي جعفر المرعب
اسم المشرف: عباس محمد رضا حسن البياتي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: وفي خضم المعطيات الثقافية المؤثرة والمتاثرة بالبيئة الزمانية والمكانية نجد المضامين الثقافية للشاعر تظهر في دلالات النص المنتج , فالادب عامة والشعر خاصة منجز من منجزات الثقافة ومعطى من معطياتها المعرفية والذهنية . فحسن اختيار المعارف التي ترفد ثقافة الشاعر لا تؤدي دورا في حسن استعمال الالفاظ وجودة اختيار المعاني فحسب بل تعطي للمنتج رؤى واسعة في استيعاب مدركات الحياة ومعطياتها والتعبير عنها , فالتجربة الشعرية هي نتاج للثقافة المكونة من الشعور والفكر . تاتي اهمية دراسة المنابع الثقافية في كونها توضح المؤثرات الفكرية والقيمية في الاتجاهات العامة للمجتمع والاتجاهات الخاصة للشعراء المتاثرة بظروف النشاة والفكر والثقافة والمذهب على حد سواء فتاثر الشاعر ببيئة ما يكون المنبع الذي يؤثر في العمل الفني على حسب استيعابه لمؤثرات ذلك المنبع , فالشعر نشاط فكري معقد يوظف المنابع الثقافية في اخراج منجزه الادبي معتمدا في استيعابها على عقلية الشاعر ومدى استجابته للمنابع الثقافية , فيكون الشاعر متعاملا مع البؤر الثقافية المحركة للحياة بشكل مستمر موظفا دلالات الالفاظ في التعبير عن نوع المنبع او المنابع التي ينتمي لها , فتاتي اهمية المنابع الثقافية في عدها محفظة ارشيفية يجد فيها الفرد الشرح الوافي لسلوكه وفكره الذي هو جزء من السلوك والفكر الجمعي لمجتمع ما في عصر بعينه . تم اختيار موضوع اطروحتي (المنابع الثقافية للشعر العربي في القرنيين الثاني والثالث الهجريين) فكانت المدة الزمنية لهذا البحث تعتمد مع التقسيم السياسي في سقوط دولة ما وقيام دولة اخرى على التقسيم الفني لان دراسة التطور الادبي لايمكن ان يكون ظاهرة فجائية تقترن بتغير نوع الحكم وبمجيء دولة وذهاب اخرى بل يتمدد العصر الادبي بعضه على بعض الاخر . فلقد بدا في القرن الثاني على اساس بدء حدوث تطور شعري جديد نتيجة المتغيرات الخطيرة والعميقة الاثر التي جدت في حياة الجماعة الاسلامية فكان الهدف المركزي معرفة مدى تقبل شعراء كل عصر لانواع الثقافة الموروثة والاسلامية والمستجدة ومدى تاثيرها بالمنجز الشعري لدى كل منهم , فلكل عصر خصوصيته النقدية التي تجعلنا نتساءل عن مدى تاثر الدور الثالث والاخير من العصر الاموي بالثقافة المستجدة ومدى ميله الى الثقافة الموروثة وانكفائه عليها وتمثله للثقافة الاسلامية مع ملاحظة طريقة التوظيف الفني والبناء الشعري والصياغة الاسلوبية , ثم نتساءل عن العصر العباسي الاول ومدى تمثل الشعراء المخضرمين الذين عاشوا في عصر الدولة الاموية وادركوا الدولة العباسية والمولدين المنابع الثقافية حيث الحضارة والثراء والترجمة والمذاهب الفكرية والفلسفية والفرق السياسية مع انقسامهم ايضا الى شعراء الطبع والالتزام بعمود الشعر وشعراء الصنعة واستعمال الافكار العميقة والصنعة الفنية والبلاغية ومعرفة مدى تمثلهم لانواع الثقافة وكيفية التعبير عنها والمقارنة مع شعراء العصر العباسي الثاني حيث الانفتاح الكبير في الحضارة والثراء والترف والاتجاهات الفلسفية ومعرفة مدى تاثرهم بانواع الثقافة وكيفية تمثلهم لها وطريقة التعبير عن الثقافة المستجدة والناي عن الثقافة الموروثة والاسلامية ومعرفة شعراء كل عصر الذين مثلوا اتجاها في تمثلهم لمنبع ما او اكثر . اما منهج البحث في الاطروحة فكان المنهج الوصفي التحليلي ليتناسب مع المنابع الثقافية وتطبيقها على الاغراض الشعرية عاقدا موازنة بين شعراء البادية والحجاز في العصر الاموي وشعراء الطبع والصنعة في العصر العباسي الاول وشعراء الصورة في العصر العباسي الثاني معتمدا استخدام المنبع على الاغراض الشعرية في كل العصور متناولا الشعراء اصحاب الدواوين . ومن المصاعب التي واجهت البحث هو البحث عن الشعراء الذين يدخلون تاريخيا وفنيا ضمن مرحلة البحث فكان يجب علي الرجوع الى كتب التراجم والاعلام والسير للتاكد من الشاعر والمعلومات التاريخية التي تخصه فكان نتاج هذا العمل الشاق ماتكون لدي في الملحق الاول من تراجم الشعراء مع ذكر المصادر التي يرجع فيها لكل منهم, ثم واجهت البحث مشكلة الحصول على الدواوين الشعرية للشعراء والبحث عن مظانها ووضعها بين دفتي البحث فضلا عن المشكلة العويصة التي واجهت الجانب البحثي في تقسيم الشعراء لانه من الخطا وضع حدود فاصلة دقيقة بين العصر الاموي والعصر العباسي الاول والثاني تعود لاسباب هي طول المدة الزمنية التي بقي بها الشاعر على قيد الحياة فضلا على انه ابعد مايكون عن الصحة وضع حدود فاصلة تماما بين العصور وعلى الاخص من الناحيتين الاجتماعية والعقلية , وعليه فاني تعاملت مع شعراء العصر الاموي والعصر العباسي الثاني بالرجوع الى مناسبة القصيدة او الشخص الذي قيلت فيه لمعرفة دخولها ضمن مدة البحث من عدمه , هذا فضلا عن السيرورة والشهرة الادبية له في عصر ما ومعاصرته لمجموعة من الشعراء وتفاعله معهم ايجابا او سلبا واسلوبه الادبي المختص بعصر بعينه فكل هذه المعطيات تعتمد في عده ضمن مدة بعينها . وهذه الدراسة حلقة من سلسلة دراسات وبحوث اكاديمية سبقتها ومن اهمها على سبيل المثال لا الحصر : - 1. الشعر والتاريخ : د . نوري حمودي القيسي (كتاب). 2. المنابع الثقافية الاولى للشاعر الجاهلي : د . عادل البياتي (بحث). 3. عناصر الوحدة الثقافية في الشعر العربي ماقبل الاسلام : د . محمود عبد الله الجادر (بحث). 4. المنابع الثقافية للشعر العربي قبل الاسلام : مزاحم علي(رسالة). 5. المنابع الثقافية للشعر العربي في عصر صدر الاسلام والعصر الاموي : د . عباس محمد رضا (اطروحة) . 6. ابو تمام ثقافته من خلال شعره : د . ابتسام مرهون الصفار (كتاب). 7. ثقافة المتنبي واثرها في شعره : د . هدى الارنؤوطي (كتاب). 8. اثر التراث في الشعر العراقي الحديث : علي حداد (كتاب). 9. المرجعيات الثقافية الموروثة في الشعر الاندلسي عصري الطوائف والمرابطين : حسين مجيد الحصونة (اطروحة). 10 . التراث في شعر المحدثين : عدنان كاظم مهدي(اطروحة) . وقد تشكل الهيكل النظري للاطروحة من مقدمة وتمهيد اوضحت فيه الثقافة لغة واصطلاحا , واثر الثقافة في الشعر , ثم قسم الموضوع الى ثلاثة فصول فكان الفصل الاول الثقافة الموروثة فاشتمل على توطئة واربعة مباحث هي الموروث الشعبي والثقافة التاريخية والثقافة القيمية الاجتماعية وثقافة الامثال , ولقد تعمدت اغفال الشعر بصفته موردا للثقافة الموروثة لانه سيدخل البحث في باب التناص وهو بحث يختلف عن موضوع البحث ببيان الاصول والمنابع الاولى للثقافة لكونها ابعد من الشعر , اما الفصل الثاني فاشتمل على توطئة وثلاثة مباحث هي ثقافة الاقتباس القراني , الثقافة العبادية والعقائدية , وثقافة القصص القراني , اما الفصل الثالث الثقافة المستجدة , فاشتمل على توطئة ومبحثين هما الثقافة السياسية والعقلية , ثقافة القيم والمعارف الاجتماعية الجديدة واخيرا اشكر الاستاذ الدكتور عباس محمد رضا المشرف على هذه الاطروحة الذي لولاه لما خرجت هذه الاطروحة بالهيئة التي وصلت اليها | The culture represents the intellectual side of individuals and communities alike, but is the basis of human thought in the production and development of creativity, and then determine the culture identity of the community in the dimensions of the physical and moral culture of a society is the source of values and actions of individuals belonging to him and through him can be understood and taught. In the midst of cultural data affecting the environment and affected the temporal and spatial find cultural contents of the poet reflected on the implications of the text and its impact product technical literature has in general and poetry in particular accomplishment of the achievements of the culture. We have chosen the subject of this thesis (Headwaters cultural Arabic poetry in the second and third centuries Alahjrien) Thus, this period of time dependent with political division in the fall of a State and the other on the division of technical, Regarding the research methodology in the thesis was a descriptive analytical approach statistical commensurate headwaters with cultural and applied to the purposes of poetry. This study is an episode of a series of studies and academic research before it, may pose a theoretical structure of the thesis of an introduction and then smooth the theme section into three chapters, Was the first chapter inherited culture Vachtml a prelude and four Detectives culture is legendary and historical culture and culture values social and culture of Proverbs, Chapter II Vachtml on the preparation and the three sections is the culture of the quote Quranic, culture, worship and faith, culture Stories Qur'an, Chapter III comprising the preparation and Mbgesin two political culture and mentality, culture and values of the new social knowledge

الاعتراضات النحوية لشراح الجمل على عبد القاهر الجرجاني Objections commentators Gamal Abdel omnipotent Jerjani

اسم المؤلف: نور مسلم صالح الغرابي
اسم المشرف: سهى كناوي حسن
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ذي قار
الصفحات الاولى:
المستخلص: The book (as in sentences) for Jrjana of the most important books shortcut Jerjani, for that this book has received attention by researchers because it is a book to explain (factors), which aims to teach the emerging Arabic grammar is far from the objections and differences of opinion ... And require the nature of the research that divides an introduction followed by a reboot and two doors, followed by a conclusion in which I explained the most important results of the research, and worked hard to be the number of doors pages equal, but the nature of the material in the book required to be the first door has the largest in search share.Boot annexation of two things : First : I talked about him Abdul omnipotent Jerjani and lineage and scientific stature and elders who took his knowledge of them and his disciples who make disciples on his hands and his writings and the year of his death. And it dealt with annotations which explained the book (as in sentences) and the most important commentators their knowledge.The second showed the meaning of the objection and idiomatically language.The doors Vtdment the following : Part I dealt with the parts of speech is on the three chapters : Chapter I : The names includes : First : Border : Name some extent, limit the actor's name, and limited exception, the case united, united the indefinite article and knowledge, and the building and expressed.Second : What caused by name and includes : Deuteronomy, and the expression of the six names, and both and both, the difference between the building and expressed.Chapter II : acts includes : First : an end Function : Second acts includes : (1) the past tense, and addressed it : transitive verb was missing and the full and distress and nearing.(2) the present tense includes : Bug lifter present tense works and what action of the verb.(3) an act which includes : building bug did it.Chapter Three : letters and includes : an end character, and the fact that (will not). And Part II dealt with the (grammatical General provisions) includes the following : Chapter One : doors grammatical and divided by three sections : First : the nominative or indicative included : Bug lifter Debutante and the news, and to provide the news that her name.II : Mouncobac includes : Bug building name not precluding sex, and do not repeat the name after the indefinite article, and factor in the Excluded, and the monument with waw passion (F brilliance). III : Prepositional includes : Addition, and added to the J speaker. The second chapter : grabbed the solo things and includes : the appeal and banned from the exchange. Then sealed conclusion searchable highlighted the findings. It has walked in my research on this analytical approach; a revenue Jerjani opinion matters, as well as the statement of the views of commentators and then present the views of grammarians, and the statement of the right of opinion.

الفاظ اجزاء الانسان في نهج البلاغة دراسة في الحقول الدلالية PARTS OF THE HUMAN BODY AND THEIR MEANINGS IN NAHJUL BALAGHA OF IMAM ALI(AS)

اسم المؤلف: مخلص عبد الزهرة رحيم الكناني
اسم المشرف: علي فرحان جواد
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: المثنى
الصفحات الاولى:
المستخلص: This research aims at numerating the parts of the human body in NahjulBalagha of Imam Ali (AS) and showing the impact of context in determining the meaning and channeling it and knowing the intention the addressee and the purpose of the discourse in addition to drawing the attention of researchers to focus on the human body and consider it physically, socially, culturally and symbolically as regards structure ,text or context in which that utterance is organized to discover itssemantic dimensions , semiotic vagueness and how it is employed and what distinguish it for Imam Ali (AS).The nature of the research and its content required that it is divided up into a preface and four chapters precede an introduction and sealed by conclusion .As for the preface , it has dealt with the meanings of the utterances of (stature and mere body ) in its first part where the term has been specified alongside te limitation of the research . Accordingly, the study of these utterances has been conducted with reference to language and usage . Part two has dealt with the utterances of the stages of man's creation . Chapter one has included the study of utterances denoting the head and face and what is annexed to them . It has been divided up into seven sections which are as follows : utterances relating to the ear and what is annexed to it, utterances relating to teeth and what is annexed to them, utterances relating to the nose and what is annexed to it, utterances relating to the head and what is annexed to it , utterances relating to the hair and what is annexed to it ,utterances relating to the eye and what is annexed to it, utterances relating to the mouth and what is annexed to it and finally utterances relating to the face and what is annexed to it. Chapter two has been devoted to the utterances relating to the man's trunk and what is annexed to it. This means that the reference is made to the utterances relating to the apparent and hidden of the back and belly which has been in their turn divided up into six sub - sections which are as follows : utterances relating to belly and what is annexed to them, utterances relating to the side and what is annexed to it, utterances relating to the chest and what is annexed to it , utterances relating to the back and what is annexed to it ,utterances relating to the neck and what is annexed to it and finally utterances relating to the heartand what is annexed to it . Chapter three has focused on utterances relating to the extremities and what is annexed to them which has been divided up into three sections which are as follows : utterances relating to the arm and what is annexed to it, utterances relating to the leg and what is annexed to it and finally utterances relating to the hand and what is annexed to it .Chapter four which is the last chapter has dealt with general utterances which has been arranged in two sections which are as follows : general utterances relating to the part of human body and utterances for the general parts of the human body and that which relates to them. After the conclusion theresearch hassupplied a comprehensive bibliography of sources and references.The research is based on the analytical descriptive approach where the text has been the judge and criterion and a source for extracting findings. The research , therefore, has arrived on the following findings : 1 - It has been made clear that the meanings of the utterances relating to the human body in NahjulBalagha that that category is open to many sciences some of which concerns naming the parts forming the body or stature , others are concerned with their movements and their indicative and social dimensions, some are religious pertaining to their behavior in an Islamic religious framework relevant to creation, life and resurrection . However, some of which relates to jurisdiction pertaining to sanctity of the body and its bounds as regards the other; while others are intellectual or conceptual pertaining to the body symbolism at a certain level.2 - The study has made manifest the usage meaning of theutterances mentioned in the research . The researcher has tried to provide a compact or terse meaning for the usage origin by the Imam.3 - The Imam (AS) has affirmed the close relation between the speaking and mute communication in some of the NahjulBalagha texts while in other texts , he has shown the conflict among them as in his saying " nobody conceals anything but it appears in the slip of his tongue and lineaments of his face" in which case he has affirmed the superiority of the mute language over the speaking one because some of the lineaments of the face can replace the speech which has been proved only in the fifties of the last century.4 - The use of the Imam has been characterized in some utterances by the Quranic oriented quotations despite the different of purposes which clearly indicates the Quranic approach , while other texts have been characterized by serving the Quran in some places to interpret some Quranic verses . He has relied in using some utterances totally on the Quran and the tradition of the Prophet (P.B.U.H) and the classical speech of the Arab such as the utterance of the "leg" . This clearly shows the linguisticauthority of the author ofNahjulBalagha.5 - The usage of the utterances of the parts of human body by the Imam has a great impact on the morphological and lexical studies for the Imam has used out of his own accord as regards some of the morphological forms and constructions. Meanwhile he has added some unknown plural forms. He has also preferred some plural grammatical views and measures in addition to giving preference to some languages and dialects of the Arabs

الشاهد القراني عند السلسيلي في كتابه شفاء العليل في ايضاح التسهيل : دراسة نحوية

اسم المؤلف: محمد حميد زامل الزيادي
اسم المشرف: عايد جدوع حنون
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: المثنى
الصفحات الاولى:

الحاكمية في فكر الامام علي (عليه السلام) : دراسة في ضوء الانساق الثقافية MAGISTRACY IN THE THOUGHT OF IMAM ALI (AS) IN THE LIGHT OF THE CULTURAL PATTERNS

اسم المؤلف: عبد الامير دلي مجباس الزيدي
اسم المشرف: وليد شاكر نعاس الرفاعي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: الادب
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: المثنى
الصفحات الاولى:
المستخلص: MAGISTRACY IN THE THOUGHT OF IMAM ALI (AS)Praise be to Allah, the Lord of the worlds, and peace and blessings be upon the master of the messengers and his purified progeny and companions .Magistracy or assuming power has been one of the topics that attracted the attention of man throughout ages and it has been the focus of his thought and most engaging concern because of what this issue has been characterizedwith as regards its being the source of the misery or welfar and happiness of the society ; hence it has been realistic and a living matter or affair which is inevitable and unavoidable. Chapter two is entitled "manifestations of the magistrate" in which the researcher dealt with, in a critical study, important issues in the Islamic history such as allegiance in addition to practicing the magistrate by Imam Ali(AS) and those who preceded him as well as those who came after him.Chapter three carries the title ' patterns of conformity and differences" in which the researcher dealt with the extent of the conformity of the magistrate practices with the Islamic revivalistic constructive project within the historical, patrimonial and juristic patterns of Imam Ali (AS) and other rulers.A conclusion has been annexed to the research in which most of the findings and general and specific outlines have been included in addition to a comprehensive bibliography of sources and references.The conclusion of our prayer will be : Praise be to Allah, Lord of the Worlds! These steps have been accompanied by a series of difficulties distributed between the topic difficulty and the abundance of the scientific material which the thesis haswithin this framework.The structure of the research required that it contain(s) a preface and three chapters followed by a conclusion . The preface has been devoted to highlighting the broad concepts of magistrate and cultural criticism .The chapters have been as follows : The title of chapter one is " scope of identity" in which the researcher has dealt with the nature of the pre - Islam Arab incubator socially, religiously and economically. Later on the well - known changes took place on the Arab field after the advent of IslaDespite the difference in people's thought , religion, culture and the discrepancy of their languages, magistrate remained an obsession irking those who incline towards it and sacrifice everything to have it in his command and to sit on its throne.So it is conspicuous that the study of this topic is of great significance especially in an era or epoch which represented the first dose for that age : an age in which the flame of assuming power glowed , specifically in the thought of a man whose period of governance was full of hidden patterns or formats not yet revealed neither by history books nor ancient critical studies.In this person , practicing magistrate varied according to philanthropy, religious culture , knowledge of the basics of religion and the extent of consistency with what religious law2 and custom through the prophet Muhammad (peace be upon him and his purified progeny).

اناشيد الطفولة في الـعراق1880م - 1940م : دراسة موضوعية فنية Children's Songs in Iraq 1880 - 1940 A.D An objective and artistic study

اسم المؤلف: حسيـــــن عطيـة علوان الس لطاني
اسم المشرف: علي هاشم طلاب الزيرجاوي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: المثنى
الصفحات الاولى:
المستخلص: The poetic texts that came smooth - spoken out of the mouths of children's song poets to be poured in the ears of our dear children are verily worth of studying and contemplation to explore the contents which they followed in order to nurture our young generations who are considered the basic edifice for each society in terms of spiritual nurturing and a good mentality promoting their thought when young and aiding them in old age.As a result of feeling of the importance of these children's songs for the child's taste and for winning his desire and care, the researcher opted that the topic of the thesis will be (Children's Poetry in Iraq) . But after a discussion with the supervisors and for objective reasons , it has been agreed to have the topic as (Children's Songs in Iraq : an objective and artistic study) which is a part of Children's poetry so that we could shed light on children's songs in Iraq from 1880 - 1940.,to show Iraqi people and the whole nation ,about the pure poets and religious men and feeding parents and linguistics and a group of famous Iraqi poets, for their efforts in poetry concerning national ,religious moral and scientific for new generation and giving high patron ship and pure for proud hearing and know the methods they use for targeted direction .The reason behind our stop for the year 1940 A.D is that; we shoud identify the beginning because it was unknown ,since there were no preceding theses to determind this period,to start from where it had finished,after we had deeply discussed in this thesis ,we should stop in the limit of the aspects which should be very clear,this was because this thesis is the only one in Iraq which is specialized in children's songs,and we put a beginning in the year 1880 A.D,when we calculate sources that fit the requirements for the thesis up to the year 1940 A.D,we stop to the overcoming of the different aspects , because past sixty years enriched the thesis and covered all what we need,if add other information ,there is a need for another thesis, because of the big efforts which were neglected and not studied.There are several reasons make us choose this title ,thus we seek all narrating works written concerning children's songs before weapply for postgraduate study this was the first.Secondly the necessity of revealing and showing in different theses in Iraqi and Arab universities,to know the names of those poets and their efforts in this modern literature which was mentioned previously throughout this thesisThirdly ;knowing their writings and distributions in this literature and their participation with others in editing poetic groups relating to children's songs and their efforts in this fieldFourthly ,attaching senior of the Iraqi children's poets and their verse ,they passes through this verse simply not deeply.in such that one of the famous Egyptian researchers in children's literature (Dr Ahmed Zalad ) could not distinguish the senior between (Al rusafi and Mustafa Jawad) in his thesis in children's literature)( origins, concept ,pioneers)168Fifthly ;necessity of knowing the figures of speech which Iraqi children's poets had deeply discussed and how they make benefit from these styles to serve the new generation and the effort done by each one sixth;Sheding light on the methods of using story , poetic play ,myth ,symbol..as could we get away and would they study these things in their verse during their beginning.Seventh;determine the poetic pioneering for each group pf poets and know the most important artistic criteria Eighth;Explaing the ambiguity for many researchers and university theses and distinguishing between poetry . As such, the thesis has been assigned a preface in which we have studied songsidiomatically and conventionally as well as their roots in Arabic poetry . We have traced the origination in classical Arabic poetry and the development in modern Arabic poetry, and we have discussed the viewpoints of both Iraqi and Arab scholars. We have also uncovered many views that have no tangible reality.Chapter one has been devoted to the origination of children's songs in Iraq and their development in Ottoman and British rule and upon the formation of the Iraqi state till the actual formation down to 1940.Chapter two is about the vision or objective goals where we have studied the enthusiastic, sentimental,educational,sociable,psychological and entertaining goals.Chapter three has been devoted to the technical study in which we dealt with the language of the songs, their forms and music. We have presented a detailed study regarding the musical leadership of the Iraqi poets of children's songs supporting our argument with poetic texts.The research has arrived at the following findings : 1. The people of Iraq being scholars, poets, men of letters and educators had for each of them an initiative and a minaret in the fields of poetry, literature, science, language and art in general. We havenot been motivated to assert this out of prejudice and partiality , rather we have been impressed by the facts of achievement. It has become, therefore, clear for us that they had the leadership in the children's song throughout the whole Arab world and for eighteen good years.2. The efforts of men of religion, linguists , great poets , judges and educators have been exerted to find poetry that was fit for children nurturing their tastes without exhausting them in its reading or its being hard for understanding . All this was around the last quarter of the 19th century A.D.3. Those noble prominent people forced their way to find very short , original and newly - used meters . They were preceded by none to such an extent that their poetic and musical leadership became the model for coming generations and the pole molar around which the songs evolved.4. The first category of the first generation was less varied in topics because it stressed the national, religious and moral aspect while the second category came to complete what the first overlooked. Then the second and third generations came and so on and so forth. They were more open - minded to all constructive topics , contents and noble sublime purposes.5. It has been manifested that more than twenty two works in forms of a single collection of poetry or joint collections have contained more than one hundred and fifty songs . A quarter of this effort has not been achieved by the whole Arab world even after its publication in the Arab journals and papers.6. Great linguists such as Mustafa Jawad and Islamic historians such as Mahmood Al - Mallah and Sheikh Qassim Al - Sha'ar have joined hands with great poets such as Ar - Russafi and the philosopher Az - Zahawi to produce this innovated poetry . This renders invalid the claim that children's poetry attracted only the weak and incapable poets. Rather, the converse was true.7. Reclining on some objective visions (goals) such as the enthusiastic vision in its being the love of homeland was one of the findings in the research. This also includedfeeling proud of self - esteem and the political life in Iraq and urging the people to resist colonialism.8. As far as poetic language is concerned, they laid emphasis in their poetry on war utterances which won the first place . As for the utterances of glory and pride , the word glory has been mentioned eleven times and pride eight times while other words were mentioned in less frequency.9. The poetic images for those pioneers were carefully selected in special spiritand scientifically so that it could be at the disposal of the child's taste. The poets were found to be acquainted with all forms of rhetoric devices.10. As regards the external music, the acatalectic ramalmeteroccupied the first rank followed by the acatalectic rajazandkamilrespectively,while other meters followed them. The rhymes had also similar presencewhere the nun rhyme won the first place.11. For internal music , the alliteration won the first place followed by the repetition.12. As for the methodology ( trends), they touched upon it in a transparent way. They aimed at the deliberate use of educational, social and psychological matters.13. It has become manifest that the vision of the ancient classical poet was different from the modern one according to the environment and culture for each age . The ancient poet wrote for his child while the modern poet looked at the child asan independent entity with capabilities and desires14. Accordingly and as Dr. Omar Ahmed Al - Talib has proved as regards the child's theatre and what the research has proved, the last quarter of the 19th century and specifically the year1880 was the real birth of children's literature in Iraq and the Arab homeland in general under the leadership of Iraqi children's song poets

الاتساق النصي في السور القرانية المستهلة باسلوبي الشرط او القسم

اسم المؤلف: جبران شاطي معلك الهلالي
اسم المشرف: صاحب منشد عباس الزيادي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: المثنى
الصفحات الاولى:
المستخلص: The subject of search is (The Cohesion textuality in the surahs of the Holy Quran initiated by condition or section), and the Cohesion is the sound, lexical, and grammatical relationships and tools that appear on the the text and link the parts and unite their meaning, and is one of the seven criteria set by the Robert de - Beugrand and Dressler which supposed the text to text, and these criteria result from the modern linguistic studies in the 1980s, to bypass sentence and starting to text in linguistic analysis.The choice was some verses of the Quran, the most informed text in existence, are the verses of Quran that starts in two styles condition or section; because these verses starts with tool of cohesion tools, linking two sentences or phrases for each other.The nature of the research required to have three chapters : first chapter (Sound cohesion), and discussing four are : Quranic comma, and paronomasia, syllable parallelism, and intonation, and second chapter (Lexical cohesion), and discussing two : recurrence and the lexical accompaniments, and third chapter (Grammatical cohesion), and It is in three are : reference, ellipsis, and Conjonction. and prior to the introduction, which showed the concepts text and cohesion, and then moved to establish cohesion in some arab heritage, books and followed by a conclusion stating the most important results are : 1 - back to the Finder differencein ratios that means cohesion of precious surahs sample study, reference types, intonation, conjunetion, and tying anniversary, Quranic comma, ellipsis, and Conjonction by condition or section, the contrast, the most visible. and the examples syllable parallelism, and some kinds of paronomasia and recurrence and lexical accompaniments less than its predecessors. While scarce or no examples of antagonism recurrence, and lexical substitution.2 - Meet precious surahs texts - in often - cohesion sound tools and lexicography and grammatical, and more what unified tools consistency per the Quranic comma as a Union, and paronomasia, syllable parallelism, and intonation for example; if anything it shows deliberate expression of the Qur'an in the selection and choice of its text, which gives it high strength in cohesion, make the receiver felt by simply receiving the text.3 - Most precious surahs studied surahs makiah are more verses with limited, and to intensify the idea, and concise wording, and this required purpose which addressed this surahs, it means to confirm the oneness of Allaah, and prove the fact gathering and calculation, reward and punishment, and other things related to the origins of the faith, not the need for redundancy and detail; the Parties means consistency closer together, if not in a single verse in the verses or verses are contiguous; And convergence that makes them more coherence and interdependence, and more reveal the purpose of this surahs.4 - Tools for grammar and coherence means more control and most of the sound and lexical tools, and make sure the reference that more elements of coherence in surahs, especially conscientious, the researcher can hardly find any or devoid of conscience, or the name of the signal, or compare, or the demonstrative pronoun, and this was in all its manifestations : endophora, exophora, anaphora, cataphora, walbadet, tribal, close and distant, in varying proportions.5 - the study proved that the exophora reference transmitting the assignor to the assignee beyond text can lead to cohesion, but provided that the receiver, its cultural inventory, and with the help of the place of revelation, and the circumstances and surroundings, functioning, and so on, to determine this element through which explains the assignor, if this condition exposed the veil which was passing the assignor and consistent text, until the assignee assignor thumb removal cohesion and in difference to what some scholars of this type does not work on text, increased casting so they may be more effective in creating other types of texts to achieve a standard of harmony and the standing, as well as cohesion

الجهود النحوية للدكتور محمود احمد نحلة Dr. Mahmood Ahmed Nahla's Grammatical Efforts

اسم المؤلف: عبير خزعل خلف هلال
اسم المشرف: عبد الرسول سلمان ابراهيم الزيدي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:

كتاب تحفة القادم لابن الابار الاندلسي ت 856 هـ : دراسة في نهجه وجماليات الاختيار Ibn Elabbar Alandalusi's (D. 658 H) Tohfat Elqadim : A Study in Approach and Aesthetics of Choice

اسم المؤلف: محمد طه جواد ياسين الساعدي
اسم المشرف: وسن عبد المنعم ياسين الزبيدي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: The present thesis deals with a significant topic in Arabic thought, that is, Choice, especially poetic one. Since choice is an act of the choosing self in its interaction with texts, thus this recipient personality will have the status it deserves in the history of Arabic literature, paying due attention to the reading and critical efforts it will perform on these texts, then choosing according to reasons related to the intellectual, artistic and aesthetic values reflected by these texts. In my study I have chosen one of the Andalusian poetic choices books to study it and to find out its secrets, norms and approach so as to gain the academic benefits in this field of study. Due to the nature of the study, it is divided into four chapters, preceded by a preface and followed by a conclusion and a list of sources and references. The preface is entitled "The Book and Motives behind Writing it". It focused on the book under study, the reason behind its title, motives of writing it, the most important sources it relied on, and its literary value. Chapter one, which is entitled "Ibn Elabbar's Approach in His Tohfat Elqadim", concentrated on the writer's approach in his book in two sections; the first dealt with his method concerning poets' biographies, while the second dealt with his method in his poetic choices. The second chapter "Critical Criteria of Choice", shed light on forming some of the norms and criteria thought to be delineated by Ibn Elabbar in his choices; they are critical, time, environmental, and moral norms.The third chapter is allocated to the study of "Poetic Music in the Choices" which is the chapter's title. It falls into two sections; the first dealt with external rhythm, while the second with internal rhythm. Chapter four is entitled "Poetic Image inthe Choices". It comprised three sections; the first dealt with

الـمـباحث اللغـــوية والنحـــوية في كــتاب (صـــرف العــنان الى قـراءة حفص بن سليمان) لـلشـيـخ عبـد الـغـني بـن اسـماعـيل الـنابـلـسـي (ت1143هـ) The Linguistic and Grammatical Topics in Sarf El - Enan to the Reading of Hafs Bin Suleiman

اسم المؤلف: هبة فائق فاضل الدليمي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة - النحو
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: It is acknowledged that the science of Quran readings is highly related to Phonology, morphology and grammar. Thus we are in great need of a book which deals with a reading of the Holy Quran in the light of linguistics and grammar. Hence, the book Sarf El - Enan to the Reading of Hafs Bin Suleiman is of the significant books that tackled Quran readings in the light of linguistic and syntactic studies. Therefore, I have chosen this book, which was first edited in 1426 H, 2005 A.D in Libya, to be the topic of my study.Moreover, I have selected the linguistic and grammatical topics in this book to be the core of my study to figure out the role of Sheikh Elnabulsi's influence on the linguistic and grammatical lessons. Due to the nature of the study, it is divided into three chapters, preceded by a preface. - In the preface, I have dealt with the life of Sheikh Elnabulsi and his methodology in Sarf El - Enan. - Chapter one, which is entitled "Phonological Topics", is subdivided into six sections; phonological terms, assimilation, spur, strong and weak forms, euphuism and attenuation, other phonological issues. - The second chapter "Morphological Topics" is subdivided into four sections; morphological terms, noun issues, verb issues, and morphological balance. - Chapter three, "Grammatical Topics", is in six sections; grammatical terms, nominative, accusative, present verb declension, particles, and complements. Furthermore, all these chapters were preceded by an introduction that is allotted to the significance of topic, reasons behind choosing it, divisions and methodology. The study ended with a conclusion which summed up the findings of the study, followed by references and works cited

المباحث النحوية في كتاب (المستقل بالمفهومية في حل الفاظ الجرومية) لشمس الدين الراعي ت 853 هـ The Grammatical Topics in Elmustaqel Bilmafhomia fi Hal Alfadh Eljoromia by Imam Shamseddin Elraai's (D.853 H)

اسم المؤلف: لقاء خضير محمد خميس السعيدي
اسم المشرف: محمد علي غناوي هاني الحمداني
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة - النحو
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: Elajromia by Ibn Ajroom (723 H) has raised scholars' attention past and present, thus, a variety of them explicated it to leave a huge body of explanations to this book. I have chosen one of those explications which is done by a scholar who lived in the ninth hijri century who is the outstanding grammarian, scholar and Imam known as Elraai (853 H0 from Andalusia. This book was first anthologized in 1433 H., 2012 A.D. moreover, I have selected the syntactic sections in the book to be the topic of my study in order to figure out the influence of Imam Elraai on syntactic lesson as well as to specify his status among scholars of Arabic.Due to the methodology of the study, it was divided into two chapters, preceded by a preface. The preface dealt with the biography of Imam shamseddin Elraai. The first chapter which is entitled "Imam Shamseddin's Methodology in His Explication and GrammaticalPrinciples and Terms in it" is subdivided into three sections. The first "Imam Shamseddin's Methodology in His Book" is in two items; item one is methodology of exposition and publication, the second is his linguistic and syntactic sources and his approach in benefiting from them. Section two "Fundamentals of Grammar and Evidence of Craftsmanship" comprised four items; listening, analogy, syntactic cause, and agreement.The third section "Grammatical Terms in the Book" is in four items; Basrah Terms, Kufa Terms, Reciprocal Terms, and Rarely used Terms.Chapter two, which is entitled "Syntactic Sections in the Book" falls into three sections. The first of them "Syntactic Introductions" is in three items; speech and what comprises it, structure, and the definite and indefinite. The second section "Syntactic Structures" comprised two items; nominal structure and its supplant, verbal structure and its apocopation and accusatives. Section three "Sentence complements" is in four items; accusatives, genitive, complements, and approaches. All these chapters were preceded by an introduction that is dealing with the significance of the topic, reason of choosing it, divisions and methodology, and followed by a conclusion summing the findings of the study and then by a list of sources and references.

الموضوعات النحوية في كتاب دليل الفالحين لطرق لمحمد بن علان الصديقي المتوفى (1057هـ)

اسم المؤلف: رابـعة حســين مهـدي الحمدانـي
اسم المشرف: مكي نومان مظلوم الدليمي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة - النحو
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:

المباحث الصوتية والصرفية في كتاب (التتمة في التصريف) لابن القبيصي The Phonetic And morphological Researches In (Al - Tattema Fi Al - Tasreef) of Ibn Al Qubaisi

اسم المؤلف: نمارق هاشم وهيب حسين القيسي
اسم المشرف: علاء حسين علي الخالدي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة - النحو
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: This book (Al - Tattema fi Al - Tasareef) was written by Abo Abdullah Muhammed Bin who lived in Qubaisa ,a village in the east of Mousil, in610H.And reviewd by Dr.Muhsin Bin Salim Al - Himiary in 1993AM - 1414A H.I selected the phonetic and morphological researches in this book to investigate it's affect in the linguitic study .This thesis was divided into four chapters preceded by a priliminary which handled the life of Ibn Al - Qubaisi.Chapter one which is entitled as(The Method of Ibn Al - Qubaisi In His Book ) is diveded into two sections : the first handled : 1) The Method Of Presentation And Compilation, 2)His Linguistic And Grammatical Sources and 3) His Method Of Getting Benefit Out Of It.And section two is entitled as (Principles of Gramar And Evidences of Composition) which discussed : 1)Hearing,2)Measuring and 3)Justification.(The Phonetic And Grammatical Terms In This Book) is the title of Chapter two which discussed the phonetic terms in it's first section and the grammatical terms in it's second section.Chapter three is entitled as (The Phonetic researches In The Book) and is divided into three sections : the first is(The Place of Articulation of Sounds), the second (The Charecteristics of Sounds) , andthe third(The Phonetic Phenomena) like Assimilation and Deflection .Chapter four (The Grammatical Researches In The Book) discusesed three topics : the first dealt with (The construction of Nouns And Verbs), the second with(The Grammatical Phenomena of Displacement,Elision and Metathesis), and the third with(The Infinitives And The Derivatives). In the introduction of this work, I talked about The importance of this subject and the reasons behind choosing it, it's method and chapters. This study was ended up with a list of conclusions and a bibliography of the books consulted to accomplish this work

المباحث الصرفية والنحوية في كتاب شرح المغني في النحو لبدر الدين الميلاني ت 811هـ Morphological and Syntactic Investigations In The Book of Sharih Al - Mughani By Badar Al - Deen Al - Milani (D 811 H)

اسم المؤلف: علي حسين مهدي
اسم المشرف: محمد علي غناوي هاني الحمداني
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: The title of my thesis is Morphological and Syntactic Investigations In The Book Of Sharih Al - Mughani By Badar Al - Deen Al - Milani (D 811 H). Al - Milani was Badar Al - Deen Mohammed Ibn Abd - Alrheem Al - Milani Al - Omari who died in (811 H) .The aim of choosing this topic was to present the explainer's effect in Arabic language . Therefore the nature of the research entailed to divide the study into four chapters preceded by an introduction and followed by the end . Consequently, I divided the introduction into two parts : In the first part I dealt with Al - Milani's biography including his life , surname, scholars (sheikhs) , literary works and their explanations. Then there was a general description of the studied book. I explained in the second part his approach in the book , his linguistic and syntactic references and his method of making use of them.I dealt with the rules of syntax and the evidence of syntactic craft used by Al - Milani in the first chapter that included five sections : the first : Al - samah, the second : measurement, the third : plurality , the fourth : the adverbs of manner , and the fifth : reasoning .Whereas in the second chapter , I dealt with the morphological and syntactic terminology in Al - Milani's book and this chapter had two sections : The first section was about the morphological terminology and I divided it into three parts : The first part included the terminology concerned nouns, while the second part was concentrated on the terminology of verbs and the third one was about terminology of prepositions.The second section concerned with the syntactic terminology and it was divided into four parts : Al - Basria terminology , Al - Kufia terminology, common terminology , Al - Milani's specialized terminology used in his explanation.In the third chapter, I dealt with the morphological investigations in explanation and this chapter had five sections. The first : appositive and reasoning , the second : minimizing , the third : plurality , the fourth : masculine and feminine , and the fifth : Al - Nasab .The fourth chapter was concentrated on explaining the syntactic investigations in the explanation and it included six sections : The first : syntactic introductions , the second : the nominal and verbal compound , the third : accusatives , the fourth : genitives, the fifth : Al - twabaa (sequences) , and the sixth : styles .

ظاهرة الاعراب في تفسير البحر المحيط

اسم المؤلف: نهاد محمد علي
اسم المشرف: مازن عبد الرسول سلمان
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:

المطولات الشعرية في الخطاب النقدي العراق الحديث

اسم المؤلف: محمد سلمان حسين
اسم المشرف: علي متعب جاسم
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:

الخبر المروي في الشعر الجاهلي انماطه ووظائفه Anecdote Irrigated in pre - Islamic poetry Types and Functions An Artistic Study

اسم المؤلف: غزوان طه لطيف جاسم
اسم المشرف: خليل ابراهيم عبد الوهاب
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: اللغة
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: ديالى
الصفحات الاولى:
المستخلص: This thesis is concerned with a literary form named as “Al - Khabar” which means in, Arabic heritage, “Anecdote” or “Tale”. Anecdote is a transmitted form, narrating people’s actions, deeds and situations, in both poetic and prosaic styles. Anecdote occupies a great stature in ancient Arabic literature.The field of this study is “Anecdote in Pre - Islamic Poetry”,in three chapters preceded by a preface and introduction. The introduction is dedicated to handle two issues, the first is the meanings of “Al - Khabar” in Arabic dictionaries and terminology, while the second is about “Al - Khabar” status between orality and inscription. The first chapter is devoted to study “Al - Khabar - Anecdote” paradigms, in four sections : Section one : Fictional Anecdote.Section two : Factual Anecdote.Section three : Fantastic Anecdote.Section four : Historical Anecdote. The second chapter is dedicated to study functions of “Al - Khabar - Anecdote”, in three sections : Section one : Documentary Function.Section two : Social Function.Section three : Psychological Function. The third chapter is assigned to deal with “Al - Khabar - Anecdote” image within structures of poetical themes, in two secions : Section one : Themes related to “Self”.Section two : Themes related to “Other”. The thesis has come up to a conclusion summarizing the final academic results.

شعر ابي دهبل الجمحي : دراسة جمالية Poetey Abe Dahbl Al - jamhi An aesthetic Study

اسم المؤلف: علي محسن حسين المعموري
اسم المشرف: هناء جواد عبد السادة العيساوي
الموضوع العام: اللغة العربية وادابها
السنة: 2015
الموضوع الدقيق: الادب
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بابل
الصفحات الاولى:
المستخلص: The attempt to search and detect the product of the poet and knowledge purposes is very important, because he is a poet crystallized in the period in which popularized a lot of poets, namely the Umayyad period, as it is well - known poets of the Quraysh five. His hair has endured a lot of aesthetic values of all kinds, whether moral, religious or political, so that was the product of a track those values. Since the subject of aesthetic values of an overall theme and laws inclusive can not be confined to a particular aspect or particular rules, but that there is a definition of findings can be placed under the title is ((everything beautiful desirable)) or in other words ((all that is desirable from perfect) ) on this aesthetic values are a set of values refers to the common cultural rations are the assessment of needs and desires. Or with respect to the approach it has adopted a curriculum based on the semiotic theory Qremas applied by some models of the poetry, and it was applied in two aspects of the theory are : Besides global form when Qremas circumscriptum (the sender and the addressee and the actor and the subject and helper and exhibitions). The second aspect of the credibility that box Yum detected by the health and whether or not to say.The message included the preparation it addressed dealt with the concept of aesthetic value in the language and terminology and philosophy. As well as the life of the poet Abu Dhbl Jamhi it dealt with all that it involves, from his birth to his death.The first chapter dealt with it : what the beauty and the beauty of nature, both silent and moving each one of them divided into several types.And dealt with in the second section of the human beauty, dividing into two parts.The message included the preparation it addressed dealt with the concept of aesthetic value in the language and terminology and philosophy. As well as the life of the poet Abu Dhbl Jamhi it dealt with all that it involves, from his birth to his death.The first chapter dealt with it : what the beauty and the beauty of nature, both silent and moving each one of them divided into several types.And dealt with in the second section of the human beauty, dividing into two parts. Aesthetics internal rhythm of the bell music and redundancy in all its types in terms of repeating letters and words and tools. The second topic dealt with the external aesthetics of rhythm and rhyme of weight. The third section handled semiotic study of the subject.Researcher have come to a set of conclusions : that looking at the beauty of a woman made the poet looks at her most than it is to see it> Separating control parts of the body one by one and laid down in a plate full of poetry dimensional. The fight poet in a political subject of religious In an era dominated by the bloodshed made it highlights in its aesthetic value of self - suggestive to his courage and Frosath. The beauty and aesthetic value science and broad and complex and confined to literary side gave valuable results, including the associated reason and moral aspects of them, including the associated self - perfection

تحضير مركبات حلقية غير متجانسة جديدة مشتقة من حامض السيناميك ودراسة الفعالية البايولوجية Synthesis of New Heterocyclic Compounds Derived from cinnamic acid and evaluation their of biological activity

اسم المؤلف: مؤيد عبود كبان
اسم المشرف: عبد الجبار خلف عطية محمد فرج شذر المرجاني
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء العضوية
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: يتضمن البحث تحضير ثلاثة وخمسين مشتق جديد من حامض السيناميك . تم تحضير المركب (C1) من خلال تفاعل حامض السيناميك مع كلوريد الثايونيل . حضر مشتق الهيدرازايد (C2) من تفاعل3 - Chlorobenzo[b]thiophene - 2 - carbonyl chloride (C1) مع الهيدرازين المائي . مركب C2) ) يمر بتفاعل تكاثف مع الديهيدات اروماتية مختلفة(4 - nitrobenzaldehyde , 4 - N,N - dimethylaminobenzaldehyde , 4 - bromobenzaldehyde , 3 - bromobenzaldehyde , 3 - chlorobenzaldehyde ) في الايثانول المطلق ينتج قواعد شيف (3 - chloro - N' - (Arylidene)benzo[b]thiophene - 2 - carbohy - drazide) ((C3 - C7 .عند معاملة فنيل حامض الخليك المذاب في ثلاثي اثيل امين مع الايمين بوجود كلوريد الثايونيل ليتكون البيتالاكتام المناسب ((N - (Aryl) - 4 - oxo - 3 - phenylazetidin - 1 - yl) - 3 - chlorobenzo[b]thiophene - 2 - carboxamide)) (C8 (C12 - . تفاعل المركب (C1) مع الكلايسين بوجود هيدروكسيد الصوديوم اعطى (2 - (3 - chlorobenzo[b]thiophene - 2 - carboxamido) acetic acid) (C13).مشتق الاوكسازول حضر تفاعل (C13) مع الديهيدات اروماتية مختلفة (4 - nitrobenzald - ehyde , 4 - N,N - dimethylaminobenzaldehyde , 4 - bromobenzaldehyde , 3 - bromobenzaldehyde , 3 - chlorobenzaldehyde , 2 - bromobenzaldehyde , 2 - chlorobenzaldehyde) بوجود حامض الخليك الثلجي وانهدريد الخليك اعطى (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (Arylidene)oxazol - 5(4H) - one)(C14 - C20) . مشتقات الاميدازول حضرت بواسطة تفاعل مشتقات الاوكسازول المختلفة مع الهيدرازين المائي بوجود البنزين ليعطي (1 - amino - 2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (Arylidene) - 1H - imidazol - 5(4H) - one) (C21 - C25) . مركب C21,C22) ) يمر بتفاعل تكاثف مع الديهيدات اروماتية مختلفة(4 - nitrobenzaldehyde , 4 - N,N - dimethylaminobenzaldehyde , 4 - bromobenzaldehyde) في الايثانول ينتج قواعد شيف (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (Arylidene) - 1 - (Arylidene) - 1H - imidazol - 5(4H) - one) (C26 - C29) .عند تفاعل مشتقات الايمين(C26 - C29) مع فنيل حامض الخليك بوجود ثلاثي اثيل امين وكلوريد الثايونيل ينتج مشتق اخر من البيتالاكتام (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (Arylidene) - 1 - (2 - (Aryl) - 4 - oxo - 3 - phenyla - zetidin - 1 - yl) - 1H - imidazol - 5(4H) - one) (C30 - C33) . مشتقات البيرميدين حضرت بتفاعل (C14,C16, C17, C19) مع اليوريا في ثنائي مثيل سلفوكسايد لينتج المركبات (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (Arylidene) - 1 - (2 - (Aryl) - 4 - oxo - 3 - phenylazetidin - 1 - yl) - 1H - imidazol - 5(4H) - one) (C34 - C37). كذلك المركبات (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 7 - (Aryl) - 6,7 - dihydrooxazolo [5,4 - d]pyrimidin - 5(4H) - one) (C38 - C41) حضرت عن طريق تفاعل مشتقات الاوكسازول (C14,C16, C17, C19) مع الثايويوريا في ثنائي مثيل سلفوكسايد . مشتقات البايرزول حضرت بوساطة تفاعل مشتقات الاوكسازول (C14,C16, C17, C19) مع الهيدرازين المائي بوجود حامض الخليك لينتج (4 - (5 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 2,3 - dihydro - 1H - pyrazolo[4,3 - d]oxazol - 3 - yl) - Aryl) (C42 - C45) . مشتقات الايزو اوكسازول حضرت من تفاعل مشتقات الاوكسازول (C14,C16, C17, C19)مع الهيدروكسيل امين هايدروكلوريد بوجود الايثانول ليكون (4 - (5 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 2,3 - dihydrooxazolo[4,5 - d]isoxazol - 3 - yl) - Aryl) (C46 - C49) . مشتق الاستر حضربوساطة تفاعل مشتق الاميدازول (C21) مع كلوروخلات الاثيل في الايثانول وهيدروكسيدالصوديوم ليكون (ethyl 2 - (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (4 - (dimethylamino)benzylidene) - 5 - oxo - 4,5 - dihydro - 1H - imidazol - 1 - ylamino) acetate) (C50).في حين المركب(C51) (2 - (2 - (3 - chlorobenzo [b] thiophen - 2 - yl) - 4 - (4 - (dimethylamino)benzylidene) - 5 - oxo - 4,5 - dihydro - 1H - imidazol - 1 - ylamino)acetohydrazide) حضر بوساطة تفاعل مشتق الاستر(C50) مع الهيدرازين المائي في الايثانول . المركب (C51) تفاعل مع الديهيدات اروماتية مختلفة(2 - bromobenzaldehyde , 2 - chlorobenzaldehyde) في الايثانول المطلق اعطى قواعد شيف (N' - (Arylidene) - 2 - (2 - (3 - chlorobenzo[b]thiophen - 2 - yl) - 4 - (4 - (dimethyl amino)benzylidene) - 5 - oxo - 4,5 - dihydro - 1H - imidazol - 1 - ylamino)acetohy - drazide) (C52 - C53).المركبات المحضرة شخصت بوساطة اطياف الاشعة الفوق البنفسجية وتحت الحمراء والبعض منهابالرنين النووي المغناطيسي للبروتون, تم دراسة الخواص البايولوجية لبعض المركبات المحضرة كمضادات للبكتيريا والفطريات وفحص السمية ,وبينت النتائج وجود فعالية عالية للمركبات [C9,C12,C14,C17,C18,C20,C25, C30,C31,C32] تجاة البكتريا الموجبة والسالبة صبغة كرام وتم تحديد LD50 بتركيز (1000 µg/ml) للمركب [C12] الذي اثبت فعالية ضد الفطر Trichophyton mentagrophytes داخل وخارج جسم الكائن الحي .

تقدير المواد الحافظة في بعض المستحضرات الصيدلانية باستعمال الاستخلاص بالطور الصلب Determination Of Preservative Compounds In Some Pharmaceutical Preparations Using Solid Phase Extraction

اسم المؤلف: محمد هادي صنكور
اسم المشرف: سلام عباس حسن العامري
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: استخدمت طريقة الاستخلاص بالطور الصلب باستعمال الراتنجات الشبكية العيانية Amberlite XAD - 8 والراتنج Amberlite XAD - 2 لتقدير اربع من المركبات الفينولية المستعملة كمواد حافظة في بعض المستحضرات الصيدلانية. تم دراسة الظروف الفضلى للطريقة المقترحة من خلال دراسة متغيرات الدالة الحامضية وزمن الاستخلاص ونوع المذيب الافضل لعملية الابتزاز واظهرت النتائج ان الظروف الفضلى للامتزاز او للاستخلاص تتمثل في دالة حامضية تساوي 3, وفي زمن استخلاص مقداره 15 دقيقة مع استخدام الاسيتوناترايل كافضل مذيب لاسترجاع وابتزاز هذه المركبات الفينولية الحافظة الاربع من الراتنجات مقارنة بالمذيبات الاخرى وعند زمن توازن مقداره 15 دقيقة. تم اجراء حسابات قيم معامل التوزيع (kd) وبطريقة الدفعات لمعرفة سلوك وامكانية الراتنجات الشبكية العيانية Amberlite XAD - 8 وAmberlite XAD - 2 لانجاز كل من عملية الامتزاز والابتزاز للمواد الفينولية الحافظة الاربع. اظهرت النتائج كفاءة وسرعة عالية لاستخلاص وامتزاز المواد الفينولية الحافظة من لدن الراتنجات الشبكية العيانية Amberlite XAD - 8 وAmberlite XAD - 2 مع وجود افضلية بسيطة للراتنج Amberlite XAD - 8 مقارنة مع الراتنج الاخر. لايجاد ولدراسة الدقة والضبط للطريقة قيد الدراسة تم تحضير 5 عينات تخليقية مختبرية لكل من مثيل بارابين والميتا كريسول بتركيز 20 ملغم.لتر - 1 , واظهرت نتائج تحليل العينات المختبرية وفق الطريقة المقترحة وجود معدل خطا مطلق ضمن مدى - 0.28 الى - 0.5 , ومعدل خطا نسبي مئوي ضمن مدى - 1.4 الى - 2.5 % واعطت النتائج انحراف معياري مقداره 0.0591 وانحراف معياري نسبي مئوي لايزيد عن 0.506%. تم تطبيق الطريقة المقترحة على بعض المستحضرات الصيدلانية التجارية للتحقق من تركيز المواد الحافظة فيها لضمان سلامة المنتج اولا بوجود هذه المواد والتحقق من وجودة ضمن مدى التركيز الذي لايؤثر على صحة المرضى, حيث تم تقدير المثيل بارابين في دواء ليدوكائين واظهرت النتائج ان تركيز المثيل باربين في الدواء ضمن مدى 977 - 985 ملغم.لتر - 1 وهو اقل قليلا من التركيز المثبت في المحتوى الاصلي للمنتج, وكذلك تم تقدير الميتا كريسول في حقن الانسولين واظهرت النتائج ان تركيز الميتا كريسول في المستحضر الدوائي ضمن مدى 2415 - 2535 ملغم.لتر - 1 وهو متوافق مع التركيز المثبت في المنتتج الاصلي. | Solid - phase extraction method using Amberlite XAD - 8 and Amberlite XAD - 2 resins is used to estimate of phenolic compounds as preservatives in some pharmaceutical preparations.To find the optimal conditions of the proposed method, several parameters and variables was studied, including; pH or acidic function, time of extraction and type of elution solvent . The results show that the optimum conditions of adsorption or extraction at pH equal to 3, at 15 minutes equilibrium time, and acetonitrile was the greatest solvent for elution or stripping these compounds from the resins compared with other solvent at equilibration time not exceed 15 minutes too. Distribution Coefficient values (kd) was applied to estimate and study the behavior and efficiency of the macroscopic resins Amberlite XAD - 8 and Amberlite XAD - 2 to the process of adsorption and desorption phenolic preservatives. The results showed high efficiency and speed of extraction and adsorption of phenolic preservatives by macroscopic resin Amberlite XAD - 8 and Amberlite XAD - 2 with a simple advantage for resin Amberlite XAD - 8. To find the accuracy and precision of the proposed method , five synthetic laboratory samples were prepared for each of the methyl paraben and meta - cresol, the results of the samples analysis in accordance with the proposed method showed that the existence of absolute error rate within the range of - 0.28 to - 0.5, and the rate of relative error percentage within the range of - 1.4 to - 2.5% .The results gave a standard deviation of 0.0591 and a standard deviation relative percentage of no more than 0.506%.The proposed method was applied on some pharmaceuticals samples to estimate and confirm the actual concentration of preservative concentration to remain this product active and did not cause any problem for patients. The actual concentration of methyl paraben in lidocaine drug found to be in the range (977 - 985) mg.L - 1 which is negligible less than that the amount installed in the original product. While the meta - cresol concentration in insulin preparation was found to be in the range (2415 - 2535) (977 - 985) mg.L - 1 which is actually equal to the amount of meta - cresol in the original product.

تحضير وتشخيص مركبات حلقية غير متجانسة جديدة مشتقة من 4 (H3) كوينازولينون Synthesis and Characterization of heterocyclic compounds derivative from the new 4(3H) quinazolinone

اسم المؤلف: لبنى حازم نصيف جاسم
اسم المشرف: فريال ولي عسكر
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تعد مشتقات ( كوينازولين ) من المشتقات المهمة من الناحية البايولوجية والصناعية لذلك تم التوسع في الدراسات التخليقية لمشتقاتها فقد تضمن هذا البحث تحضير اربع واربعين مركبا جديدا , تحتوي على حلقات غير متجانسة بطرائق متعددة كما موضح في المخططات (1 - 5) وقد تمت دراستها وتشخيصها بوساطة اطياف الاشعة تحت الحمراء ( FT - IR ) واطياف الاشعة فوق البنفسجية ( UV ) والبعض منها عن طريق اطياف الرنين النووي المغناطيسي (1H - NMR ) واطياف الكتلة (GC - Mass) وتحديد الخواص الفيزيائية مثل درجة الانصهار واللون . ويمكن اجمال ما جاء في البحث : 1) تحضيرالمركب الاساس (2 - (4 - methoxyphenyl) - 4H - benzo[d][1,3]oxazin - 4 - one) - (L) باجراء الغلق الحلقي لمركب (antharanilic acid) مع ( p - Methoxy benzoyl chloride) بوجود البيريدين . 2) تحضير اربعة مشتقات (L26,L16,L9,L1) لمشتق الكوينازولين (L) بتفاعل امينات اولية مختلفة ( 4 - Aminoacetophenone وEthyl 4 - aminobenzoate و1,4 - Phenylene diamineو Ethylenediamine) مع المركب ( L ) على التوالي .3) تحضير ثلاثة مشتقات جديدة للجالكون (L4,L3,L2) عن طريق تفاعل المركب (L1) مع الالديهايدات الاروماتية المختلفة وبوجود هيروكسيد الصوديوم .4) تحضير مشتقات جديدة تتضمن الغلق الحلقي للجالكون (L4,L3,L2) مع اليوريا ، ثايويوريا ، المالونترايل والهيدروكسيل امين هايدروكلورايد وبظروف مختلفة من العوامل المساعدة والدالة الحامضية للحصول على المركبات ( L6, L5, L7,L8). 5) تحضير مشتقين جديدين للكوينازولين عن طريق تفاعل (L9) مع الثايوسيميكاربازايد (thiosemicarbazide) والهيدرازين المائي (Hydrazinehydrate80%) ((L11,L10على التوالي .6) تحضير مشتقات جديدة من قواعد شيف (L13 , L12) من خلال مفاعلة المركبات (L11,L10) مع الالديهايدات الاروماتية (4 - dimethylamino)benzaldehyde nitrobenzaldehyde - 3 ) .7) .8) تحضير مشتق الثايوزولدينون (4L1) من تفاعل قاعدة شيف ((L13 مع مركبتو حامض الخليك (Mercpto aceticacid) .9) تحضير مشتق الترايازول (L15) ، عن طريق تفاعل المركب الاساس (L) مع سيميكاربازايد (Semicarbazide) في البيريدين كمذيب.10) تحضير قواعد شيف (L18 , L17) ،من تكاثف المركب (L16) مع الالديهايدات الاروماتية المختلفة ثم مفاعلة قواعد شف (L18 , L17) مع كلورو استايل كلورايد بوجود تراي اثيل امين ، ليعطي مركبات البيتا لاكتام(L20 , L19 ) . ومفاعلة ( L18) مع مركبتو حامض الخليك ليعطي مشتق الثايازولدينون ((L21.11) تحضير مشتقات جديدة تحتوي على حلقات غير متجانسة (L23 , L22) عن طريق تفاعل المركب (L16) مع مركبات الثايول mercaptobenzoxazol, - 2) mercaptobenzothiazol) - 2 .12) يتضمن اكسدة المركب (L16) بوساطة حامض النتريك وحامض الفسفوريك للحصول على ملح الدايازونيوم ، ومن ثم مفاعلة هذا المشتق مع مركب ( 2 - هيدروكسي بنزلديهايد) للحصول على مركب الازو (L24) .13) تحضير مشتق الكومارين ((L25 وذلك باجراء الغلق الحلقي لمركب الازو (L24) بمفاعلته مع اثيل اسيتو اسيتات ((Ethyl acetoacetate .14) تحضير حوامض الاميك (L28 , L27)عن طريق تفاعل المركب (L26) مع انهدريد الماليك او 4 - نايترو فثاليك .15) تحضير مشتق الثايوريا (L29) من تفاعل المركب (L26) مع فنيل ايزو ثايوسيانات Phenyl isothiocyanate)) ثم مفاعلة مشتق الثايوريا (L29) مع حامض مالونيك (malonic acid) ليعطي مشتق البيريمدين (L30) في مذيب التولوين الجاف. 16) تحضيرالمركب (2 - Mercapto - 3 - phenylquinazolin - 4(3H) - one) (31(L باجراء الغلق الحلقي لمركب (antharanilic acid) وذلك بمفاعلته مع فنيل ايزو ثايوسيانات Phenyl isothiocyanate)) باستعمال الميثانول كمذيب .17) تحضيرمشتق جديد (L32) عن طريق مفاعلة المركب (L31) مع الهيدرازين المائي (80%Hydrazine hydrate).18) تحضير المركبات (L34 , L33) وذلك عن طريق الغلق الحلقي للمركب (L32) مع انهيدريد الماليك او الفثاليك. 19) تحضير مشتقات جديدة من قواعد شيف (L36 , L35) من خلال مفاعلة المركب (L32) مع الالديهايدات الاروماتية ( , 4 - (dimethylamino)benzaldehyde bromobenzaldehyde - 4 ) .20) تحضير مشتقات اليوريا ((L39, L38, L37 من تفاعل مشتق الهيدرازيد (L32) مع 4 - كلوروفنيل ايزوثايوسيانات والفا - نافثيل ايزوسيانات وفنيل ايزو ثايوسيانات على التوالي.21) تحضير مشتق الثايوزولدينون (L40) وذلك باجراء الغلق الحلقي لمشتق الثايوريا (L39) مع كلورو اثيل اسيتات (Ethylchloroacetate) باستعمال الايثانول كمذيب.22) تحضير مشتق الاستر((L41 عن طريق تفاعل المركب (L31) مع كلورو اثيل اسيتات (Ethylchloroacetate) ثم مفاعلة مشتق الاستر (L41) مع الهيدرازين المائي (80%Hydrazine hydrate) ليعطي مشق الهيدرازيد ( (L42بوجود الايثانول كمذيب .23) تحضير مشتقين جديدين (L44 , L43) عن طريق الغلق الحلقي لمشتق الهيدرازيد ( (L42مع اثيل اسيتو اسيتات وانهدريد الفثاليك على التوالي. 24) يتضمن تقييم الفعالية البايولوجية لعشرة مركبات محضرة وهي على التوالي L20,L18,L16,L7,L5,L2,L1),L30,L25,L24) التي تمت دراستها على اربعة انواع من البكتريا هي (Staphylococcus aureus , Staphylococcus pyogenes , ,Escherichia coli aeragines (Proteus ، ونوعين من الفطريات هما Candida albicans , Aspergillus niger))، ومقارنتها مع نوعين من المضادات الحيوية ((Fluconazole ,Ampicillin. | The quinazoline core and its derivatives form an important class of compounds, as they are present in a large family of products with broad biological and industrial activities. This fact lead as to synthesis Fourty - four compounds containing heterocyclic moieties by several methods, as shown in the diagrams (1 - 5). The synthesized compounds have been characterized by some spectral analysis such as (FT - IR), (UV), (GCMS) and (1H - NMR) and determination of their physical properties such as melting points and color . This work involved : 1) Synthesis of starting material (L) (2 - (4 - methoxyphenyl) - 4H - benzo [d][1,3]oxazin - 4 - one ) by ring closer of (Anthranilic acid) with ( p - Methoxy benzoyl chloride) in pyridine as a solvent. 2) Synthesis of four new derivatives of quinazoline )L26 , L16 , L9 ,L1 (by the reaction of starting material (L) with appropriate primary amines (4 - Aminoacetophenone,Ethyl4 - aminobenzoate ,1,4 - Phenylenediamine , Ethylene diamine) respectively. 3) Synthesis of three new derivatives of chalcone (L4 ,L3 ,L2) by reaction compound (L1) with appropriable aromatic aldehydes.4) Synthesis of new derivatives includes cyclization of chalcone (L4 , L3 , L2) with urea, thio - urea, malononitrile and hydroxyl amine hydrochloride in different conditions from catalysis and pH medium to obtain compounds ( L8, L7, L6, L5).5) Synthesis of two new derivatives of quinazoline by reaction compound (L9) with (thiosemicarbazide) and (Hydrazinehydrate80%) (L11 , L10) respectively.6) Synthesis of tow derivatives of Schiff's bases (L13 , L12) by reactions of compounds (L11 , L10) with appropriable aromatic aldehydes.7) Synthesis new derivative of thiazolidinone (L14) by reactions of Schiff's base (L13( with Mercpto aceticacid .8) Synthesis of triazole derivative (L15) by the reaction of starting material (L) with semicarbazide, and pyridine as a solvent.9) Synthesis of Schiff bases (L18 , L17) from condensation of compound (L16) with different aromatic aldehydes while Schiff bases (L18 , L17) reacted with (chloro acetylchloride) in presence of triethylamine to form β - lactam compounds (L20 , L19 ) . The compound (L21) can be synthized from the reaction of (L18) with mercapto acetic acid to form thiazolidinone.10) Synthesis of new derivatives containing hetrocyclic compounds )L23 , L22( by the reaction of compound (L16) with thiol compounds (2 - mercaptobenzoxazol , 2 - mercaptobenzothiazol). 11) Includes the oxidation of compound (L16) with nitric acid and phosphoric acid to give diazonium salt with compounds (2 - hydroxy benzaldehyde) to get azo compound (L24).12) Synthesis of derivative of coumarine (L25) by ring closer of compound (L24) with ethylacetoacetate.13) Synthesis of two amic acid (L28, L27) by the reaction of compound (L26) with anhydride (4 - NitroPhthalic anhydride , Maleic anhydride(. 14) Synthesis of compound (L29) by the reaction of compound (L26) with phenyl isothiocyanate to give thiourea derivative by the reaction with (malonic acid) in dry toluene to get derivative of Pyrimidine. 15) Synthesis of starting material (Mercapto - 3 - phenylquinazolin - 4(3H) - one - 2) (L31) by ring closer of (Anthranilic acid) with (Phenyl isothiocyanate) , in methanol as a solvent. 16) Synthesis of new derivative (L32) by the reaction of compound (L31) with (Hydrazine hydrate 80%), in ethanol as a solvent .17) Synthesis of compounds (L34 , L33 ) by cyclization of compound (L32) with (maleic , phathalic anhydride).18) Synthesis of tow derivatives of Schiff's bases (L36 , L35) by reactions of compound (L32) with aromatic aldehydes (4 - (dimethylamino)benzaldehyde , 4 - bromobenzaldehyde).19) Synthesis of urea derivatives (L39, L38 ,L37) by the reaction of hydrazide derivative (L32) with (P - chloro phenyl isothiocyanate, Naphthyl isocyanate , Phenyl - isothiocyanate) respectively. 20) Synthesis of thiazolidinone derivative )L40 (by ring closer of urea derivative (L39) with Ethylchloroacetate, in ethanol as a solvent .21) Synthesis of ester derivative (L41) by the reaction of compound (L31) with Ethylchloroacetate while ester derivative (L41) with (hydrazine hydrate 80%) to get hydrazide derivative (L43), in ethanol as a solvent.22) Synthesis of two new derivatives )L44 , L43 (by cyclization of hydrazide derivative (L42) with ethylacetoacetate and phathalic anhydride respectively.23) Includes the evaluation of biological activity of ten synthesized compounds (L1,L2,L5 ,L7,L16,L18,L20,L24,L25,L30( against four types of bacteria (Staphylococcus aureus , Staphylococcus pyogenes , ,Escherichia coli, Proteus aeragines ) and against two types of fungal (Candida albicans , Aspergillus niger) and compared with two types of antibiotics (Fluconazole ,Ampicillin).

تحضير وتشخيص بعض البلورات السائله الدايمرية غير متماثلة ودراسة خصائص اطوارها الوسطيه Synthesis and Characterization of some non - symmetric Dimeric liquid crystals and study of Their mesophases properties

اسم المؤلف: عادل كريم جاسم
اسم المشرف: علي كريم عبد الحسن
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: الدايمرات البلورية السائلة غير المتماثلة هي احد اصناف المركبات البلورية السائلة التي لها تطبيقات واسعة في مجالات مختلفة كالصناعة والطب .في هذه الرسالة تم تحضير اثنان وثلاثون مركب بطرق عضوية مختلفة. شخصت جميع هذه المركبات من خلال بعض الطرق الطيفية مثل تقنية الاشعة تحت الحمراء وطيف الرنين النووي المغناطيسي للبروتون وطيف الرنين النووي المغناطيسي للكاربون كذلك تمت دراسة الخواص البلورية السائلة لهذه المركبات باستعمال المجهر ذو الضوء المستقطب ومسعر المسح التفاضلي .السلسلة الاولى من الدايمرات البلورية السائلة غير المتماثلة تمتلك الصيغة التركيبية الاتيةحضرت هذه الدايمر ابتدا من تحضيرالمركبات [A1_A7]من خلال تفاعل 4 - هيدروكسي بنزالديهايد مع بروميد الالكيل في السايكلوهكسانون ثم حضرت المركبات الجالكونية[A8_A14] من تفاعل المركبات اعلاه مع 4 - هيدروكسي اسيتوفينون في الايثانول بعد ذلك حضر المركب A15 من تفاعل 4 - هيدروكسي بنزالديهايد مع ثنائي بروميد الايثان في الاسيتون وبعدها حضرت المركبات [A16_A22] من تفاعل المركب A15مع الجالكون المحضر اما الدايمرات البلورية السائلة غير المتماثلة[A23_A29] حضرت من خلال تفاعل المركبات الناتج في الخطوة الاخيرة مع4 - اثيل انلين في الايثانول. درست الخواص البلورية السائلة للدايمرات غير المتماثلة باستخدام مجهر الضوء المستقطب ومسعر المسح التفاضلي حيث اظهرت الدايمرات البلورية السائلة غير المتماثلة اطوار بلورية سائلة متعددة عند التسخين والتبريد من النوع ( النيماتيوالسمكتي ) حيث اعطت هذه الدايمرات الطور النيماتي عند تغير مجموعة R الالكيلية من المثيل الى البنتيلبينما اعطت الطور السمكتي عندما تكونR مجموعة هكسيل وهبيتيل وهذا يدل على ان المجموعة الطرفية المعوضة توثر على نوع الاطوار البلورية السائلة واستقرارها الحراري فعند اضافة مجموعة مثلين الى اطراف الجريئة فان ذالك يؤدي الى زيادة قوى التجاذب بين جوانب الجريئة وذلك بسبب استقطابية مجاميع المثلين المضافة وانخفاض قوى التجاذب بين اطراف الجريئةحيث ان ظهور الطور السمكتي والنيماتي يعتمد على درجة الاختلاف بين نسبة قوى التجاذب الجانبية والطرفية للجريئة حيث ان لظهور الطور السمكتي لابد من وجود قوى تجاذب بين جوانب الجريئة اكبر من قوى التجاذب بين اطراف الجريئة وهذا النوع من القوى يزداد عند وجود عزم ثنائي القطب عبر المحور الطولي للجريئة وكذالك في السلاسل الالكيلية الطويلة بسبب استقطابية مجاميع المثلين. اما السلسلة الثانية التي تمتلك الصيغة التركيبية الاتيةحضرت هذه السلسلة بنفس خطوات تحضير السلسلة الاولى حيث تم في هذه السلسلة تثبيت السلسلة الطرفية R عند البنتيل وتغيير السلسلة الطرفية الثانية باستخدام الانلين المعوض في الموقع 4 بمجاميع المثيل والنايترو والبروم حيث اعطت دايمرات هذه السلسلة الطور البلوري النيماتي وهذا يعود الى ان هذه المجاميع توفر عزم ثنائي القطب على طول المحور الطولي للجريئة وفي حال امتلاك الجزيئات مجاميع لها عزم ثنائي القطب من هذا النوع سوف يحدث تنافر بين الجزيئات وذالك لتقارب الشحنات المتشابهة مما يسبب ضعف قوى التجاذب الجانبية بين جوانب الجريئة وظهور الطور النيماتي | Dimeric liquid crystal asymmetric is one of the classes of liquid crystal compounds which have wide applications in various fields such as industry and medicine.In this thesisThirty - two compounds have been synthesized by various chemical methods. All of these compounds characterized through some of the ways spectroscopic techniques such as infrared,1H and 13C - NMR.The mesophases and their corresponding transition temperatures were identified by differential scanning calorimetric measurements andpolarized optical microscope.The first series of liquid crystalline dimers asymmetric possess the following structural formulaThese dimers were prepared viasome steps involved. First, 4 - hydroxy benzaldehyde was reacted with alkyl bromide in Cyclohexanone to prepare compounds [A1_A7].Second, 4 - hydroxyl acetophenone was reacted with compounds [A1_A7] in ethanol to produce chalcone compounds [A8_A14]. Third, the compound [A15] was prepared via reacted 4 - hydroxyl benzaldehyde with dibromo ethane in acetone ,then the compound A15 was reacted with chalcone to prepare compounds [A16_A22]. Finally, 4 - ethyl aniline was reacted with compounds [A16_A22] in ethanol to produce the final products dimers [A23_A29].The mesophases and their corresponding transition temperatures were identified by differential scanning calorimetric measurements and Polarized optical microscope .All members of the series exhibited liquid crystalline behavior with an enantiotropic nematic phase(A - A) and smectic phase (A—A).The smaller length/width ratio reduces theformation of the closed - packed layer structure, which normally has a parallelarrangement. For the members of two series, an increase in the alkoxy chain length increases the ratio of the lateral to terminal attraction betweenthe molecules, increasing the probability that the layer arrangement willpersist after melting (crystal - liquid crystalline transition) when the terminalattractions are weakened. The smectic phase was observed in the longchain members of the series while the small chain members exhibit nematic.The second series, which has the following structural formulaThis series was prepared via the same above steps .Alkoxy chain R fixedat pentyl group, while the other chain varies4 - methyl, nitro and bromine All members of the series exhibited liquid crystalline behavior with an enantiotropic nematic phases methylene groups, while the other spacer varies from two to sevengroups.molecules , the spectrum will happen to the convergence of similar shipments , causing the weakness of the forces of attraction between the lateral aspects of the bold and the emergence of nematic phase .

حضير 5,2 - ثنائي معوضات - 4,3,1 - ثاياديازول ودراسة فعاليتها البايولوجية Synthesis of 2,5 - disubstituted - 1,3,4 - Thiadiazole Derivatives And Study of Their Biological Activity

اسم المؤلف: احمد نور حميد
اسم المشرف: الفة عبد نايف
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: يتضمن البحث تحضير خمسه وثلاثون مشتقا اغلبها مشتقات جديدة للثايادايازول والتي تمتلك اهمية كيميائية وصناعية وبايولوجية درست وشخصت باستعمال الطرق الطيفية (13C.NMR,1H - NMR,UV,FTIR) فضلا عن دراسة تاثيراتها البايولوجية كمواد مضادة للبكتيريا .ويمكن اجمال خطوات البحث في محورين هما : المحور الاول : - طرق تحضير مشتقات الثايادايازول وتشمل : 1. تحضير 5,2 - ثنائي ميركيبتو - 4,3,1 - ثايادايازول [S1] وذلك من تكاثف الهيدرازين مع ثنائي كبريتيد الكاربون بوجود البريدين كمذيب.2. تحضير مشتقات 5,2 - ثنائي(هيدرازينو او فنيل هيدرازينو)4,3,1 - ثايادايازول [S3 - S2] وذلك بمفاعلة المشتق [S1] مع الهيدرازين او الفنيل هيدرازين بوجود الايثانول المطلق كمذيب.3. تحضير مشتقات كاربواوكسامايد وكاربوثايوامايد [S6 - S4] وذلك من مفاعلة مشتق الهيدرازينو [S2] مع (الفنيل ازوسينات,فنيل ازو ثايوسينات,4 - كلورو فنيل ازو ثايوسينات) بوجود الايثانول المطلق كمذيب .4. تحضير مشتقات الاميدات الحلقية [S10 - S8] وذلك من مفاعلة مشتق الهيدرازينو [S2] مع الانهدريدات (انهدريد الماليك,انهدريد الفثاليك,انهدريد السكسنيك) بوجود حامض الخليك الثلجي كمذيب.5. تحضير مشتقات البايرزول [S12 - S11] وذلك من مفاعلة مشتق الهيدرازينو [S2] مع الاسيتايل اسيتون واثيل اسيتو اسيتيت بوجود الايثانول المطلق.6. تحضير المركب (ثنائي[4,2,1]ترايازول)[d - 4*,3* : b - 4,3] ثايادايازول - 6,3 - ثنائي امين [S7] وذلك من تفاعل مول واحد من مركب [S1] ومولين من الثايوسيماكاربازايد في الايثانول المطلق وقد استعمل المركب في اعلاه في تحضير مشتق الكاربمات [S22]وذلك من تفاعله مع اثيل كلورو فورميت بوجود البريدين كمذيب يتبعه تحضير مشتق الكاربواوكزامايد [S26]وذلك بتفاعل المشتق [S22] مع الهيدرازين بوجود الايثانول المطلق.7. تحضير المركب (2 - امينو - 5 - ميركبتو - 4,3,1 - ثايادايازول) [S13] وذلك من تكاثف كميات متساوية من الثايوسيماكاربازايد مع ثنائي كبريتيد الكاربون بوجود كاربونات الصوديوم اللامائية يتبعها تحضير املاح الديازونيوم وصبغة الازو [S14] والتي استخدمت كمواد اولية في تحضير قواعد شيف [S28 - S27] وايضا تم استخدام املاح الديازونيوم لتحضير مشتق الازايد [S15],وعند مفاعلة مشتق الازايد مع الاثيل اسيتو اسيتات اعطى مشتق الترايزول [S16].8. تحضير المشتق (2 - امينو - 5 - ثايواثيل اسيتلت - 4,3,1 - ثايادايازول) [S17] من تكاثف المركب [S13] مع الاثيل كلورو اسيتات الذي عند مفاعلة مع الهيدرازين بوجود الايثانول كمذيب ليعطي المشتق [S24] 9. تحضير المركب5*,5 - (بروبان - 3,1 - ثنائي يل ثنائي (سلفون ثنائي يل))ثنائي(4,3,1 - ثايادايازول - 2 - امينو) [S18] وذلك من مفاعلة المركب [S13] مع 3,1 - ثنائي برمو بربان بوجود هيدروكسيد الصوديوم تبعها مفاعلته مع اثيل كلوروفورمات ليعطي المشتق [S21],تفاعل المركب [S21] مع الهيدرازين بوجود الايثانول كمذيب اعطى المشتق [S25].10. تحضير قواعد شيف [S35 - S29] وذلك من تكاثف مركبات الامين [S13 - S7 - S2] مع الالديهايدات الاروماتية (فيوران - 2 - كاربوالديهايد,ثايوفين - 2 - كاربوالديهايد,4 - بيريدين كاربوكسالديهايد)وبوجود قطرة من حامض الخليك الثلجي كعامل مساعدالمحور الثاني : - ويشمل دراسة الفعالية البايولوجية لبعض المركبات المحضرة على اربعة انواع من البكتيريا هي (ايشيريشيا القالون,السودوموناس,ستفايلوكوكس,ستريبتوكوكس) | This research includes the synthesis of thirty five new derivative of 1,3,4 - Thiadiazole which have chemical , industrial and biological chemical importance.These derivatives were identified by spectroscopic methods (FTIR,UV - VS,1H - NMR,13C.NMR)in addition to physical properties from colour , melting point and their biological effects against various bacterial .This work was achieved by two axis principals : - First Axis : Synthetic method of these new 1,3,4 - thiadiazole derivative which included : 1. Synthesis of (2,5 - dimercapto - 1,3,4 - thiadiazole) [S1] derivative was synthesis from of the condensation hydrazine with (CS2) in the presence of pyridine as a solvent.2. Synthesis of (2,5 - di(hydrazine or phenyl hydrazine) - 1,3,4 - thiadiazole)[S2 - S3] were prepared by reactions of derivative [S1] with hydrazine or phenyl hydrazine in the presence of absolute ethanol as a solvent.3. Synthesis of carboaoxamide and carbothiaoamide derivatives [S4 - S6] were performed from treatment of hydrazino derivative [S2] with (phenyl isocyanite,phenyl isothiocyanite, 4 - chloro iso thio cyanite) in presence of absolute ethanol as a solvent .4. Synthesis of cyclic imides [S8 - S10] were preformed from treatment of hydrazino derivative [S2] with anhydrides (succinic, malic, phthalic) in presence of glacial acetic acid as a solvent.5. Synthesis of pyrazol derivatives [S11 - S12] were performed from treatment of hydrazino derivative [S2] with(acetyl acetone, ethyl aceto acetate) in the presence of absolute ethanol as a solvent.6. Synthesis of (bis([1,2,4]triazolo)[3,4 - b : 3',4' - d][1,3,4]thiadiazole - 3,6 - diamine) [S7] for the reaction of one mole of thiosemicarbazaide and [S1] in absolute ethanol,the above compound [S7] was used to prepare carbamite derivative [S22] through the reaction with ethyl chloroformate in presence of pyridine as a solvent.Followed the preparation of acarboxamide derivative [S26] from reaction of [S22] with hydrazine in the presence of absolute ethanol.7. Synthesis of (2 - amino - 5 - mercapto - 1,3,4 - thiadiazole) [S13] through the condensation equal moles of thiosemicarbazaide with carbon disulfide in presence of anhydrous sodium carbonate , followed the preparation of diazonium salts to give azo dye [S14] and used as starting material to prepare Schiff base [S27 - S28] and also has been used to prepare the diazonium salt derivative azide [S15] and when you reactance derivative azido with ethyl aceto acetate give the triazolo derivative [S16].8. Synthesis of (2 - amino - 5 - thioethylacetate - 1,3,4 - thiadiazole)[S17] through condensation of compound [S13] with ethyl chloroacetate was performed the [S17] ,which on reaction with hydrazine in the presence of ethanol as a solvent give a derivative [S24].9. Synthesis of (5,5' - (propane - 1,3 - diylbis(sulfanediyl))bis(1,3,4 - thiadiazol - 2 - amine) [S18] was carried out through the reaction of compound [S13] with dibromo propane in presence of sodium hydroxide , followed reaction with ethyl chloroformate to give derivative [S21].The reaction of derivative [S21] with hydrazine in the presence of ethanol as a solvent to give derivative [S25]. 10. Synthesis of Schiff base [S29 - S35] through the condensation of amino compounds [S2,S7,S13] with carried out aromatic aldehydes [Furan - 2 - carbaldehyde,Thiophen - 2 - carbaldehyde,4 - pyridine Carboxaldehyde) in the presence a few drop of glacial acetic acid as catalyst.Second Axis : This axis including the biological activity of some compounds to four type of bacteria (Escherichia Coli,Strepto coccus,Psendomonus,Staphylococcus).

تقدير مستويات بعض العناصر النزرة وانزيم الكلوتاثيون بيروكسيديز في دم مرضى حصاة الكلى في محافظة البصرة - العراق Estimation Levels of Some Trace Elements and Glutathion Peroxidase in The Blood of Patients Infected Kidney Stones in Basrah Governorate - iraq

اسم المؤلف: نور حامد فيصل
اسم المشرف: بيداء حسين علي العزاوي
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: البصرة
الصفحات الاولى:
المستخلص: The current study aimed to find relationship between some of biochemical variables with kidney stone patients and study the effectiveness of antioxidants (Zinc Zn,Selenium Se,Glutathion peroxidase GPx) and Calcium Ca ,Magnesium Mg and Cupper Cu. The samples were collected from Lithotripsy center in Basrah General Hospital and samples were selected from 104 patients with stones (55male and 49 female) their age ranged between (12 - 67) and 70 healthy people (40 male and 30 female) their age ranged between (17 - 65).The result were : 1 - Highly significant decreasing in patients in the level of zinc (p˂0.01) compared with healthy people. 2 - Significant decreasing or increasing was observed in level of Cu in patients compared with healthy people.3 - Highly significant in patients in the level of calcium p˂0.01 compared with healthy people.4 - Highly significant decreased in level of Mg p˂0.01 in patient compared with healthy.5 - highly significant decrease was observed in Se in patients compared with healthy people p˂0.01 6 - highly significant decrease was observed in GPx in patients compared with healthy people p˂0.01 7 - Presence positive correlation between antioxidants (Zn,Se and GPx) and negative correlation between (Zn,Cu) and negative correlation between (Ca,Mg).
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