دراسة بعض الخواص الفيزيائية والميكانيكية للمتراكبات البوليمرية الجديدة المحضرة من الستايرين بيوتادين == Study of Some Physical and Mechanical Properties of New Polymeric Composition from prepared SBR
تقدير الكميات الضئيلة من الخارصين (II) والنحاس (II) والنيكل (II) باستعمال الكاشف الجديد انتي بايرايل ازو (2,7) - نفثالين دايول بالطرق الطيفية == Determination of Trace Amounts of Zinc (II) , Copper (II) And Nickel (II) Using New Reagent of Antipyriyl Azo(2,7) - Naphthalindiol By Spectrophotometric Methods
Author name:
مسار علي عواد عناد الزيادي
Supervisor name:
حسين جاسم محمد
University location:
Najaf
Abstract:
تم في هذه الدراسة تفاعل الكاشف المحضر الجديد 1 - ('4 - انتي بايرايل ا?زو ) 2,7 - نفثالين دايول(1 - APANDOL) مع (11) ايون فلزي مع استحداث طريقة طيفية لتقدير كل من ايونات الخارصين (II) ,والنحاس (II) ,والنيكل (II) بهذا الكاشف اذ كان الطول الموجي للامتصاص الا | The research includes primary study of the reaction of 1 - ( '4 - anti pyriyl azo) 2,7 - naphthalindiol (1 - APANDOL) with (11) metal ions ,and development of Spectrophtometric method for the determination of Zinc (II) ,Copper (II) and Nickel (II)with this reagent. The wavelength of maximum absorption for the reagent was found at (453) nm and for the complexes formed between these ion with this reagent was found at (492,499,514) nm for Zinc (II), Copper(II) and Nickel (II), respectively in aqueous medium ,also the optimum conditions for the reaction of these ion with the reagent were employed ,such as the volume of reagent solution ,time ,temperature, order of addition and effectives of pH, The calibration curves of these complexes were constructed ,Beer,s law was obeyed in the range of (0.1 - 2.5) ppm for zinc (II) with a correlation coefficient of ( r =0.9976) and molar absorptivity( ? =1.3x104) L.mol - 1.cm - 1 and sandell sensitivity was (0.0049) ?g.cm - 2. For copper (II) the rang was (0.1 - 2.5) ppm with a correlation coefficient of (r =0.9979) molar absorptivity (? =1.9x104) L.mol - 1.cm - 1, and sandell sensitivity was (0.0032) ?g.cm - 2 , as for nickel (II), the range was (0.1 - 2.0) ppm with acorrlation coefficient (r =0.9962) and molar absorptivity (? =2.0x104) L.mol - 1.cm - 1 and sandell sensitivity was ( 0.0029) ?g.cm - 2 The stoichiometry of the formed soluble complexes among Zinc (II), Copper (II) and Nickel (II) with reagent was investigated by both the continuous variations method and mole ratio method ,the ratio (M : L) was (1 : 2) for complexes at pH(8,8 and 9) respectively.The stability constant (Kst) for the complexes were equal to (Kst = (Kst =0.29 x108L.mol - 1) (Kst =1.6 x1010L.mol - 1) and (0.128 x108L.mol - 1) for Zinc ,Copper and Nickel respectively. Precision and accuracy of the analytical procedure were showed for (0.5) ppm of Zinc(II) , Copper(II) and Nickel (II) that R.S.D% was equal to (1.41 , 0.77 and 0.63 %) and Erel % was found to be (0.53% ,0.65% and 0.95%) for these ions , respectively. the analytical procedure were showed for (1.0) ppm of Zinc(II), Copper(II) and Nickel (II) that R.S.D% was equal to (0.58, 0.36 and 0.4 %) and Erel % was found to be (0.28%,0.30% and 0.99%) for these ions , respectively.The interference of metal ions in the presence of related ions was determined , as well as masking of these ions by suitable masking agents was studied. The physical properties of precipitants were studied through the establishment of melting point, solubility and molar conductivity as well as the measurement of infrared spectra ,with the suggestion of structural formula of the formed complexes with the reagent (1 - APANDOL). The method was applied for the determination of the content of Zinc(II), Copper (II) and Nickel (II), in tea leaves.. Finally ,The biological activity of these complexes was tested with two types of bacteria.
التقدير الطيفي للاكسده الضوئيه المحفزه للباراسيتامول والبروكائين == Spectrophotometric Determination of Photocatalytic Oxidation of Paracetamol And Procaine
تحضير دقائق مغناطيسيه متناهيه الصغر (نانو) ودراسة تقييدها لانزيم الزانثين اوكسيديز == Prepared of Magnetic Nanoparticles And Study The Immobilized For Xanthine Oxidase
تحضير وتشخيص مركبات غير متجانسة حلقية متعددة من مشتقات الازو اوقواعد شف == Synthesi And Identifecation of Heterocyclic Multiple Ring Compounds of Azo Derivatives And Schiff Bases
تطبيقات طريقة استخلاص سائل - سائل للفصل والتقدير الطيفي لبعض العناصر الانتقالية بواسطة معقدات عضوية جديدة == Applcations of Liquid - Liqid Extraction Method For Separation And Spectrophotometric Determiination To Some Transition Metal Elements By New Organic Reagents
دراسات كيمياء الكم لمركبات الروثينيوم العضوية الفلزية == Quantum Chemical Studies of Ruthenium Organometallic Compounds
دراسة بعض القياسات الكيموحياتية والمناعية في مرض الفصام واضطرابات الاكتئاب الشديد في مدينة النجف الاشرف == Study of Somebiochemical And Immunological Parameters In Schizophrenia And Major Depressive Disorders In Najaf Alashraf Province
