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دراسة الخواص الكهروحرارية لـ (Bi2Te3),(Bi2Te3)xSb1 - x, (Bi2Te3)xSe1 - x كنبيطة بلتير Study Thermoelectrical Characterization (Bi2Te3),(Bi2Te3)Xsb1 - X And (Bi2Te3)Xse1 - X As Apeltier Device

اسم المؤلف: خليل ابراهيم عناد
اسم المشرف: حسين خزعل رشيد غصون حميد محمد
الموضوع العام: علوم الفيزياء
السنة: 2015
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: ان ھذه الاطروحة تتضمن دراسة تاثير عاملين وھما اختلاف تركيز والعامل الاخر ھو ھو تلدين الاغشية المحضرة بدرجتي (x= المواد( 0.5،0.7،0.9،1 حرارة( 473،373 ) كلفن على كل من الخصائص التركيبية، طبيعة السطح، الكھربائية (Bi2Te3)xSe1 - x و(Bi2Te3)xSb1 - x، (Bi2Te وال | This thesis was including of studying the structural, optical and thermoelectric properties of(Bi2Te3), (Bi2Te3)xSb1 - x and (Bi2Te3)xSe1 - xthin films as function of concentration and annealing temperatures prepared by flash thermal evaporation technique

دراسة نظرية لتحديد افضل قدرة مستحصلة في منظومة القدرة التناضحية المفتوحة Theoretical Study And Optimization of An Open Cycle Osmotic Power Process

اسم المؤلف: مضر صباح حميد
اسم المشرف: عادل عبيد شريف الحسيني احمد فرحان عطوان
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: A great quantity of renewable energy can be potentially generated when waters of different salinities are mixed together. The harnessing of this energy for conversion into power can be accomplished by means of the Pressure Retarded Osmosis (PRO). This tec

توليف ودراسة طيفية لتراكيب الكاربون النانوية النقية والمطعمة باستخدام التقنية الهايدروحرارية Synthesis And Spectroscopic Study of Pure And Doped Carbon Nano - Structures Using Hydrothermal Technique

اسم المؤلف: سعد محمد حسن الشريفي
اسم المشرف: زينب صبيح صادق دنيا كامل مهدي
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: Hydrothermal Technique has been used to synthesis Carbon Nano - Structures. Three weights of Sodium Hydroxide (4gm, 8gm and 12gm) have been used Cold Substitution in water and study its effect on Carbon Nano - Structures production. This Technique is achi

تاثير بعض المضافات على الخواص الميكانيكية لمتراكبات المطاط المستخدمة لتخميد الصدمة Effect of Some Additives on Mechanical Properties of Rubber Composites For Shock Damping

اسم المؤلف: سمير حسن هادي النصراوي
اسم المشرف: عبد الرضا سلمان حساني محمد حمزة المعموري
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: الرؤيا الاساسية او الاطار الرئيسي للبحث الحالي هو اكتشاف مواد مدعمة او مقوية مناسبة في صناعة مصدات السفن عند الموانئ حيث تعتبر مصدات السفن (Fenders)المستخدمة في الموانئ جزء اساسي فيها حيث تحافظ على السفن من الاضرار الناجمة عن التصادم او الاحتكاك مع ارصفة | The main scope of the present research to explore alternatives basic materials and reinforcement materials for manufacturing suitable and highly reinforced fenders for shipping at harbors which is maintain to the ships from damage and friction due to bert

تصنيع ودارسة خصائص كاشف ضوئي من المفرق الهجيني cdo : Al/si Fabrication And Study of Photodetector Properties From Cdo : Al/Si Heterogunction

اسم المؤلف: اياد احمد صالح
اسم المشرف: سمير عطا مكي علية عبد المحسن شهاب
الموضوع العام: علوم الفيزياء
السنة: 2015
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: في هذا البحث, تم تصنيع كاشف ضوئي من المفرق الهجين (n - CdO : Al/p - Si) ثم دراسة خصائصه, والمحضر من ترسيب اغشية (CdO) النقية والمطعمة بالالمنيوم (CdO : Al) بطريقة التبخير الحراري في الفراغ على قواعد سليكونية احادية البلورة باتجاهية (111). اذ تم تحضير هذه | In this work, photovoltaic detector of (n - CdO : Al/p - Si) heterojunction has been fabricated and its properties were studied, which prepared by deposition CdO and CdO : Al via thermal evaporation under vacuum method on an (111) oriented single crystal

تصنيع مفرق هجين للمركب (CuIn1 - XGaxSe2) واستخدامه كخلية شمسية Fabrication Heterojunction of Compound (Cuin1 - Xgaxse2) And Used As Solar Cell

اسم المؤلف: علي حسين عبد الرزاق
اسم المشرف: ايمان حميد خضير حسون الميالي بشرى كاظم
الموضوع العام: علوم الفيزياء
السنة: 2015
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: حضرت في هذا البحث سبائك للمركب الرباعي (CIGS) على وفق الصيغة الكيميائية (CuIn1 - xGaxSe2) لقيم مختلفة لـ (x)، (x= 0.3, 0.6, 0.9) باذابة عناصر السبيكة في انبوب مفرغ من الكوارتز تحت ضغط (2×10 - 3mbar)، وباجراء فحوصات حيود الاشعة السينية لمساحيق السبائك الث | In this research (CIGS) quarter compound alloys prepared for chemical formula (CuIn1 - xGaxSe2) for different x (x=0.3,0.6,0.9) by melting them in a evacuated quartz tube (2×10 - 3 mbar).XRD analysis show that all three alloy prepared (powder) are polycr

دراسة نظرية وعملية لجسيمات (CdSe) النانوية Theoretical And Experimental Study For (CdSe) Nanoparticles

اسم المؤلف: حسين بخيت جاسم
اسم المشرف: محمد تقي حسين بشرى عباس حسن
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تم تقسيم هذا البحث الى جزئين رئيسيين هما النظري والعملي، الجزء النظري الذي تم من خلاله دراســـة الخوا ص الالكترونية التركيبية لبلورة كادميوم - سيلينــــيوم ذات التركيــــــب المكعب (Zinc - blende) وللابعاد ((1.76 - 2.34 نانومـــــــــــــــتر باستخــــدا | This investigation can be classified into two main parts (theoretical and experimental). Theoretical investigation is carried out in experimental optical, structure and electrical study of CdSe nanocrystals. In the first part the electronic structure prop

حساب الكثافات النووية وعوامل التشكل باستعمال طريقة سكيرم - هارتري - فوك Calculation of The Nuclear Densities And Form Factors Using Skyrme - Hartree - Fock Method

اسم المؤلف: نبيل فوزي لطوفي
اسم المشرف: رعد عبد الكريم راضي علي عبد اللطيف كريم
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: التفاعلات المؤثرة من نوع سكيرم قد استخدمت لعدة عقود في نموذج الهارتري فوك لمعدل - المجال، كما وان حدود مختلفة للتفاعل قد استنتجت بحيث تعطي افضل نتائج لقيم كثافة المادة النووية، انصاف الاقطار النووية وقيم اخرى مختلفة. في الدراسة الحالية قد تم وصف تفاعل سكي | The effective Skyrme type interactions have been used in the Hartree - Fock (HF) mean - field model for several decades, and many different parameterizations of the interaction have been realized to better reproduce nuclear masses, radii, and various othe

حساب دوال توزيع الكثافة الالكترونية المختلفة للاغلفة الذرية غير المتناظرة كرويا Calculation of Various Electronic Density Distribution Functions For Non - Spherically Symmetric Atomic Shells

اسم المؤلف: نعيمة جيجان مذكور التميمي
اسم المشرف: خليل هادي احمد البياتي علي عبد اللطيف كريم
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: يتــضمن البحث الحالي دراسة نظريـة للخصائص الذرية للانظمة ذات الاغلفة المفتوحة في المستويات المتهيجة 1s2 2p و1s2 3p و1s2 3d لذرة الليثيوم والمستقرة 1s2 2s2 2p و1s2 2s2 2p2 لذرتي البورون والكربون والايونات المشابهة لهما. تمت الدراسة باستخدام تقنية التجزئة ح | The atomic properties of open - shell systems in the excited states 1s2 2p, 1s2 3p and 1s2 3d of Li - atom and the ground states 1s2 2s2 p and 1s2 2s2 p2 of B - and C - like ions are examined. The study was conducted using partitioning technique to analyz

تصنيع وتوصيف خلايا شمسية مرنة Fabrication And Characterization of Flexible Solar Cells

اسم المؤلف: علي محسن عبد الحسين اللامي
اسم المشرف: زينب عبد السلام الرمضان فلاح ابراهيم العطار
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تعد الانظمة الفوتوفولتائية من مصادر الطاقة النظيفة والتي بدات تاخذ مساحة مهمة من البحث، ان الاغلبية من الخلايا الشمسية تتميز بكونها صلبة ولم يراعى فيها عامل المرونة, لذا توفر الانظمة الفوتوفولتائية المرنة عدة ميزات في مجال سهولة النقل, مقاومة الكسر وخفة | As a source of clean, remote energy, photovoltaic (PV) systems are an important area of research. The majority of solar cells are rigid materials with negligible flexibility. Flexible PV systems possess many advantages, such as being transportable, unbrea

الميكانيك الاحصائي والخصائص الثرموديناميكية لتكاثف بور - اينشتاين في الاوساط الكسورية Statistical Mechanics And Thermodynamic Properties of Bose - Einstein Condensation In Fractal Media

اسم المؤلف: ابراهيم عبد المهدي صادق
اسم المشرف: محمد عبد الزهرة حبيب اياد عبد العزيز عباس
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: The phenomenon of Bose - Einstein condensation (BEC), which was predicted by Einstein in 1925 and experimentally realized in 1995, has been the subject of intensive research in the last decades. On the theoretical side, several approaches have been formulat

تاثير جسيمات الاستطارة على خواص مركبات الصبغة العضوية Scattering Particles Effect on Characterization of Organic Dye Compounds

اسم المؤلف: جعفر فاضل عودة
اسم المشرف: بهاء طعمة جياد فراس جواد كاظم
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: In this thesis, two types of nanoparticles were synthesized using sol - gel technique, silica (SiO2) and titania (TiO2) as scatterrers, each of these nanoparticles was mixed at different concentrations with Keton Red laser dye then doped with silica Xerog

بناء نموذج رياضي احصائي لطاقة الرياح في العراق باستخدام دوال مختلفة لتوزيع ويبل Construction of Mathematical - Statistical Model of Wind Energy In Iraq Using Different Weibull Distribution Functions

اسم المؤلف: فراس عبد الرزاق هادي
اسم المشرف: اياد عبد العزيز العاني محمد احمد صالح
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: في السنوات القليلة الماضية، شهد العالم اندفاعا نحو استخدام مصادر الطاقة النظيفة والمتجددة من اجل التقليل من التلوث البيئي وتكلفة الطاقة واستهلاك الوقود. لذلك انصب هذا العمل نحو قطاع مهم من قطاعات الطاقةالمتجددة وهو طاقة الرياح، حيث تم تقسيم العمل الى ارب | In the past few years, the world has witnessed a rush towards the use of clean renewable energy sources in order to reduce environmental pollution, energy cost, fuel consuming. Therefore, this work focused toward an important sector in renewable energy, w

تحضير غشاء رقيق لخلية شمسية لاساس (CZT(S,Se) Synthesis of Thin Film Solar Cell Based on CZT(S,se)

اسم المؤلف: عدنان مرموص منصور
اسم المشرف: ميسون فيصل احمد الياس اقبال سهام ناجي
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الاغشية الرقيقة
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تم تحضير اغشية 4( Cu2ZnSn(SexS1 - xبطريقتين, التبخير الحراري والتبخير المشترك الحراري. بالتقنية الاولى تم تحضير مركب 4( Cu2ZnSn(SexS1 - x بتراكيز مختلفة وذلك بتفاعل عناصر النحاس والزنك والقصدير والسلينيوم والكبريت ذات النقاوة العالية في حاوية من الكوارتز | Cu2ZnSn(SexS1 - x)4 films have been prepared by two techniques, thermal evaporation and thermal co - evaporation. By the first technique, Cu2ZnSn(SexS1 - x)4compound was synthesized by reacting high - purity elements (Cu, Zn, Sn, Se and S) in an evacuated q

دراسة التركيب النووي لبعض النوى باستخدام طريقة سكيرم - هارتري - فوك Nuclear Structure Study For Some Nuclei Using Skyrme - Hartree - Fock Method

اسم المؤلف: شيماء ذياب العبودي
اسم المشرف: زاهدة احمد دخيل علي عبد اللطيف الزبيدي
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: The present research is concerned mainly with the effective Skyrme interaction as applied to the Haretree - Fock mean - field model for studying the nuclear structure of some nuclei, namely : Si, Ti, Zr and Be. The static nuclear ground state proprieties

تصميم مضخة هجينة شمسية - جيوحرارية Design of Hybrid Solar - Geothermal Heat Pump

اسم المؤلف: علاء حسين شنيشل السوداني
اسم المشرف: احمد فرحان عطوان نصير كريم قاسم السوداني
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: مصادر الطاقة التقليدية مضرة بيئيا على العكس من مصادر الطاقة المتجددة. سعى العالم سوية في نهاية القرن الماضي الى تشخيص مشاكل تغير المناخ الذي ادى بدوره الى التفكير في سبل حفظ الطاقة والتقليل من الانبعاثات. تعتبر طاقة الجيوحراري (Geothermal energy) من الطاق | Conventional energy resources are environmentally harmful unlike renewable energy resources. At the end of the last century the world came together to address the problems of climate change; which led to the thinking of ways to conserve energy and reduce

استعمال معامل صلابة عضلة البطين الايسر للتنبؤ باداء عضلة القلب في المرضى الذين يعانون من ارتفاع ضغط الدم The Use of Left Ventricular Myocardial Stiffness Index As Apredictor of Myocardial Performance In Patients With Systemic Hypertension

اسم المؤلف: سمر عمران عيسى
اسم المشرف: معتز فوزي حسين اسيا حميد المشهداني
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: ارتفاع ضغط الدم يؤدي الى زيادة الجهد على القلب. هذا الجهد هو اكثر تاثيرا على البطين الايسر عند ارتفاع الضغط الانقباضي. عضلة القلب يمكن ان تتحمل هذا الجهد الزائد لفترة معينة من الزمن; وهذا يعتمد على شدة ومدة المرض. ان ارتفاع ضغط الدم غير المنضبط على المد | It is well known that hypertension results in cardiac overload. This overload is more profound on the left ventricle were systolic high pressure is present. The cardiac muscle can tolerate this overload for a certain period of time; this depends on the se

تصميم وبناء الماكنترون غير المستقر ذي المجال المغلق لمنظومة البلازما لتحضير كاشف الاغشية الرقيقة النانوية Design And Construction of Closed Field Unbalanced Magnetron of Plasma System To Prepare Nano Film Detector

اسم المؤلف: عدي عطا حمادي
اسم المشرف: فراس جواد كاظم محمد خماس خلف
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تم في هذا العمل تصميم وبناء مجمع الماكنترون المزدوج غير المستقر ذي المجال المغلق لغرض استخدامه في منظومة الترذيذ المستمر بالبلازما وقد جرى قياس التوزيع الفضائي للمجال المغناطيسي بين قطبي المنظومة ونمذجته لغرض تحديد التاثيرات الناجمة عن تغيير شكل المجمعين | In the present work, closed - field unbalanced dual magnetron (CFUBDM) system was designed and constructed to be employed in a dc plasma sputtering system. The spatial distribution of magnetic field between the two electrodes was measured and the maximum

مواصفات المواد المتحللة (بولي لاكتك اسد خلائط البولي لاكتك اسد متراكبات البولي لاكتك اسد) Characterizations of Biodegradable Materials (PLA, PLA Blends, PLA Nanocomposites)

اسم المؤلف: نادية عباس علي
اسم المشرف: فرح طارق محمد نوري
الموضوع العام: علوم الفيزياء
السنة: 2014
الموضوع الدقيق: الفيزياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: في هذا البحث تم استخدام مادة البولي لاكتك اسد والخلائط البولمرية )البولي لاكتك اسد/ السليلوز, البولي لاكتك اسد /شيتوزان, البولي لاكتك اسد /بولي اثلين كلايكول( التي حضرت بطريقة الصب باستخدام مجانس الخلط بنسب 02 % من السليلوز والشيتوزان والبولي اثلين كلايكو | In this work Pure Polylactic acid (PLA) and PLA/MCC, PLA/Cs, and PLA/PEG blends prepared by casting method using shearing mixer with ratio 20% from micro crystalline cellouse, chitosan, polyethylene glycol. Polylactic acid nanocomposites prepare with dif

تحضير ودراسة طيفية ومعالجة نظرية لمعقدات مزيج ليكاندي مشتقات البنزاميدازول والفينانثرولين

اسم المؤلف: دعاء حبيب محل
اسم المشرف: محاسن فيصل الياس
الموضوع العام: علوم الكيمياء
السنة: 2015
الموضوع الدقيق: الكيمياء العضوية
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الكلمات الدلالية:
  • تحضیر
  • حلقیة غیر متجانسة
  • جالكون، بایرازولین
  • ثنائي هایدروبایرمدین - - 2 اون
  • ثنائي هایدروبایرمدین - 2 - ثایون، بولي ایماید
  • فعالیة بایولوجیة
  • موجات فوق صوتیة Synthesis
  • Heterocyclic
  • Chalcone
  • derivatives
  • Pyrazoline
  • Dihydropyrimidin - 2 - one
الصفحات الاولى:
المستخلص: In this study, two new aromatic chalcones have been synthesized. The first one contain one amino phenyl group while the second contain two amino phenyl groups , from the reaction of 2 - acetothiophene or pamino acetophenone with p - or m - amino benzaldehyde respectively by Claisen - Schmidt condensation in alcoholic base medium (10%NaOH ).Also, some of heterocyclic compounds have been derived from these prepared chalcones as a derivatives for 2 - pyrazoline ring and for dihydro pyrimidine - 2 - one/thione as follows : 1 - Preparation of 3,5 - di (amino phenyl ) - 2 - pyrazoline (3,9) derivatives from condensation of (1,2) chalcone with hydrazine hydrate in absolute ethanol.2 - Preparation of 3,5 - di (amino phenyl) - 1 - phenyl - 2 - pyrazoline (4,10) derivatives by the reaction of chalcone (1,2)with phenyl hydrazine in presence of acetic acid.3 - Preparation of 3,5 - di (amino phenyl) - 1 - substituted - 2 - pyrazoline (5 - 7,11 - 13) from the reaction of chalcones (1,2) with semicarbazide, thiosemicarbazide and isoniazide in strong basic medium (45% NaOH) in absolute ethanol.4 - Preparation of 4,6 - di(amino phenyl ) - 3,4 - dihydro pyrimidine - 2 - one / thion (14,15) : from the reaction of chalcone(2)with urea and thiourea in presence of sodium ethoxide in absolute ethanol in two ways : thermal catalyse and ultrasonic waves with high yield for the last one.The phenyl amines derivatives (3 - 7,9 - 15)included benzidine (8) were converted into N - substituted maleimic acid (16 - 28) , by reacted it with maleic acid anhydride in ether or dry acetone.These derivatives (16 - 28) were undergo dehydration by using anhydrous acetic and sodium acetate to give N - substituted malimide products ( 29 - 41) in good yield.Also, the homopolymers (42 - 54) for these malimides were prepared by free radical polymerization with benzoyl peroxide as initiator and dimethyl formamide (DMF) as a solvent at 130 0C. PDF created with pdfFactory Pro trial version www.pdffactory.com The copolymers (55 - 104)have been prepared by the samemethod and initiator with vinyl acetate for polymers (55 - 67)and with acryl amide for polymers (68 - 72) and with allyl benzene for polymers (73 - 80) and with maleimide (31) for the polymers (81 - 88) , also with maleimide (32) for the polymers (89 - 96) and finally with maleimide (33) for the polymers (97 - 104).The structures of these new compounds were characterized by UV spectra (as a comparable study for unpolymered molecules ),IR (infra - red ) spectra and 1H - NMR (nuclear magnetic resonance ) spectra for some of the prepared compounds and followed by TLC (thin layer chromatography ).The stability of these compounds (9 - 12) were studied spectrally from the changing in its high absorbance values (peaks) ?max for their solutions at concentrations 2×10 - 5M in light and dark with time for comparability. These compounds showed good stability whichcan be suggested to be used as an organic reagents for analytical study especially with drugs and phenolic compounds.More ever, the identification study , here we have studied the heoretical study of formation heat for intermediates and final compounds bodies length of the bond which was agreement with the particularly results.This study ,also includes the biological activity for some of the prepared compounds against four kinds of germs which known by its resistance against antibiotics ,these are Staphylococcus aureus (positive for Gram stain )and Escherichia coli ,Pseudomonas aeruginosa and Salmonalla typhi (negative for Gram stain ) and studiesy the inhibition values for these compounds comparable with three of standard antibiotics as controls (ampicilline : C1, Cloxacilin : C2, erythromycin : C3) , and the results show the ability of these prepared compounds to inhibit all the used germs except Pseudomonas which shows clear resistant for less polarity comparable with control samples.

تحضير ,تشخيص, دراسة فعالية مضادة للاكسدة ومضادة للسرطان لمعقدات الذهب (III) مع مركبات حلقية غير متجانسة Synthesis ,Characterization ,Antioxidant And Anti - Cancer Activity Studies of Gold (III) Complexes With Heterocyclic Compounds

اسم المؤلف: اية جمال عبد الحميد
اسم المشرف: فراس عبد الله حسن
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: دكتوراه
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تضمن موضوع البحث تحضير مركبات حلقيه خماسية وسباعية غير متجانسة متنوعة،من خلال اربعة اجزاء هي : الجزء الاول : - تضمن هذا الجزء تحضير مركبات مشتقات 1, 3, 4 - اوكسادايزول من مركب (ثنائي اثيل مالونيت)، كما موضح بالمخطط (1).الجزء الثاني : - تضمن هذا الجزء تحض | This work involves synthesis of different five, and seven membered heterocyclic rings, and divided into four different parts and the reaction steps for each part are summarized as shown below.First part : This part involved the synthesis of 1,3,4 - Oxadiazoles derived from diethyl malonate.Scheme (1).Second part : This part involved the synthesis of Oxazepine , tetrazoles, and thiazolidinone,from 4,4' - ((((methylenebis(1,3,4 - oxadiazole - 5,2 - diyl))bis(3,1 - phenylene))bis(azanylylidene))bis(methanylylidene))bis(N,N - dimethylaniline).(Scheme 2).Third part : This part involved the synthesis of 1,1' - (1,4 - phenylene)bis(N - substitutedmethanimine) [C1 - 9] from terephthalaldehyde. (Scheme 3). Fourth part : This part involved the synthesis of 1,3,4 - Oxadiazoles derived from terephthalaldehyde and hydrazone carboxamide.In addition, this part deals with the evaluation of antibacterial activities of some of the synthesized compounds. These activities were determined in vitro using disc diffusion method against four pathogenic strains of bacteria (E.coli a, Pseudomonas, Bacillus, and Staphylococcus.), the results revealed that some of these compounds showed measurable activity. (Scheme 4).The liquid crystalline behaviors of the two series have been examined by means of hot - stage polarizing microscopy for the determination of phase transition temperatures and the type of mesophases. The prepared compounds are characterized through determining their melting points, colors physical properties) and (FT - IR, 1H - NMR,) spectroscopy, (C.H.N.S, DSC) analysis and checked by T.L.C.

نمط جديد للتحليل بالحقن الجرياني المستمر باستخدام نظام تشعيع متعدد القنوات مرتبة بهيئة مصفوفة خطية واثنان من الخلايا الشمسية لقياس التعكرية لتقدير الفصائل التحليلية ذات الاهمية : دراسة وتطبيق New Mode of Cfi Analysis Using Multiple Channel Irradiation System In A Linear Array Arrangement With Twin Solar Cells For Turbidimetric Determination of Analytically Interesting Species : Study & Application

اسم المؤلف: عمر اياد ياسين القيسي
اسم المشرف: نغم شاكر تركي العوادي
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: الفصل الاول : يشمل الفصل الاول مقدمة عن تفاعلات الترسيب، مبادئها، ميكانيكية تكوين الرواسب، انواع الرواسب. وكما يتضمن الفصل الاول مقدمة عن الضوء والنظرية الكهرومغناطسية، وتداخل الضوء مع المادة (الانعكاس، الانكسار، النفاذية، الامتصاص). ناقش الفصل الاول بشكل

التقدير الطيفي لبعض المركبات العضوية المعوضة والمستحضرات الصيدلانية من خلال الاكسدة بايون السيريوم الرباعي باستخدام المحلل الطيفي الدقيق للتحليل بالحقن الجرياني المستمر (Ayah 3S BGR x3 -3D solar cell) Spectrophotometric Determination of Some Substituted Organic Compounds And Pharmaceuticals Formulation Via Their Oxidation With Ce(IV) Ion Using Ayah 3SBGRx3 - 3D Solar Cell CFIA Microphotometer

اسم المؤلف: مالك حسين علي العلوش العامري
اسم المشرف: نغم شاكر تركي العوادي
الموضوع العام: علوم الكيمياء
السنة: 2014
الموضوع الدقيق: الكيمياء الفيزيائية
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: تم استخدام حسابات ميكانيك الكم التقريبية شبه التجريبية وفق نموذج الحساب PM3)) وحسابات ميكانيك الكم الاساسية التامة غير التقريبية وفق نظرية دوال الكثافة (DFT) وباسلوب B3LYP وعناصر قاعدة 6 - 311G لحساب جزيئة الفلرين التي امتلكت التماثل Ih مع وحدات بناءها (5 | Semi - empirical quantum mechanical methods (PM3) and Density Functional theory calculations (DFT/ B3LYP/ 6 - 311G) were executed to evaluate the fullerene molecule ,the internal coordinates (bond length and angles) and some physical and energetic properties.Calculations of the geometrical Parameters (bond lengths and bond angles), have shown that the (C=C) bond length is increased with increasing the size of the molecule that increased elasticity especially to fullerene to be like a ball. The (C - C) bond length is decreased with increasing the size of molecule, that means fullerene will be more stable than the other molecules.The energetic values (heat of formation) is found to be increased with the increasing of the size of molecule. The total energy is decreased with increasing size of molecule that means the stability will increase with the increasing of the size of unit construction of fullerene molecule , on the other hand , the energetic difference (E HOMO - LUMO) between the higher level of orbital and the lower level of orbital are decreased with the increasing of the size of molecule ' unit construction reaching to the fullerene molecule. So, this property will increase the significance of fullerene in the industrial and the electrical purposes.The vibrational modes frequencies with ( 3N - 6) whereas N is represented by number of molecule atoms which are evaluated with the absorption intensities of infrared frequencies. symmetrical and coordinated modes were discussed at the equilibrium geometric formation by using the programs MOPAC & Gaussian 05.It is worthy to say that it was not mentioned before that the complementary classification for the vibrated motion modes for such molecules , so our evaluations may considered unique. It is noted , as well , that CH stretching frequency has had fluctuations that means increasing and decreasing in the values of frequencies. In connected with the bending vibrated modes which taking place out of plane of the molecule are decreased with the increasing size of the unit constructions of molecule but it is increased only at the fullerene molecule. Conversely, the bending vibrated modes which are taken place in the plane of molecule are increased with the increasing the size of unit construction of molecule but are decreased at the fullerene molecule.The distribution of the electronic charges density on the atoms of unit construction of fullerene molecule were studied, the results shown the absence of the electronic charge on the atoms of Fullerene molecule and its concentrated at atoms of the outer circumferential edges C - Cc for the aromatic rings in its own unit construction. Semi - empirical methods (PM3) and Density Functional theory calculations (DFT/ B3LYP/ 6 - 311G) were carried out to evaluate the vibration frequencies and infra - red (IR) absorption intensities for equilibrium geometries of construction units of (6,0) zigzag (Mono (D6h), Di (D6d), Tri(D6h), Tetra (D6d)) ring layers SWCNTs and the internal coordinates ( bond length & angles ) at the equilibrium geometric formation symmetrically according to group theory were evaluated. The most important notes were axial bond length C - Ca which is decreased with the increasing of the tube length whether odd or even number of ring layers. The length of these mentioned axial bonds will be longer in the outer layers than the middle layers that means the increasing of stability of the tube with its length increasing , with the ability of replacing the external atoms of the tube because they are connected with longer and weaker bonds. The reverse was found with the circumferential bond lengths C - Cc was as they were increased with the increasing length of the tube whether the tube was odd or even in number of ring layers. Moreover , the lengths of these bonds are decreased in the middle side to the outer one for the odd and even ring layers. This will confirm the stability of the tube with its length increasing. The lengths of outer bonds C - H which are situated on the edges of the tube which were approximately fixed , with exception of the bond length of CH bonds in Mono ring layers which were longer because the large negative charge on carbon to which it is bonded and the large positive charge on it compared with the positive charge on hydrogen atoms of the multi - layers tubes. The heat of formation which was found to be increased with the increasing of the length of the tube , that means increasing of the stability and the aromatic properties , with the increasing of number of tube' layers. This property will increase the importance in the uses of these tubes for the industrial and electrical purposes as semi - conductors.The vibrational modes frequencies with 3N - 6 with the absorption intensities of infrared frequencies were evaluated and classified. These modes were discussed in symmetrical and coordinating manners at the equilibrium geometric formation, by using the programs of MOPAC and Gaussian 05 , with confirming on unavailability of bounded specification for such modes with 3N - 6 in the literature. We have a through our studies that the stretching vibration modes of symmetric and anti - symmetric Carbon - Carbon axial bond (C - Ca) increased with the increasing length of tube , and this will increase the physical properties for electrical conductivity with confirming on the significance of nanotube industrially. For the vibrational bending frequencies which are taking place in plane and out of plane of molecule surface as well as the vibrational stretching for odd number of ring layers (Mono and Tri) fluctuation will be happening in the relations , as all of them will be decreased with the increasing of tube ' length except (C - Caasym, C - Casym , ? CHsciss. , ? ringasym , ? ringsym and ? ringsym ) which be increased with the increasing the length of tube. The vibrational bending frequencies which are taking place in plane and out of plane of molecule surface for the even number of ring layers ( Di and Tetra layers ) will be decreased with the increasing of tube' length except (? CHsciss.) which is increased with the increasing of tube' length. Furthermore , all vibrational modes which are related to the puckering , breathing and bending movements of clockwise and anti - clockwise according to "group theory" were determined in accurate manner to which deformations are related , which are happened in the tubes , as a result of vibration, that may prevent the flow of electrons' movements and their transitions. The numerical values for the vibrational frequencies which are resulted from Semi - empirical methods (PM3) were acceptable in comparing with the strict calculations , hopping to achieve best values and to be close to the values obtained for the strict calculations (DFT) method to be suited with the basis and standards that are depended internationally. Some of these values were corrected by multiplied by constant scaling factors for such molecules. The results of scaling were good and very close to the experimental and calculated values.The distribution of charges' density on units of construction atoms of (6,0) zigzag nanotube SWCNTs also were studied. The results were consistent with the physical and experimental conductivity properties for such calculated tubes , as the intensity of the electronic charge was concentrated on the outer circumferential edges of atoms C - Cc for the aromatic molecules as well as for nanotubes with its disappearing form outer side towards the middle side of multi - ring layers ( Mono , Di , Tri and Tetra ).

دراسـة بيئيــة للافقريات القاعيـة في هور الدلمج - وسط العراق An Ecological Study of The Benthic Invertebrates In Al Dalmage Marsh - Middle of Iraq

اسم المؤلف: ميسون حسن مشجل السراي
اسم المشرف: هيفاء جواد جوير
الموضوع العام: علوم الحياة
السنة: 2015
الموضوع الدقيق: الحيوان - اللافقريات
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: العربية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: استهدفت الدراسة الحالية التنوع الاحيائي لمجتمع لافقريات القاع في هور الدلمج / وسط العراق فضلا عن بعض الخصائص الفيزياوية والكيمياوية لمياه الهور، اختيرت ست محطات لجمع العينات وذلك للمدة من بداية كانون الثاني وحتى كانون الاول 2013. استخدم تحليل التوافق CCA | Benthic invertebrate diversity on the Al - Dalmage marsh in the middle of Iraq, in addition to the some physical and chemical properties was the goal of the present study, for a period from January to the end of December 2013. Six stations along the eastern side of the marsh were chosen for monthly samples collection.The results showed water temperature ranged from(9 - 34.1)?C. The pH values were neutral but tends to near alkaline and ranged from (7.2 - 9).The Electrical conductivity values varied from (22735 - 2330) ?s/cm, according to the values of salinity (1.5 - 14.6) ‰ the marsh was classified as mesohaline (TDS) which showed high values ranged from (1820 - 17762) mg/L.This study showed that the marsh were well oxygenated due to the dissolved oxygen values which ranged from 7 - 12 mg/L, the study recorded values to BOD5 were ranging from (1.5 - 3)mg/L, and the marsh classified as very hard according to the total hardness values from (6980 - 825) CaCo3 mg/L. The high perecentage of organic matter in the sediment was 2.7 %. The results showed the station were characterized by sediment texture varied from silt clay sand sediment in the stations 1, 4, 5 , silt clay in St(2) and sand silt in St(3), sand clay silt in St(6).A total of 21286 individual benthic invertebrates was sorted, which represents which 78 taxonomic units, including 9 taxa. The Crustacea was the dominate group representing 29% of the total number of benthic invertebrates. It was noted that there were obvious differences in the total number of sorted individuals in which varied in each location and each month. The highest total number recorded in was st (2) was 4360 including 73 taxonomic units, while the highest total number recorded in April was 2624.The results of The relative abundance index showed that the species insects : Polypedilum sp Were more abundant in St(2 - 6), and dominant in St(6), while the Seinura sp were dominant in St(6), while the other taxonomy units varied from less abundant to rare abundant. Also the results of constancy index showed The which were considered "constant " However the other taxonomy units varied from "accessory " and" accidental" taxonomy units in study stations.The Shanon - Weiner index of totall benthic invertebrates varied from (1.2 - 3.8) bit/Ind, The uniformity index of benthic invertebrates varied from(0.7 - 1), these high values indicate that there is no ecological stress on benthic invertebrates in the study area.The Results of Jaccard Presence - community of similarity showed the highest degree of similarity to be 96% which recorded between St(1) and St(2).The values of the index of spcies richness varied from 1.3 - 15 with the greatest values recorded in April while lower values were in October.Six species of Turbellarian Platyhelminthes that were recorded, from which Stenostomum leucops, Stenostomum bryophilum, Stenostomum unicolor, Gyratrix hermaphrodites, Macrostomum sp, Dalyelliidae, which were considered as new records for Iraq, with Gyratrix hermaphrodites as the most abundant species and representing 25% of the total number of Turbellarian. It was noted that there were obvious differences in the total number of sorted individuals which varied in each location and each month, the highest total number recorded in St 3 was 400, while the highest total number recorded in November was (198).The present study result showed that three species of Nematoda were recorded incuding Seinura sp, Alaimus sp, Dorylaimus sp, Seinura sp as the most abundent species representing 84% of the total number of Nematoda. Spatially the highest total number of 590 individuals was recorded in St (4) , while temporally, the highest total number of 366 was recorded in October.One unidentified species of Gastrotricha was recorded for the first time in Iraq, 102 Ind were sorted these were considered "constant" recording to constancy index 63.8% which were sorted from all stations.A total of 2319 individuals of Rotifera was sorted, these were identified as 15 species that included Philodina sp, Rotaria citrinus, Dipleuchlanis sp, Euchlanis sp, Notholca sp, Ttriploeuchlainis sp, Colurella sp, Lepadella sp, Lecane sp, Proales sp, Cephalodela sp, Synchaeta sp, Hexarthra mira, and finally Brachionus sp which was recorded the highest number of individuals 540 individuals.A total of 1888 individual Annelida were sorted representing 12 species including nine species belonging to the family Naididae (three belong to the sub family Naidinae and six belonging to Tubificoid worms), two species belonged to Aleosomatidae including Aeolosoma hemprichi, Aeolosoma variegatum, and finaly one specie belong to Hirudinea which was Glossiphonia heteroclite, with three 3 ind in all study.The family Aleosomatidae recorded the highest percentage of 58% of the total number of Annelida.The sub family Naidinae including Paranais litoralis, Dero (Aulophorus) furcata, Stylaria lactustris.The highest frequency of 23.6% was recorded by P. litoralis.The Tubificoid worms represent six species which were Limnodrlius hoffmeisteri, Limnodrlius profundicola, L. claparedeianus, L udekemianus, Tubifex tubifex, Branchiura sowerbyi. This study also isolated 6238 individual Crustacea, these were identified as 15 species that included five species belonged to Cladocera, four order belong to copepod, which were recorded the highest percentage 30% of the total number of Crustacea, in addition to Macrobrachium nipponense from Decapoda, Sphaeroma annadalei anndalei from Isopoda, Ostracoda, Amphipoda, Conchostracha. It was noted that there was obvious differences in the total number of sorted individuals which varied in each location and each month, The highest total number recorded in st (2) was 1480, while the highest total number of 730 was recorded in April. The study finds 4297 individual insects groups, were sorted represent seven order includes larvae of Ephemeroptera, Trichoptera, Odonata, (Zygoptera, Anisoptera) Diptera (Culicidae, Chironomus sp, Polypedilum sp) Lepidoptera larvae Hemiptera (Corixidae, Nepa cinerea), and adult of Coleoptera (Dysitidae, Hydrophilidae Elmidae, Curculionidae, Coleoptera larvae), the Diptera larvae were recorded the highest percentage 55 % of the total number of insects groups, and Nepa cinerea was considered as new records for Iraq.This study showed two class from Mollusca, 1956 Ind were sorted, including Gastropoda and Pelecyopoda.The Gastropoda which were recorded the highest percentage 94% of the total number of Mollusca, these were identified to physa acuta, Lymnaea sp, Melonoides tuberculata, Melnopsis nodosa, Theodoxus sp, physa acuta which was the greatest percentage 41% of the total number of gastropoda. pelecyopoda which were including Pseudodontopsis euphraticus, Tigridis Unio, Corbicula fluminea, Corbicula fluminali

تكامل جرعة منخفضة من مبيد الترفلان مع مخلفات زهرة الشمس في مكافحة الادغال وتحسين نمو محصول الماش لتقليل الاعتماد على المبيدات والحد من مخاطرها Integration of Reduced Dose of Trifluralin Herbicide With Sunflower Residues For Weed Control In Mungbean Field

اسم المؤلف: اﺭﻭﻯ ﻋﺒﺪ ﺍﻟﻜﺮﻳﻢ ﺗﻮﻓﻴﻖ
اسم المشرف: اﺑﺮﺍﻫﻴﻢ ﺷﻌﺒﺎﻥ ﺍﻟﺴﻌﺪﺍﻭﻱ
الموضوع العام: علوم الحياة
السنة: 2014
الموضوع الدقيق: النبات - الفسلجة
الدرجة: دكتوراه
الجامعة: جامعة بغداد
اللغة: الانكليزية
مكان الجامعة: بغداد
الصفحات الاولى:
المستخلص: Two field experiments, several greenhouse and laboratory experiments were conducted during the course of study to evaluate the allelopathic potential of two sunflower (Helianthus annuus L.) cultivars on companion weeds and weeds grown in mungbean (Vigna radiata L. R. Wilczek) field alone and in combination with reduced rate herbicide, and to determine the chemical and genetical bases of allelopathic traits in the test cultivars. The aim of the first experiment was to test whether the variation in weed growth between the sunflower cultivars (Shumoose and Sin Altheeb), which was observed in the field, was due to differences in their allelopathic potential. Results showed the ability of both cultivars to reduce weed population and biomass with the superiority of Shumoose cultivar in suppression of weed density at 60 and 120 days after sowing compared to Sin Altheeb. Weed biomass was significantly reduced up to 90 and 71% by Shumoose and Sin Altheeb cultivars, respectively. Stair case experiment indicated that root exudates of Shumoose cultivar showed more suppression to weeds than Sin Altheeb giving additional evidence for the superiority of Shumoose cultivar in its allelopathic weed suppression. Chemical analysis by High performance liquid chromatography indicated the presence of 9 compounds in root exudates of Sin Altheeb and 8 compounds in Shumoose, and all are Phenolic in nature. However, total of the isolated phenolics was doubled in Shumoose than in Sin Altheeb. Most of the isolated chemicals are reported to have inhibiting ability for germination and growth of plants, including weeds. Second field experiment was undertaken to explore the response of weeds and mungbean crop to soil incorporated with sunflower residues in combination with lower rate of a pre - plant herbicide (trifluralin). Sunflower residues of the two cultivars Shumoose and Sin Altheeb at 3.2 and 6.4 t ha - 1 were used either alone or in combination with trifluralin at 1.2 L ha - 1 (50% of label rate). Weedy check (control), trifluralin at full label rate (2.4 L ha - 1), and weed free treatments were also included for comparison. Plots treated with 50% of label rate of herbicide and amended with sunflower residues of cultivar Sin Altheeb recorded least weed density and dry biomass and this suppression was much greater than the residue treatments alone and more than cultivar Shumoose. Application of herbicide at 50% rate in plots amended with Sin Altheeb residue resulted yield 64 % more than with the label rate of herbicide treatment. Chromatographic analysis of sunflower amended field soil revealed the presence of several potent allelopathic compounds in the residues of both cultivars with greater quantity (355.5 µg/ml) in Sin Altheeb than in Shumoose (250.9 µg/ml). Dynamics of release, decomposition and degradation of allelochemicals into the soil showed that different compounds exhibited differential behavior for these processes. Overall quantity of allelochemicals started to increase after 2 weeks of decomposition and peaked at 4 week of decomposition (180.1 ppm) then declined sharply in their quantities thereafter. Periods indicating higher quantities of total phenolics as shown by chromatographic analysis was coincided with the periods in which higher suppressive activity against weeds grown under field conditions. Bioassay of sunflower residues decomposed in soil at different times on Echinochloa colonum L, one of the weeds dominated the mungbean field, revealed that residues of both cultivars suppressed growth of E. colonum weed. The phytotoxicity started after 2 weeks and persisted for 8 weeks. However, Sin Altheeb residues showed greater inhibition than Shumoose cultivar at the last three decomposition periods. Shumoose residues recorded appreciable reduction to the growth of test weed compared to Sin Altheeb. The effect of residues of both cultivars on chlorophyll content and ions uptake in Amaranthus retroflexus L. weed revealed that residues of both species reduced chlorophyll content of leaves and the reduction increased with the increased residue rate. Sin Altheeb cultivar residues were more inhibitory than Shumoose at the lower residue rate. In the same weed, ions uptake was significantly averted by the residues of both cultivars. P and K was significantly increased over control, while Ca, Mg an Fe were found to be decreased over control due to application of sunflower residues in soil at 8 g per kg soil. N was the only test element that did not significantly influence by the residue treatments. No significant differences were found in the test ion uptake between the test sunflower cultivars. Results of using RAPD technique on the sunflower genomic DNA revealed that all the 19 primers used in this study scored different amplification monomorphic and polymorphic bands in the tested genotypes with 12 primers generated polymorphic bands. These bands present in one cultivar and absent in another. They could be responsible for allelopathic trait or secondary compounds associated with this phenomenon. Further work is recommended to analyze the sequence of this band to find out whether it is related to allelopathic trait or not.
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