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دراسة تاثير تركيزانابيب الكاربون النانوية متعددة الطبقات على الخصائص الفيزيائية لمتراكبات الايبوكسي == Study The Effect of Multi Walled Carbon Nanotubes (MWCNTs) Concentration on Physical properties of Epoxy composites

Author name: الفت احمد محمود

Supervisor name: خالد رشاد الراوي | عدوية جمعة حيدر

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Doctorate

University: University of Baghdad - College Of Science For Girls - Physics Department

Language: English

University location: Baghdad

First pages:

Abstract: Multi wall carbon nanotubes (MWCNTs) have excellent mechanical, electrical, and thermal properties. When MWCNTs incorporated in to polymer, that’s leads to better improvement in mechanical, electrical, and thermal properties result at low MWCNTs content. Due to the change in the electrical and mechanical properties MWCNTs / Epoxy composites have attracted significant research interest specially due to their potential for application in active control of strain sensing in composites structure or as strain sensor .Different type of MWCNTs, long and short (L - MWCNTs & S - MWCNTs) were used as reinforcement in epoxy resin with volume fraction ( 0.1,0.2, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0 ,4.5, & 5%) respectively were used to prepare epoxy composites in order to examine and study some of their mechanical properties ( tensile strength, Young's modulus, flexural strength, fracture toughness, flexural modulus, Impact strength, and microhardness ), conductivity properties (AC conductivity, thermal conductivity), and morphology properties (SEM,FTIR). Direct mixing processes use to prepared (Epoxy / MWCNTs) composites, its involved use ultrasonic and magnetic stirrer bar mixing process to disperse the MWCNTs into the epoxy resin system. The results shown an improves in the mechanical, thermal, and electrical properties with increase volume fraction (0.1 to 2%), and then decreased with further increasing the MWCNTs content but stay higher than of pure epoxy. At (1.5%) we observed enhancement in tensile strength (28.19%, 15.74%) and Young's modulus (35.71%, 30.95%) for L - MWCNTs and S - MWCNTs respectively, and the higher enhancement in flexural modulus and flexural strength due to 2% vol. fraction of L - MWCNTs reached to (71.43 %, 102.26 %). The high impact strength and microhardness values result at (1. 5%L - MWCNTs) reached to (823.996%), and (41,102%) respectively.Better improvement in thermal conductivity and AC conductivity result at 2% volume fraction for both MWCNTs types compare with pure epoxy. The high thermal conductivity values due to L - MWCNT reached to (369.31%) or three times from the thermal conductivity of pure epoxy, compare with the value of enhancement for S - MWCNTs (183.39 %).Investigations of electrical properties of MWNT/polymer show a significant increase of electrical conductivity with the increase of the MWCNTs content. The AC. electrical conductivity of the sample with 2 % vol. fraction L - MWCNTs reached to four orders of magnitude higher than that of the pure polymer at a frequency range of (5E 4 to 5 E6) Hz, its present(9.66E - 7 to 5.78E - 5 Ω/cm) compare with the AC. electricalconductivity for S - MWCNTs ( 6.57 E - 11 to 2.24E - 5 Ω/cm) at same volume fraction and frequency range and with the electrical conductivity of pure epoxy (4.5E - 12 to 6.2E - 9 Ω /cm).Scanning Electron Microscope images illustrate the morphology of tensile fractured surface of EP/MWCNTs composites, although the morphologies of tensile fractured surface show ductile fracture with dispersed stresses in more than one crack propagation. Increased roughness and ductile behavior shown with increased volume fraction of MWCNTs. Above 2% vol. fraction of MWCNTs we shown increase the agglomeration that’s lead to decrease in properties of epoxy composites.

المتحسسات الطبيعية للخلايا الشمسية ذات الصبغات المتحسسة على قواعد اوكسيد الخارصين == Natural Sensitizer for Dye - Sensitized Solar Cells Based on Zinc Oxide

Author name: اوراس طارق شاكر

Supervisor name: صلاح عبد الله حسون | رعد محمد صالح الحداد

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: University of Baghdad - College Of Science For Girls - Physics Department

Language: English

University location: Baghdad

First pages:

Abstract: This thesis focused on the study of dye - sensitized solar cells (DSSCs) based on ZnO nanoparticle as a semiconducting layer with two natural dyes.The present study began by synthesizing ZnO nanoparticles by two methods. The first method ZnO nanoparticles prepared by sol - gel method with (0.1, 0.2, 0.3 M) zinc acetate and then thin films of zinc oxide prepared by using spin coating technique with thickness equal to (109 nm), while the second method technique of ZnO nanoparticles prepared by sol gel method (0.2 M) from zinc acetate was selected as the optimum concentration to make thin film of zinc oxide (In the form of a paste) by using doctor - blade technique with thickness equal to (111nm).The effective mass model for spherical particles (Brus equation) for ZnO nanoparticles were (1.3147, 1.4056, 1.6379 nm) for three concentration.The characteristic of the prepared films on glass substrates have been examined by X - ray diffraction analysis (XRD), UV - Vis spectroscopy, photoluminescence spectrum (PL), scanning electron microscopy (SEM), Atomic Force Microscope (AFM) and Thermo Graviometric Analysis (TGA).In both methods , ZnO films were prepared on transparent conducting oxide (ITO) coated glass then addition of chlorophyll as sensitized dye which extracted from spinach leaves and anthocayanin pigment from pomegrenate juice and they were used as the working electrode (anode) of dye - sensitized solar cell (DSSCs).The absorption spectra of all dyes were performed by UV - Visible spectroscopy which showed that the dye absorbed light in the visible region from (400 nm) for chlorophyll pigment and (510 nm) for anthocyanenpigment.The (I - V) characteristic curves of the fabricated tow cells were measured and studied at constant light intensity. All photovoltaic parameters of the cells were presented. The results revealed that the extract of Pomegranate by using spin coating lead to the highest efficiency (15%).

دراسة تاثير معقداث معدنية على الخواص البصرية والكهربائية وفوق السمعية لاغشية بولي فينيل الكحول وبولي فينيل استيت المحضرة بطريقة الصب == Studying the Effect of Metal Complexes on the Optical, Electrical and Ultrasound Properties of PVA and PVAc Films Prepared by Casting Method

Author name: الاء جواد كاظم الكدساوي

Supervisor name: ندى خضير عباس | مجيد علي حبيب

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: University of Baghdad - College Of Science For Girls - Physics Department

Language: English

University location: Baghdad

First pages:

Abstract: The present study focused on the modification of the structural, optical and electrical properties and acoustical parameters of poly (vinyl alcohol), poly (vinyl acetate) and polyblend of (poly (vinyl alcohol) + poly (vinyl acetate)) by adding (0, 3, 6 and 9) wt.% of metal complexes, which are : Chloropentaaminecobalt (III) chloride [Co(NH3)5Cl]Cl2 and Potassium Dioxalatocuprate (II) Dihydrate K2[Cu(C2O4)2].2H2O. The mentioned composites films were prepared by solvent casting technique.All samples were structurally investigated by X - ray Diffraction XRD, Fourier transform infrared spectroscopy FTIR, Scanning electron microscope SEM which revealed that there is an association between the polymer matrix and the additive.The optical data at wavelengths range (190 - 800) nm, were analyzed and interpreted in term of the theory of phonon assisted indirect electronic transition. It is observed that energy gap decreases as the metal complexes content increases. The smallest obtained energy gap is 1.86 eV for PVAc / [Co(NH3)5Cl]Cl2 composites films. The refractive index, extinction coefficient, and the dielectric constant increase with increasing the concentration of the additive.The D.C electrical conductivity increases with temperature which exhibited a semiconductor behavior. Also the activation energy values are decreases with increase of additive concentration.The A.C electrical conductivity is increased with increasing applied electrical field frequency (102 to 5*106) Hz and with additive concentration. The dielectric constant and dielectric loss were decrease with increasing the frequency and increase with the concentration of the additive.The acoustical parameters have been measured in frequency range of (25, 30, 35 and 40) KHz. Metal complex enhances the ultrasonic absorption coefficient of polymer matrix. The velocity decreases with increasing metal complex.

دراسة متانة الربط الانتشاري بين السيراميك والمعادن في الحالة الصلبة == Investigation of the Relaibility of Diffusion Bond Strength Between Ceramic - Metals in Solid State

Author name: اروى غازي ناجي الطائي

Supervisor name: زاريه ازات سركيس | ثامر عبد الجبار جمعة

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: Al-Nahrain University - College Of Science - Physics Department

Language: English

University location: Baghdad

First pages:

دراسة الفجوات المصنعة بهيئة عيوب بواسطة الاشعة السينية لمصبوبة المنيوم ومفاصل لحام الفولاذ == X - ray Radiographic Study of Simulated Voids - Like Defects in Aluminum Casting and Welded Joints in Steel

Author name: فرقد رشيد سعيد الزبيدي

Supervisor name: مازن فضيل محروك | ثامر عبد الجبار جمعة

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: Al-Nahrain University - College Of Science - Physics Department

Language: English

University location: Baghdad

First pages:

Abstract: This project investigates the detection and evaluation of imperfections in internal structures of castings and welded joints by x - ray radiography. Optimum radiography conditions that lead to clear and high contrast image on the radiograph were studied.Equations derived earlier for finding the size and depth of defects in castings were used in this project to test their applicability to a wide range of geometrical parameters used in radiography.The importance of non - destructive testing NDT in industry is discussed. X - ray radiography being one of the NDT techniques, has some privilege over other techniques. For example, welded joints sometimes contain internal flaw or blowholes that may escape detection by other NDT techniques but can not escape detection by x - rays. Two kinds of samples are prepared for radiography. The first sample is aluminum casting through which two different sizes of steel spheres are included. This sample was radiographed from two opposite sides and the x - ray films were analyzed.The second sample is steel plates which are welded by arc welding and then radiographed by x - rays.Imperfections in this sample such as incomplete root penetration, undercut and porosity were detected by x - ray radiography. Different conditions influencing the preparation and radiography of the above samples were studied. The prepared welded sample was radiographed three times for different high voltages (120,140,160) kV respectively with an exposure time of (80) second. The best quality image where the defects can be detected clearly if its size is (5%) of the radiographed object using (120) kV and (140) kV. Moreover the results show that the optimum film gradient was found at (140)kV and the contrast is better than obtained with (120)kV while darkening image was found at (160)kV.In field of the aluminum casting, the two equations were derived earlier proved their capabilities as a right method for identification each of size and depth of such defects in castings and welded joints

دراسة تحضير مادة كاؤلين دويخله كمالات في صناعة الورق == A STUDY OF USING KAOLIN DUEKHLA AS FILLER IN THE PAPER INDUSTRY

Author name: علي رزاق عبد الرضا

Supervisor name: ازهار جواد داوود

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: Al-Nahrain University - College Of Science - Physics Department

Language: English

University location: Baghdad

First pages:

Abstract: يتناول البحث دراسة تاثير خفض نسبة اكاسيد الحديد والتيتانيوم السيليكا الحرة من اطيان كاؤولين دويخله لغرض استخدامها كمالات في صناعه حشوه الورق.لما لهذه المكونات من تاثير على خواص الحشوه. يحتوي خام الكاؤولين المستخدم في هذا البحث على حوالي 1.7% من اوكسيد الحديد و1.2% من اكسيد التيتانيوم و51.16% من اوكسيد السيلكون من ضمنه12% من السيليكا الحرة. ويعتبر وجود هذه النسب من اوكسيد الحديد والتيتانيوم والسيليكا الحره ضمن الخام غير مرغوب في صناعة الورق , لقد اجريت معامله كيميائية لكاؤولين دويخله بهدف تنقيته من الشوائب التي يمكن ان تذوب بحامض الهيدروكلوريك حيث ثم الاستمرار بغسل الكاؤولين بالماء المقطر لتصل درجةpH الى قيمة خمسة . ثم تجفيفه لمدة 3 ساعات بدرجة حرارة من (40 - 60) م0 وبعدها تم طحن المسحوق بالمطحنة البورسلينيه لمدة 5 ساعات. ثم نخل المسحوق بمنخل ذو حجم حبيبي 65 مايكرون ليتم استخدامه في الدراسة. استخدمت في هذا البحث طريقة الترسيب, وقد اعتمد في طريقة الترسيب على فصل الاكاسيد المذ كوره من الاطيان استخدام ماده مشتته هي فوسفات الصوديوم. كما تم دراسة تاثير الماده المشتتة على لزوجة الخليط حيث تبين ان بزيادة الماده المشتته تقل نسبه اللزوجة الى ان تصل الى اقل قيمه. كما تم دراسة تاثير كبريتات الخارصين المائية كماده قاصرة على نموذج المجموعه M4 وباوزان تراوحت( بين10 الى 22 غم) من الماده القاصرة كخطوه ثانيه لتقليل نسبه الشوائب المذكورة والتي بالنتيجة تؤدي الى زيادة نصوعيه كاؤولين دويخله حيث تم ازالة حوالي 73% من اوكسيد الحديد,91% من اكسيد التيتانيوم, 15% من اوكسيد السيلكون, و50% من السيليكا الحرة في نموذج المجموعه G7. النتائج المستحصله تبين كفاءة هذه الطريقة في فصل الشوائب الغير مرغوب فيها اذ انخفضت نسبة اوكسيد الحديد المتبقي في الماده المعالجه (من 1.71% الى0.3%), واكسيد التيتانيوم ( من1.2% الى 0.09%), واوكسيد السيلكون (من 51.16% الى 39.7%). وكون الطريقة المتبعه في الفصل هي طريقة فيزيائيه فلم يلحظ حدوث تغير في خواص الخام بعد المعالجه, مما يمكنا استخدام الخام المعالج بهذه الطريقه في صناعات اخرى. | This study is carried out to investigate the possibility of using Iraqi clay; Duekhla kaolin as filler in the paper industry by reducing the percentage of iron oxide, titanium dioxide, and free silica. Duekhla Kaolin containe about 1.7% iron oxide, 1.2% titanium dioxide, 51.16% silicon dioxide, and 12% free silica. The existence of these oxides in kaolin is undesired in paper - making. The process started by washing Duekhla kaolin with (4N) HCl to remove all the soluble oxides which are not required in paper making. The washed kaolin then separated using filter papers and under a sequence of operations of dilution and filtering until the pH - value become 5. The separated materials then dried at temperature range 40 - 60 °C for 3 hours, and the dried powders then milled using ball mill of porcelain body, with different sizes of spheres, for 5 hours. Finally the powders of Duekhla Kaolin sieved with a sieve of 65 μm. The sedimentation method is used for the separation of the above mentioned oxides from clay by using sodium phosphate as dispersant agent. The viscosity parameter of the mixture was studied under the effect of the dispersant agent, and it was found that with the increasing of added dispersant agent the viscosity decreased to a minimum value which is equal to 0.31dyne.cm2/sec, after that the viscosity increased with the increasing of adding sodium phosphate. The study performed; depending on the minimum viscosity value corresponds to the dispersant amount added. The zinc hydrosulfite was used as a bleaching agent in a second step for removing the undesired impurities which implies to raise the brightness degree of kaolin Duekhla as a result. As a result of these treatment, the undesired oxides are reduced from sample G7 by the following percentages; (73% of iron oxide, 91% of titanium dioxide, 15% of silicon dioxide, and 50% of free silica removed), the results of this study reveals that the oxides percentages decreased from (1.71% to 0.3% in iron oxide, 1.2% to 0.09% in titanium dioxide, and 51.16% to 39.7% in silicon dioxide). The crystal structure of kaolin did not change after these treatments to decrease the percents of impurities in this clay to be used as filler in the paper industry

تاثير الحجم الحبيبي لاسود الكاربون على الخواص الميكانيكية لمتراكبات البيوتادين == Effect of Carbon Black Particles Size on the Mechanical Properties of Butadiene Composites

Author name: علي نزال عواد

Supervisor name: سمير حسن هادي النصراوي

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Higher Diploma

University: University of Babylon - College Of Education For Pure Sciences - Physics Department

Language: English

University location: Babylon

First pages:

تحضير ودراسة خواص مادة اوكسيد الرصاص النانوية == Preparation and Study of ( PbO ) Nanomaterials Properties

Author name: علي فاضل مرموص عبود

Supervisor name: عبد العزيز عبيد موسى العكيلي

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: University of Babylon - College Of Science - Physics Department

Language: English

University location: Babylon

First pages:

Abstract: في هذا العمل تم تحضير اغشية رقيقة من اوكسيد الرصاص (PbO) باستخدام تقنية الرش الكيميائي الحراري وهي طريقة سهلة ومناسبة للترسيب على مساحات كبيرة. استخدم كلوريد الرصاص المائي PbCl2.2H2O كمصدر للحصول على جسيمات الرصاص. تم انماء مزيج اغشية (PbO) بدرجات حرارة مختلفة °C (200, 250 ,300 , 350, 400 و450) على قواعد زجاجية وقد استخدم غاز النتروجين بضغط (4.5 بار) كغاز حامل . تم فحص التركيب البلوري للاغشية بطريقة حيود الاشعة السينية ( XRD) اوضحت النتائج ان جميع الاغشية المحضرة كانت متعددة التبلور واظهرت النتائج بان الاغشية المرسبة بـ (200 °C ) , ( (250 °C ,( 300°C) , و( 350 °C )كانت بقمة (002) بينما الاغشية المرسبة بـ (400°C و450 °C ) كانت تحمل القمة (112) القمم. في حين اظهرت النتائج وجود تحول من النظام الرباعي القائم الى النظام المعيني القائم فوق (350 °C) . درست طبوغرافية السطح للاغشية المحضرة باستخدام مجهر القوى الذرية (AFM) والمجهر الالكتروني الماسح) SEM) ومبدد الطاقة للاشعة السينية (EDX) . الحجم الحبيبي لجسيمات (PbO) النانوية وجد انه يقل بزيادة درجة حرارة السطح . ام فحص (EDX) اظهر احتواء الاغشية المحظرة على عناصرPb ) وO ) كما هو متوقع ، مشيرا الى تشكيل اغشية(PbO) نقية. الخصائص البصرية للاغشية المحضرة بسمك (177nm) تم دراستها باستخدام قياسات النفاذية البصرية في المنطقة الطيفية (250 - 760 nm) . نتائج النفاذية كانت اكبر من 80% . فجوة الطاقة المباشرة للــ (PbO) كانت ضمن مدى 1.61 - 2.80) eV) ، والتي تتزايد مع زيادة درجة حرارة السطح . الثوابت البصرية كمعامل الانكسار ومعامل الخمود وثوابت العزل تم حسابها لجميع الاغشية المحضرة . الخصائص الكهربائية مثل التوصيلية الكهربائية المستمرة وتاثير هول تم دراستها ايضا . وكانت نتائجها تشير الى ان الاغشية من النوع السالب ( n - type ) وتمتلك طاقتي تنشيط ( Ea1 , وEa2 )، وقد وجد ان التوصيلية الكهربائية المستمرة تزداد مع زيادة درجة حرارة سطح القاعدة. | In this work, thin films of lead oxide (PbO) were prepared by using a homemade chemical spray pyrolysis (CSP) technique, which is a simple, inexpensive and suitable technique for large deposition area. The lead chloride PbCl2.2H2O is used as a source of lead particles. (PbO) thin films with different substrate temperatures (200, 250, 300, 350, 400, and 450) ̊C have been grown on clean glass substrate with the nitrogen carrier gas (4.5 bar).The crystal structures were examined by X - ray diffraction (XRD) analysis. The result shows that all the prepared films are polycrystalline structure. It indicates that the films coated at 200°C, 250°C, 300°C, and 350°C are (002) oriented, while the films deposited at 400 °C and 450 °C are (112) oriented. Above 350 °C, the pure tetragonal nature deteriorated and the peaks corresponding to orthorhombic phase are observed. The surface morphology of the deposits films have been studied by using atomic force microscopy (AFM), scanning electron microscopy (SEM) and energy dispersive X - ray (EDX). The grain size of the (PbO) nanocrystalline observed at the surface decreases with increasing of substrate temperature, leads to increase in the surface roughness. (EDX) shows that all the films contain the elements (Pb and O) as expected, indicating formation of the (PbO) films with high purity. The optical properties of the films, which are prepared with thickness of (177 nm), have been determined by using the optical transmittance measurements in the spectral region from (250 - 750) nm. Transmittance results is upper than 80%. Direct energy gap for (PbO) is in the range (1.61 - 2.80)eV, it increases with increasing substrate temperature. The optical constants such as refractive index, extinction coefficient and dielectric constant have been calculated for all preparing films. The electrical properties include D.C conductivity and Hall effect are studied. The results show that the prepared films are n - type, and have two activation energies (Ea1 and Ea2). It is found that the electrical D.C conductivity increased with the increase of substrate temperature.

دراسة الخصائص لفيرايت النيكل المطعم بالكوبلت والكروم == Studying The Properties of Co And Cr Doped Nickel Ferrite

Author name: هند محمد حسن

Supervisor name: فرح طارق محمد نوري

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: University of Baghdad

Language: English

University location: Baghdad

First pages:

دراسة تاثير الحجم البلوري في خواص اوكسيد الكالسيوم المحضر بالتفكك الحراري == A Study of The Effect of Crystallite Size In Cao Properties Prepared By Thermal Decomposition

Author name: امل دشر حسين الربيعي

Supervisor name: عباس فاضل عيسى | ستار عبود عباس

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: Wasit University - College Of Science - Physics Department

Language: English

University location: Wasit

First pages:

دراسة تاثير اشعة كاما على الخواص التركيبية والكهربائية للبولي انيلين المحضر مختبريا == Study the Effect of Gamma Radiation on the Structural and Electrical Properties of Prepared Polyaniline

Author name: زهراء عبد الامير حسين المظفر

Supervisor name: سلمى محمد حسن

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: University of Baghdad

Language: English

University location: Baghdad

First pages:

محاكاة العزل الحراري والميزات الميكانيكية والكهربائية للمتراكبات النانوية المنتحرة == Simulation Of Thermal Insulation, Mechanical, And Electrical Characteristics Of Sacrificed Nanocomposites

Author name: علي جابر يوسف الموسوي

Supervisor name: بهجت بهلول كاظم

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Master

University: Mustansiriyah University - College Of Science

Language: English

University location: Baghdad

First pages:

الانماء البلوري والخواص الالكترونية لشبه الموصل (CdSnP2) وتصنيع وصلة بوليمر موصل (PT/ CdSnP2) == Crystal Growth And Electronic Properties Of Semiconductor Cdsnp2 And Fabrication Of Conducting Polymer (PT/CdSnP2) Junction

Author name: صلاح عبد الجبار جاسم

Supervisor name: K. M. Zaidan

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Doctorate

University: University Of Basrah - College Of Science

Language: English

University location: Basrah

First pages:

استخلاص مسحوق الالومينا طور ـ من الكاؤولين العراقي ودراسته == The Investigation Of The ? - Alumina Powder Extracted From Iraqi Kaolin

Author name: ايوب صابر كريم

Supervisor name: فاضل عبد رسن | طارق عبد الرضا الظاهر

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Doctorate

University: University of Baghdad - Ibn Al-Haytham College Of Education For Pure Sciences - Physics Department

Language: English

University location: Baghdad

First pages:

خواص ترانزستور تاثير المجال ذو البوابة المعزولة (ترانزستور الاغشية الرقيقة) == Characteristics of Insulated Cate Field Effect Thin Film Transistor ( TFT)

Author name: اسماعيل خلف عباس

Supervisor name: مصطفى عرب محمد | يحيى نوري الجمال

General topic: Physics

Specific topic: Solid State and Materials Physics

Degree: Doctorate

University: University of Al Mosul - College Of Science

Language: English

University location: Mosul