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بناء ودراسة منظومات تحلية المياه وتسخينها باستخدام الطاقة الشمسية == CONSTRUCTIN AND STUDY THE PERFORMANCE OF WATER DESALINATION AND HEATING SYSTEMS USING SOLAR ENERGY

Author name: رسل داود سالم الخفاجي

Supervisor name: جاسم مهدي الاسدي | عقيل يوسف هاشم

General topic: Physics

Specific topic: Solar Energy Physics

Degree: Doctorate

University: University Of Basrah - College Of Education For Pure Sciences

Language: English

University location: Basrah

First pages:

تقييم اداء تصاميم جديدة لسخان الماء الشمسي في مدينة البصرة30.5°N == Evaluation of new designs of solar water heater in Basrah city 30.5° N

Author name: كوثر كاظم منخي

Supervisor name: نوري حسين نور الهاشمي | جاسم مهدي الاسدي

General topic: Physics

Specific topic: Solar Energy Physics

Degree: Doctorate

University: University Of Basrah - College Of Education For Pure Sciences

Language: Arabic

University location: Basrah

First pages:

Abstract: The main goal of the current study is the benefit of solar energy as the origin of any renewable energy for producing a hot water through multiple solar collectors each one with overall capacity about 26 liter so that, these collectors arranged in sequential order within the construction of the house without affecting the artistic aspects of the house. These collectors will capable of providing the house the needs of hot water for domestics use especially during the winter season. It will reduce the amount of energy such as electricity and or kerosene or any other source of energy that usually used in Basrah.The present study is included the design and manufacture of seven models of solar collectors. The tools that have used into manufactured of these collectors are some cheap materials that are available in Basrah markets. These models are differ from each other by some aspects with additions properties. The thermal performance and efficiency have a test and then choose the best one in order to use it in four different modern designs of solar heaters.the thermal performance of the manufactured heaters models are tested by calculate the amount of hot water supply under difference weathers conditions in the city of Basrah, which sorts as a large abundance of solar radiation. It also test two types of arrangement of difference parts of heaters. The practical test has been proven the advantage of linking hot water reservoir tank with cold water and then linking the whole system with the hot water tank. This arrangement will allow of gradual warming of the water, which allows the consumer get the hot water directly from the system and not from the reservoir. This study include what is called a feedback arrangement system in order to increase the benefit from solar radiation. In this case, the hot water will recycle to allow for moreexposure to solar radiation repeatedly, that in the case of non - use or the case of little use.All the experiment Steps carried out on the roof of the department of physics building's in the college of education for pure Sciences, Basrah university in the northern city of Basrah, located at latitude 30.50 N and longitude 47.80 E during the winter season 2013 - 2014. Al thought this winter characterized by abundant of rain and clouds the models No.5 shows very good results interm of high temperature of hot water and the amount of it. The temperature was reach (900 C). In addition the model No.4 which depend on the technique of feedback idea shows a good result interm of the amount of hot water produce which reach (146 liter) at a temperature about (500 C) with in only five hours starting at 10 : 00 am until the 2 : 00 pm.In order to develop the optimum dimensional measurements of the solar collectors a mathematical model was developed to predict the output temperature of hot water from the solar collectors or from the radiator in general for different dimensions. This model is working successfully and achieved data that in comparable with our experimental ones. The experimental results have been analyzed theoretically to compare the performance of all solar collectors of the heaters, in different weather conditions and in a same time.

قياس مستوى الاشعاع الطبيعي في منطقة القبلة في محافظة البصرة == The Measurement of Natural Radiation Level in Qubla District in Basrah Governorate

Author name: محمد قاسم خضير

Supervisor name: عبد الرضا حسين صبر

General topic: Physics

Specific topic: Solar Energy Physics

Degree: Master

University: University Of Basrah - College Of Education For Pure Sciences

Language: Arabic

University location: Basrah

First pages:

Abstract: The aims of this study is to measure the natural radioactivity in the selected areas from the province of Basrah using solid state nuclear tracks detectors SSNTDs both types of CR - 39 and LR - 115type Π to determine the concentration of radon gas. Gamma spectrometer Sodium Iodide NaI was used also to find specific activity of 238U, 232Th, 226Ra and 40K, in soil. This action is considered necessary from the point of view prevention of radiation hazard associated natural radioactivity of the soil in those areas and its impact on them. The first chapter includes an introduction to radiation and to shed light on the sources of radiation, natural and man made. Chapter 2 contains a highlight of radon gas and to identify the health effects of this gas as important sources of radiation in nature that can enter the human body through breathing. Chapter III contains the identification of the study area and samples collection of and preparation methods of the samples. The preparation of the measuring cylinder for measuring radon gas concentration at dwelling presented in the area. The natural gamma radioactivity measured by the NaI(Tl), also presented in the same chapter. This chapter also clarified; the equations used in calculations of radon gas concentration, the equations used to measure the specific activity of 238U, 232Th, 226Ra and 40K in selected soil samples taken from the area and assess the hazard indiceis caused by radioactivity (Raeq). Chpter 4, contains a review of methods used in the measurements includes materials and equipment used. Chapter five includes our findings from this study which is shows that, The radon gas concentration in dwelling has been measured found to be in the range of; 11.91 ± 1.3 Bq / m3 to 606.7 ± 66.52Bq / m3 with average value equal to 78.51Bq / m3, which is much less of the value specified by the United States Environmental Protection Agency EPA a 150Bq / m3 and this does not constitute a high risk to the health. The next part of this research; is the measurement of the natural gamma radiation emitted by the surface soil. We found that the lowest value for the concentration of isotope 226Ra is 2.5Bq / kg and maximum value was 147.4 Bq / kg with range of 47.3 Bq / kg. The minimum gamma concentration of 238U is 0.09 Bq/kg, while the maximum value is 94.7Bq / kg and an average of 23.5Bq / kg .The minimum concentration of 232Th is 1Bq / kg and maximum value of 83.9 Bq / kg at a range of 41.1Bq / kg. The minimum value of 40K was found to be 1 Bq / kg and the greatest value is 1048.6 Bq / kg and an average of 499.2 Bq / kg.All of these results are within the rangeof permitted and there is no rise in the value of the concentration of radioactive elements naturally calls for action to clean up pollution action cleaning , As for the soil of the region have indicated results found that the greater the intensity of the effects recorded in the soil of the area studied detector CR - 39 is 56187.5±3533.9 Track/cm2 while the lowest value was 1437.5±90.413 Track/cm2,which can be relied upon in radon concentration and content of radium account effective, but for the detector LR - 115TYPE it was found that the greatest density of the recorded Track 17250±1085 Track/cm2,while the less dense traces recorded Track 188±12Track/cm2 .

دراسة الخواص البصرية والكهربائية لبوليمرPoly (3 - Hioxy Thiophene, 2 - 5 dily) (P3HT) وتاثير اضافة صبغة Orang G على تلك الخواص مع تطبيقه في صناعة الخلايا الشمسية == Study of the optical and electrical properties of Poly (3 - Hioxy Thiophene, 2 - 5 dily) (P3HT) and the effect of Orang G on the properties and it's application in Fabrication of solar cells

Author name: فاطمة حميد مالك التميمي

Supervisor name: وليد علي حسين

General topic: Physics

Specific topic: Solar Energy Physics

Degree: Master

University: University Of Basrah - College Of Education For Pure Sciences

Language: Arabic

University location: Basrah

First pages:

Abstract: تم في هذه الدراسة تحضير اغشية رقيقة من بوليمر P3HT غير المشوب والمشوب بصبغة Orang G وبنسب تشويب Vol(1%,3%,4%,5%,7%,10% ) وبوليمر PEDOT : PSS غير المشوب وقد حضرت الاغشية بطريقة طلاء البرم .Spin Coating شخصت الاغشية البوليميرية المحضرة بواسطة الاشعة السينية X - Ray والاشعة تحت الحمراء FT - IR . اظهرت نتائج فحص الاشعة السينية X - Ray ان النماذج المحضرة لبوليمر P3HT غير المشوب والمشوب، اذ تكون اغشية البوليمر P3HT غير المشوب ذات تركيب عشوائي ونتيجة التشويب بدات النماذج المحضرة تكون شبه بلورية نتيجة تاثير صبغة Orang G المستخدمة. كذلك شخصت النماذج المذكورة انفا بطيف الاشعة تحت الحمراء FT - IR اذ اظهرت النتائج ان لهذه الاغشية مجاميع فعالة واضحة. درست كذلك الخواص البصرية لجميع الاغشية المحضرة كالامتصاصية(A) والنفاذية (T) والانعكاسية R)) ضمن مدى الطيف (300 - 900nm)،ودرس ايضا معامل الامتصاص(α) ومعامل الخمود(K) ومعامل الانكسار(n) وثابت العزل الحقيقي (ϵr) وثابت العزل الخيالي (ϵi) والتوصيلية البصرية (σopt) كدالة للطول الموجي . اظهرت الدراسة ان طيف الامتصاصية لاغشية المواد قيد الدراسة ضمن منطقة الطيف المرئي، حيث تم تسجيل اعظم قمة لبوليمر P3HT غير المشوب والمشوب بصبغة Orang G عند الطول الموجي 530 - 572nm)) وكتف (Shoulder) عند الطول الموجي 600nm .اظهرت الدراسة ان طيف الامتصاص لبوليمر PEDOT : PSS غير المشوب يكون ذات امتصاصية واطئة بحدود (0.1a.u) ويكون ذو نفاذية عالية تصل الى 85% .حسبت فجوة الطاقة البصرية للبوليمر P3HT غير المشوب فكانت (1.95eV) وتتناقص قيمة الفجوة مع زيادة نسبة التشويب حتى تصل الى (1.88eV)عند نسبة التشويب 5% Vol - (O.G) - P3HT،كذلك تزايد في كلا من معامل الامتصاص(α) ومعامل الخمود(k). تم حساب التوصيلية الكهربائية باستخدام ميزة(I - V)،ووجد ان التوصيلية الكهربائية تزداد مع زيادة درجة الحرارة والتي تكون ضمن مدى(30 - 70OC) وهو السلوك الغالب لجميع الاغشية المحضرة وهذا يدل انها اشباه الموصلات . تم حساب طاقة التنشيط لجميع الاغشية المحضرة ووجد ان طاقة التنشيط لبوليمر PEDOT : PSS تكون قليلة وهي بحدود (0.41eV) وهذا يفسر التوصيلية الجيدة لهذا البوليمر . ووجد ان طاقة التنشيط لبوليمر P3HT غير المشوب تكون بحدود0.6eV وعند نسبة التشويب بنسبة 1% Vol(O.G) - P3HT تصل طاقة التنشيط 0.4eV وبزيادة نسبة التشويب الى 5% Vol (O.G) - P3HT تصل طاقة تنشيطه الى 0.23 eV . استثمرنا النتائج التي تم الحصول عليها لعمل خلية شمسية ذات الطبقة الواحدة وحسبت معاملات الخلية الشمسية باستخدام ميزة (J - V) ووجد انها تكون ذات كفاءة تصل الى 0.1% عند نسبة التشويب 1% Vol(O.G) - P3HT وذات كفاءة 0.2% عند نسبة الشوائب 5% Vol(O.G) - P3HT Vol(O.G) - P3HT . | In this study thin films of un doped P3HT and (1%,3%,4%,5%,7%,10 %) Orang G doping P3HT and un doped PEDOT : PSS, have been prepared using spin coating method . The prepared films were characterized under XRD and FTIR .The XRD spectra shows an amorphous structures of the un doping which were become semicrystline as a results of doping . The FTIR spectra of un doping P3HT and pure (O.G) shows principle functional group as recorded in literature .The UV - IS optical properties related to absorbance (A), Transmit (T) and reflectance (R) in the rang (300 - 900) nm have been studies to and absorption coeffienct (α), refractive index (n), extinction coefficient (K) and the real dielectric constant (ϵr), and a imaginary dielectric constant (ϵi) as well as optical conductivity( σopt)funacton of Wavelength.In this found that un doping of P3HT and O.G doping thin films have broad bound peaks in the rang ( 530 - 572nm) with as shoulder at the wave length 600nm .PEDOT : PSS shows high transmittance of 85% . The calculated optical energy gap for un doping P3HT be (1.95eV) , and decreases with increasing O.G of doping reached to (1.88eV) at 5% Vol (O.G) P3HT doping .It is also that absorption coeffienct (α) and extinction coefficient (K), increasing as function of wave length (λ).The electrical conductivity (σ) due at (I - V) characteristic for un doping and O.G - doping found to be increases with increasing temperature for (30 - 70oC), for all sample . Shows is Organic semiconductors behavior .A activation energy of prepared thin films were estimated and found to be (0.41,0.6 ,0.4 eV) and 0.23 eV for PEDOT : PSS un doping P3HT ( 1% Vol (O.G) - P3HT ) ,(5% Vol( O,G) - P3HT) nespectivity . A inlayer solar cells wave constructers from the upper mention un doping and evaluated ,and found to have efficacies(0.1% ,0.2%) respectively.

تحضير ودراسة بعض الخواص الكهربائية والبصرية للبوليمر الموصل بولي (انيلين اوكزالك) - وامكانية تطبيقاته في الخلايا الشمسية == preperation and studying some of the electrical and optical properties of conducting polymer poly(aniline - oxalic) and the possibility of its applications to solar cell

Author name: صفا نزار رمضان

Supervisor name: غفران محمد باقر شبيب

General topic: Physics

Specific topic: Solar Energy Physics

Degree: Master

University: University Of Basrah - College Of Education For Pure Sciences

Language: Arabic

University location: Basrah

First pages:

Abstract: We present in this study away of preparing Poly(aniline - oxali) (PAni - ox) by a Chemical polymerization with an ideal environment and temperature (5 - 0)0C. The Optical properties have been studied included the absorbance and transmitance measurements and calculations of the energy gap for (PAni - ox), which was found equal to (2.6eV). Electrical properties of (PAni - ox) have been also studied. The electrical conductivity for these materials was ( 8.22x10 - 2S.cm - 1) at room temperature.Thin films of titanium dioxide TiO2 of particle size (50 nm) and (25 nm) have been prepared and then deposited on a conductive glass bases Fluorine doped tin oxide (FTO) to study the optical properties.The materials under study have been diagnozid by using several techniques including X - rays (XRD) technique to determine the crystalline structures , Infrared (FT - IR) to determine the effective groups ,and Atomic Force Microscope (AFM) to determine the surface roughness and the regularity range of the nanoparticles compositions. Optical Anode was prepared by adding (PAni - ox) to TiO2, and the efficiency of the solar cell was calculated Two types of pigments alpha - Naphtholbenzein and EOSIN Y were added to TiO2 films and the prepared polymer is (PAni - ox). The pigments absorbs the solar energy and converte it to free electrons that are injected into titanium dioxide, which works as a collector for electrons. Electro solution was added to compensate for the loss electrons from the organic dye molecules. Thereafter, the electrode for the solar cell was prepared from carbon which has been obtained from candle flame.After preparation, the individual parts of solar cell have been collected by multi - layeres method . The (carrent - voltage) feature for cells by electrical properties have beem measured device and Light source.From this measurement , we calculate the open circuit voltage Voc and closed - circuit current Isc ,maximum power Pmax ,filling factor F.F, cell efficiency η, and Parallel resistance Rs and Resistance respectively Rsh.