تحضير ودراسة بعض الخواص الكهربائية والبصرية للبوليمر الموصل بولي (انيلين اوكزالك) - وامكانية تطبيقاته في الخلايا الشمسية == preperation and studying some of the electrical and optical properties of conducting polymer poly(aniline - oxalic) and the possibility of its applications to solar cell
Author name:
صفا نزار رمضان
Supervisor name:
غفران محمد باقر شبيب
General topic:
Physics
Specific topic:
Solar Energy Physics
Degree:
Master
University:
University Of Basrah - College Of Education For Pure Sciences
Language:
Arabic
University location:
Basrah
First pages:
26T1679 - p.pdf
Abstract:
We present in this study away of preparing Poly(aniline - oxali) (PAni - ox) by a Chemical polymerization with an ideal environment and temperature (5 - 0)0C. The Optical properties have been studied included the absorbance and transmitance measurements and calculations of the energy gap for (PAni - ox), which was found equal to (2.6eV). Electrical properties of (PAni - ox) have been also studied. The electrical conductivity for these materials was ( 8.22x10 - 2S.cm - 1) at room temperature.Thin films of titanium dioxide TiO2 of particle size (50 nm) and (25 nm) have been prepared and then deposited on a conductive glass bases Fluorine doped tin oxide (FTO) to study the optical properties.The materials under study have been diagnozid by using several techniques including X - rays (XRD) technique to determine the crystalline structures , Infrared (FT - IR) to determine the effective groups ,and Atomic Force Microscope (AFM) to determine the surface roughness and the regularity range of the nanoparticles compositions. Optical Anode was prepared by adding (PAni - ox) to TiO2, and the efficiency of the solar cell was calculated Two types of pigments alpha - Naphtholbenzein and EOSIN Y were added to TiO2 films and the prepared polymer is (PAni - ox). The pigments absorbs the solar energy and converte it to free electrons that are injected into titanium dioxide, which works as a collector for electrons. Electro solution was added to compensate for the loss electrons from the organic dye molecules. Thereafter, the electrode for the solar cell was prepared from carbon which has been obtained from candle flame.After preparation, the individual parts of solar cell have been collected by multi - layeres method . The (carrent - voltage) feature for cells by electrical properties have beem measured device and Light source.From this measurement , we calculate the open circuit voltage Voc and closed - circuit current Isc ,maximum power Pmax ,filling factor F.F, cell efficiency η, and Parallel resistance Rs and Resistance respectively Rsh.
