البحث — المستودع الرقمي العراقي

المستخلص: Silica nano particles were prepared from Iraqi rice husk (al - Najaf province) by precipitation method. Rice husk (RH) was treated with two different concentrations of inorganic acid (i.e. 1 & 3 N HCl) then burning at 700 °C under two heating rates. Chemical composition of rice husk ash (RHA) determined by X - Ray fluorescence (XRF) was contained about 89.5 wt% and 95.2 wt% SiO2 by treatment with 1N HCl at 10 and 5 °C/min heating rates for 3 hrs, respectively. While, XRF analysis was given 97.5 wt% SiO2content in RHA by treatment with 3 N HCl at 5 °C/min heating rates for 2 hrs. 3N HCl and heating rate at 5°C/min seems to be the best method to reduce the metallic ingredients and to obtain highly purified nanosilica powder at a purity of 98.9 wt%.The prepared nanosilica was also characterized by X - ray diffraction (XRD), BET surface, Fourier transform infrared spectroscopy (FTIR) and Atomic Force Microscope (AFM), in order to investigate its properties.X - ray results revealed a strong single beak of 2? at about 22° with an amorphous phase. Surface area was measured for nano silica to be 298 m2/g. The average diameter of prepared nanosilica is 89.58 nm as obtained by AFM analysis. Rice husk is seen to be a frugal waste material, high silica content, and it will be able to apply as a natural source of silica for preparation the zeolite - Y catalysts rather than burnt or dumped it as waste, causing environmental and health problems. On the other hand, the commercial source of silica (i.e. Ludox As - 40) is industrially used with other materials for synthesizing the zeolite type - Y catalyst and economically it has an expensive cost. Hence, it is essential to find out another pathway for silica source.This work deals with the replacing of costly commercial precursors of silica by a cheap natural nano - source silica from Iraqi RH. As such this study focuses on the optimization of percentages of natural and/or commercial silica applied within either seed gel or feed stock gel in the zeolite - Y synthesis process in order to investigate the effect of the nature of the silica used on both the structural properties of produced of Y - catalyst as well as on the catalytic performance of these catalysts in hydrocarbon cracking reactions forimproving the production catalytic activity and selectivity. Commercial zeolite - Y catalyst was laboratory prepared by means of commercial silica source and named as “A” sample, whereas other four samples of zeolite catalysts were successfully synthesized with a desired zeolite - Y phase and so - called “B, C, D and E” using different percentages of natural silica source. All the achieved samples are investigated by characterization techniques (i.e. XRD, BET - surface area, Pore volume, FTIR SEM, AAS, and EDX). The synthesized HY - catalyst samples were catalytically tested in the cracking of Hexane (C6H14) through an experimental cracking rig, and the reaction products were analyzed by GC. The performance of Iraqi RH zeolite type - Y catalysts was compared with the commercial lab HY - catalyst. Catalyst B prepares from only natural nanosilicasource and in comparison with other synthesized Y - catalysts; it gives the best catalytic behavior with 98 - 95 mol% conversion together with the selectivity domination of isomer and normal paraffin within the reaction products during more than 2 hrs at 450 °C. This result confirms that the use of natural silica source can be enhanced the catalytic properties of zeolite type - Y catalyst.

دراسة تاكل الصلب الكربوني في محلول ملحي والمنتجات البترولية بوجود غاز ثاني اوكسيد الكربون == Studying of Carbon Steel Corrosion In Salt Solution And Petroleum Products In Presence of CO2

اسم المؤلف: نضال احمد شاكر

اسم المشرف: شذى احمد سامح | شروق طالب الحميري

الموضوع العام: الهندسة الكيمياوية

السنة: 2014

الموضوع الدقيق: الهندسة الكيمياوية

الدرجة: ماجستير

الجامعة: الجامعة التكنولوجية - قسم الهندسة الكيمياوية

اللغة: الانكليزية

مكان الجامعة: بغداد

الصفحات الاولى:

المستخلص: يتضمن البحث دراسة سلوك التاكل للصلب الكربوني في محلول ملحي من (3.5wt%NaCl) ومشبع طبيعيا بالهواء بوجود غاز CO2 المستخدم في انابيب النفط. وتم تصميم منظومة القطب الاسطواني الدوار (RCE) لانجاز الدراسة.واجريت تجارب الاستقطاب في ظروف الجريان المضطرب باستخدام | The present work is to study the corrosion behaveior of carbon steel, in naturally aerated 3.5wt% NaCl (brine solution) and petroleum products in presence of CO2. A rotating cylinder electrode (RCE) system were used to study the potentiostatic polarization experiments, under turbulent flow conditions, using 3.5wt% brine solution as electrolyte at different temperatures (298, 308, 318 and 328)K and rotating speed of (0, 100, 200, 300 and 400)r.p.m. at each temperature.Similar experiments were carried out in 3.5wt% brine solution using CO2 gas at (32 ml/sec) flow rate.Corresponding experiments by weight loss were carried out in 3.5wt% brine solution with compunds of : - 1. Kerosene + 10V% brine solution.2. Gas oil + 10V% brine solution. At 328Kand flow rates of (0 and 400) r.p.m.3. Similar experiments were carried out in kerosene + 10V% brine solution at (298, 308 and 318)K and static condition speed of (0) r.p.m at each temperature.4. Experiments were carried out in pure kerosene at a temperature of (298 and 318) K and speed of (0) r.p.m.All above experiments were carried out with and without CO2 gas.The results indicated that the corrosion rate of carbon steel was increased in presence of CO2 gas.The anodic dissolution kinetics were activation control processes affected by temperature.The activation energy of carbon steel with CO2 gas system (2.87 - 1.8) Kcal/mol at different r.p.m. was lower than that without CO2 gas system of (11.4 - 1.7) Kcal/mol at different r.p.m.The corrosion potentials without CO2 gas were shifted to the noble direction with increasing flow rate at a constant temperature, whereas such potential were shifted to the less noble direction with increasing temperatures at a constant speed. However, the corrosion potential with CO2 gas was more noble than that obtained without CO2 gas.The corrosion rate is increased with increasing temperature and velocity. The results indicated that the corrosion rates of ( gas oil +10V% brine solution ) are higher than that of (kerosene +10 V % brine solution) with and with out CO2 gas, and the corrosion rate of pure kerosene is lower than that of (kerosene+10V% brine solution) with and without CO2 gas.In the presence of CO2 gas the results indicated that corrosion rate increases due to continuous dissoultion of iron ion and formation of weak carbonic acid. The carbonic acid accelarteed corrosion rate and affected carbonate and hydrogen ion, which increased the cathodic reactions on the metal surface.