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تقدير السلينيوم بالطرق الطيفية في نماذج حياتية وبيئية == Estimation of Se By Spectrophotometric Method In Vital And Environmental Samples

Author name: داليا عبد الامير احمد
Supervisor name: صادق جعفر باقر
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:
Abstract: يعد مرض السكري من الامراض المزمنة الواسعة الانتشار في العالم، ومن المشاكل الصحية الرئيسية في معظم دول العالم يضم هذا المرض مجموعة من الاضطرابات الايضية المختلفة (كاربوهيدرات، بروتينات، دهون )، اهمها ارتفاع مزمن في مستوى سكر الدم، حيث ان لتحلل الكلوكوز ف | Diabetes is a chronic disease widespread in the world and lt is amajor health problem. It is agroup of metabolic disorderd including carbohydrates , proteins and lipids. It is considerded as chronic high blood sugar (hyperglycemia). The glycolytic pathway in the cells play an important role to produce the serine which is formed by turning the phosphoglycerate in a series of steps. Serine is behaved as a donor of methyl group catalyzed by serine hydroxyl methyl transferase to produce homocysteine in a series of steps using vitamine B12 and tetrahydro folate (folate cycle) to control the lack of homocysteine that causes high damage to the lining of arteries and other organs , which in turn leads to partial decrease in insulin secretion or lack of insulin receptors. This may effect the eyes , kidneys , blood vessels, and nerves. This research includes people with diabetes type II. admitted to the teaching hospital in Tikrit, Samples have been taken from 40 patients (22 males and 18 females) and (5) samples of healthy males from the staff of the University of Tikrit, The study included two parts : - 1 - Biochemical study : - included the measurement of plasma level of homocysteine from the blood of patients with type II diabetes which showed : - 1 - Significant increase (P

تحضير وتشخيص ليكاندات ازو جديدة غير متجانسة الحلقة مشتقة من 5,4 - ثنائي فنيل اميدازول ومعقداتها مع بعض الايونات الفلزية == Synthesis And Characterization of New Heterocyclic Ligands Based On 4,5 - Diphenyl Imidazole And Their Complexes With Some of Metal Ions

Author name: اسراء نور كاظم وتوت
Supervisor name: حسين عبد محمد صالح
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:
Abstract: تضمن العمل تحضير ليكاندين جديدين من ليكاندات الازو العضويه غير المتجانسه المشتقة من البنزامبدازول الاول هو اليكاند 2'] - 2 - (بنزايميدازوليل) ازو [ - 6,4 - ثنائي كلورو فينول Benzimidazolyl) Azo] - 4,6 - dichloro phenol (BIADClP)) 2 - [2' - والليكاند الثا | This study deals with the preparation of two new ligands from the heterogeneous organic azo ligands drived from Benzimidazol.The first) 2 - [6 - Benzimidazolyl) Azo] - 2,4 - dichloro phenol (BIADClP). The second is 2 - [6 - (benzimidazolylazo)] - 2,4 - dibromo phenol(BIADBrP).The heterogeneous chain in both ligands includes two nitrogen atoms. These two ligands have been identification by the proton nuclear magnetic resonance spectra (1H - NNMR) ,the mass spectrum, infrared, visibale ultraviolet as well as the analysis of the micro - elements (C.H.N).And two new series of the solid canine complexes for these ligands. The first series includes six solid complexes of the ligand (BIADClP) with the metallic ions Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II). The second series includes the preparation of six solid complexes of the ligand (BIADBrP) with the metallic ions mentioned above. The effect of the solvent and the complexes stsbility have been studied on the prepared ligands with the passage of time starting from the moment of the metallic ion solution reaction with the ligand solution and up to 170 minutes. Also, the stability constants for these complexes have been calculated spectrally by visbale - ultraviolet spectra.All results show that these complexes have high stability. The infrared spectra of the prepared complexes have been studied and when compared with the free ligand spedtra give obvious changes as these spectra show new bands not already found in the spectra of both ligands and this is due to the occurance of the correlation between the metallic ions under study with the donar atoms [the nitrogen atom azo group near the heterogeneous chain (N3) and nitrogen atom benzimidazole molecule (N3) , the oxygen atom of hydroxyl group in the heterogenous chain ] in the ligand molecule whereas the other band suffered from obvious changes in shape, intensity and location and this is a proof on the occurance of consistency process between the metallic ions under study and the tow ligands. Atomic absorption spectrometer is used for assigning percentages of the metallic ions in the prepared complexes as well as the analysis of micro - elements (C.H.N). These results indicate the great consistency between the percentages theoretically calculated and practically gained. The magnetic sensitivity indicated that Ni(II) - complex and Cu(II) - complex for both ligands have baramagnatic characteristics whereas the Co(III) - complex, Zn(II) - complex, Cd(II) - complex, Hg(II) complex have adia magnetic characteristics. Also , the study deals with the molar conductivity of the canine complexes dissolved in DMF nad ethanol in a concentration (1×10 - 3) molar and in lap temperature. The results show that the complexes of Ni(II) , Cu(II), Zn(II), Cd(II), Hg(II) do not have ionic characteristics and they are solution of non - electrolytes nature whereas the complexes of Co(III) and for both prepared ligands (BIADClP) and (BIADBrP) have ionic characteristics of the electrolytes nature of type (1 : 1) whereas other remaining complexes do not have any ionic characteristics. Throughout the results that have been reached at, certain structural forms for the canine complexes have been suggested.It has been indicated that the azo Benzimidazol ligands under study behave as tridentate ligands where the consistency happens through the N atom benzimidazole chain (N3) and N azo group far from the heterogeneous chain (N3) oxygen hydroxyl group of the homogeneous chain which leads to forming canine hexagonal complexes having octahydral as steric form.The hybridization of these complexes is d2sp3 concerning Co(III) - complexes of the ligands (BIADClP) and (BIADBrP) whereas the other complexes have the hybridization sp3d2 with the tow prepared ligands under syudy. Moreover, the study deals with the biological activity of these ligands and metallic complexes in the growth of four types of bacterial spores (germs) by using the solvent DMSO and deployment technology as anti - bacterial such as Staphylococcus aureuse and Staph.lentus representative for Gram positive bacteria and enterobacte and Escherichia coli representative for Gram negative bacteria. It is found that ligands and there complexes have different effect as antidepressants in the inhibition and the growth of bacteria under study wheras the ligand (BIADClP) gave the ability in inhibition of the growth of bacteria more than the ligand (BIADBrO) this is due to the change of substituted group on the homogeneous chain and their different in both ligands which led to the emergence of such difference in the inhibition and growth of bacteria.

التخليق الاخضر لدقائق الفضة متناهية الصغر باستخدام مستخلصات الكيوي الاخضر == Green Synthesis Of Silver Nanoparticles By Using Actinidia Deliciosa Extracts

Author name: حوراء سعد حمود الكواز
Supervisor name: لمياء عبد المجيد المشهدي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تحضير وتشخيص معقدات كاربوبلاتين جديدة للبلاتين II ودراسة خواصها الطيفية والفيزيائية == Preparation and Characterization of New Carboplatin Complexes of Platinum (II) and Studied their Spectral and Physical Properties

Author name: سماء مهدي حسن
Supervisor name: جاسم محمد عبد الحسين | سعدون عبد الله عودة
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

البلمرة التكاثفية لمشتقات الاثيلين ثنائي الامين رباعي حامض الخليك وتطبيقاتها == Polycondensation of Ethylene Diamine Tetra Acetic acid derivative and applications

Author name: حذام عبد علي عبد الحسين عبد علي
Supervisor name: داخل ناصر طه الزركاني | خضير جواد كاظم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

التخليق الخضري لدقائق الفضة النانوية باستخدام مستخلص الزعفران وتخمين بعض تاثيراتها البايولوجية في سرطان الكبد المستحث في ذكور الجرذان == Green Synthesis Of Silver Nanoparticles Using Crocus Sativus L. Extracts And Evaluation Of Some Biological Effects In Induced Pre - Hepatocellular Carcinoma In Male Rats

Author name: نيران علي ثامر
Supervisor name: لمياء عبد المجيد المشهدي
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Babylon
First pages:

التقديرالطيفي لبعض المركبات الدوائية الامينية ذوات الاهمية الصيدلانية == Spectrophotometric Determination of Some Amino Drugs Compounds With Pharmaceutical Important

Author name: مروة سعد محمد سعد الحداد
Supervisor name: قاسم حسن كاظم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

طرائق طيفية جديدة لتقدير هيدروكلوريد الرانتدين في المستحضرات الصيدلانية == New Spectrophotometric Methods For The Determination Of Ranitidine Hydrochloride In Pharmaceutical Preparations

Author name: امنين محمد عبد الكريم
Supervisor name: عباس نور محمد الشريفي | صادق جعفر باقر
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تحضير وتشخيص ليكاندي ازو غير متجانسي الحلقة جديدة ومعقداتهما مع بعض الايونات الفلزية == Preparation and Characterization of Two New Heterocyclic Azo Ligands and Their Complexes with Some Metal Ions

Author name: زينب محسن نجم الكلابي
Supervisor name: حسين عبد محمد
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

تحضير بعض المشتقات العضوية الجديدة ودراسة السلوك التفلوري لها == Synthesis of Some New Organic Derivatives and Their Spectrofluorescence Behaviors Study

Author name: عمار كريم مدلول
Supervisor name: ناظر نجم عبد الله | عباس نور الشريفي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

دراسة حركية في معالجة المياه الصناعية لصناعة الجلود في مفاعل التكسير الضوئي المحفز باستخدام اوكسيد النيوبيوم == Kinetic Study of Leather Industry Wastewater Treatment in Photocatalytic Reactor Using Niobium Oxide

Author name: الاء سلمان حسين اللبان
Supervisor name: ندى يحيى فيروز
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تقدير الفناديوم الثلاثي والرباعي والخماسي بتقنية الحقن الجرياني (رحيل وتداخل المناطق) == Determination of Vanadium (III), (IV), (V) by flow injection analysis using merging zone technique

Author name: سلام محمد ناصر
Supervisor name: داخل ناصر طه الزركاني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

دراسة تحضير خلية المغنيسيوم الحرارية العاملة في درجات الحرارة المحيطة == Preparation Study of Magnesium Thermal Cell Operating at Ambient Temperatures

Author name: سماء سعدي محمود
Supervisor name: عباس عبد علي دريع الصالحي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

تقدير الفناديوم (V)، الكروم (VI) والمنغنيز (II) باستخدام الكاشف اللوني hydroxyquinoline8 - (6 - bromo - 2 - benzothiazolylazo) - 7 - - : دراسة طيفية وثرموديناميكية == Determination of Vanadium (V),Chromium (VI) and Manganese (II)Using Chromogenic Reagent 7 - (6 - bromo - 2 - benzothiazolylazo) - 8 - hydroxyquinoline (Spectroscopic and Thermodynamic Study)

Author name: زینب هادي حمید
Supervisor name: قاسم حسن كاظم | عباس عبد علي دریع
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

تصاميم جديدة ومبتكرة لمنظومات الحقن الجرياني والمايكروفلويد واستخدامها لتقدير البزموث الثلاثي في نماذج صيدلانية وبيئية == New Innovative Designs Of Flow Injection And Microfluidic Systems For the Determination Of Bismuth (III) In Pharmaceutical And Environmental Samples

Author name: امل سعدون مجيد الابراهيمي
Supervisor name: داخل ناصر طه الزركاني
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Babylon
First pages:

تحضير وتطبيقات الكاربون النانوي الانبوبي == Synthesis And Applications Of Carbon Nanotubes

Author name: فراس حبيب عبد الرزاق الدهلكي
Supervisor name: فلاح حسن حسين الخفاجي
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Babylon
First pages:

دراسة تحضير وتشخيص العاملين المساعدين Cr2O3 - Ag2O وMn - Cr2O3 وقياس كفاءة التحفيز الضوئي في عملية التكسير الضوئي لصبغة الكونغو الاحمر == Preparation And Characterization Study Of Ag2O - Cr2O3 And Mn - Cr2O3 Catalysts And Determine Their Photocatalytic Efficiency In Photodegradation Of Congo Red Dye

Author name: محمد زهير حسن الجواد
Supervisor name: ندى يحيى فيروز
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تحضير مشتقات اوكسازبين كمضافات لفلكنة المطاط == Synthesis Of Oxazepine Derivatives As Additives Of Rubber Vulcanization

Author name: ناردين عدنان برتو
Supervisor name: سعدون عبد الله عودة | محمد حمزة المعموري
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تحضير وتشخيص قواعد شف جديدة مشتقة من ثنائي الكيتون ومعقداتها الفلزية واستعمال احداها في تحضير قطب انتقائي سائل للنحاس == Synthesis And Characterization of New Schiff Bases Derived From Diketones And Their Metallic Complexes And Using one of them for Fabrication of liquid Membrane Cu2+ Ion Selective Electrode

Author name: هشام محمد حسن حسين مبارك
Supervisor name: حسين عبد محمد صالح | عباس نور الشريفي
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: Arabic
University location: Babylon
First pages:

تحضير وتشخيص مركبات حلقيه غير متجانسة من مشتقات الاميدازول ودراسة بعض تطبيقاتها التحليليه == SYNTHESIS AND IDENTIFICATION OF HETEROCYCLIC COMPOUNDS FROM IMIDAZOLE DERIVATIVES AND STUDY SOME OF THE ANALYTICAL APPLICATIONS

Author name: شيماء عدنان بهجت عبد الله
Supervisor name: حسن ثامر غانم | قاسم حسن كاظم
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: Arabic
University location: Babylon
First pages:

تحضير وتشخيص العامل المساعد المسند (Co,Mn)3O4 == Preparation And Characterization Of Supported (Co,Mn)3O4 Spinel Catalyst

Author name: حيدر منعم عبد محمد صالح
Supervisor name: صالح هادي كاظم
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

تصميم منظومة لتقدير المركبات الدوائية (البراسيتامول، المثيل دوبا، الريسورسينول) بطريقة الحقن الجرياني == Design system for the determination of pharmaceutical compounds(paracetamol, methyl dopa and resorcinol) by flow injection method

Author name: احمد شعلان خليف العماري
Supervisor name: داخل ناصر طه الزركاني
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: Arabic
University location: Babylon
First pages:

تقديرالمركبات الاروماتية المتعددة الانوية في المياه السطحية لشط الحلة وامكانية معالجة الانثراسين مختبريا == Determination Of Poly Nuclear Aromatic Hydrocarbons (PAHs) In Surface Water Of Shatt Al - Hilla River And Possibility Of Laboratory Treatment For Anthracene

Author name: فائق فتح الله كرم الصياد
Supervisor name: فلاح حسن حسين الخفاجي | صادق جعفر باقر
General topic: Chemistry
Specific topic: Chemistry
Degree: Doctorate
Language: English
University location: Babylon
First pages:

تطبيقات انابيب الكربون النانوية في معالجة المياه الملوثة == Applications Of Carbon Nanotubes In Wastewater Treatment

Author name: احمد مسلم كامل عمران
Supervisor name: فلاح حسن حسين الخفاجي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:

دراسة نظرية لالية تفاعل الاوزون مع هاليدات الهيدروكاربونات الخفيفة == Theoretical Study Of Reaction Mechanism For Ozone With Light Halohydrocarbons

Author name: عقيل علاء حسين الخفاجي
Supervisor name: عباس عبد علي دريع الصالحي
General topic: Chemistry
Specific topic: Chemistry
Degree: Master
Language: English
University location: Babylon
First pages:
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