Author name:
حسنين نجم عبود السوداني
Supervisor name:
علي حسين عبد الكريم العامري | خديجة صادق جعفر الحسيني
Abstract:
In the current study was used eggshell chicken eggs components (internal membranes only, eggshell without membranes and non - activated eggshell with internal membranes and activated eggshell with membranes by concentrated sulfuric acid) as natural adsorbent vital materials to removed organic dyes such as methylene blue, methyl orange dye and metal ions such as lead, copper, cadmium and zinc from their water solutions, and then used as clearifing materials to removed turbidity from apple juice considering and removed metal ions from municipal waters, The results of chemical composition for eggshell showed that increased on percentage of moisture, protein and fat for internal membranes reaching to (3.100, 58.85 and 1.834) % respectively comparison with eggshell without membranes which reaching to )1.813, 0.984 and 0.301) % respectively and on eggshell with internal membranes were (2.198,4.810 and 0.513) % respectively, while there was increased on percentage of ash on eggshell without membranes and eggshell with internal membranes reaching to (96.451 and 94.780)% respectively comparison with internal membranes was 26.200 %, metal ions in ash estimated, It also the percentage of calcium, potassium, magnesium , iron, copper, zinc and manganese in internal membranes reaching to (23.30, 7.20, 8.42, 3.00, Nil, 1.14 and 0.14) % respectively, for the eggshell without membranes (29.80, 8.80, 8.65, 0.11, 1.77, 0.40 and 0.01) % respectively, and for the eggshell with internal membranes (28.70, 6.90, 8.64, 1.86, Nil, 0.04 and 0.58) % respectively.Study of infrared (FTIR) for components was observed absorption bands that related to many active groups such as group (OH - ) and a (NH)it were ( 3423.66,32987.28 and 3423.65) cm - 1 centralized on internal eggshell with internal membranes and (C - H) , (C - H, C = O) , (CH2, CH3) and (C - C, C - O) which were (2983.88, 2879.72, 1799.58, 1643.35 and 1797.66) cm - 1 respectively centralized on eggshell without membranes and eggshell with active internal membranes.Also when examination using diffraction X - ray technique, results indicated the finding a number of peaks vary in intensity and location, but being in similar sharp peaks and this shows the possession of eggshells microcrystalline structure. conducted aAAbstractstudy using Microscope electronic scanning, results showed the eggshells components do have a porous surface as well as her crystalline that making it an effective and well suited material to linked with a material to be removed.Factors affecting on the adsorption of dyes and ions were studied, Ability of internal membranes, eggshell without membranes and non - activated eggshell internal membranes to remove of methylene blue dye was Studied. the results showed that the best conditions for the adsorption was to be the initial concentration of the dye was (10) ppm for the non - activated eggshell with the membrane and (5) ppm for internal membranes and eggshell without membranes in size (50)ml ,the degree of heat (20) C and (pH = 8) for the eggshell without membranes and non - activated eggshell with membrane and (pH=6) for the membranes only, also the time to contact (60) min for each of the membranes only and non - activated eggshell with membrane and (45) min for eggshell without membranes, also showed a positive relationship between the percentage of the speed of adsorption of the dye with the increased weight of adsorbent material and reached the highest percentage when using the internal membranes, eggshell without membranes and eggshell with internal membranes (94.240, 97.680 and 97.170) % respectively, when the weight (1.25) g.Ability of eggshell with internal membranes activated by concentrated sulfuric acid (1 : 1) to removed methyl orange dye was studied, the results showed that the best conditions for the process of adsorption was to be the time of the contact (20) min, temperature (30) C, primary and concentration (25) ppm in size (50) ml and the weight of adsorbent material (0.5) g, The percentage of removal decreases with increasing pH and the highest percentage for the removal was reaching to 50.30 % when (pH = 2) and the lowest percentage of removing was 37.50 % when (pH = 8).Removal of divalent ions (Cu+2,Cd+2,Pb+2,Zn+2) by eggshells components and the best component used as material for removing (Pb+ 2, Cu+ 2) ions was eggshell without membranes. But the best component to removed (Zn+ 2,Cd+ 2) ions was the inner membrane, and that the best conditions for adsorption was to have weight of adsorbent material (1) g and the degree of temperature (60) C for copper and cadmium and (80) C for lead and zincBAbstractand the initial concentration of the dye was (20, 40, 100 and 100) ppm for zinc, lead, copper and cadmium respectively, and the contact time (60) min for (Cd+ 2,Pb+ 2) and (40) min for (Cu+2 , Zn+ 2) also (pH = 4) for lead and (pH = 8) for (zinc, copper and cadmium), it was observed that the increased in contact time helps to increased the speed of the removal process ions, as found the time to reach equilibrium for lead and cadmium was when (60) min and percentage of removing them (99.38, 81.86) % respectively, and for copper and zinc was reached to (99.76, 99.24) % respectively, at the time (40 ) min and solution volume (50) ml. When study of the isotherms adsorption. The study showed that the adsorption to methyl orange dye by eggshells with non - activated internal membranes was submitted to Gliese,s classification because the isotherms take shape (S) as well as submitted to the equation Langmuir apparently at (pH = 7) within the range of concentrations of the dye (10 - 30) ppm and the degree of temperature (30) C and time of (30) min and the weight (1) g. For the methylene blue dye ,the adsorption by internal membranes powder was submitted to the form (L) of Gliese,s classification, but adsorbed it by using eggshell without membranes and non - activated eggshell with the membrane was submitted to the shape (S) as well as the adsorption submitted to equation Langmuir apparently at (pH = 8) for powders of eggshells without membranes and the non - activated eggshell with membrane and at (pH = 6) for internal membranes when contact time was (30) min, degree of heat (35) C , weight (0.5) g and the size (50) ml within the range of concentrations (5, 10, 15 and 20) ppm.The results showed that the adsorption of ions was submitted to equation Langmuir because it's had shape (S) at (pH=8) for (Cu+2, Zn+2) ions and at (pH=4) for (Pb+2) ion. And the size of molecules of powder of adsorption material was (500) μm and speed of mixing was (200) rpm except( Cd+2) apparently .A study was conducted to identify their ability to bleaching natural apple juice using peels components, and founded that the best material was non - activated eggshell with internal membranes, the natural apple juice was treated with weight of (0.25) g, as that the turbidity dropped from 2.625 % to 1.101 %, and total soluble solids decreased from 13 % to 10.1 % , andCAbstractpH raised from (pH = 3.9) to (pH = 4.6) .Also sensory evaluation of the juice as results showed superiority of the juice plant material clarification and receiving a degree (8.768) compared to juice untreated who got the degree evaluate (6.37). This demonstrates the efficiency of bleaching material in improving the qualities of natural juice.Also study was conducted to determine the efficiency of the components in the removal of ions from municipal water, and it founded that the best component was eggshell without inner membrane, and the percentage of removal of 100 % of the lead an cooper for tow weighit (0.5 and 1) g respectively and for eggshell with the inner membrane weighit (2) g for tow ions, but for zinc the highest removal percentage up (95~ 97) % for all eggshell component, and better weight was (0.5) g ,the best time to contact (40) min and best degree of heat (80) C, this shows the efficiency of the eggshell with the internal membranes to removal of ions from polluted waters.D
