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دراسة تجريبية ونظرية للمعقدات الجزيئية ل 6-ميركابتوبيورين (6-MP) و6- ثيوغوانين (6-TG) ومشتقاتها وتقدير نشاطها مع المستقبل HGPRT

Author name: الاء عبادي حبيب
Supervisor name: فلاح شريف سهيل
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
Key words:
  • : 6-MP, SDS , N.hexan, Thermodynamic parameters ΔG○.,HGPRT

تحضير متراكبات نانوية من بعض الاكاسيد المعدنية والبولي ثايوفين مضادة للتاكل ومعالجة للمياه

Author name: هناء كاظم
Supervisor name: عامر موسى
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
Key words:
  • الفولتامتري الحلقي, متراكبات نانوية, تاكل , تفكك كهربائي

Studying The behavior of Liquid Crystals of some New synthesized Anil Compounds

Author name: نورهان علي حمزة الخفاجي
Supervisor name: ساجدة هادي رضا
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: English
University location: Najaf
Key words:
  • البلورات السائلة, قواعد شيف

Studies of Electrochemical and Geometrical Parameters for Anticancer Drug 5 - Fluorouracil with Respiratory Chain Components:Computerized and In Vitro Modes

Author name: رزاق عبد الـزهرة ابراهيم حمود العامري
Supervisor name: فلاح شريف عبد سهيل | حسين كاظم الحكيم
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
Key words:
  • فلورويوراسيل

متحسس - ابتمر الكتروكيميائي عالي الحساسية للكشف المبكر عن التهاب الكبد الفايروسي نوع B == Ultrasensitive Electrochemical Aptasensor for Earlier Detection of Hepatitis B Virus

Author name: ضياء حسين محسن
Supervisor name: مثنى صالح مشكور | فتانة فاطمي
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
Key words:
  • Electrochemical aptasensor, aptamer , Hepatitis B virus Reduced graphene oxide
First pages:

تحضير محفزات متراكبة نانوية ثانوية وثالثية لاوكسيد المغنسيوم MgO عالية النشاط وتطبيقاتها البيئية == Preparation of High Activity Binary and Ternary MgO Nanocomposites Catalysts and their Environmental Application

Author name: فاطمة علاوي عبد السجاد الحجامي
Supervisor name: عامر موسى جودة سامي وحيد راضي
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
Key words:
  • الاكسدة الضوئية الخلايا الشمسية الاستئصال الليزري
First pages:

دراسة ثرموديناميكية وحركية لامتزاز بعض الاصباغ على مسحوق بذور الرمان == Thermodynamic and Kinetic Study for Adsorption of Some Dyes on to Pomegranate Seeds Powder

Author name: رسل مهدي عبيد جبر الشريفي
Supervisor name: سعد عزيز حسن حسوة
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

دراسة امتزان بعض المركبات العضوية على سطح الصخور السيليسية

Author name: زينب نايف مجيد الجبوري
Supervisor name: احمد محمد علوان المشهداني | سعد عزيز حسن حسوة
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

دراسة حركيات امتزاز المركبات الفينولية على مسحوق الصخور السيليسية

Author name: سنى عدنان حبيب الخفاجي
Supervisor name: احمد محمد علوان المشهداني | موسى عمران كاظم
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

دراسة ثرموديناميكية لامتزاز اصباغ الرودامين - G6 والايوسين - B والبرلنت الاخضر على بعض سطوح الميسلات

Author name: نهى عبد الصاحب رضا العندليب
Supervisor name: موسى عمران كاظم
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

دراسة حاسوبية لمحاكاة حيوية لنموذج معقدات الروثينيوم والحديد العنقودية لاختزال النيتروجين == Computational Study on Biomimetic Model Ruthenium and Iron Clusters for Reduction of N2

Author name: خلود عبيد كزار المسعودي
Supervisor name: محسن عبود محسن العبادي | سميرا شامل
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Doctorate
University: University of Kufa - College Of Science - Chemistry Department
Language: English
University location: Najaf
First pages:

دراسة بعض الخواص الفيزيائية والميكانيكية للمتراكبات البوليمرية الجديدة المحضرة من الستايرين بيوتادين == Study of Some Physical and Mechanical Properties of New Polymeric Composition from prepared SBR

Author name: حيدر عبد الواحد مهدي
Supervisor name: عامر موسى جودة الشمري
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Science - Chemistry Department
Language: Arabic
University location: Najaf
First pages:
Abstract: ان الاهمية المتزايدة لاستعمال المتراكبات البوليمرية جاءت نتيجة التطور الصناعي التكنولوجي الكبير الذي يشهده العالم بوصفة بديلا عن المواد الهندسية التقليدية التي ساد استخدامها في الصناعة لذا فان الدراسة الحالية تهدف الى تحضير متراكبات بوليمرية ذات مواصفات ميكانيكية جيدة من مادة الستايرين بيوتاداين مع مالئات من السيليكا والكاولين العراقي بنسب وزنية مختلفة (1%,5.2 %,5%,5.7%,10%,5.12%,15%) ان اضافة السيليكا والكاولين العراقي كان الهدف منة تحسين الخواص الفيزيائية والميكانيكية وكذلك خواص الفلكنة لمطاط الستايرين بيوتاداين اذ تم قياس خواص الشد(الاستطالة ,المرونة) وكذلك الصلابة والكثافة النسبية ومعدل سرعة الفلكنة والاحتكاك الخارجي للاطار. اظهرت النتائج ان جميع الصفات الفيزيائية والميكانيكية وكذلك خواص الفلكنة قد تحسنت بنسب عالية عند زيادة النسب الوزنية للمالئات وان افضل نسبة وزنية لتحسين الخواص هي (5.7%) حيث بلغت قيمة الشد عند هذة النسبة (16.81Mpa) عند اضافة السيليكا و(19.97Mpa)عند اضافة الكاولين بينما كانت (8.69Mpa) بدون اي اضافة, الاستطالة (441%) عند اضافة السيليكا و(417.078%) عند اضافة الكاولين, المرونة ((9.5Mpa عند اضافة السيلكيا و(14.12 Mpa)عند اضافة الكاولين بينما كانت ((7.69 Mpa بدون اي اضافة , الصلابة (68 IRHD) عند اضافة السيليكا و(65 IRHD) عند اضافة الكاولين بينما كانت (57 IRHD) بدون اي اضافة, معدل سرعة الفلكنة (74.07min (للسيليكا و(54.34min) للكاولين , الكثافة النسبية (1.156) عند اضافة السيليكا و(1.183)عند اضافة الكاولين بينما كانت (1.133) بدون اي اضافة اما للاحتكاك الخارجي للاطار (0.18 gm) عند اضافة السيليكا و(0.54 gm) عند اضافة الكاولين بينما كانت (0.75 gm) بدون اي اضافة,اما الجانب الاخر فقد تم دراسة الخواص الفيزيائية والميكانيكة وكذلك خواص الفلكنة ولكن هذة المرة تم مزج نسب وزنية مختلفة من السيليكا والكاولين وبينت نتائج المزج ايضا تحسين الخواص المذكورة اعلاه, | The important increasing for using polymeric composites came from result of industrial large to chronology development which it was seeing in world and sbstitute from traditional engineering materials which used in industry. the present research aim to preparation of new polymeric composites with good mechanical properties to Substance Styrene - Butadiene Rubber (SBR) with filler Silica and Iraqi Kaolin with different perceentage (1%,2.5%, 5%,7.5%, 10%,12.5%,15%).Addition of Silica and Iraqi Kaolin aim to improvement physical and mechanical properties also Cure characteristics to Substance Styrene - Butadiene Rubber (SBR) as it was measured tensile properties (tensile strength, elongation at break and modulus), also Hardness, Specific gravity ,Cure rate index and abrasion. The result had shown all physical and mechanical properties also Cure characteristics by improved high with increase of percentage of filler. The best ratio by weight to improve properties (7.5%). As the value of tensile strength(16.81 Mpa) when addition Silica and (19.97 Mpa) when addition Kaolin While the (8.69 Mpa) with any addition, elongation (441%) when addition Silica and (417.078%) when addition Kaolin, Modulus (9.5 Mpa) when addition Silica and (14.12 Mpa) when addition Kaolin While the (7.69 Mpa) with any addition , hardness (68 IRHD) when addition Silica and (65 IRHD) when addition Kaolin While the (57 IRHD) with any addition, Cure rate index (74.07 mint) when addition Silica and (54.34 mint) when addition Kaolin, specific gravity (1.156) when addition Silica and (1.183) when addition Kaolin While the (1.133) with any addition ,abrasion (0.18 gm) when addition Silica and (0.54 gm) when addition Kaolin While the (0.75 gm) with any additon. On the other hand Study the physical and mechanical properties also cure characteristics but this time was mix different percentage from Silica & Kaolin the results of blending increase properties the above - mentioned.

تحضير وتشخيص الدقائق النانوية لاوكسيد النحاسوز بواسطة الكتروليتات مختلفة == Preparation And Characterization of Cuprous Oxide Nanoparticles By Different Electrolytic Media

Author name: حيدر خضير خطار
Supervisor name: فؤاد عبد الامير السعدي | سامي وحيد راضي الحسناوي
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Science For Girls - Chemistry Department
Language: English
University location: Najaf
First pages:
Abstract: في الواقع، لم تلقي عملية فصل واستخلاص الكميات الضئيلة من الادوية في العينات الحيوية وكذلك في المستحضرات الصيدلانية اهتماما واسعا وكبيرا باستعمال مايسمى الاستخلاص بنقطة الغيمة. وفي هذا الصدد، نعتقد ان العمل البحثي الحالي سوف يسهم في فتح افاق جديدة في تصم | The separation and extraction of trace amounts of medicaments in biological specimens, as well as in pharmaceutical formulations have not received much attention by using the so - called cloud - point extraction (CPE). In this context, we think that the present research work will contribute to opening new prospects in designing procedural steps and expands the applications of the cloud point extraction methodology in most important areas, including pharmaceutical sciences, forensic and environmental analyses. The present work concentrates on the developing of new eco - friendly procedures for determination of two selected antibiotic medicaments namely cirprofloxacin chloride (CIPRO) and norfloxacin (NOR) using iron (III) ion in human serums and pharmaceutical formulations, as well as the exploitation of these two drugs in chemical analysis as chelating agents for the detection of iron in pharmaceutical formulations via using cloud point extraction coupled with molecular spectrophometry. Generally, these methods implicate the use of a nonionic surfactant (Triton X - 114) as an extracting medium which entrap the hydrophobic colored complex formed between one of these drugs and iron (III) ion in acidic medium as a reaction system for designing the CPE procedures.This thesis includes three main chapters as follows;Chapter One summarizes some theoretical and practical principles of cloud point extraction (CPE) methods and then highlights the knowledge of the target analytes (CIPRO, NOR and iron) in term of their structures, pharmacological importance besides a concise chemical literature review for the estimation of these analytes by different analytical techniques. Chapter Two consists of an outline of instrumental techniques , general apparatus and chemicals used in the present work. The full analytical procedures for CPE which have been designed for the determination of the target analytes under study are made in this thesis.Chapter Three covers a detailed study for the discussion of the analytical data obtained throughout this work which can be summed up as follows;A. Formation of chelates between CIPRO or NOR and Fe(III) in acidic medium , where the drugs have individually been estimated in the resulting complex by spectrophotometry after the cloud point extraction at each respective ?max, and the use of developed method so that to determine any of the interested drug in human serum and pharmaceuticals. At first, the study was conducted to pinpoint the optimum conditions for the formation of complexes by CPE and the results were as follows; 1. The optimum experimental conditions for Fe - CIPRO and Fe - NOR complex for the determination of CIPRO and NOR respectively : H2SO4 concentration (5x10 - 4 M and 2.5x10 - 4M; Fe(III) concentration ( 6 ?g mL - 1 and 10 ?g mL - 1); Triton X - 114 amount ( 1%) for both drugs; temperature and time ( 75 °C at 25 min and 65 °C at 20 min).2. The achieved analytical figures of merit on applying the developed methods for CIPRO and NOR are : linear range (2.5 - 120 ?g mL - 1 ) for drugs, limit of detection (0.770 and 0.204 ?g mL - 1), Enrichment factor (143 and 280 fold), extraction efficiency (96.46 and 96.62%) and mean recovery percentage (98.89±0.87% and 98.95±1.09). 3. The newly established procedures have been applied for the determination of CIPRO and NOR in human blood serum and pharmaceuticals. For the determination of these medicaments in serum samples , the statistical paired t - test was used to test the significance of the proposed method comparing with the conventional UV - spectrophotometry, while in pharmaceuticals, the findings were compared statistically with quoted values that stated by the manufactures. B. Iron (III) ion was also determined in the pharmaceutical formulations based on the above reaction system in (A) via formation of yellow colored complexes with each medicament which extracted by micelles generated by CPE and subsequently detected spectrophotometrically at the same ?max of the above mentioned complexes. The optimum established conditions and the analytical data obtained could be summarized as follows : 1. The same optimum conditions were used in (A) except that the concentration of CIPRO or NOR here was of 7x10 - 5 M and Triton X - 114 amount of 0.6% in final solutions.2. The analytical figures of merit obtained on applying the developed methods for iron using CIPRO and NOR respectively; linear range (5 - 150 ng mL - 1); limit of detection (2.67 and 3.42 ng mL - 1); preconcentration factor (71 and 83 fold); mean recovery percentage (99.78±0.53% and 98.77±2.29); extraction efficiency (99 and 98.7%). 3. The effect of some additives of the pharmaceutical formulations was also studied and the iron determined in three selected formulations collected from local drugstores. The results were compared statistically with quoted values and shown not to be significant at 95% confidence level.

امتزاز بعض الادوية على سطح طين الكاؤولين العراقي الابيض == Adsorption of some drugs on the surface of white Iraqi kaolin clay

Author name: جلال اسماعيل ابراهيم الكناني
Supervisor name: سعد عزيز حسن حسوة
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

دراسة طيفية لامتزاز بعض الصبغات على سطوح بعض المنشطات الصلبة والسائلة == Spectral Study for Adsorption of some DyesOn some Solid and Liquid Surfactants

Author name: نهى سالم كريم
Supervisor name: موسى عمران كاظم
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Education For Girls - Chemistry Department
Language: Arabic
University location: Najaf
First pages:

قابلية بعض السطوح الصلبة في امتزاز الانلين والباراتولودين والبارانايتروانلين

Author name: ماجدة حميد عبيد الخزاعي
General topic: Chemistry
Specific topic: Physical Chemistry
Degree: Master
University: University of Kufa - College Of Science - Chemistry Department
Language: Arabic
University location: Najaf
First pages: