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تصميم العتبات الخرسانية احادية التسليح بالثني == Flexural Design of Reinforced Concrete Beams

Author name: محمد دارا جليل الخياط

Supervisor name: قيس فؤاد سرسم

General topic: Civil Engineering

Specific topic: Structural Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Structural Engineering Branch

Language: English

University location: Baghdad

First pages:

ادارة المخاطر الفنية في مواقع مشاريع الابنية المدرسية باستخدام النظام الخبير == Risks Management Technical In Sites School Building Projects Using Expert System

Author name: هديل سلام داود

Supervisor name: رائد سليم عبد علي اللامي | طارق عبد المجيد خليل

General topic: Civil Engineering

Specific topic: Structural Engineering - Project Management

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: Arabic

University location: Baghdad

First pages:

نظام الري بالرش والمحافظة على المياه حالة دراسية من جنوب العراق == Sprinkler Irrigation System And Water Saving A Case Study From South of Iraq

Author name: سرى عبد الحميد رشيد

Supervisor name: عقيل شاكر العادلي

General topic: Civil Engineering

Specific topic: Water Resources Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: English

University location: Baghdad

First pages:

سلوك السدود الترابية اثناء التفريغ المفاجئ للخزانات المائية == Behavior of Earth Drawdown of Reservoir

Author name: محمد عائد حسن العمشاوي

Supervisor name: محمد يوسف فتاح | حسن علي عمران

General topic: Civil Engineering

Specific topic: Water Resources Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: English

University location: Baghdad

First pages:

بناء نظام للسيطرة على الكلفة والوقت في تنفيذ مشاريع الطرق == Building Control System on Cost And Time In The Implementation of Roads Projects

Author name: لبنى وليد سعيد

Supervisor name: رائد سليم عبد علي اللامي | افراح محمد حسن

General topic: Civil Engineering

Specific topic: Structural Engineering - Project Management

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: Arabic

University location: Baghdad

First pages:

تقييم وتحسين اداء انابيب نقل النفط الخام من K2 الى مصفى الدورة == Evaluating And Improving The Performance of Crude Oil Pipelines From K2 To Dora Refinery

Author name: عصام فخري محمود العبيدي

Supervisor name: كريم خلف الجميلي | مؤيد سعد الله

General topic: Civil Engineering

Specific topic: Structural Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Structural Engineering Branch

Language: Arabic

University location: Baghdad

First pages:

تقييم شبكة مسارات النفط الخام العراقي بمساعدة التقنيات الجيوماتيكية == Evaluation of The Iraqi Crude Oil Network Routes With Assistance of Geomatics Techniques

Author name: شيماء خضر الياس

Supervisor name: عباس زيدان خلف | امزاحم عبد الكريم علوان

General topic: Civil Engineering

Specific topic: Geomatics Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Geomatics Engineering Branch

Language: English

University location: Baghdad

First pages:

تطبيق المقاومة النوعية الكهربائية التصويرية ورادار الاختراق الارضي في التحريات الموقعيه تحت السطحيه لمدينة الكوت == Application of Resistivity Imaging (RI) And Ground Penetrating Radar (GPR) In Subsurface Site Investigation In Kut City

Author name: محمد علي حسين الربيعي

Supervisor name: حسين حميد كريم | كريم هادي ابراهيم

General topic: Civil Engineering

Specific topic: Geotechnical Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: English

University location: Baghdad

First pages:

الخواص الحرارية والميكانيكية للخرسانة الخالية من الرمل والمعززة بالالياف == Thermal And Mechanical Properties of Fiber Reinforced No - Fines Concrete

Author name: باسم هوير امانة

Supervisor name: باسل صلاح مهدي | اسامة عبد الامير عيدان

General topic: Civil Engineering

Specific topic: Structural Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Structural Engineering Branch

Language: English

University location: Baghdad

First pages:

بناء قواعد بيانات مكانية للخواص الجيوتكنيكية لمنطقة محافظة ذي قار باستخدام التقنيات الرقمية الحديثة == Building Geodatabase For Geotechnical Properties of Thi - Qar Governorate Area Using Modern Digital Techniques

Author name: قاسم عبد الحسين عبد العباس

Supervisor name: عبد الرزاق طارش زبون | فلاح حسن رحيل

General topic: Civil Engineering

Specific topic: Geomatics Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Geomatics Engineering Branch

Language: English

University location: Baghdad

First pages:

تحليل وسلوك الانحناء لعتبات خرسانة المساحيق الفعالة ذات المقطع (T) == Analysis And Behavior of RPC T - Beams In Flexure

Author name: حيدر ميثم حكمت

Supervisor name: Hisham Mohammed Al | Hassani | Bassman R. Mohammad

General topic: Civil Engineering

Specific topic: Structural Engineering

Degree: Master

University: University of Technology - Department Of Civil Engineering - Structural Engineering Branch

Language: English

University location: Baghdad

First pages:

تطوير نظام لادارة الهدر الانشائي خلال مرحلة التنفيذ : محافظة كربلاء كحالة دراسية == A Construction Waste Management System Developed For The Execution Phase - Karbala Projects As A Case Study

Author name: علي حسن هادي ال عايم

Supervisor name: زياد سليمان محمد خالد | باسل صلاح الشذر

General topic: Civil Engineering

Specific topic: Structural Engineering - Project Management

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: English

University location: Baghdad

First pages:

تطوير عملية تسعير العطاءات في قطاع المباني في العراق باستخدام تقنية تكاليف الانشطة : دراسة تطبيقية على احدى شركات القطاع الخاص == Developing The Tenders Pricing In Iraq Building Sector Using Cost Activities Technique : A Case Study on one of Private Companies

Author name: حيدر حامد عطشان السلامي

Supervisor name: رائد سليم عبد علي اللامي

General topic: Civil Engineering

Specific topic: Structural Engineering - Project Management

Degree: Master

University: University of Technology - Department Of Civil Engineering

Language: Arabic

University location: Baghdad

First pages:

العوامل المؤثرة على الخرسانة ذاتية الرص المسلحة بالالياف == Factors Affecting on Self Compacting Fiber Reinforced Concrete

Author name: غزوان عبد الصمد سلمان

Supervisor name: شاكر احمد صالح المشهداني

General topic: Civil Engineering

Specific topic: Structural Engineering

Degree: Doctorate

University: University of Technology - Department Of Civil Engineering - Structural Engineering Branch

Language: Arabic

University location: Baghdad

First pages:

تحضير عامل مساعد زيوت Y من قشور الرز العراقية لتطبيقات تكسير الهكسان == Preparation Of Zeolite Y Catalyst From Iraqi Rice Husk For Cracking Of n - Hexane

Author name: زينب محمد صبار

Supervisor name: نجاة جمعة صالح | بشير يوسف شرهان

General topic: Chemical Engineering

Specific topic: Oil Refining and Petrochemical Industries

Degree: Master

University: University of Technology - Department Of Chemical Engineering - Chemical Engineering and Oil Refining Branch

Language: English

University location: Baghdad

First pages:

Abstract: Silica nano particles were prepared from Iraqi rice husk (al - Najaf province) by precipitation method. Rice husk (RH) was treated with two different concentrations of inorganic acid (i.e. 1 & 3 N HCl) then burning at 700 °C under two heating rates. Chemical composition of rice husk ash (RHA) determined by X - Ray fluorescence (XRF) was contained about 89.5 wt% and 95.2 wt% SiO2 by treatment with 1N HCl at 10 and 5 °C/min heating rates for 3 hrs, respectively. While, XRF analysis was given 97.5 wt% SiO2content in RHA by treatment with 3 N HCl at 5 °C/min heating rates for 2 hrs. 3N HCl and heating rate at 5°C/min seems to be the best method to reduce the metallic ingredients and to obtain highly purified nanosilica powder at a purity of 98.9 wt%.The prepared nanosilica was also characterized by X - ray diffraction (XRD), BET surface, Fourier transform infrared spectroscopy (FTIR) and Atomic Force Microscope (AFM), in order to investigate its properties.X - ray results revealed a strong single beak of 2? at about 22° with an amorphous phase. Surface area was measured for nano silica to be 298 m2/g. The average diameter of prepared nanosilica is 89.58 nm as obtained by AFM analysis. Rice husk is seen to be a frugal waste material, high silica content, and it will be able to apply as a natural source of silica for preparation the zeolite - Y catalysts rather than burnt or dumped it as waste, causing environmental and health problems. On the other hand, the commercial source of silica (i.e. Ludox As - 40) is industrially used with other materials for synthesizing the zeolite type - Y catalyst and economically it has an expensive cost. Hence, it is essential to find out another pathway for silica source.This work deals with the replacing of costly commercial precursors of silica by a cheap natural nano - source silica from Iraqi RH. As such this study focuses on the optimization of percentages of natural and/or commercial silica applied within either seed gel or feed stock gel in the zeolite - Y synthesis process in order to investigate the effect of the nature of the silica used on both the structural properties of produced of Y - catalyst as well as on the catalytic performance of these catalysts in hydrocarbon cracking reactions forimproving the production catalytic activity and selectivity. Commercial zeolite - Y catalyst was laboratory prepared by means of commercial silica source and named as “A” sample, whereas other four samples of zeolite catalysts were successfully synthesized with a desired zeolite - Y phase and so - called “B, C, D and E” using different percentages of natural silica source. All the achieved samples are investigated by characterization techniques (i.e. XRD, BET - surface area, Pore volume, FTIR SEM, AAS, and EDX). The synthesized HY - catalyst samples were catalytically tested in the cracking of Hexane (C6H14) through an experimental cracking rig, and the reaction products were analyzed by GC. The performance of Iraqi RH zeolite type - Y catalysts was compared with the commercial lab HY - catalyst. Catalyst B prepares from only natural nanosilicasource and in comparison with other synthesized Y - catalysts; it gives the best catalytic behavior with 98 - 95 mol% conversion together with the selectivity domination of isomer and normal paraffin within the reaction products during more than 2 hrs at 450 °C. This result confirms that the use of natural silica source can be enhanced the catalytic properties of zeolite type - Y catalyst.

دراسة تاكل الصلب الكربوني في محلول ملحي والمنتجات البترولية بوجود غاز ثاني اوكسيد الكربون == Studying of Carbon Steel Corrosion In Salt Solution And Petroleum Products In Presence of CO2

Author name: نضال احمد شاكر

Supervisor name: شذى احمد سامح | شروق طالب الحميري

General topic: Chemical Engineering

Specific topic: Chemical Engineering

Degree: Master

University: University of Technology - Department Of Chemical Engineering

Language: English

University location: Baghdad

First pages:

Abstract: يتضمن البحث دراسة سلوك التاكل للصلب الكربوني في محلول ملحي من (3.5wt%NaCl) ومشبع طبيعيا بالهواء بوجود غاز CO2 المستخدم في انابيب النفط. وتم تصميم منظومة القطب الاسطواني الدوار (RCE) لانجاز الدراسة.واجريت تجارب الاستقطاب في ظروف الجريان المضطرب باستخدام | The present work is to study the corrosion behaveior of carbon steel, in naturally aerated 3.5wt% NaCl (brine solution) and petroleum products in presence of CO2. A rotating cylinder electrode (RCE) system were used to study the potentiostatic polarization experiments, under turbulent flow conditions, using 3.5wt% brine solution as electrolyte at different temperatures (298, 308, 318 and 328)K and rotating speed of (0, 100, 200, 300 and 400)r.p.m. at each temperature.Similar experiments were carried out in 3.5wt% brine solution using CO2 gas at (32 ml/sec) flow rate.Corresponding experiments by weight loss were carried out in 3.5wt% brine solution with compunds of : - 1. Kerosene + 10V% brine solution.2. Gas oil + 10V% brine solution. At 328Kand flow rates of (0 and 400) r.p.m.3. Similar experiments were carried out in kerosene + 10V% brine solution at (298, 308 and 318)K and static condition speed of (0) r.p.m at each temperature.4. Experiments were carried out in pure kerosene at a temperature of (298 and 318) K and speed of (0) r.p.m.All above experiments were carried out with and without CO2 gas.The results indicated that the corrosion rate of carbon steel was increased in presence of CO2 gas.The anodic dissolution kinetics were activation control processes affected by temperature.The activation energy of carbon steel with CO2 gas system (2.87 - 1.8) Kcal/mol at different r.p.m. was lower than that without CO2 gas system of (11.4 - 1.7) Kcal/mol at different r.p.m.The corrosion potentials without CO2 gas were shifted to the noble direction with increasing flow rate at a constant temperature, whereas such potential were shifted to the less noble direction with increasing temperatures at a constant speed. However, the corrosion potential with CO2 gas was more noble than that obtained without CO2 gas.The corrosion rate is increased with increasing temperature and velocity. The results indicated that the corrosion rates of ( gas oil +10V% brine solution ) are higher than that of (kerosene +10 V % brine solution) with and with out CO2 gas, and the corrosion rate of pure kerosene is lower than that of (kerosene+10V% brine solution) with and without CO2 gas.In the presence of CO2 gas the results indicated that corrosion rate increases due to continuous dissoultion of iron ion and formation of weak carbonic acid. The carbonic acid accelarteed corrosion rate and affected carbonate and hydrogen ion, which increased the cathodic reactions on the metal surface.

تاثير الجزيئات وحجم الندف على معالجة المياه بواسطة العمليات الفيزيائية - الكيمياوية لمياه النهر == Effect of Particle Floc Size On Water Treatment By Physico - Chemical Process

Author name: مهند ابراهيم فرحان

Supervisor name: ثامر جاسم محمد

General topic: Chemical Engineering

Specific topic: Chemical Processes

Degree: Master

University: University of Technology - Department Of Chemical Engineering - Chemical Process Engineering Branch

Language: English

University location: Baghdad

First pages:

تحسين اداء مفاعل الطبقة الوشله المشغل بالحالة الغير مستقرة لمعالجة المياه من ملوثات الفينول == Performance Enhancement In Unsteady State Operated Trickle Bed Reactor of Phenolic Wastewater Treatment

Author name: غيداء ضياء الدين نجيب

Supervisor name: صفاء الدين عبد الله النعيمي | فرح طالب السوادني

General topic: Chemical Engineering

Specific topic: Chemical Processes

Degree: Master

University: University of Technology - Department Of Chemical Engineering - Chemical Process Engineering Branch

Language: English

University location: Baghdad

First pages:

Abstract: تضمن البحث دراسة عملية ونظرية لاكسدة محلول الفينول بطريقتي (CWAO & PP - CWAO) باستخدام عمود الطبقة الوشله Trickle Bed Reactor لكل من التشغيل المستقروالتشغيل الدوري (Unsteady Periodic Operation) والمتضمن التقطيع الدوري لمعدل جريان السائل (Liquid Flow Mod | Catalyst Wet Air Oxidation (CWAO) and Hydrogen Peroxide Promoted Catalytic Wet Air Oxidation (PP - CWAO) of phenol in aqueous phase are studied experimentally and theoretically in this work using a trickle bed reactor operating in both steady state and periodic operation; liquid flow and hybrid modulation. A laboratory unit was constructed for this purpose, where a versatile reactor setup required "high pressure stainless steel reactor of 0.018 m i.d.×0.76 m height", in which experiments could be carried out under different modes of operation. The effect of key parameters that influence on the performance of trickle bed reactor (TBR) for CWAO and PP - CWAO is studied in a steady - state operation to provide a basis for comparison with periodic experiments and kinetic measurements in TBR under constant operating pressure (0.1 MPa) throughout Initial phenol concentration (0.84 - 1.5 g/L), liquid hourly space velocity (1.16 - 19.87 h - 1), superficial gas velocity (0.163 - 0.655 m/s), and bed temperature (30 - 80oC) for CWAO. Hydrogen peroxide concentration (5 - 40%) and feed rate (0.0499 - 0.1465 L/h) for PP - CWAO at constant liquid hourly space velocity (1.16 h - 1), initial phenol concentration (1.35 g/L), superficial gas velocity (0.163 m/s), and bed temperature (80oC).In periodic operation, the effect of cyclic parameters is investigated in a broader range of cycle period (5 - 180 sec) and split (0.2, 0.5 and 0.7) for both liquid flow and hybrid modulation under some of the conditions chosen on the basis of the steady state results for PP - CWAO.The results showed that the CWAO and PP - CWAO of phenol are kinetically controlled. In CWAO, LHSV and air flow rate have a slight effect on the phenol conversion, whilst they have a positive effect on the rate of reaction. The conversion and reaction rate of phenol increase with increasing initial phenol concentration and bed temperature, but they have a little pronounced effect in the range of temperature. The highest phenol conversion (75.26%) was obtained over Pt/? - Al2O3 at LHSV=1.16 h - 1, bed temperature=80°C, air flow rate=10 L/min and initial phenol concentration=1500 ppm.For PP - CWAO, the promoting effect of hydrogen peroxide was less marked in the range (5 to 25) %H2O2 concentration while at (35 - 40) %H2O2 concentration, the removal efficiency became more pronounced where the phenol conversion enhanced from 73.26% conversion at 25% H2O2 to 88.88% conversion at 40% H2O2. Hydrogen peroxide flow rate has a negligible effect on the removal of phenol. According to the kinetic results, the reaction kinetic was pseudo first order with respect to phenol concentration, (0.3) order with respect to oxygen, and the apparent activation energy equals to (19.8247) kJ/mol. The rate expression for CWO is - r_ph= C_ph^ For periodic operation, the time average conversion enhancement is indeed quite considerable in liquid flow modulation as split is lowered from steady state (? =1) to a value of (? =0.5) and reached as much as 6.66 % over the steady state at cycle period (?_p)= 15 sec; which is close to the hybrid modulation, where enhancement reached to 6.91% at ? =0.2 and (?_p)=5 sec.Intermediate compounds were analyzed for CWAO and PP - CWAO in steady state operation. Four intermediate compounds were indicated, namely oxalic acid, acetic acid, formic acid and maleic acid (carboxylic acid). Acetic acid being the main refractory intermediate in the catalytic oxidation of phenol at the operating conditions employed for CWAO process in steady state operation. The PP - CWAO of phenol in steady state and periodic operation has a positive impact on the intermediate compound mineralization as compared with the CWAO in steady state operation. In the modeling part, a suitable reactor scale model is evaluated and extended to predict the performance of TBR under the employed conditions. The model was solved numerically by finite difference approach with a semi implicit solution of the differential equations. The simulated results for steady - state and periodic operation (liquid flow modulation) performance showed that the expected trends in performance enhancements as experimental results. The experimental data results showed the relative error for the conversion (1.22 - 8.9%) in the broad range of experimental.

ازالة الكبريت ودراسة الحركية لوقود الديزل بعملية الامتزاز ذو الوجبة باستخدام الكاربون المنشط == Desulfurization And Kinetic Study of Diesel Fuel By Batch Adsorption On Activated Carbon

Author name: سمر خالد الجنابي

Supervisor name: نيران خليل ابراهيم

General topic: Chemical Engineering

Specific topic: Oil Refining and Gas Technology

Degree: Master

University: University of Technology - Department Of Chemical Engineering - Chemical Engineering and Oil Refining Branch

Language: English

University location: Baghdad

First pages:

Abstract: منتجات التقطير في المصافي , وخاصة قطفة زيت الغاز تحتوي على كميات كبيرة من مركبات الالكيل - بنزوثيوفين والتي هي الاكثر تمردا لازالة الكبريت عن طريق السلفرة الهيدروجينية التقليدية. وتستمر لوائح الوقود في جميع انحاء العالم في التشديد استجابة للحاجة الملحة | Refinery distillates, especially gas oil fractions contain considerable amounts of alkylated benzo - thiophene which are the most recalcitrant to desulfurization via conventional hydrodesulfurization. Fuel regulations continue to tighten worldwide in response to the need to cleaner air and refiners meet these regulations at a very significant cost. The need to cut the operational and capital costs has necessitated a renewed look to the non - hydrogen, low temperature and pressure processes for producing ultra low sulfur fuels.Non - conventional approaches for ultra low - sulfur fuels belong either to oxidative or a selective adsorption routes. The present research focuses on a batch adsorption desulfurization process for diesel fuel containing 580ppm sulfur, based on physical adsorption of refractory sulfur compounds on activated carbon (AC). The effects of time (0 - 3.5 hr), temperature (30 - 70 °C), diesel to AC ratio (2 - 10 ml/gm), AC particle size (0.2 - 1.44 mm), mixing velocity(100 - 1000 rpm), and initial sulfur concentration (280 - 580ppm) in commercial diesel fuel on the desulfurization efficiency were studied. The residual sulfur concentration in diesel fuel was decreased from 580 to 247 ppm, corresponding to a desulfurization efficiency of 57 %, at best conditions of 2.5 hr contact time, 50 ?, 2ml diesel/gm AC, 0.8 mm AC particle size, and 1000rpm mixing rate. The sulfur adsorption dependency on contact time and initial sulfur concentration in commercial diesel fuel (280 - 580ppm) were studied. Different kinetic models : Pseudo - first order (PFO), pseudo - second order (PSO) and intraparticle diffusion models were applied to fit the experimental data. The results of the kinetic analysis showed that the pseudo - first order model underestimates the equilibrium sorption capacity by about 33%. However the pseudo - second order model has succeeded in predicting the equilibrium sorption capacity with correlation coefficient, R2 = 0.995. The experimental adsorption isotherms were correlated by Langmuir and Freundlich models. The results indicated that Freundlich isotherm exhibits the best fits for the adsorptive desulfurization of diesel fuel with correlation coefficient (R2) of 0.989 as compared with the Langmuir model ( ). The adsorption intensity as estimated from the Freundlich isotherm is larger than one which is indicative of physical adsorption.

عمليات التحميض للطبقات المنتجة للنفط الخام في ابار الانتاج البترولية == Acidification of Crude Petroleum Bearing Strata In Production Wells

Author name: سيف عبد الحق عبد الستار

Supervisor name: نجاة جمعة صالح

General topic: Chemical Engineering

Specific topic: Oil Refining and Gas Technology

Degree: Higher Diploma

University: University of Technology - Department Of Chemical Engineering - Chemical Engineering and Oil Refining Branch

Language: English

University location: Baghdad

First pages:

Abstract: تم في هذا البحث دراسة عملية التحميض بصورة عامة وتحميض طبقتي ( التنومة والخصيب) المنتجة ) ضمن حقول EB - 91 للنفط والواقعة ضمن حقول شرقي بغداد بصورة خاصة. وتم اعتماد البئر (.(Case Study ) شرق بغداد كـ نموذج تعتبر عملية تحميض الابار النفطية من العمليات ا | In this work, acidification process in general and in particular at Al - Tanuma and Khasib layers is studied. Al - Tanuma and Khasib layer's in well (EB - 91)are located in east of Baghdad oil field. That well was taken as a case study.Acidification process is important to increase productivity of old oil well, and new one. Before acidification a test was carried out with water. During the test water is injected in these two layers under high pressure. If the test is successful that means the two layers are able to absorbed the dilute acid. - At first acid concentration must be diluted for 30 % to 15 % by using water as dilutent. - Additives are added to the acid, these additives are : • Anti - corrosion (A1 - 48) 0.5%.• Anti - emulsifier (NE - 50) 0.5%.• Emulsifier (WFT - 9256) 0.5%.• Solvent (WMS - 121) 1%. - Acid and the additives were injected inside Al - Tanuma and Khasib layers under high pressure. - Displacement liquid (gas oil) was injected inside the two layers to remove the acid and let it enter the formation. - The well was closed for minimum (1) hour to complete the reaction of acid with well formations. - The well was opened.The crude oil, gas oil and remaining acid will elute from the well by the action of pressure. - The crude oil eluted from the well was transferred by fire pipes to burning hole, where it was burned for about (3 - 4) hours. - After burning process is completed the well is ready for production.

المعالجة البايولوجية في المياه الصناعية المصرفة لتخفيض تركيز الميثانول == Bioremediation of Industrial Wastewater For Reducing Methanol Concentration

Author name: نغم اديب عبد الكريم

Supervisor name: Mahmood M. Barbooti | Mumtaz A. Zablouk

General topic: Chemical Engineering

Specific topic: Biochemistry Engineering

Degree: Master

University: University of Technology - Department Of Chemical Engineering

Language: English

University location: Baghdad

First pages:

Abstract: تعتمد المعالجة البايولوجية للمياه الصناعية المصرفة على عملية بسيطة وذلك بتامين الكائنات الحية التي لها القدرة على تفكيك المركبات العضوية حيث تستغلها البكتريا كمصدر للتغذية.ان اغلب المركبات العضوية واللاعضوية يمكن ازالتها بصورة فعالة من خلال المعالجة الباي | The present work biological treatment by activated sludge is advocated to reduce methanol concentration in wastewater.Activated sludge is prepared in laboratory from contaminated soil with heavy hydrocarbon. Aerobic biological treatment is applied for synthetic wastewater containing 2 gm/L methanol. Important operating parameters in this system are the sludge volume, temperature, pH and total time. Investigating these parameters can establish sufficient microbial mass for efficient treatment. The treatment is carried out under various conditions of temperature (20, 30 & 40) 0C, pH (6, 7 & 8), total treatment time (2, 3 & 5) days and for different sludge volume (100 ,280 & 450) ml. The best volume used is 280 ml from the prepared activated sludge which gives best removal down to 160 ppm. Treated wastewater samples were collected at different time and stored in deep freeze.The stored samples are analyzed for methanol content by direct injection to Gas - Chromatography. From the experimental investigation results, it has been shown that the aerobic biological treatment is efficient in reducing methanol concentration in treated wastewater. The addition of 280 ml of sludge to seven liters of synthetic wastewater gives maximum removal of methanol. The results are analyzed mathematically. The experimental data collected by this sludge volume are successfully fitted to a second order polynomial empirical correlation.The most favorable operating conditions for the 280 ml sludge volume are 400C temperature, pH = 6.8 and 102 hr total treatment time with 30h aeration.On the basis of the best conditions obtained the empirical correlation, is obtained as follows : Y = 14616.62 - 17.4202X1 - 10.6311X2 - 3592.75X3+ 0.028335 - 0.159515 + 254.532X32 - 0.1263X1X2 + 0.452606X1X3 + 1.7638X2X3. Where : X1=Treatment time. X2=Temperature.X3= pH Average absolute error =10.8 % Correlation coefficient =0.98.

التصميم الابتدائي لمحطة معالجة المياه الملوثة نفطيا في مصفى ميسان == Preliminary Design of Wastewater Treatment Plant In Missan Refinery

Author name: محمد خليل ابراهيم

Supervisor name: رياض صادق محمد صالح المختار

General topic: Chemical Engineering

Specific topic: Chemical Engineering

Degree: Higher Diploma

University: University of Technology - Department Of Chemical Engineering

Language: English

University location: Baghdad

First pages:

اتزان الاطوار لاستخلاص الملوثات الفينولية من المياه الصناعية باستخدام تقنية الاغشية السائلة == Phase Equilibria For Extraction of Phenolic Pollutants From Industrial Wastewater Using Liquid Membrane Technique

Author name: انور جاسم محسن

Supervisor name: خالد فرهود جسب

General topic: Chemical Engineering

Specific topic: Chemical Processes

Degree: Master

University: University of Technology - Department Of Chemical Engineering - Chemical Process Engineering Branch

Language: English

University location: Baghdad

First pages:

Abstract: كلا من الصناعة الكيميائية (chemical industry) والبحث الاكاديمي (academia search) للمذيبات البديلة يجب ان تلبي متطلبات التكنولوجيا النظيفة (cleaner technology) حيث ان المذيبات الاكثر استخداما على نطاق واسع هي المتطايرة والضارة. في العمل الحالي، تم تحقيق | Both chemical industry and academia search for alternative solvents to meet the cleaner technology requirements since the most widely used solvents are volatile and harmful. In the present work, the technical feasibilities of room temperature ionic liquids (RTILs) as bulk liquid membranes (BLM) for phenol removal from Industrial Wastewater was investigated. Room temperature ionic liquids (RTILs) used as a membrane mainly due to their properties of low vapor pressure, low volatility and they are often stable. Four ionic liquids with high hydrophobicity were used : 1 - butyl - 3 - methylimidazolium hexafluorophosphate [Bmim] [PF6], 1 - butyl - 3 - methylimidazolium bis(trifluoromethylsulfonyl) imide [Bmim][NTf2], 1 - Ethyl - 3 - methyimidazolium bis(trifluoromethanesulfonyl) imide [Emim][NTf2] and 1 - hexyl - 3 - methylimidazolium hexafluorophosphate [Hmim][PF6], in which, phenol Extraction efficiency and stripping efficiency were studied. The effect of different types of anion and hydrophobicity of the ionic liquids on the phenol extraction and stripping efficiencies were investigated. Different operating parameters of feed phase pH, feed concentration, NaOH concentration were studied. In addition to the effect of single ionic liquid (SILs) and binary mixtures ionic liquid (BMILs) on the phenol extraction and stripping efficiencies were also studied. The study shows that highest phenol extraction and stripping efficiencies were [Bmim][NTf2], [Bmim][NTf2+PF6] and [Emim][NTf2], [Bmim+Emim][NTf2] respectively. Phase equilibria for the extraction of phenol from industrial wastewater using ionic liquid membranes was determined. The efficiency of ten new solvents as a selective ILs solvent in the extraction of phenol from wastewater was investigated. Data have been estimated experimentally for ten systems containing, phenol + water as a common component liquid and + ten IL solvents. The consistency and accuracy of the tie line data were evaluated using three correlation namely, Bachman, Hand, and Othmer and Tobias. The Plait Point for each ternary system was estimated. Among the ILs used to extract the phenol from wastewater, [Bmim][NTf2+PF6] shows the highest selectivity and distribution coefficient. The liquid - liquid equilibrium data have been predicated using electrolyte non - random - two - liquid (e - NRTL) model and extended UNIversal - QUAsi - Chemical (e - UNIQUAC) model. The binary interaction parameters have been calculated using Maximum Likelihood Principle technique. The experimental data fitted by the e - NRTL model is more accurate than the e - UNIQUAC model.

اختيار الافضل للمفاعل النازل لوحدة التكسير بالعامل المساعد == Optimization Technique of Fcc Downer Reactor

Author name: علي محسن غضبان

Supervisor name: Safa A. Al | Naimi

General topic: Chemical Engineering

Specific topic: Oil Refining and Gas Technology

Degree: Higher Diploma

University: University of Technology - Department Of Chemical Engineering - Chemical Engineering and Oil Refining Branch

Language: English

University location: Baghdad

First pages:

Abstract: يشتمل البحث على عمل نموذج رياضي لمفاعل النازلdowner) ) في وحدة التكسير المحفز بالعامل المساعد وان التفاعل يشمل اربع مكونات هي التغذية Gas oil)) والغازات الخفيفة (Light gases) والكازولين (Gasoline) والفحم (Coke) اوما يسمى ب Four lumps model لوصف حركة تفاعل | In this work, mathematical model for downer reactor have been developed, in which a four - lump model is used to characterize the feed and the products, where gas oil cracks to give lighter fractions and coke. The integrated reactor steady state model makes gross assumption about the hydrodynamics, using 4th. order Runga Kutta method. Polymath version 5.1 and Aspen version 7.3 programs are used to solve the simulation model. This model can predict the mixing temperature and pressure profiles at mixer (MxR) chamber; also shows the physical performance and productivity all over the downer height. An interactive excel worksheet is constructed and used as a powerful tool for solving the model equations and studying the effect of any change in operating variables on the unit performance. Also observed the simulated results by using two programs (Polymath and Aspen) and the difference between them especially in temperature , pressure and product yield profile plotted along the reactor length and shows that the results from Aspen are better than Polymath because the first is more advanced and accurate. The operation of downer reactor for catalytic cracking is associated with several important objectives such as feed rate and height, diameter of reactor and amount of catalyst rate as well as the production requirements, all of which need to be optimized simultaneously. In this study, a validated mathematical model was used to perform the single - objective optimization of the FCC system at the design stage. In the optimization study, four operating parameters were used as decision variables. These variables were chosen based onsystematic sensitivity analysis of the system which showed complex interplay of the decision variables over the system performance indicators. Elitist Polymath version 5.1 enhanced with Excel flow sheet 2007 were used to solve a number of objective function optimization problems. The objective functions used are maximization of the gasoline yield, and minimization of the catalyst flow rate. The optimal results obtained here provide physical insights that can help in the design stage of the downer reactor.

الاضافات على زيوت التزيت لتحسين خواصها == Additives For Lubricantion Oil To Improve Its Properties

Author name: وسام عدنان حيدر العبيدي

Supervisor name: عدنان عبد الجبار عبد الرزاق السالم

General topic: Chemical Engineering

Specific topic: Oil Refining and Gas Technology

Degree: Higher Diploma

University: University of Technology - Department Of Chemical Engineering - Chemical Engineering and Oil Refining Branch

Language: English

University location: Baghdad

First pages: