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التغيرات الفصلية والموقعية لتراكيز بعض العناصر النزرة في الرواسب والمياه والنبات المائي الشمبلان Ceratophyllum demersum في نهر الفرات عند قضاء سوق الشيوخ جنوب العراق == Seasonal and Reginal changes in concentration of some trace elements in sediment, water, and aquatic plant(Ceratophyllum demersum) in the Euphrates River at Suq Alshuyoukh districtsouthern of Iraq.

اسم المؤلف: نور كاظم خير الله
اسم المشرف: باسم يوسف الخفاجي
الموضوع العام: علوم الحياة
السنة: 2017
الموضوع الدقيق: البيئة - التلوث البيئي
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ذي قار
الصفحات الاولى:
المستخلص: The current study was performed to get the knowledge of seasonal and Reginal changes in concentration of some trace elements(Zn, Pb , Ni and Co) in sediment, water and aquatic plant (Ceratophyllum demersum) in the Euphrates River at Suq _ Alshuyoukh district, south of Iraq . The study was include some of the chemical and physical properaties for water (air and water temperature,turbidity, electrical conductivity,salinity,dissolved oxygen , biochemical oxygen dimand, pH,nitrate,phosphat also total organic carbon and sediment texture). The samples were collected from the river on seasonaly from Autumn 2015 to summer 2016. There are three stations were selected for the study , the first station was near by the tourist Alfadhliyah bridge, afertile farmland on both sides of the river. The second station was in Suq_Alshuyokh , it's away from the first station about 15 km , it's a center of boats which used for fishing ,agriculture lands and homes. The third station was located in stream of ALkermashiya which lieson snuffa_marsh (apart of the Hammar marsh) ,It's away from the second station about 11 km and it's near by villages and fertile farmland. The results of study showed that air temperature was ranged between (15.8 - 49.5)° C and water temperature was ranged between (13.8 - 48.7 ) °C . The highest temperature recorded in the third location during Summer. Turbidity concentrations ranged between (5.7 - 15.6) NTU. The electrical conductivity are ranging between (3920 - 8336) Ms/cm , and salinity of water was low (Oligohaline) ranging between (2.50 - 5.33) ppt and recorded the highest concentrations in the third station . the highest value of pH was (8.9) in the secondstation and the lowest value was (7.3) in the first location while the Dissolved Oxygen concentrations ranged between (3.1 - 8.45) mg/L. The biological oxygen demand (BOD5) was ranged between (0.35 - 4.5) mg /L. As for concentration of nitrates was ranged from (0.02 - 6.33) mg/L. and phosphate ranged between (0.01 - 5.8) mg/L. the total organic carbon as percentage was ranged between (0.48 - 3.1) %.while sediment texture was mixed from sand ,silt,clay,the percentage for the mentiond compenents was,(50%,20% and 30%)in station 1,(40%,10%,50%)for station 2 and (10%,20% and 70%) for station3Atomic absorption spectrofotometer was used to estimate four trace elements (Zn,Pb, Co, and Ni) .The concentrations of the mentionel elements in water dissolved phase were (2.86,5.87,1.63,0.51) μg /L,while their concentrations in particulate phase were (12.48,28.21,17.74,1.08) μg /gm dry weight respectively. In sediment the concentrations averages oftrace elements were (142.73,127.70,176.82,29.24) μg /gm dry weight respectively.In aquatic plant (Ceratophylum demersum) the concentrations averages of trace elements were (123.32,117.54,157.54,27.90) μg /gm dry weight respectively . It concluded that the concentration of studied elements in sediment more than their concentration in water (dissolved and particulate) phase and more than their concentration in plant (Ceratophyllum demersum), also all concentrations of trace elements were in the international acceptable values.

دراسة لنوعية المياه وتركيز الهيدروكربونات النفطية وبعض العناصر النزرة في المياه الجوفية للابار القريبة من مصافي الجنوب في منطقة الشعيبة - البصرة جنوب العراق == Study Water Quality and Concentration of Petroleum Hydrocarbons and Some Trace Elements in Groundwater of Wells Near South Refineries in Al - Shiaba region - Basrah, Southern Iraq

اسم المؤلف: بثينة مهدي يونس
اسم المشرف: باسم يوسف الخفاجي
الموضوع العام: علوم الحياة
السنة: 2017
الموضوع الدقيق: البيئة - التلوث البيئي
الدرجة: ماجستير
اللغة: العربية
مكان الجامعة: ذي قار
الصفحات الاولى:
المستخلص: The present study was carried out to determine the concentration of total petroleum hydrocarbons in two phases dissolved and suspended in water, and Water Quality, in addition to three trace metals nickel Ni, lead Pb and cadmium Cd were determined in the groundwater, in eight wells. Six wells from W1 to W6 close to the source of pollution about half kilometer to three kilometer and two wells (w7 - w8) were far with in12.5Km from the mentioned source pollution area (well control).Wells were located on surrounding southern refineries (Al - hiaba ) - Zubair - Basra in southern Iraq .Water samples were collected seasonally from autumn 2015 to summer 2016.The present study including, the measurements of some environmental factors, water and air temperatures , salinity, electrical conductivity, turbidity, total dissolved soluble solids (TDS), pH , dissolved oxygen , total hardness and chloride ions .Results were ranged between ,( 19.5 - 48.8) ºC ( 25.0 - 29.3) ºC , (4.35 - 10.95) mg∕L, (5.01 - 11.45) mS ∕cm , (1.110 - 6.803) NTU , (3206 - 7328) mg∕L (7.05 - 8.72) , (1.35 - 12.25) mg ∕L ,(1275 - 4200) mg ∕L and ( 1560 - 5416) mg∕L respectively .Total petroleum hydrocarbons (TPHs) were determined using spectroflurometer . Results showed that concentrations of means TPHs as dissolved fraction in water were in all wells highest in spring 2016 than winter then autumn 2015, while less concentration recorded was during summer 2016.The highest mean concentration was 35.91 μg /L in well W1 in a spring 2016 while lowest value 0.73μg/L in well W7 in summer 2016 . Results of highest means concentrations of TPHs particular fraction in water were 137.39 μg /g dry weight in well W1 in spring 2016 and lower means concentrations of TPHs particular fraction 9.89 μg /g dry weight in well W8 summer 2016. Sixteen compounds of Polycyclic Aromatic Hydrocarbons(PAHs) were identified in water (dissolved and particulate fractions ) during spring 2016 using a liquid Chromatograph high performance (HPLC). The total concentrations of dissolved PAHs in water ranged between the highest concentration 7205 ng∕L in well W1, and lowest concentration 39.1 ng∕L in well W8 ,the highest concentration of Phenanthrene compound in well W1 was 3472 ng∕L and lower concentration for Benzo(a) Pyrene compound was 0.37 ng∕L in well W8,was the more dominate PAHs compound in dissolved phase recorded Benzo(b)Fluranthene .The total concentrations of PAHs particular fraction ranged between the highest concentration 9334 μg /g dry weight in well W1, while lowest concentration 370 μg /g dry weight in well W8.The more dominant PAHs compound as particular fraction Fluorene in spring season ,were compound Dibenzo(a,h)anthracene has a highest concentration 6689 ng∕g dry weight in well W3 and the to west concentration compound was Benzo(a)anthracene ng∕g in well W8. Results recorded highest concentration of lead 0.933 μg /L in well W1 in spring 2016 and lowest concentration 0.208 μg /L in well W7 in summer 2016. While means concentrations of nickel ranged between 0.445 μg /L in well W1 in winter 2016 and lowest concentration 0.055 μg /L in wellW8 in autumn 2015.Cadmium record its highest level 0.496 μg /L in well W3 in spring 2016 and lowest concentration 0.053 μg/L in well W8 in summer 2016.Results of this revealed that southern refineries have a major effects on ground water pollution in vicinity of oil fields by some hydrocarbons derived from those refineries