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تحضير وتشخيص بعض البلورات السائلة وخلائطها الثنائية البلورية السائلة ودراسة بعض خواصها الفيزيائية == Preparation & Characterization of some liquid crystals and Binary liquid crystalline mixtures and study some of their physical properties
Author name:
زينب نديم مطشر
Supervisor name:
اياد جاسم الحجاج
General topic:
Physics
Specific topic:
Physics
Degree:
Master
University:
University Of Basrah - College Of Science
Language:
Arabic
University location:
Basrah
First pages:
26T1698 - p.pdf
Abstract:
study included as a first step the preparation of compound 4 - heptyloxy benzaldehyde and derivatives by linking alkoxy series with the aldehyde, and in the second step was to prepare Schiff base compounds through interaction of equal moles of the compound 4 - heptyloxy benzaldehyde with some primary amines with different polar groups, and in the third stage was to prepare mixtures from the Schiff base compounds resulting from the second step,and we obtained five liquid crystalline mixtures at low temperatures and some of them close to room temperature, and then the chemical structures was chacterized and the absorption bands for functional groups was given by FTIR spectroscopy scan . A microscope with polarized light (POM) and a differential scaning calorimeter (DSC) was also used to study the liquid crystalline phases for individual compounds, as well as binary liquid crystalline mixtures and then a discussion of changes taking place at phase transition temperatures for individual liquid crystalline compounds as well as their binary mixtures , as characterized by these mixtures it owns a wide range of temperatures and some are close to room temperature ranging between (22.1 - 53.1 ℃). we has been studying some of the physical properties of these mixtures and compare them with the pure liquid crystals to see what has been achieved to improve these properties by studying the electrical properties (conductivity and dielectric ), as well as the activation energy , we has also been studying the photoelectric effect and determine the threshold voltage in the cases of parallel and vertical alignments , and the study shown a variation in the dielectric behaviour of binary liquid crystalline mixtures of remarkable increase compared to individual liquid crystalline compounds either the positive or negative dielectricanisotropy , ranging from ( - 1.320 - 2.234), while the variation in the electrical conductivity of binary mixtures of liquid crystal range (0.138 - 0.351 (ohm.m) - 1, and finally studied photoelectric effects for individual liquid crystalline compounds, as well as binary liquid crystal mixtures show that liquid crystalline mixtures have seen a clear decline in the threshold voltages (1.3 - 3.9Volt
