مشاركة
تحضير الكاربون المنشط من نوى التمر باستخدام كاربونات البوتاسيوم كعامل منشط في ازالة صبغة المثيلين الزرقاء == Preparation of Activated Carbon From Date Stones By K2Co3 Activation For Methylene Blue Dye Adsorption
اسم المؤلف:
اسماء فاضل عباس
اسم المشرف:
مثنى جبار احمد
الموضوع العام:
الهندسة الكيمياوية
السنة:
2014
الموضوع الدقيق:
الهندسة الكيمياوية
الدرجة:
ماجستير
الجامعة:
جامعة بغداد - كلية الهندسة - قسم الهندسة الكيمياوية
اللغة:
الانكليزية
مكان الجامعة:
بغداد
الصفحات الاولى:
38T268 - p.pdf
المستخلص:
Present study deals with the preparation of activated carbon (AC) from date stones by K2CO3 activation via microwave heating and the removal of methylene blue (MB) dye from aqueous solution by using such carbon as adsorbent. The influence of radiation time (4 - 12min), radiation power (540 - 700W) and impregnation ratio (0.5 - 2.5g/g) on the yield and MB uptake of such carbons were studied. Central composite design was used to determine the optimum preparation conditions and two quadratic models were developed to correlate the preparation variables for both responses.The optimum preparation conditions were reported as 8 min radiation time, 660 W radiation power and 1.5 g/g impregnation ratio resulting in 19.99% yield and 460.123 mg/g MB uptake. From the analysis of variance (ANOVA), it was found that the radiation time had the greatest effect on the yield while impregnation ratio had the greatest effect on MB uptake.The characteristics of AC were examined by pore structure analysis, scanning electron microscopy (SEM) and Fourier transforms infrared spectroscopy (FTIR). The BET surface area and total pore volume were indentified to be 1144.25 m²/g and 0.656 m³/g, respectively. Batch adsorption study was adopted to determine the experimental adsorption isotherm data of different initial concentration of MB (50 - 450 mg/l). The equilibrium data were analyzed using Langmuir, Freundlich and Sips isotherm models. The results showed that the experimental data were well fitted with sips isotherm with maximum monolayer adsorption capacity of 484.7 mg/g. Pseudo - First order, Pseudo - Second order, and intraparticle diffusion models were used to analyze experimental kinetics data with high correlation coefficient for Pseudo - second - order model.
