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تحضير وتشخيص ليكاند قاعدة شف جديدة مشتقة من 4 - امينو انتي بايرين ومعقداتها مع بعض الايونات الفلزية ودراسة فعاليتها المضادة للبكتيريا == Synthesis And Characterization of New Schiff Base Ligand Derived From 4 - Aminoantipyrine And It'S Complexes With Some Metal Ions And Their Antibacterial Effective Study
Author name:
هيام هادي علكم
Supervisor name:
ساجد محمود لطيف
General topic:
Chemistry
Specific topic:
Chemistry
Degree:
Master
University:
University of Baghdad
Language:
Arabic
University location:
Baghdad
First pages:
25T1531 - p.pdf
Abstract:
تضمن البحث تحضير ليكاند قاعدة شف جديدة (L) ثنائية السن نوع (NO)1,5 - dimethyl - 4 - ( 2 - oxo - 1,2 - diphenyl ethylidene amino) - 2 - phenyl - 1,2dihydropyrazol - 3 - one.وذلك من مفاعلة 4 - aminoantipyriene مع Benzil باستعمال الايثانول وسطا للتفاعل. | This work covers the synthesis and characterization of the new Schiff base bidentate ligand(L) type (NO) 1,5 - dimethyl - 4 - (2 - oxo - 1,2 - diphenylethylidene amino) - 2 - phenyl - 1,2 dihydropyrazol - 3 - oneThe ligand (L) was prepared from reaction of 4 - aminoantipyrine with Benzil under reflux in ethanol solvent. The Ligand Complexes for the metal ions : VO(II) ,Mn(II) , Co(II) , Ni(II) , Cu(II) , Zn(II) , Cd(II) and Hg(II) were prepared. The Ligand and its complexes were characterized by spectral methods [FT - IR , UV - Vis , Atomicabsorption , 1HNMR ] in addition to molar conductivity , Microanalysis (C.H.N) , Magnetic moment effect and melting point and mole ratio Ligand : Metal. From the above data for the ligand and its complexes , we suggested that the ligand (L) behaves as bidentate on complexation with metal ions Via Natom of ( C = N) group and O atom for ( C = O) of pyrazol ring. The suggested molecular formula and geometrical structure are : 1 - Squarepyrimide for [VO(L) (SO4) (H2O) ] 2 - Tetrahedral for [M(L)Cl2]. n H2O M = Zn (II) , n = 1 M = Cd(II) and Hg(II) ; n =0 3 - Octahedral for [M(L)2Cl X ]. Y M = Mn(II) , X = Cl , Y = H2O M = Co(II) , Ni(II) and Cu(II) X = H2O , Y = Cl
