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تعديل سطوح التيتانيوم وسبيكة التيتانيوم باستخدام المواد الاحيائية السيراميكية بواسطة الرشرشة بالترددات الراديوية == Surface Modification of Titanium and Titanium Alloy Using Ceramic Biomaterials by RF Sputtering
Author name:
دنيا عبد الصاحب هاشم حمدي
Supervisor name:
ثامر عبد الجبار جمعة | ثائر لطيف مزعل
General topic:
Physics
Specific topic:
Atomic Physics
Degree:
Doctorate
University:
Al-Nahrain University - College Of Science - Physics Department
Language:
English
University location:
Baghdad
First pages:
26T1723 - p.pdf
Abstract:
The current in this thesis research deals with the plasma sputtering which was used to deposit single and triple layers ceramics on (cpTi) and ( Ti - 6Al - 4V) alloy. Also ,in this work the in vitro electrochemical tests , formation of HAp by biomimetic process on the coated layers by the immersion in Simulated Body Fluid(SBF) at PH equal to 7.4 and room temperature was done . The single layer TiO2and HAp , multi - layer consist of TiO2 and Al2O3 were deposited on cpTi and Ti - 6Al - 4Valloy, followed by the deposition of third layer of HAp. The deposition conditions in the RF sputtering system such as vacuum pressure, substrate temperature, power, gas type, gas flow and deposition time were fixed for the sputtering system where as the distance between the target and the substrate was varied (9 and 7 cm). Structural analysis was carried out , on the deposited layers(single and triple) using X - ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Furrier Transformation Infra - Red (FTIR), Raman Spectroscopy and X - ray Photoelectron Spectroscopy (XPS). Elemental analysis for HAp deposited in the single and triple layer was done using Energy Dispersive X - ray Spectroscopy (EDS).To investigate the biocompatibility of coatings the formed layers, were immersed in (SBF) for one month. After one month the samples were taken and anlyezed using the same structural analysis techniques used before immersion. Electrochemical investigation was carried out on the deposited layers used Open Circuit Potential (OCP),Linear Sweep Voltage(LSV) and Electrochemical Impedance Spectroscopy(EIS) in SBF. The XRD structural results show that the formation of HAp which was dominated on the phase formation on the surface of the single and triple layers. Also another Calcium - Phosphorus compound phases are found such as Tri Calcium Phosphate(TCP), Octa Calcium Phosphate(OCP) and Calcium Phosphate(CP) along with small fractionIIof the Titanium phase belong the substrate .For TiO2 single layer, XRD pat reins shows the formation of the rutile TiO2which covered the substrate surface.Elemental analysis by using EDS for the single and triple layer deposited in cpTi and Ti - 6Al - 4Valloy shows the energy transitions belong to the dominated elements, Ca and P, which contained in the HAp layer that already showed by XRD. Surface analysis by XPS for immersed samples in SBF for one month show the bonding type and the compound that formed. The XPS results confirmed the SEM observation, the FTIR and Raman results. It was found from the XPS analysis that most of the compound covers the surface are belongs to the Ca - P companies to the carboxyl groups (C - O, C - H) and this was confirmed by the XRD investigation which show the domination of (HAp) in the highest intensity (211) reflection at 2θᵒ of 31.7 for the single and triple layer coating. The XRD results also show the disappearance of the other CaP compounds after one month of immersion in SBF like TCP and CP .The increase in the HAp concentration after immersion indicates the occurrence of the biomimetic process that increases the precipitation of Ca+ and P - from the SBF and the two roots combined together to form CaP compound that increases the HAp concentration. The electrochemical parameters predicted from corrosion test show the improvement in the corrosion resistance of both cpTi and Ti - 6Al - 4Valloy after coated by shifting the OCP toward the nobel direction which was the same behaviour for the corrosion potential Ecorr, and decreases in the corrosion current Icorr and the corrosion rate CR comparing to the uncoated specimens. The (EIS) measurements conformed the improvement in the corrosion parameters result of from OCP and LSV by the very low capacitance for the coated specimens compared to that for the uncoated one which means that the single layer and triple layer protect the surface by increasing the equivalent circuit impedance block
