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تحضير ودراسة الفعالية الحيوية لبعض مشتقات الكرمارين الجديدة == Synthesis And Study Biological Activity of Some New Coumarin Derivatives
Author name:
قاسم عبد الحسين جابر الشيباني
Supervisor name:
نبيل عبد عبد الرضا
General topic:
Chemistry
Specific topic:
Chemistry
Degree:
Master
University:
University of Al-Qadisiyah - Faculty Of Education - Chemistry Department
Language:
Arabic
University location:
Qadisiyah
First pages:
25T1493 - p.pdf
Abstract:
تم في هذه الدراسة تحضير المعقدات على النحو الاتي : 1 - اوكسو 1,1 - ثنائي مثيل هايدرازيدو - ثنائي( ثنائي اثيل ثنائي ثايوكارباماتو) موليبدنيوم (VI) 2 - اوكسو 1,1 - ثنائي مثيل هايدرازيدو - ثنائي(ثنائي مثيل ثنائي ثايوكارباماتو) موليبدنيوم (VI) 3 - اوكسو 2,1 | In this study for complexes have been prepared are : 1 - Oxo 1,1 - dimethyl hydrazido - bis (diethyl dithiocarbamato) molybdenum (VI). 2 - Oxo 1,1 - dimethyl hydrazido - bis (dimethyl dithiocarbamato) molybdenum (VI) 3 - Oxo 1,2 - dimethyl hydrazido - bis (diethyl dithiocarbamato) molybdenum (VI). 4 - Oxo 1,2 - dimethyl hydrazido - bis (dimethyl dithiocarbamato) molybdenum (VI). Via two intermediate complexes are di oxo bis (diethyl dithiocarbamato) molybdenum (VI) and di oxo bis (dimethyl di thiocarbamato) molybdenum (VI). All complexes was characterized spectrophometically by UV - vis and FTIR. The kinetic of photo chemical reaction have been studied for these complexes by irradiate there solution by mono wave length light at (?= 366nm)supplied from medium pressure mercury lamp at 293 K for 90 minutes by using ethanol as solvent. Following the photo chemical reaction showed the order of photo dissociation reaction is pseudo - first reaction for all complexes and reaction rate constants were calculated , so the spectrum change were recorded during irradiation period. The effect of several factors have been studied included : period of irradiation , complex concentration , light intensity , PH value , solvent polarity and temperature. Where the periods of irradiation time were followed which last in the complex dissociation , were between 390 - 450 min. study of seven concentration of all complex where the dissociation rate was proportional inversty with concentration , so the dissociation increases when light intensity increase , and notice that changing in pH value between 4 - 10 lead to dissociation increment toward naturalization and decrease when alkalinity rise. According to the solvent effect , the photodissociation take the sequence for all complexes Isopropanol > 1 - butanol > Ethanol > Methanol. Besides the photo dissociation of all complexes was studied in the range 283 - 303 K and found that in the temperature rising the rate of dissociation rises and the activation energy for all complexes and study was calculated. Quantum yields have been calculated for all prepared complexes and the value was more than one , it raters to the photolysis was chain reaction and reaction done by heterogonous splitting of metal - ligand bond according to uv - vis spectrums where oxidation of ligand and the metal was reduced giving opposite complexes
