تحضير وتشخيص بعض الليكندات الحلقية غير المتجانسة الجديدة وبوليمراتها الكلابية ودراسة انتقائيتها في استخلاص بعض الايونات == Synthesis And Characterization of Some New Cyclic Legand And Chelating Polymer And The Study of Their Selectivity For Some Ions
Author name:
احمد جاسم محمد الحوري
Supervisor name:
علي طه علي السامرائي | غزوان حسن الصميدعي
General topic:
Chemistry
Specific topic:
Chemistry
Degree:
Master
University:
Tikrit University - College Of Science - Chemistry Department
Language:
Arabic
University location:
Salahaddin
First pages:
25T1527 - p.pdf
Abstract:
In this study ,some Chalcons were prepared by using terphthaldehyde with aromatic ketone compounds in basic surrounding NaOH 10% ,adopting the basic medium rought ,compound that were prepared was studied by infrared (IR) , Nuclear Magnetic Resonance(NMR) and (CHN). table below includes numbers and structure of the prepared ChalconsCompound Structure Compound name No. (2,2') - 3,3' - (1,4 - phenylene) bis(1 - pyridin - 2 - yl)prop - 2 - en - 1 - one) 1 (2,2') - 3,3' - (1,4 - phenylene) bis(1 - pyridin - 3 - yl)prop - 2 - en - 1 - one) 2 (2,2') - 3,3' - (1,4 - phenylene) bis(1 - pyridin - 4 - yl)prop - 2 - en - 1 - one) 3 (2,2') - 3,3' - (1,4 - phenylene) bis(2 - hydroxyphenyl)prop - 2 - en - 1 - one) 4 (2,2') - 3,3' - (1,4 - phenylene) bis(2,5 - dihydroxyphenyl)prop - 2 - en - 1 - one) 5 (2,2') - 3,3' - (1,4 - phenylene) bis(4 - hydroxyphenyl)prop - 2 - en - 1 - one) 6 (2,2') - 3,3' - (1,4 - phenylene) bis(1 - phenylprop - 2 - en - 1 - one) 7Solution of (Cu2+,Mg2+,Hg2+,Ca2+,Co2+,Cd2 +,Cr3 +,Ni2+) metal ions in ethanol tested with solution of the prepared ligands in ethanol using spot test method ,compound (1) showed colored complex with Ni2+ ions, the complex was studied as a solution for the color metal determination of Ni2+ ions, metal to light ratio and calibration curve for Ni2+ ions, were established.The prepared chalcones were supported on rigid polymer than foam and the produced chelating polymers were evaluated for their loading capacity towards (Pb2+,Ni2+,Cu2+,Cr2+, Cd2+, Co2+,Mn2+,Zn2+) ions , the resins showed no response toward (Mn2+ and Zn2+ ) ions, and Avery low loading capacity towards ( Cr2+ and Cd2+) ions, but the studied resins showed a good resins toward the rest of the studied ions (Pb2+,Ni2+,Cu2+,Co2+) The effect of treatment time and pH on the loading capacity of the resins were studied while other parameters , like temperature ,weight of resin and metal ion concentration were kept constant. The results of max. loading capacity were as shown in the table below : Resin Loading Capacity (mg ion / gm resin) Ni2+ Pb2+ Cu2+ Co2+R1 8.8 9.5 8.9 8.6R2 7.5 7.8 7.3 7.0R4 8.9 9.3 9.1 8.5R5 8.7 9.3 8.4 8.2 A study of the recovery of ions from resins [(R1),(R2),(R4),(R5)] and the regeneration of the resin were also the studied carried out using 3M HNO3 as an eluent, the table below shows the %recovery of each ion from the studied resins.Resin Recovery % Ni2+ Pb2+ Cu2+ Co2+R1 64.8 74.6 52.9 49.2R2 64.5 76.4 51.2 47.6R4 44.0 61.1 52.4 48.7R5 48.1 68.6 57.4 50.1
