المستودع الرقمي العراقي
Iraqi Digital Repository
ازالة الكبريت من زيت الوقود باستخدام الاكسدة المعززة بالموجات الفوق الصوتية == Ultrasound - Assisted Oxidative Desulfurization of Fuel Oil
اسم المؤلف:
جعفر مازن جعفر
اسم المشرف:
نيران خليل ابراهيم | ولاء عبد الهادي نوري
الموضوع العام:
الهندسة الكيمياوية
السنة:
2014
الموضوع الدقيق:
الهندسة الكيمياوية
الدرجة:
ماجستير
الجامعة:
الجامعة التكنولوجية - قسم الهندسة الكيمياوية
اللغة:
الانكليزية
مكان الجامعة:
بغداد
الصفحات الاولى:
📎 38T277 - p.pdf
المستخلص:
Due to the dramatic environmental impact of sulfur emissions associated with the exhaust of engines, sulfur content specification for diesel fuels became more and more stringent worldwide. Last environmental regulations for ultralow sulfur diesel require very deep desulfurization processing, which cannot be met by the conventional hydrodesulfurization process (HDS).The present work focuses on benefiting from integrating an ultrasoundassisted oxidative desulfurization process (UAODS) with the conventional HDS process to produce ultra - low sulfur fuels. The proposed method involves a batch ultrasound - assisted oxidative desulfurization process to desulfurize a previously hydrotreated diesel containing 480 ppm sulfur. The oxidizing system used was H2O2/CH3COOH with FeSO4 being used as a catalyst. An ultrasonic probe system was used to enhance the conversion of sulfur - bearing compounds that exist in diesel to sulfones and sulfoxides to affect their removal by a certain separation method, such as extraction or adsorption.The major influential parameters related to UAODS process have been investigated, namely : ratio of oxidant/fuel, ratio of the promoter/oxidant, dose of catalyst, reaction temperature, intensity of ultrasonic waves. A set of comparative studies were also carried out including type of extraction solvent, effect of initial sulfur content, and type of sulfur separation method. Total evaluation for the treated diesel was performed, including GC - MS analysis which has been used to monitor the change of organic sulfur compounds andhydrocarbons in diesel during the desulfurization process.The oxidation treatment, in combination with ultrasonic irradiation, revealed a synergistic effect for diesel desulfurization. The experimental results showed that the removal efficiency for sulfur compounds could amount to 98%, and sulfur level can be reduced to 12 ppm at mild operating conditions (70 and 1 bar). This indicates that this process is so efficient and promising for the production of ultra - low sulfur diesel fuels.The kinetics of the reaction has been also studied. It was observed that the UAODS of diesel fuels fitted pseudo - first - order kinetics under the studied experimental conditions. During this process, values of the apparent rate constant and activation energy were 0.373 min - 1 and 24 kJ/mol, respectively.
مشاركة البيانات
Share Data